CA1292979C - Procede de transformation a sec de l'amidon sous forme de cation - Google Patents

Procede de transformation a sec de l'amidon sous forme de cation

Info

Publication number: CA1292979C
Authority: CA; Canada
Prior art keywords: process according; starch; silica; weight; oxide
Prior art date: 1987-02-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000529638A

Other languages

English (en)

Inventor

Reinhard Stober

Wolfgang Fischer

Michael Huss

Klaus Udluft

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Evonik Operations GmbH

Original Assignee

Degussa GmbH

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-02-13

Filing date

1987-02-13

Publication date

1991-12-10

1987-02-13 Application filed by Degussa GmbH filed Critical Degussa GmbH

1987-02-13 Priority to CA000529638A priority Critical patent/CA1292979C/fr

1991-12-10 Application granted granted Critical

1991-12-10 Publication of CA1292979C publication Critical patent/CA1292979C/fr

2008-12-10 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

229920002472 Starch Polymers 0.000 title claims abstract description 63
235000019698 starch Nutrition 0.000 title claims abstract description 62
239000008107 starch Substances 0.000 title claims abstract description 57
238000000034 method Methods 0.000 title claims description 43
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 64
239000000377 silicon dioxide Substances 0.000 claims abstract description 32
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
229910001868 water Inorganic materials 0.000 claims abstract description 22
-1 alkylidene epoxides Chemical class 0.000 claims abstract description 11
239000000203 mixture Substances 0.000 claims description 28
238000006243 chemical reaction Methods 0.000 claims description 22
229920001592 potato starch Polymers 0.000 claims description 11
239000000920 calcium hydroxide Substances 0.000 claims description 10
229910001861 calcium hydroxide Inorganic materials 0.000 claims description 10
239000003513 alkali Substances 0.000 claims description 8
238000003860 storage Methods 0.000 claims description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 6
229910001854 alkali hydroxide Inorganic materials 0.000 claims description 5
229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims description 5
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical group [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 5
239000000292 calcium oxide Substances 0.000 claims description 5
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 5
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
150000001875 compounds Chemical class 0.000 claims description 4
238000005259 measurement Methods 0.000 claims description 4
229910021653 sulphate ion Inorganic materials 0.000 claims description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
240000003183 Manihot esculenta Species 0.000 claims description 3
235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 3
230000002209 hydrophobic effect Effects 0.000 claims description 3
TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 claims description 3
150000004706 metal oxides Chemical class 0.000 claims description 3
239000007921 spray Substances 0.000 claims description 3
241000209140 Triticum Species 0.000 claims description 2
235000021307 Triticum Nutrition 0.000 claims description 2
240000008042 Zea mays Species 0.000 claims description 2
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 2
235000002017 Zea mays subsp mays Nutrition 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims description 2
235000005822 corn Nutrition 0.000 claims description 2
150000002118 epoxides Chemical group 0.000 claims 3
SLRMQYXOBQWXCR-UHFFFAOYSA-N 2154-56-5 Chemical compound [CH2]C1=CC=CC=C1 SLRMQYXOBQWXCR-UHFFFAOYSA-N 0.000 claims 1
239000000758 substrate Substances 0.000 claims 1
125000002091 cationic group Chemical group 0.000 abstract description 10
150000002170 ethers Chemical class 0.000 abstract description 4
238000001035 drying Methods 0.000 abstract description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 26
239000012190 activator Substances 0.000 description 17
238000002156 mixing Methods 0.000 description 15
230000000875 corresponding effect Effects 0.000 description 13
229910052757 nitrogen Inorganic materials 0.000 description 13
150000002924 oxiranes Chemical class 0.000 description 13
238000006467 substitution reaction Methods 0.000 description 12
229940045720 antineoplastic alkylating drug epoxides Drugs 0.000 description 10
239000003153 chemical reaction reagent Substances 0.000 description 10
PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 description 10
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 9
239000000243 solution Substances 0.000 description 7
238000004458 analytical method Methods 0.000 description 6
239000000725 suspension Substances 0.000 description 5
235000012255 calcium oxide Nutrition 0.000 description 4
229940087373 calcium oxide Drugs 0.000 description 4
238000006266 etherification reaction Methods 0.000 description 4
230000014759 maintenance of location Effects 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
239000000126 substance Substances 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
244000061456 Solanum tuberosum Species 0.000 description 3
235000002595 Solanum tuberosum Nutrition 0.000 description 3
239000012467 final product Substances 0.000 description 3
239000000047 product Substances 0.000 description 3
LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 description 3
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
229920002261 Corn starch Polymers 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
241000218657 Picea Species 0.000 description 2
LODJVTYHEMGBKX-UHFFFAOYSA-N [Cl-].[NH4+].ClCC(CCC(O)(C)C)O Chemical compound [Cl-].[NH4+].ClCC(CCC(O)(C)C)O LODJVTYHEMGBKX-UHFFFAOYSA-N 0.000 description 2
239000002585 base Substances 0.000 description 2
239000008120 corn starch Substances 0.000 description 2
229940099112 cornstarch Drugs 0.000 description 2
238000009826 distribution Methods 0.000 description 2
239000000945 filler Substances 0.000 description 2
150000003944 halohydrins Chemical class 0.000 description 2
239000002245 particle Substances 0.000 description 2
238000012216 screening Methods 0.000 description 2
238000004513 sizing Methods 0.000 description 2
238000003756 stirring Methods 0.000 description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 2
GONFBOIJNUKKST-UHFFFAOYSA-N 5-ethylsulfanyl-2h-tetrazole Chemical compound CCSC=1N=NNN=1 GONFBOIJNUKKST-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
240000000731 Fagus sylvatica Species 0.000 description 1
235000010099 Fagus sylvatica Nutrition 0.000 description 1
241000294754 Macroptilium atropurpureum Species 0.000 description 1
229920000881 Modified starch Polymers 0.000 description 1
239000004368 Modified starch Substances 0.000 description 1
239000013543 active substance Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
229960001040 ammonium chloride Drugs 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
230000033228 biological regulation Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229920006319 cationized starch Polymers 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000003945 chlorohydrins Chemical class 0.000 description 1
239000011362 coarse particle Substances 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
239000008394 flocculating agent Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
229910052602 gypsum Inorganic materials 0.000 description 1
239000010440 gypsum Substances 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000000265 homogenisation Methods 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
235000019426 modified starch Nutrition 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
230000036647 reaction Effects 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
229960001866 silicon dioxide Drugs 0.000 description 1
235000011121 sodium hydroxide Nutrition 0.000 description 1
239000007787 solid Substances 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
229940100445 wheat starch Drugs 0.000 description 1

Landscapes

Polysaccharides And Polysaccharide Derivatives (AREA)

CA000529638A 1987-02-13 1987-02-13 Procede de transformation a sec de l'amidon sous forme de cation Expired - Lifetime CA1292979C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000529638A CA1292979C (fr)	1987-02-13	1987-02-13	Procede de transformation a sec de l'amidon sous forme de cation

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000529638A CA1292979C (fr)	1987-02-13	1987-02-13	Procede de transformation a sec de l'amidon sous forme de cation

Publications (1)

Publication Number	Publication Date
CA1292979C true CA1292979C (fr)	1991-12-10

Family

ID=4134963

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000529638A Expired - Lifetime CA1292979C (fr)	1987-02-13	1987-02-13	Procede de transformation a sec de l'amidon sous forme de cation

Country Status (1)

Country	Link
CA (1)	CA1292979C (fr)

1987
- 1987-02-13 CA CA000529638A patent/CA1292979C/fr not_active Expired - Lifetime

Legal Events

Date	Code	Title	Description
2001-12-10	MKLA	Lapsed

Publication	Publication Date	Title
US4812257A (en)	1989-03-14	Process for dry cationization of starch
CN101443363B (zh)	2012-04-18	阳离子多糖及其制备和应用
CA1098655A (fr)	1981-04-07	Traduction non-disponible
SU1228793A3 (ru)	1986-04-30	Способ изготовлени бумаги
US4281109A (en)	1981-07-28	Pollution-free cationization of starch
US3778431A (en)	1973-12-11	Gelatinizable crosslinked cationic starch and method for its manufacture
US4758282A (en)	1988-07-19	Process for dry cationization of galactomannans
US4840705A (en)	1989-06-20	Papermaking method
US4981958A (en)	1991-01-01	Method for the dry cationization of starch II
US3884909A (en)	1975-05-20	Gelatinizable crosslinked cationic starch and method for its manufacture
CA1292979C (fr)	1991-12-10	Procede de transformation a sec de l'amidon sous forme de cation
US5116967A (en)	1992-05-26	Method of manufacturing an adjustable-viscosity cationic starch
CA1309090C (fr)	1992-10-20	Procede pour la cationisation a sec des galactomannanes
CA2082702A1 (fr)	1993-05-13	Procede de fabrication de derives d'amidon cationique a l'aide d'alcalis concentres
CA1292980C (fr)	1991-12-10	Procede de cationisation a sec des galactomannanes
EP0874000A2 (fr)	1998-10-28	Polymères naturels, pulvérulents et substitués, un procédé pour leur préparation et leur application
JPH0235762B2 (fr)	1990-08-13
KR100226154B1 (ko)	1999-10-15	고치환도 양성전분의 제조방법
JPS5941646B2 (ja)	1984-10-08	カチオン澱粉の製造方法
CS202374B1 (en)	1981-01-30	Process for preparing derivatives of polysaccharides containg quaternary ammonium groups