CA1326432C - Emulsions visqueuses hydrocarbures dans l'eau - Google Patents

Emulsions visqueuses hydrocarbures dans l'eau

Info

Publication number: CA1326432C
Authority: CA; Canada
Prior art keywords: hydrocarbon; emulsion; water; water emulsion; surfactant
Prior art date: 1987-09-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000616589A

Other languages

English (en)

Inventor

Ignacio A. Layrisse R.

Domingo Rodriguez Polanco

Hercilio Rivas

Euler Jimenez G.

Lirio Quintero

Jose Salazar P.

Mayela Rivero

Antonio Cardenas

Maria Luisa Chirinos

Daysi Rojas

Humberto Marquez

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Petroleos de Venezuela SA

Original Assignee

Petroleos de Venezuela SA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-09-11

Filing date

1993-01-28

Publication date

1994-01-25

1987-09-11 Priority claimed from US07/096,643 external-priority patent/US4795478A/en

1993-01-28 Application filed by Petroleos de Venezuela SA filed Critical Petroleos de Venezuela SA

1993-01-28 Priority to CA000616589A priority Critical patent/CA1326432C/fr

1994-01-25 Application granted granted Critical

1994-01-25 Publication of CA1326432C publication Critical patent/CA1326432C/fr

2008-08-15 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000839 emulsion Substances 0.000 title claims abstract description 198
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 106
229930195733 hydrocarbon Natural products 0.000 claims abstract description 36
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 36
239000004094 surface-active agent Substances 0.000 claims abstract description 30
239000002736 nonionic surfactant Substances 0.000 claims abstract description 28
239000000203 mixture Substances 0.000 claims abstract description 19
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 16
-1 ethoxylated alkyl phenols Chemical class 0.000 claims abstract description 16
150000001298 alcohols Chemical class 0.000 claims abstract description 8
239000003513 alkali Substances 0.000 claims abstract description 8
229910021529 ammonia Inorganic materials 0.000 claims abstract description 8
JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims abstract description 7
150000004679 hydroxides Chemical class 0.000 claims abstract description 4
239000000654 additive Substances 0.000 claims description 37
239000004215 Carbon black (E152) Substances 0.000 claims description 28
230000000996 additive effect Effects 0.000 claims description 26
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 17
239000005864 Sulphur Substances 0.000 claims description 16
229920000642 polymer Polymers 0.000 claims description 3
230000001804 emulsifying effect Effects 0.000 claims 3
239000002994 raw material Substances 0.000 abstract description 2
239000003995 emulsifying agent Substances 0.000 description 34
150000003839 salts Chemical class 0.000 description 27
238000002485 combustion reaction Methods 0.000 description 26
230000015572 biosynthetic process Effects 0.000 description 21
238000007872 degassing Methods 0.000 description 21
239000003921 oil Substances 0.000 description 21
238000000034 method Methods 0.000 description 17
230000003068 static effect Effects 0.000 description 14
239000000446 fuel Substances 0.000 description 12
238000004519 manufacturing process Methods 0.000 description 12
230000008569 process Effects 0.000 description 12
239000008186 active pharmaceutical agent Substances 0.000 description 9
238000007792 addition Methods 0.000 description 9
230000000694 effects Effects 0.000 description 9
230000005484 gravity Effects 0.000 description 9
239000011777 magnesium Substances 0.000 description 9
239000000463 material Substances 0.000 description 9
238000012545 processing Methods 0.000 description 9
238000000926 separation method Methods 0.000 description 9
230000001143 conditioned effect Effects 0.000 description 8
239000008398 formation water Substances 0.000 description 8
238000005260 corrosion Methods 0.000 description 7
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 7
239000010426 asphalt Substances 0.000 description 6
230000007797 corrosion Effects 0.000 description 6
239000010779 crude oil Substances 0.000 description 6
238000012360 testing method Methods 0.000 description 6
239000002956 ash Substances 0.000 description 5
239000007789 gas Substances 0.000 description 5
239000012071 phase Substances 0.000 description 5
238000005086 pumping Methods 0.000 description 5
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
229910017974 NH40H Inorganic materials 0.000 description 4
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
229920001222 biopolymer Polymers 0.000 description 4
239000011575 calcium Substances 0.000 description 4
230000003750 conditioning effect Effects 0.000 description 4
239000003085 diluting agent Substances 0.000 description 4
239000011734 sodium Substances 0.000 description 4
239000000243 solution Substances 0.000 description 4
239000011345 viscous material Substances 0.000 description 4
235000002918 Fraxinus excelsior Nutrition 0.000 description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
230000007423 decrease Effects 0.000 description 3
229910052749 magnesium Inorganic materials 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
230000009467 reduction Effects 0.000 description 3
238000002407 reforming Methods 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Inorganic materials O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 3
238000011144 upstream manufacturing Methods 0.000 description 3
229910052720 vanadium Inorganic materials 0.000 description 3
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
230000002411 adverse Effects 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
238000000889 atomisation Methods 0.000 description 2
230000008901 benefit Effects 0.000 description 2
239000003876 biosurfactant Substances 0.000 description 2
125000002091 cationic group Chemical group 0.000 description 2
238000000855 fermentation Methods 0.000 description 2
230000004151 fermentation Effects 0.000 description 2
239000003546 flue gas Substances 0.000 description 2
239000002803 fossil fuel Substances 0.000 description 2
239000010763 heavy fuel oil Substances 0.000 description 2
239000003112 inhibitor Substances 0.000 description 2
239000002563 ionic surfactant Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000010747 number 6 fuel oil Substances 0.000 description 2
239000002245 particle Substances 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
238000007670 refining Methods 0.000 description 2
238000009877 rendering Methods 0.000 description 2
239000011780 sodium chloride Substances 0.000 description 2
150000004763 sulfides Chemical class 0.000 description 2
150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 2
239000007762 w/o emulsion Substances 0.000 description 2
229920001285 xanthan gum Polymers 0.000 description 2
241000589291 Acinetobacter Species 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
102000001183 RAG-1 Human genes 0.000 description 1
108060006897 RAG1 Proteins 0.000 description 1
CVBNMWXECPZOLM-UHFFFAOYSA-N Rhamnetin Natural products COc1cc(O)c2C(=O)C(=C(Oc2c1)c3ccc(O)c(O)c3O)O CVBNMWXECPZOLM-UHFFFAOYSA-N 0.000 description 1
238000010793 Steam injection (oil industry) Methods 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
238000003915 air pollution Methods 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
239000002585 base Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
239000001913 cellulose Chemical class 0.000 description 1
229920002678 cellulose Chemical class 0.000 description 1
230000008859 change Effects 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000010276 construction Methods 0.000 description 1
238000013461 design Methods 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
150000004676 glycans Chemical class 0.000 description 1
230000003993 interaction Effects 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
QENHCSSJTJWZAL-UHFFFAOYSA-N magnesium sulfide Chemical compound [Mg+2].[S-2] QENHCSSJTJWZAL-UHFFFAOYSA-N 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
238000005065 mining Methods 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
239000007764 o/w emulsion Substances 0.000 description 1
229920002401 polyacrylamide Chemical class 0.000 description 1
229920001282 polysaccharide Polymers 0.000 description 1
239000005017 polysaccharide Substances 0.000 description 1
DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
238000004064 recycling Methods 0.000 description 1
239000002893 slag Substances 0.000 description 1
238000002791 soaking Methods 0.000 description 1
229910052979 sodium sulfide Inorganic materials 0.000 description 1
GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
238000013112 stability test Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
235000011149 sulphuric acid Nutrition 0.000 description 1
239000001117 sulphuric acid Substances 0.000 description 1
239000013008 thixotropic agent Substances 0.000 description 1
238000012546 transfer Methods 0.000 description 1
239000002699 waste material Substances 0.000 description 1
239000000230 xanthan gum Substances 0.000 description 1
229940082509 xanthan gum Drugs 0.000 description 1
235000010493 xanthan gum Nutrition 0.000 description 1

Landscapes

Liquid Carbonaceous Fuels (AREA)

CA000616589A 1987-09-11 1993-01-28 Emulsions visqueuses hydrocarbures dans l'eau Expired - Lifetime CA1326432C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000616589A CA1326432C (fr)	1987-09-11	1993-01-28	Emulsions visqueuses hydrocarbures dans l'eau

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US096,643		1979-11-23
US07/096,643 US4795478A (en)	1986-06-17	1987-09-11	Viscous hydrocarbon-in-water emulsions
CA000574768A CA1318216C (fr)	1987-09-11	1988-08-15	Emulsions hydrocarbure - eau visqueuses
CA000616589A CA1326432C (fr)	1987-09-11	1993-01-28	Emulsions visqueuses hydrocarbures dans l'eau

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000574768A Division CA1318216C (fr)	1987-09-11	1988-08-15	Emulsions hydrocarbure - eau visqueuses

Publications (1)

Publication Number	Publication Date
CA1326432C true CA1326432C (fr)	1994-01-25

Family

ID=25672054

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000616589A Expired - Lifetime CA1326432C (fr)	1987-09-11	1993-01-28	Emulsions visqueuses hydrocarbures dans l'eau

Country Status (1)

Country	Link
CA (1)	CA1326432C (fr)

1993
- 1993-01-28 CA CA000616589A patent/CA1326432C/fr not_active Expired - Lifetime

Legal Events

Date	Code	Title	Description
2011-01-25	MKLA	Lapsed
2012-12-05	MKEC	Expiry (correction)	Effective date: 20121205

Publication	Publication Date	Title
US4795478A (en)	1989-01-03	Viscous hydrocarbon-in-water emulsions
US4923483A (en)	1990-05-08	Viscous hydrocarbon-in-water emulsions
US4801304A (en)	1989-01-31	Process for the production and burning of a natural-emulsified liquid fuel
US5556574A (en)	1996-09-17	Emulsion of viscous hydrocarbon in aqueous buffer solution and method for preparing same
US4886519A (en)	1989-12-12	Method for reducing sox emissions during the combustion of sulfur-containing combustible compositions
Salager et al.	2001	Heavy hydrocarbon emulsions
EP0582762A1 (fr)	1994-02-16	Procédé de préparation d'une émulsion continue aqueuse à partir d'une fraction lourde de brut
JPH086107B2 (ja)	1996-01-24	予め細霧化された燃料を利用する放出物の低減方法
US4824439A (en)	1989-04-25	Inflame desulfurization and denoxification of high sulfur containing fuels
US4834775A (en)	1989-05-30	Process for controlling sulfur-oxide formation and emissions when burning a combustible fuel formed as a hydrocarbon in water emulsion
CA1326432C (fr)	1994-01-25	Emulsions visqueuses hydrocarbures dans l'eau
EP0363300A1 (fr)	1990-04-11	Procédé de préparation d'une émulsion d'huile en phase aqueuse
US4994090A (en)	1991-02-19	Process for controlling sulfur-oxide formation and emissions when burning a combustible fuel formed as a hydrocarbon in water emulsion
WO2010086619A1 (fr)	2010-08-05	Compositions de combustible comprenant des émulsions de gaz dans l'huile dans l'eau et leurs procédés de fabrication
JP2892155B2 (ja)	1999-05-17	硫黄含有可燃性組成の燃焼中における酸化硫黄化合物放出の抑制方法
GB2231060A (en)	1990-11-07	Hydrocarbon-in-water-emulsions
KR900005084B1 (ko)	1990-07-19	점성 수중(水中)탄화수소 에멀젼
KR900004547B1 (ko)	1990-06-29	천연유화 액체연료의 제조 및 연소방법
KR900004506B1 (ko)	1990-06-28	물중의 탄화수소 에멀젼으로서 형성된 가연성 연료 연소시 형성 및 배출되는 황 산화물 조절방법
US20130227877A1 (en)	2013-09-05	Three-phase emulsified fuel and methods of preparation and use
CA1333331C (fr)	1994-12-06	Procede limitant la formation et les emissions de dioxyde de soufre lors de la combustion d'un combustible de type hydrocarbure en emulsion aqueuse
DK174722B1 (da)	2003-10-06	Viskøse hydrocarbon-i-vand emulsioner
JPH0247194A (ja)	1990-02-16	粘性炭化水素／水乳濁液
GB2246142A (en)	1992-01-22	Hydrocarbon in oil emulsion formation and emissions when burning