CA1287814C - Procede d'elaboration de poudres de metaux de transition par electrolyse en bains de sels fondus - Google Patents

Procede d'elaboration de poudres de metaux de transition par electrolyse en bains de sels fondus

Info

Publication number: CA1287814C
Authority: CA; Canada
Prior art keywords: electrolysis; metal; bath; transition metal; molten salts
Prior art date: 1986-01-06
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000526634A

Other languages

English (en)

French (fr)

Inventor

Marcel Armand

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Pechiney SA

Original Assignee

Pechiney SA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-01-06

Filing date

1987-01-05

Publication date

1991-08-20

1987-01-05 Application filed by Pechiney SA filed Critical Pechiney SA

1991-08-20 Application granted granted Critical

1991-08-20 Publication of CA1287814C publication Critical patent/CA1287814C/fr

2008-08-20 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 18
239000000843 powder Substances 0.000 title claims abstract description 13
238000005868 electrolysis reaction Methods 0.000 title claims abstract description 12
150000003839 salts Chemical class 0.000 title claims abstract description 10
229910052723 transition metal Inorganic materials 0.000 title claims abstract description 7
150000003624 transition metals Chemical class 0.000 title claims abstract description 7
229910052751 metal Inorganic materials 0.000 claims abstract description 15
239000002184 metal Substances 0.000 claims abstract description 15
239000003513 alkali Substances 0.000 claims abstract description 7
229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 7
230000008021 deposition Effects 0.000 claims abstract description 7
150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 3
150000004820 halides Chemical class 0.000 claims description 9
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 3
229910052731 fluorine Inorganic materials 0.000 claims description 3
239000011737 fluorine Substances 0.000 claims description 3
239000000203 mixture Substances 0.000 claims description 3
238000002360 preparation method Methods 0.000 claims description 3
229910021645 metal ion Inorganic materials 0.000 claims description 2
230000007704 transition Effects 0.000 claims description 2
108091006629 SLC13A2 Proteins 0.000 claims 2
230000000536 complexating effect Effects 0.000 claims 1
239000008139 complexing agent Substances 0.000 claims 1
239000010936 titanium Substances 0.000 abstract description 8
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 7
229910052719 titanium Inorganic materials 0.000 abstract description 7
229910052735 hafnium Inorganic materials 0.000 abstract description 5
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract description 5
150000002739 metals Chemical class 0.000 abstract description 5
230000000737 periodic effect Effects 0.000 abstract description 2
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
238000004519 manufacturing process Methods 0.000 abstract 1
229910052726 zirconium Inorganic materials 0.000 abstract 1
210000001787 dendrite Anatomy 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
210000004027 cell Anatomy 0.000 description 2
230000000694 effects Effects 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000005406 washing Methods 0.000 description 2
235000011299 Brassica oleracea var botrytis Nutrition 0.000 description 1
240000003259 Brassica oleracea var. botrytis Species 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
230000001464 adherent effect Effects 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
238000010668 complexation reaction Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000010894 electron beam technology Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
230000004927 fusion Effects 0.000 description 1
238000007499 fusion processing Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
PDPJQWYGJJBYLF-UHFFFAOYSA-J hafnium tetrachloride Chemical compound Cl[Hf](Cl)(Cl)Cl PDPJQWYGJJBYLF-UHFFFAOYSA-J 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
238000004845 hydriding Methods 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
238000009434 installation Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000000463 material Substances 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
238000005272 metallurgy Methods 0.000 description 1
239000011591 potassium Substances 0.000 description 1
238000004663 powder metallurgy Methods 0.000 description 1
238000007789 sealing Methods 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
235000013024 sodium fluoride Nutrition 0.000 description 1
239000011775 sodium fluoride Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C5/00—Electrolytic production, recovery or refining of metal powders or porous metal masses
- C25C5/04—Electrolytic production, recovery or refining of metal powders or porous metal masses from melts

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Electrolytic Production Of Metals (AREA)
Length Measuring Devices By Optical Means (AREA)

CA000526634A 1986-01-06 1987-01-05 Procede d'elaboration de poudres de metaux de transition par electrolyse en bains de sels fondus Expired - Lifetime CA1287814C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR8600390		1986-01-06
FR8600390A FR2592664B1 (fr)	1986-01-06	1986-01-06	Procede d'elaboration de poudres de metaux de transition par electrolyse en bains de sels fondus

Publications (1)

Publication Number	Publication Date
CA1287814C true CA1287814C (fr)	1991-08-20

Family

ID=9331054

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000526634A Expired - Lifetime CA1287814C (fr)	1986-01-06	1987-01-05	Procede d'elaboration de poudres de metaux de transition par electrolyse en bains de sels fondus

Country Status (7)

Country	Link
US (1)	US4770750A (2)
EP (1)	EP0253841B1 (2)
JP (1)	JPS63500187A (2)
CA (1)	CA1287814C (2)
DE (1)	DE3762890D1 (2)
FR (1)	FR2592664B1 (2)
WO (1)	WO1987004193A1 (2)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO1991001942A1 (en) *	1989-08-01	1991-02-21	Australian Copper Company Pty. Ltd.	Production of copper compounds
WO2001062994A1 (en) *	2000-02-22	2001-08-30	Qinetiq Limited	Method of manufacture for ferro-titanium and other metal alloys electrolytic reduction
WO2005111272A1 (ja) *	2004-04-06	2005-11-24	Iox Co., Ltd.	プラズマ誘起電解による微粒子の製造方法
PL377451A1 (pl) *	2005-10-05	2007-04-16	Instytut Wysokich Ciśnień PAN	Sposób prowadzenia reakcji i reaktor chemiczny
EP2794943B8 (en)	2011-12-22	2019-07-10	Universal Achemetal Titanium, LLC	A method for extraction and refining of titanium
CA3047102C (en)	2016-09-14	2023-12-05	Universal Achemetal Titanium, Llc	A method for producing titanium-aluminum-vanadium alloy
CA3049769C (en)	2017-01-13	2023-11-21	Universal Achemetal Titanium, Llc	Titanium master alloy for titanium-aluminum based alloys

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2951021A (en) *	1952-03-28	1960-08-30	Nat Res Corp	Electrolytic production of titanium
GB736567A (en) *	1952-07-03	1955-09-07	Horizons Titanium Corp	Improvements in production of metallic titanium
FR1265427A (fr) *	1960-06-03	1961-06-30	Ciba Geigy	Procédé d'élaboration électrolytique des métaux niobium et tantale

1986
- 1986-01-06 FR FR8600390A patent/FR2592664B1/fr not_active Expired - Fee Related
1987
- 1987-01-05 JP JP62500612A patent/JPS63500187A/ja active Granted
- 1987-01-05 EP EP87900658A patent/EP0253841B1/fr not_active Expired - Lifetime
- 1987-01-05 DE DE8787900658T patent/DE3762890D1/de not_active Expired - Fee Related
- 1987-01-05 US US07/099,317 patent/US4770750A/en not_active Expired - Fee Related
- 1987-01-05 WO PCT/FR1987/000001 patent/WO1987004193A1/fr not_active Ceased
- 1987-01-05 CA CA000526634A patent/CA1287814C/fr not_active Expired - Lifetime

Also Published As

Publication number	Publication date
WO1987004193A1 (fr)	1987-07-16
EP0253841A1 (fr)	1988-01-27
FR2592664A1 (fr)	1987-07-10
US4770750A (en)	1988-09-13
EP0253841B1 (fr)	1990-05-23
DE3762890D1 (de)	1990-06-28
FR2592664B1 (fr)	1990-03-30
JPS63500187A (ja)	1988-01-21
JPH0312156B2 (2)	1991-02-19

Legal Events

Date	Code	Title	Description
1994-02-22	MKLA	Lapsed

Publication	Publication Date	Title
US5336378A (en)	1994-08-09	Method and apparatus for producing a high-purity titanium
EP0570308B1 (fr)	1996-12-27	Alliages de métaux réfractaires aptes à la transformation en lingots homogènes et purs et procédés d'obtention des dits alliages
CA1287814C (fr)	1991-08-20	Procede d'elaboration de poudres de metaux de transition par electrolyse en bains de sels fondus
Wang et al.	2023	Electrochemical separation of Fe (III) impurity from molten MgCl2-NaCl-KCl for magnesium electrolytic production
NO862234L (no)	1986-06-04	Fremgangsmaate ved fremstilling av kalsium og legeringer av hoey renhet.
Zhang et al.	2023	Clean separation of vanadium from NaVO3 in NaF-KF-AlF3 molten salt by electrochemical reduction
JP6095374B2 (ja)	2017-03-15	チタンの製造方法。
FR2494726A1 (fr)	1982-05-28	Procede ameliore de preparation de titane par electrolyse
JPH08225980A (ja)	1996-09-03	高純度チタンを製造する方法及び装置
GB2031463A (en)	1980-04-23	Process for electrodeposition of iron-nickel alloys
Uda et al.	2000	Contactless electrochemical reduction of titanium (II) chloride by aluminum
RU2423557C2 (ru)	2011-07-10	Способ получения высоко- и нанодисперсного порошка металлов или сплавов
US2892763A (en)	1959-06-30	Production of pure elemental silicon
ZHANG et al.	2012	Preparation of Mg–Li—La alloys by electrolysis in molten salt
Su et al.	2025	Electrochemical formation of Mg-Li-Ce-Y alloys by codeposition of Mg, Li, Ce and Y in molten LiCl-KCl salt
JPH01184295A (ja)	1989-07-21	高純度アルミニウム−リチウム母合金の製造方法
RU2278183C2 (ru)	2006-06-20	Способ рафинирования благородных металлов
US4113581A (en)	1978-09-12	Electrodeposition process
CA1268446A (fr)	1990-05-01	Procede d'amelioration de la purete des metaux de transition obtenus par electrolyse de leurs halogenures en bain de sels fondus
Withers	2020	Electrolysis of carbothermic treated titanium oxides to produce Ti metal
US4784742A (en)	1988-11-15	Cathode for magnesium production
RU2135615C1 (ru)	1999-08-27	Способ получения лития
RU2621508C2 (ru)	2017-06-06	Электрохимический способ получения наноразмерных порошков интерметаллидов гольмия и никеля в галогенидных расплавах
CH451638A (fr)	1968-05-15	Procédé pour le dépôt de métaux réfractaires par voie électrolytique
SU238984A1 (ru)		Способ получения титанового покрытия электролизом из расплава