CA1281677C - Methode de deparaffinage catalytique pour ameliorer le point d'ecoulement,par recours a l'agent de catalyse zms-11 a teneur d'un elementd'hydrogenation-deshydrogenation - Google Patents

Methode de deparaffinage catalytique pour ameliorer le point d'ecoulement,par recours a l'agent de catalyse zms-11 a teneur d'un elementd'hydrogenation-deshydrogenation

Info

Publication number: CA1281677C
Authority: CA; Canada
Prior art keywords: zsm; catalyst; pour point; hydrogenation; hydrogen
Prior art date: 1984-03-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA 475330

Other languages

English (en)

Inventor

Arthur W. Chester

Jeffrey Hsing-Gan Yen

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mobil Oil AS

Original Assignee

Mobil Oil AS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-03-19

Filing date

1985-02-27

Publication date

1991-03-19

1985-02-27 Application filed by Mobil Oil AS filed Critical Mobil Oil AS

1991-03-19 Application granted granted Critical

1991-03-19 Publication of CA1281677C publication Critical patent/CA1281677C/fr

Status Expired legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 62
230000003197 catalytic effect Effects 0.000 title claims abstract description 49
238000000034 method Methods 0.000 title claims abstract description 32
230000008569 process Effects 0.000 title claims abstract description 27
238000005984 hydrogenation reaction Methods 0.000 title claims abstract description 23
238000006356 dehydrogenation reaction Methods 0.000 title claims abstract description 18
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 30
239000001257 hydrogen Substances 0.000 claims description 30
229910052739 hydrogen Inorganic materials 0.000 claims description 30
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 26
239000003921 oil Substances 0.000 claims description 26
229910052751 metal Inorganic materials 0.000 claims description 21
239000002184 metal Substances 0.000 claims description 21
229930195733 hydrocarbon Natural products 0.000 claims description 19
150000002430 hydrocarbons Chemical class 0.000 claims description 19
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 19
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 18
239000004215 Carbon black (E152) Substances 0.000 claims description 16
239000000377 silicon dioxide Substances 0.000 claims description 15
239000000295 fuel oil Substances 0.000 claims description 14
238000006243 chemical reaction Methods 0.000 claims description 12
239000007788 liquid Substances 0.000 claims description 11
239000000203 mixture Substances 0.000 claims description 7
150000002739 metals Chemical class 0.000 claims description 5
239000011230 binding agent Substances 0.000 claims description 4
235000012239 silicon dioxide Nutrition 0.000 claims description 4
229910052681 coesite Inorganic materials 0.000 claims description 3
229910052906 cristobalite Inorganic materials 0.000 claims description 3
229910052809 inorganic oxide Inorganic materials 0.000 claims description 3
229910052682 stishovite Inorganic materials 0.000 claims description 3
229910052905 tridymite Inorganic materials 0.000 claims description 3
229910052593 corundum Inorganic materials 0.000 claims description 2
229910001845 yogo sapphire Inorganic materials 0.000 claims description 2
239000010457 zeolite Substances 0.000 description 49
239000011148 porous material Substances 0.000 description 34
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 28
229910021536 Zeolite Inorganic materials 0.000 description 27
239000007789 gas Substances 0.000 description 14
239000000047 product Substances 0.000 description 14
239000002808 molecular sieve Substances 0.000 description 11
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 11
230000000694 effects Effects 0.000 description 10
239000007787 solid Substances 0.000 description 9
239000002253 acid Substances 0.000 description 7
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
-1 ZSM-5 Chemical compound 0.000 description 6
229910052782 aluminium Inorganic materials 0.000 description 6
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
239000013078 crystal Substances 0.000 description 6
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 5
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
238000004517 catalytic hydrocracking Methods 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
238000005336 cracking Methods 0.000 description 5
238000005470 impregnation Methods 0.000 description 5
239000000463 material Substances 0.000 description 5
229910052750 molybdenum Inorganic materials 0.000 description 5
238000012545 processing Methods 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
230000008901 benefit Effects 0.000 description 4
150000002431 hydrogen Chemical class 0.000 description 4
238000005342 ion exchange Methods 0.000 description 4
239000010687 lubricating oil Substances 0.000 description 4
229910052717 sulfur Inorganic materials 0.000 description 4
239000011593 sulfur Substances 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
229910003296 Ni-Mo Inorganic materials 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
238000004523 catalytic cracking Methods 0.000 description 3
239000001307 helium Substances 0.000 description 3
229910052734 helium Inorganic materials 0.000 description 3
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 3
238000010348 incorporation Methods 0.000 description 3
DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
229910052763 palladium Inorganic materials 0.000 description 3
239000003208 petroleum Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000000126 substance Substances 0.000 description 3
WJYMPXJVHNDZHD-UHFFFAOYSA-N 1,3,5-triethylbenzene Chemical compound CCC1=CC(CC)=CC(CC)=C1 WJYMPXJVHNDZHD-UHFFFAOYSA-N 0.000 description 2
PFEOZHBOMNWTJB-UHFFFAOYSA-N 3-methylpentane Chemical compound CCC(C)CC PFEOZHBOMNWTJB-UHFFFAOYSA-N 0.000 description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
230000009286 beneficial effect Effects 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
150000007942 carboxylates Chemical class 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
230000008859 change Effects 0.000 description 2
229910052804 chromium Inorganic materials 0.000 description 2
239000011651 chromium Substances 0.000 description 2
229910017052 cobalt Inorganic materials 0.000 description 2
239000010941 cobalt Substances 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
239000000470 constituent Substances 0.000 description 2
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
230000006872 improvement Effects 0.000 description 2
229910003480 inorganic solid Inorganic materials 0.000 description 2
WUHYYTYYHCHUID-UHFFFAOYSA-K iridium(3+);triiodide Chemical compound [I-].[I-].[I-].[Ir+3] WUHYYTYYHCHUID-UHFFFAOYSA-K 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
238000006317 isomerization reaction Methods 0.000 description 2
239000011733 molybdenum Substances 0.000 description 2
229910052680 mordenite Inorganic materials 0.000 description 2
230000007935 neutral effect Effects 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
125000004430 oxygen atom Chemical group O* 0.000 description 2
MUJIDPITZJWBSW-UHFFFAOYSA-N palladium(2+) Chemical class [Pd+2] MUJIDPITZJWBSW-UHFFFAOYSA-N 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
229910052697 platinum Inorganic materials 0.000 description 2
230000009467 reduction Effects 0.000 description 2
239000002594 sorbent Substances 0.000 description 2
239000010936 titanium Substances 0.000 description 2
229910052719 titanium Inorganic materials 0.000 description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
229910052721 tungsten Inorganic materials 0.000 description 2
239000010937 tungsten Substances 0.000 description 2
229910052720 vanadium Inorganic materials 0.000 description 2
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
MBVAQOHBPXKYMF-LNTINUHCSA-N (z)-4-hydroxypent-3-en-2-one;rhodium Chemical compound [Rh].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O MBVAQOHBPXKYMF-LNTINUHCSA-N 0.000 description 1
KLFRPGNCEJNEKU-FDGPNNRMSA-L (z)-4-oxopent-2-en-2-olate;platinum(2+) Chemical compound [Pt+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O KLFRPGNCEJNEKU-FDGPNNRMSA-L 0.000 description 1
KFUSEUYYWQURPO-UHFFFAOYSA-N 1,2-dichloroethene Chemical compound ClC=CCl KFUSEUYYWQURPO-UHFFFAOYSA-N 0.000 description 1
QSHYGLAZPRJAEZ-UHFFFAOYSA-N 4-(chloromethyl)-2-(2-methylphenyl)-1,3-thiazole Chemical compound CC1=CC=CC=C1C1=NC(CCl)=CS1 QSHYGLAZPRJAEZ-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
OTOBABIFUHCBCF-UHFFFAOYSA-P C=1C=CC=CC=1P(C=1C=CC=CC=1)(C=1C=CC=CC=1)[Ir](C(=O)Cl)P(C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(C=1C=CC=CC=1)[Ir](C(=O)Cl)P(C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 OTOBABIFUHCBCF-UHFFFAOYSA-P 0.000 description 1
PLZNEAAEBKBGCC-UHFFFAOYSA-O C=1C=CC=CC=1P(C=1C=CC=CC=1)([Pt])C1=CC=CC=C1 Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)([Pt])C1=CC=CC=C1 PLZNEAAEBKBGCC-UHFFFAOYSA-O 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
239000005864 Sulphur Substances 0.000 description 1
DKBAQFAPARKJMS-UHFFFAOYSA-I [Re](Cl)(Cl)(Cl)(Cl)Cl.C(CN)N Chemical compound [Re](Cl)(Cl)(Cl)(Cl)Cl.C(CN)N DKBAQFAPARKJMS-UHFFFAOYSA-I 0.000 description 1
XRJHOHOZMIECRE-UHFFFAOYSA-N [Rh].C1(C=CC=C1)C=C Chemical compound [Rh].C1(C=CC=C1)C=C XRJHOHOZMIECRE-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
230000004913 activation Effects 0.000 description 1
239000008186 active pharmaceutical agent Substances 0.000 description 1
239000003463 adsorbent Substances 0.000 description 1
230000032683 aging Effects 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
230000029936 alkylation Effects 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 description 1
239000011959 amorphous silica alumina Substances 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
238000001833 catalytic reforming Methods 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
239000004927 clay Substances 0.000 description 1
229910001603 clinoptilolite Inorganic materials 0.000 description 1
239000000571 coke Substances 0.000 description 1
238000010960 commercial process Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000010779 crude oil Substances 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000006477 desulfuration reaction Methods 0.000 description 1
230000023556 desulfurization Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
230000018109 developmental process Effects 0.000 description 1
125000004989 dicarbonyl group Chemical group 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000007323 disproportionation reaction Methods 0.000 description 1
229910052675 erionite Inorganic materials 0.000 description 1
125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000011010 flushing procedure Methods 0.000 description 1
239000000446 fuel Substances 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
239000003502 gasoline Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000012263 liquid product Substances 0.000 description 1
230000001050 lubricating effect Effects 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
229910017464 nitrogen compound Inorganic materials 0.000 description 1
150000002830 nitrogen compounds Chemical class 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
IHUHXSNGMLUYES-UHFFFAOYSA-J osmium(iv) chloride Chemical compound Cl[Os](Cl)(Cl)Cl IHUHXSNGMLUYES-UHFFFAOYSA-J 0.000 description 1
PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000008188 pellet Substances 0.000 description 1
239000003209 petroleum derivative Substances 0.000 description 1
238000005504 petroleum refining Methods 0.000 description 1
239000012071 phase Substances 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
238000007670 refining Methods 0.000 description 1
238000012552 review Methods 0.000 description 1
SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
FZHCFNGSGGGXEH-UHFFFAOYSA-N ruthenocene Chemical compound [Ru+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 FZHCFNGSGGGXEH-UHFFFAOYSA-N 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000004576 sand Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
238000010025 steaming Methods 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
238000012360 testing method Methods 0.000 description 1
230000009466 transformation Effects 0.000 description 1
238000005292 vacuum distillation Methods 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000001993 wax Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1
150000003738 xylenes Chemical class 0.000 description 1

Landscapes

Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA 475330 1984-03-19 1985-02-27 Methode de deparaffinage catalytique pour ameliorer le point d'ecoulement,par recours a l'agent de catalyse zms-11 a teneur d'un elementd'hydrogenation-deshydrogenation Expired CA1281677C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US59109484A	1984-03-19	1984-03-19
US591,094		1984-03-19

Publications (1)

Publication Number	Publication Date
CA1281677C true CA1281677C (fr)	1991-03-19

Family

ID=24365033

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 475330 Expired CA1281677C (fr)	1984-03-19	1985-02-27	Methode de deparaffinage catalytique pour ameliorer le point d'ecoulement,par recours a l'agent de catalyse zms-11 a teneur d'un elementd'hydrogenation-deshydrogenation

Country Status (1)

Country	Link
CA (1)	CA1281677C (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2020205354A1 (fr)	2019-03-29	2020-10-08	Exxonmobil Chemical Patents Inc.	Zéolite de type mel pour la conversion d'hydrocarbures aromatiques, procédé de fabrication et composition catalytique comprenant ladite zéolite
WO2020205357A1 (fr)	2019-03-29	2020-10-08	Exxonmobil Chemical Patents Inc.	Nouvelle zéolite, son procédé de fabrication et son utilisation dans la conversion d'hydrocarbures aromatiques
CN112619686A (zh) *	2019-10-09	2021-04-09	中国石油化工股份有限公司	负载型非贵金属脱氢催化剂及其制备方法和应用

1985
- 1985-02-27 CA CA 475330 patent/CA1281677C/fr not_active Expired

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2020205354A1 (fr)	2019-03-29	2020-10-08	Exxonmobil Chemical Patents Inc.	Zéolite de type mel pour la conversion d'hydrocarbures aromatiques, procédé de fabrication et composition catalytique comprenant ladite zéolite
WO2020205357A1 (fr)	2019-03-29	2020-10-08	Exxonmobil Chemical Patents Inc.	Nouvelle zéolite, son procédé de fabrication et son utilisation dans la conversion d'hydrocarbures aromatiques
CN112619686A (zh) *	2019-10-09	2021-04-09	中国石油化工股份有限公司	负载型非贵金属脱氢催化剂及其制备方法和应用
CN112619686B (zh) *	2019-10-09	2024-01-30	中国石油化工股份有限公司	负载型非贵金属脱氢催化剂及其制备方法和应用

Legal Events

Date	Code	Title	Description
1993-09-21	MKLA	Lapsed

Publication	Publication Date	Title
US5853566A (en)	1998-12-29	Zeolite-beta containing catalyst compositions and their use in hydrocarbon conversion processes for producing low boiling point materials
US5468368A (en)	1995-11-21	Lubricant hydrocracking process
US5013422A (en)	1991-05-07	Catalytic hydrocracking process
US5447623A (en)	1995-09-05	Hydrocracking catalyst and process
US5279726A (en)	1994-01-18	Catalyst containing zeolite beta and processes for its use
TWI466996B (zh)	2015-01-01	脫蠟觸媒與方法
EP1651738B1 (fr)	2011-10-12	Processus de transformation d'hydrocarbure et catalyseur
US6231749B1 (en)	2001-05-15	Production of high viscosity index lubricants
US5358917A (en)	1994-10-25	Hydrocarbon conversion catalyst
WO2006032989A1 (fr)	2006-03-30	Procede d'hydrocraquage et composition de catalyseur
US4502945A (en)	1985-03-05	Process for preparing olefins at high pressure
WO1991014753A1 (fr)	1991-10-03	Procede d'hydroisomerisation catalytique
EP0155822B1 (fr)	1990-12-19	Procédé de déparaffinage catalytique avec une zéolite ZSM-11
CA1281677C (fr)	1991-03-19	Methode de deparaffinage catalytique pour ameliorer le point d'ecoulement,par recours a l'agent de catalyse zms-11 a teneur d'un elementd'hydrogenation-deshydrogenation
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