CA1281873C - Pellicule de copolymere avec sequence de poly(thio-1,4-phenylene) a orientation biaxiale; methode de preparation - Google Patents

Pellicule de copolymere avec sequence de poly(thio-1,4-phenylene) a orientation biaxiale; methode de preparation

Info

Publication number: CA1281873C
Authority: CA; Canada
Prior art keywords: film; heat; block copolymer; recurring units; measured
Prior art date: 1985-12-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000525954A

Other languages

English (en)

Inventor

Toshiya Mizuno

Yo Iizuka

Takao Ichii

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Kureha Corp

Original Assignee

Kureha Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-12-27

Filing date

1986-12-22

Publication date

1991-03-26

1986-12-22 Application filed by Kureha Corp filed Critical Kureha Corp

1991-03-26 Application granted granted Critical

1991-03-26 Publication of CA1281873C publication Critical patent/CA1281873C/fr

2008-03-26 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

XWUCFAJNVTZRLE-UHFFFAOYSA-N 7-thiabicyclo[2.2.1]hepta-1,3,5-triene Chemical compound C1=C(S2)C=CC2=C1 XWUCFAJNVTZRLE-UHFFFAOYSA-N 0.000 title claims abstract description 70
229920001400 block copolymer Polymers 0.000 title claims abstract description 53
238000000034 method Methods 0.000 title claims abstract description 24
238000002425 crystallisation Methods 0.000 claims abstract description 29
230000008025 crystallization Effects 0.000 claims abstract description 29
239000000155 melt Substances 0.000 claims abstract description 28
238000002844 melting Methods 0.000 claims abstract description 25
230000008018 melting Effects 0.000 claims abstract description 25
230000009477 glass transition Effects 0.000 claims abstract description 15
229920006254 polymer film Polymers 0.000 claims abstract description 13
238000009998 heat setting Methods 0.000 claims description 29
238000001816 cooling Methods 0.000 claims description 11
238000000465 moulding Methods 0.000 claims description 10
239000010408 film Substances 0.000 description 137
239000000203 mixture Substances 0.000 description 30
238000006116 polymerization reaction Methods 0.000 description 28
239000000243 solution Substances 0.000 description 28
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
229920000642 polymer Polymers 0.000 description 24
SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 11
230000005291 magnetic effect Effects 0.000 description 10
239000011541 reaction mixture Substances 0.000 description 10
150000001491 aromatic compounds Chemical class 0.000 description 9
239000002585 base Substances 0.000 description 9
230000015572 biosynthetic process Effects 0.000 description 9
229910052751 metal Inorganic materials 0.000 description 9
239000002184 metal Substances 0.000 description 9
238000003786 synthesis reaction Methods 0.000 description 9
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 8
238000010438 heat treatment Methods 0.000 description 8
238000002360 preparation method Methods 0.000 description 8
OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 7
229920001577 copolymer Polymers 0.000 description 7
238000000151 deposition Methods 0.000 description 7
VDQVEACBQKUUSU-UHFFFAOYSA-M disodium;sulfanide Chemical compound [Na+].[Na+].[SH-] VDQVEACBQKUUSU-UHFFFAOYSA-M 0.000 description 7
229910052976 metal sulfide Inorganic materials 0.000 description 7
229910052979 sodium sulfide Inorganic materials 0.000 description 7
SOHCOYTZIXDCCO-UHFFFAOYSA-N 6-thiabicyclo[3.1.1]hepta-1(7),2,4-triene Chemical compound C=1C2=CC=CC=1S2 SOHCOYTZIXDCCO-UHFFFAOYSA-N 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
230000008021 deposition Effects 0.000 description 6
238000007738 vacuum evaporation Methods 0.000 description 6
150000001875 compounds Chemical class 0.000 description 4
239000013078 crystal Substances 0.000 description 4
230000006866 deterioration Effects 0.000 description 4
238000001035 drying Methods 0.000 description 4
229920001519 homopolymer Polymers 0.000 description 4
238000001465 metallisation Methods 0.000 description 4
239000003495 polar organic solvent Substances 0.000 description 4
239000010409 thin film Substances 0.000 description 4
239000004734 Polyphenylene sulfide Substances 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
239000011248 coating agent Substances 0.000 description 3
238000000576 coating method Methods 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000001704 evaporation Methods 0.000 description 3
230000008020 evaporation Effects 0.000 description 3
239000003960 organic solvent Substances 0.000 description 3
229920000069 polyphenylene sulfide Polymers 0.000 description 3
ZPQOPVIELGIULI-UHFFFAOYSA-N 1,3-dichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1 ZPQOPVIELGIULI-UHFFFAOYSA-N 0.000 description 2
125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
206010037660 Pyrexia Diseases 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
238000002441 X-ray diffraction Methods 0.000 description 2
229910045601 alloy Inorganic materials 0.000 description 2
239000000956 alloy Substances 0.000 description 2
-1 arylene sulfide Chemical compound 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
238000005266 casting Methods 0.000 description 2
230000008602 contraction Effects 0.000 description 2
238000006297 dehydration reaction Methods 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
230000005294 ferromagnetic effect Effects 0.000 description 2
125000005843 halogen group Chemical group 0.000 description 2
229910052744 lithium Inorganic materials 0.000 description 2
239000000463 material Substances 0.000 description 2
238000002074 melt spinning Methods 0.000 description 2
239000011259 mixed solution Substances 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
229920006267 polyester film Polymers 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000001771 vacuum deposition Methods 0.000 description 2
229910000859 α-Fe Inorganic materials 0.000 description 2
AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 description 1
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
235000010893 Bischofia javanica Nutrition 0.000 description 1
240000005220 Bischofia javanica Species 0.000 description 1
IBNQSWKJEBUSIE-UHFFFAOYSA-N CNP(NC)(NC)=O.CNP(NC)(NC)=O.CNP(NC)(NC)=O.CNP(NC)(NC)=O.CNP(NC)(NC)=O.CNP(NC)(NC)=O Chemical compound CNP(NC)(NC)=O.CNP(NC)(NC)=O.CNP(NC)(NC)=O.CNP(NC)(NC)=O.CNP(NC)(NC)=O.CNP(NC)(NC)=O IBNQSWKJEBUSIE-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
229920001730 Moisture cure polyurethane Polymers 0.000 description 1
229910004874 Na2S 9H2O Inorganic materials 0.000 description 1
244000166490 Tetrameles nudiflora Species 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910052977 alkali metal sulfide Inorganic materials 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
238000012661 block copolymerization Methods 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
239000001506 calcium phosphate Substances 0.000 description 1
229910000389 calcium phosphate Inorganic materials 0.000 description 1
235000011010 calcium phosphates Nutrition 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
239000002826 coolant Substances 0.000 description 1
229910001873 dinitrogen Inorganic materials 0.000 description 1
238000004821 distillation Methods 0.000 description 1
230000002708 enhancing effect Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
230000004927 fusion Effects 0.000 description 1
239000011521 glass Substances 0.000 description 1
XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
239000002245 particle Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
238000003825 pressing Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
238000005096 rolling process Methods 0.000 description 1
238000007788 roughening Methods 0.000 description 1
229910052701 rubidium Inorganic materials 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000004781 supercooling Methods 0.000 description 1
230000003746 surface roughness Effects 0.000 description 1
238000010301 surface-oxidation reaction Methods 0.000 description 1
229920005992 thermoplastic resin Polymers 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
150000003672 ureas Chemical class 0.000 description 1
238000005406 washing Methods 0.000 description 1
230000002087 whitening effect Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/10—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
- B29C55/12—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/0204—Polyarylenethioethers
- C08G75/0209—Polyarylenethioethers derived from monomers containing one aromatic ring
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/0204—Polyarylenethioethers
- C08G75/0245—Block or graft polymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/0204—Polyarylenethioethers
- C08G75/0286—Chemical after-treatment
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2081/00—Use of polymers having sulfur, with or without nitrogen, oxygen or carbon only, in the main chain, as moulding material
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
- C08J2381/02—Polythioethers; Polythioether-ethers

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Mechanical Engineering (AREA)
General Chemical & Material Sciences (AREA)
Materials Engineering (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)
Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

CA000525954A 1985-12-27 1986-12-22 Pellicule de copolymere avec sequence de poly(thio-1,4-phenylene) a orientation biaxiale; methode de preparation Expired - Fee Related CA1281873C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
JP60294681A JPH066339B2 (ja)	1985-12-27	1985-12-27	パラフエニレンスルフイドブロツクコポリマ−２軸延伸フイルム及びその製造法
JP294681/85		1985-12-27

Publications (1)

Publication Number	Publication Date
CA1281873C true CA1281873C (fr)	1991-03-26

Family

ID=17810927

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000525954A Expired - Fee Related CA1281873C (fr)	1985-12-27	1986-12-22	Pellicule de copolymere avec sequence de poly(thio-1,4-phenylene) a orientation biaxiale; methode de preparation

Country Status (5)

Country	Link
JP (1)	JPH066339B2 (fr)
CA (1)	CA1281873C (fr)
DE (1)	DE3644365A1 (fr)
FR (1)	FR2592384B1 (fr)
GB (1)	GB2184978B (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS62242517A (ja) *	1986-04-14	1987-10-23	Kureha Chem Ind Co Ltd	ポリパラフェニレンスルフィド２軸延伸フィルム及びその製造方法
JPS6333427A (ja) *	1986-07-25	1988-02-13	Diafoil Co Ltd	ポリフエニレンスルフイドフイルム
CA2001097C (fr) *	1988-10-25	1996-01-30	Yoshikatsu Satake	Fibres a base de copolymere avec sequence de poly(sulfure d'arylene); leur preparation
US5155207A (en) *	1988-12-29	1992-10-13	Phillips Petroleum Company	Arylene sulfide polymers and articles of manufacture
EP2478989A4 (fr) *	2009-09-16	2017-06-21	Nippon Steel & Sumitomo Metal Corporation	Dispositif de soudage permettant de fabriquer un tube soudé par résistance électrique
BR112012005765A2 (pt)	2009-09-16	2021-01-05	Nippon Steel Corporation	Aparelho de solda de tubo soldado com resistência elétrica
JP2014001363A (ja) *	2012-05-21	2014-01-09	Toray Ind Inc	金属接着用二軸延伸ポリアリーレンスルフィドフィルム

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4286018A (en) *	1978-04-28	1981-08-25	Toray Industries, Incorporated	Biaxially oriented poly-p-phenylene sulfide films
US4629778A (en) *	1982-05-20	1986-12-16	Dainippon Ink And Chemicals, Inc.	Poly(p-phenylene sulfide) film and process for production thereof
JPS6096439A (ja) *	1983-10-31	1985-05-30	Sumitomo Chem Co Ltd	垂直磁化用ポリｐ−フエニレンスルフイドフイルム
CA1260174A (fr) *	1984-06-29	1989-09-26	Kureha Chemical Ind Co Ltd	Copolymeres sequences de sulfure de para-phenylene; methode de preparation et utilisation
DE3587463D1 (de) *	1984-08-07	1993-08-26	Bayer Ag	Polyphenylensulfide, verfahren zur herstellung der polyphenylensulfide und deren verwendung.

1985
- 1985-12-27 JP JP60294681A patent/JPH066339B2/ja not_active Expired - Lifetime
1986
- 1986-12-22 CA CA000525954A patent/CA1281873C/fr not_active Expired - Fee Related
- 1986-12-23 GB GB8630779A patent/GB2184978B/en not_active Expired
- 1986-12-24 DE DE19863644365 patent/DE3644365A1/de active Granted
- 1986-12-24 FR FR868618153A patent/FR2592384B1/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
GB2184978B (en)	1989-10-18
JPH066339B2 (ja)	1994-01-26
GB8630779D0 (en)	1987-02-04
GB2184978A (en)	1987-07-08
DE3644365A1 (de)	1987-07-02
FR2592384A1 (fr)	1987-07-03
FR2592384B1 (fr)	1992-05-15
JPS62152828A (ja)	1987-07-07
DE3644365C2 (fr)	1991-01-17

Legal Events

Date	Code	Title	Description
2001-03-26	MKLA	Lapsed

Publication	Publication Date	Title
US4286018A (en)	1981-08-25	Biaxially oriented poly-p-phenylene sulfide films
CA1285733C (fr)	1991-07-09	Pellicule de poly(sulfure de p-phenylene) a orientation biaxiale; methode de preparation
US4777228A (en)	1988-10-11	Biaxially oriented paraphenylene sulfide block copolymer film and process for producing the same
CA1301422C (fr)	1992-05-26	Procede pour la production de pellicule de copolymere bloque de sulfure de paraphenylene a orientation biaziale
US4897238A (en)	1990-01-30	Stretched poly(arylene thioether-ketone) films and production process thereof
KR910003720B1 (ko)	1991-06-08	폴리아릴렌 티오에테르의 고 결정화 성형물
GB2184978A (en)	1987-07-08	Biaxially oriented paraphenylene sulfide block copolymer film and process for producing the same
EP0244093B1 (fr)	1992-01-22	Film ou feuille biaxialement orientés de polyparaphénylènesulfide
CA1289710C (fr)	1991-10-01	Pellicules de poly(thioether d'arylene-cetone) etirees et leur procede de production
GB2192831A (en)	1988-01-27	Polyphenylene sulfide film
US4774298A (en)	1988-09-27	Process for producing biaxially oriented paraphenylene sulfide block copolymer film
US5095078A (en)	1992-03-10	Heat-resistant film and production process thereof
CA2004273C (fr)	1994-04-12	Feuille a base de polysulfure d'arylene et son procede de fabrication
EP0323179B1 (fr)	1993-05-26	Feuille en polyarylènesulfure et son procédé de fabrication
US5137992A (en)	1992-08-11	Process for producing an easily-slidable polyarylene thioether film
JP2855351B2 (ja)	1999-02-10	ポリアリーレンスルフィドシートおよびその製造方法
CA1323480C (fr)	1993-10-26	Film etire thermoresistant et procede de production connexe
US5200501A (en)	1993-04-06	Easily-slidable polyarylene thioether film and process for producing the same
JPS63260426A (ja)	1988-10-27	ポリフエニレンスルフイドフイルムの製造方法
CN118076481A (zh)	2024-05-24	聚酰胺膜层叠体
CA2004884A1 (fr)	1990-06-29	Polymeres de sulfure d'arylene; articles fabriques
JPH02235929A (ja)	1990-09-18	ポリフェニレンスフィド共重合体フィルム
JPS62290733A (ja)	1987-12-17	二軸延伸ポリケトンフイルム
JPH02199132A (ja)	1990-08-07	フィルム及びその製造法
JPH048457B2 (fr)	1992-02-17