CA1326318C - Melanges de polyesters extrudables contenant un stabilisant phosphate/epoxy - Google Patents

Melanges de polyesters extrudables contenant un stabilisant phosphate/epoxy

Info

Publication number: CA1326318C
Authority: CA; Canada
Prior art keywords: component; phosphate; weight percent; stabilizer; epoxy
Prior art date: 1987-12-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000616125A

Other languages

English (en)

Inventor

Mo-Fung Cheung

Henk Van Oene

Amos Golovoy

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Ford Motor Company of Canada Ltd

Original Assignee

Ford Motor Company of Canada Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-12-28

Filing date

1991-07-22

Publication date

1994-01-18

1987-12-28 Priority claimed from US07/138,255 external-priority patent/US4983654A/en

1991-07-22 Application filed by Ford Motor Company of Canada Ltd filed Critical Ford Motor Company of Canada Ltd

1991-07-22 Priority to CA000616125A priority Critical patent/CA1326318C/fr

1994-01-18 Application granted granted Critical

1994-01-18 Publication of CA1326318C publication Critical patent/CA1326318C/fr

2008-11-03 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 110
239000003381 stabilizer Substances 0.000 title claims abstract description 66
229920000728 polyester Polymers 0.000 title claims abstract description 47
239000004593 Epoxy Substances 0.000 title claims abstract description 32
229910019142 PO4 Inorganic materials 0.000 title claims description 23
239000010452 phosphate Substances 0.000 title claims description 23
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title claims description 22
229920002959 polymer blend Polymers 0.000 claims abstract description 40
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 33
150000001875 compounds Chemical class 0.000 claims abstract description 27
238000005809 transesterification reaction Methods 0.000 claims abstract description 17
150000003949 imides Chemical class 0.000 claims abstract description 8
-1 polyarylsulfone Polymers 0.000 claims description 41
229920000642 polymer Polymers 0.000 claims description 36
125000003118 aryl group Chemical group 0.000 claims description 34
229920001230 polyarylate Polymers 0.000 claims description 29
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 28
229920000515 polycarbonate Polymers 0.000 claims description 16
239000004417 polycarbonate Substances 0.000 claims description 16
239000007795 chemical reaction product Substances 0.000 claims description 15
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 14
229920000139 polyethylene terephthalate Polymers 0.000 claims description 14
239000005020 polyethylene terephthalate Substances 0.000 claims description 14
229920005989 resin Polymers 0.000 claims description 14
239000011347 resin Substances 0.000 claims description 14
150000005690 diesters Chemical class 0.000 claims description 13
229920001169 thermoplastic Polymers 0.000 claims description 11
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 8
150000002009 diols Chemical class 0.000 claims description 8
229920002492 poly(sulfone) Polymers 0.000 claims description 8
125000001931 aliphatic group Chemical group 0.000 claims description 7
239000004416 thermosoftening plastic Substances 0.000 claims description 6
IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical group C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 claims description 5
229920001519 homopolymer Polymers 0.000 claims description 5
235000011007 phosphoric acid Nutrition 0.000 claims description 5
239000007983 Tris buffer Substances 0.000 claims description 4
229920001400 block copolymer Polymers 0.000 claims description 4
229910052739 hydrogen Inorganic materials 0.000 claims description 4
239000001257 hydrogen Substances 0.000 claims description 4
229920000090 poly(aryl ether) Polymers 0.000 claims description 4
229920001643 poly(ether ketone) Polymers 0.000 claims description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
229920013745 polyesteretherketone Polymers 0.000 claims description 3
238000001816 cooling Methods 0.000 claims description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 2
125000003700 epoxy group Chemical group 0.000 claims 2
VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 claims 1
235000010290 biphenyl Nutrition 0.000 claims 1
239000004305 biphenyl Substances 0.000 claims 1
125000006267 biphenyl group Chemical group 0.000 claims 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 1
238000012545 processing Methods 0.000 abstract description 13
125000003504 2-oxazolinyl group Chemical group O1C(=NCC1)* 0.000 abstract description 2
239000002253 acid Substances 0.000 description 28
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 17
238000006243 chemical reaction Methods 0.000 description 17
150000002148 esters Chemical group 0.000 description 14
239000000463 material Substances 0.000 description 13
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 11
150000007513 acids Chemical class 0.000 description 11
239000000178 monomer Substances 0.000 description 11
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 10
229920000578 graft copolymer Polymers 0.000 description 10
229920001577 copolymer Polymers 0.000 description 9
238000000034 method Methods 0.000 description 9
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 8
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239000000243 solution Substances 0.000 description 8
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 7
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 7
238000012360 testing method Methods 0.000 description 7
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
229920001634 Copolyester Polymers 0.000 description 6
125000005250 alkyl acrylate group Chemical group 0.000 description 6
150000001718 carbodiimides Chemical class 0.000 description 6
150000001993 dienes Chemical class 0.000 description 6
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
239000000047 product Substances 0.000 description 6
KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 5
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 5
ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 5
229920001971 elastomer Polymers 0.000 description 5
238000000465 moulding Methods 0.000 description 5
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 5
150000002989 phenols Chemical class 0.000 description 5
239000001294 propane Substances 0.000 description 5
239000002904 solvent Substances 0.000 description 5
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
239000004925 Acrylic resin Substances 0.000 description 4
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
239000000470 constituent Substances 0.000 description 4
230000009477 glass transition Effects 0.000 description 4
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
238000002156 mixing Methods 0.000 description 4
230000000704 physical effect Effects 0.000 description 4
150000003457 sulfones Chemical class 0.000 description 4
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
229920002554 vinyl polymer Chemical group 0.000 description 4
229930185605 Bisphenol Natural products 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
239000004609 Impact Modifier Substances 0.000 description 3
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
125000000732 arylene group Chemical group 0.000 description 3
230000008901 benefit Effects 0.000 description 3
125000004432 carbon atom Chemical group C* 0.000 description 3
150000004649 carbonic acid derivatives Chemical class 0.000 description 3
230000008859 change Effects 0.000 description 3
238000001035 drying Methods 0.000 description 3
229940093476 ethylene glycol Drugs 0.000 description 3
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150000002430 hydrocarbons Chemical class 0.000 description 3
238000010348 incorporation Methods 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
238000006116 polymerization reaction Methods 0.000 description 3
229920005862 polyol Polymers 0.000 description 3
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
GPAPPPVRLPGFEQ-UHFFFAOYSA-N 4,4'-dichlorodiphenyl sulfone Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C1=CC=C(Cl)C=C1 GPAPPPVRLPGFEQ-UHFFFAOYSA-N 0.000 description 2
KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
229920003319 Araldite® Polymers 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
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YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
125000001309 chloro group Chemical group Cl* 0.000 description 2
239000012141 concentrate Substances 0.000 description 2
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
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230000032050 esterification Effects 0.000 description 2
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125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 1
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159000000032 aromatic acids Chemical class 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
150000008378 aryl ethers Chemical class 0.000 description 1
125000004104 aryloxy group Chemical group 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
125000002619 bicyclic group Chemical group 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 1
125000001246 bromo group Chemical group Br* 0.000 description 1
NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000007707 calorimetry Methods 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
FOCAUTSVDIKZOP-UHFFFAOYSA-M chloroacetate Chemical compound [O-]C(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-M 0.000 description 1
229940089960 chloroacetate Drugs 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
229930003836 cresol Natural products 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
HDFFVHSMHLDSLO-UHFFFAOYSA-M dibenzyl phosphate Chemical compound C=1C=CC=CC=1COP(=O)([O-])OCC1=CC=CC=C1 HDFFVHSMHLDSLO-UHFFFAOYSA-M 0.000 description 1
ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
150000002118 epoxides Chemical group 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
125000001033 ether group Chemical group 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
230000004927 fusion Effects 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
APPOKADJQUIAHP-UHFFFAOYSA-N hexa-2,4-diene Chemical compound CC=CC=CC APPOKADJQUIAHP-UHFFFAOYSA-N 0.000 description 1
125000001145 hydrido group Chemical group *[H] 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
238000002329 infrared spectrum Methods 0.000 description 1
239000004611 light stabiliser Substances 0.000 description 1
238000011068 loading method Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
125000002950 monocyclic group Chemical group 0.000 description 1
YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
LCCNCVORNKJIRZ-UHFFFAOYSA-N parathion Chemical compound CCOP(=S)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 LCCNCVORNKJIRZ-UHFFFAOYSA-N 0.000 description 1
239000008188 pellet Substances 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
239000000049 pigment Substances 0.000 description 1
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
229920000412 polyarylene Polymers 0.000 description 1
229920005668 polycarbonate resin Polymers 0.000 description 1
239000004431 polycarbonate resin Substances 0.000 description 1
125000003367 polycyclic group Chemical group 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
150000003077 polyols Chemical class 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920000874 polytetramethylene terephthalate Polymers 0.000 description 1
229920005749 polyurethane resin Polymers 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000000979 retarding effect Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000001174 sulfone group Chemical group 0.000 description 1
239000000725 suspension Substances 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
239000003017 thermal stabilizer Substances 0.000 description 1
239000012815 thermoplastic material Substances 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1

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Compositions Of Macromolecular Compounds (AREA)

CA000616125A 1987-12-28 1991-07-22 Melanges de polyesters extrudables contenant un stabilisant phosphate/epoxy Expired - Fee Related CA1326318C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000616125A CA1326318C (fr)	1987-12-28	1991-07-22	Melanges de polyesters extrudables contenant un stabilisant phosphate/epoxy

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US138,255		1987-12-28
US07/138,255 US4983654A (en)	1987-12-28	1987-12-28	Phosphate/epoxy stabilizer for extrudable polyester blends
CA000582151A CA1312155C (fr)	1987-12-28	1988-11-03	Stabilisant phosphate/epoxy pour des melanges extrudables de polyesters
CA000616125A CA1326318C (fr)	1987-12-28	1991-07-22	Melanges de polyesters extrudables contenant un stabilisant phosphate/epoxy

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000582151A Division CA1312155C (fr)	1987-12-28	1988-11-03	Stabilisant phosphate/epoxy pour des melanges extrudables de polyesters

Publications (1)

Publication Number	Publication Date
CA1326318C true CA1326318C (fr)	1994-01-18

Family

ID=25672219

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000616125A Expired - Fee Related CA1326318C (fr)	1987-12-28	1991-07-22	Melanges de polyesters extrudables contenant un stabilisant phosphate/epoxy

Country Status (1)

Country	Link
CA (1)	CA1326318C (fr)

1991
- 1991-07-22 CA CA000616125A patent/CA1326318C/fr not_active Expired - Fee Related

Legal Events

Date	Code	Title	Description
1996-07-20	MKLA	Lapsed

Publication	Publication Date	Title
US4786692A (en)	1988-11-22	High strength, reduced heat distortion temperature thermoplastic composition
CA1235833A (fr)	1988-04-26	Melange thermoplastique a base de resine, et sa preparation
EP0021979B1 (fr)	1984-10-31	Mélanges de polyarylates avec des copolyesters
EP0055472B1 (fr)	1985-11-21	Compositions de polyarylate ayant une stabilité hydrolytique
CA2130907A1 (fr)	1993-09-16	Melanges de polyester/polycarbonate, en plusieurs constituants, resistant mieux aux chocs et plus facilement transformables
CA1148685A (fr)	1983-06-21	Melanges de polyarylate avec des copolyesters
US3891719A (en)	1975-06-24	Thermoplastic moulding compositions of a polycarbonate and a graft copolymer of styrene and acrylonitrile on an acrylic acid ester polymer
KR100238505B1 (ko)	2000-01-15	고 충격 폴리에스테르/에틸렌 코폴리머 블렌드
JPS63213554A (ja)	1988-09-06	改良された色特性を示すポリカーボネート樹脂とポリエステル樹脂のブレンド
JPH02380B2 (fr)	1990-01-08
EP0111810A2 (fr)	1984-06-27	Composition thermoplastique à haute performance, déformable à température réduite
JPH0395257A (ja)	1991-04-19	難燃性ポリエステル樹脂組成物
CA1272538A (fr)	1990-08-07	Compositions de polyester modifie
EP0107048A1 (fr)	1984-05-02	Compositions de polycarbonate et de poly(téréphtalate d'éthylène) modifiées par des résines acryliques
AU617734B2 (en)	1991-12-05	Phosphate/epoxy stabilizer for extrudable polyester blends
US4628074A (en)	1986-12-09	Polycarbonate compositions
CA2074961A1 (fr)	1993-02-01	Melanges polycarbonate-polyester resistant aux solvants, a resistance a l'impact amelioree
JPH01234459A (ja)	1989-09-19	ポリブチレンテレフタレートおよび臭素化ポリスチレンを有するポリマー混合物
NL8900910A (nl)	1990-11-01	Polymeermengsel met polybutyleentereftalaat en thermoplastisch elastomeer; daaruit gevormde voorwerpen.
EP0248352A2 (fr)	1987-12-09	Compositions résilientes à base de polyester et leur procédé de préparation
EP0321126B1 (fr)	1994-03-16	Système stabilisant pour des compositions à base de polyester aptes à l'extrusion
KR0149450B1 (ko)	1998-10-15	난연성 수지조성물
EP0384460A1 (fr)	1990-08-29	Composition de résine thermoplastique
AU608927B2 (en)	1991-04-18	Stabilizer system for extrudable polyester blends
JP2007514859A (ja)	2007-06-07	ポリエステル成形組成物