CA1330476C - Methods and compositions to enhance stain resistance of carpet fibers - Google Patents
Methods and compositions to enhance stain resistance of carpet fibersInfo
- Publication number
- CA1330476C CA1330476C CA000578108A CA578108A CA1330476C CA 1330476 C CA1330476 C CA 1330476C CA 000578108 A CA000578108 A CA 000578108A CA 578108 A CA578108 A CA 578108A CA 1330476 C CA1330476 C CA 1330476C
- Authority
- CA
- Canada
- Prior art keywords
- carpet
- fiber
- effective amount
- fabric
- sulfonated aromatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 146
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- 239000000203 mixture Substances 0.000 title claims abstract description 126
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- 125000003118 aryl group Chemical group 0.000 claims abstract description 97
- 238000004383 yellowing Methods 0.000 claims abstract description 50
- 150000003839 salts Chemical class 0.000 claims abstract description 31
- 239000002270 dispersing agent Substances 0.000 claims abstract description 28
- 239000003352 sequestering agent Substances 0.000 claims abstract description 27
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- 238000007254 oxidation reaction Methods 0.000 claims abstract description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 103
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- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical group [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 claims description 54
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims description 44
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims description 44
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- 238000010186 staining Methods 0.000 claims description 25
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- FEPBITJSIHRMRT-UHFFFAOYSA-N 4-hydroxybenzenesulfonic acid Chemical compound OC1=CC=C(S(O)(=O)=O)C=C1 FEPBITJSIHRMRT-UHFFFAOYSA-N 0.000 claims description 6
- 239000013078 crystal Substances 0.000 claims description 4
- 210000002268 wool Anatomy 0.000 claims description 3
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- 159000000000 sodium salts Chemical class 0.000 description 8
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- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
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- 239000003599 detergent Substances 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
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- 229910052700 potassium Inorganic materials 0.000 description 6
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- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 6
- 229910052725 zinc Inorganic materials 0.000 description 6
- NNARPPSIYMCXMB-UHFFFAOYSA-N 1,4-bis(2-methylpropoxy)-1,4-dioxobutane-2-sulfonic acid Chemical compound CC(C)COC(=O)CC(S(O)(=O)=O)C(=O)OCC(C)C NNARPPSIYMCXMB-UHFFFAOYSA-N 0.000 description 5
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 5
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- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 1
- NTWXWSVUSTYPJH-UHFFFAOYSA-M sodium;1,4-bis(2-methylpropoxy)-1,4-dioxobutane-2-sulfonate Chemical compound [Na+].CC(C)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(C)C NTWXWSVUSTYPJH-UHFFFAOYSA-M 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000004347 surface barrier Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 235000016804 zinc Nutrition 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/41—Phenol-aldehyde or phenol-ketone resins
- D06M15/412—Phenol-aldehyde or phenol-ketone resins sulfonated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Coloring (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Carpets (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10165287A | 1987-09-28 | 1987-09-28 | |
| US101,652 | 1987-09-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1330476C true CA1330476C (en) | 1994-07-05 |
Family
ID=22285740
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000578108A Expired - Fee Related CA1330476C (en) | 1987-09-28 | 1988-09-22 | Methods and compositions to enhance stain resistance of carpet fibers |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0382724B1 (de) |
| JP (1) | JPH03500307A (de) |
| AT (1) | ATE118837T1 (de) |
| CA (1) | CA1330476C (de) |
| DE (1) | DE3853165T2 (de) |
| WO (1) | WO1989002949A1 (de) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5135774A (en) * | 1990-03-27 | 1992-08-04 | Allied-Signal Inc. | Method to impart coffee stain resistance to polyamide fibers |
| US5118551A (en) * | 1990-03-27 | 1992-06-02 | Allied-Signal Inc. | Method to impart stain resistance to polyamide textile substrates |
| US5670246A (en) * | 1995-09-22 | 1997-09-23 | E. I. Du Pont De Nemours And Company | Treatment of polyamide materials with partial fluoroesters or fluorothioesters of maleic acid polymers and sulfonated aromatic condensates |
| US6852134B2 (en) | 1999-07-08 | 2005-02-08 | Invista North America S.A.R.L. | Method of imparting stain resistance to a differentially dyeable textile surface and the article produced thereby |
| US7491805B2 (en) | 2001-05-18 | 2009-02-17 | Sirna Therapeutics, Inc. | Conjugates and compositions for cellular delivery |
| US6811574B2 (en) | 2000-07-03 | 2004-11-02 | Dupont Textiles & Interiors, Inc. | Method of after-treatment of a dyeable nylon textile surface with a stain resist and the article produced thereby |
| US6814758B1 (en) * | 2001-04-26 | 2004-11-09 | Simco Holding Corporation | Process for protecting dyed nylon fibers from colorants and chemical agents |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3039981A (en) * | 1955-12-27 | 1962-06-19 | Owens Corning Fiberglass Corp | Aqueous binder composition of phenolformaldehyde condensate, aluminum sulfate and mineral oil, and glass fiber coated therewith |
| BE759823A (fr) * | 1969-12-03 | 1971-05-17 | Bayer Ag | Agents ameliorant la solidite au mouille |
| CA1264505A (en) * | 1986-02-14 | 1990-01-23 | E.I. Du Pont De Nemours And Company | Method for producing stain resistant polyamide fibers |
| DE3683151D1 (de) * | 1986-03-06 | 1992-02-06 | Monsanto Co | Fleckenabweisende nylonfasern. |
-
1988
- 1988-04-06 AT AT88904055T patent/ATE118837T1/de not_active IP Right Cessation
- 1988-04-06 DE DE3853165T patent/DE3853165T2/de not_active Expired - Fee Related
- 1988-04-06 EP EP88904055A patent/EP0382724B1/de not_active Expired - Lifetime
- 1988-04-06 WO PCT/US1988/001112 patent/WO1989002949A1/en not_active Ceased
- 1988-04-06 JP JP63503627A patent/JPH03500307A/ja active Pending
- 1988-09-22 CA CA000578108A patent/CA1330476C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0382724A1 (de) | 1990-08-22 |
| DE3853165D1 (de) | 1995-03-30 |
| EP0382724B1 (de) | 1995-02-22 |
| DE3853165T2 (de) | 1995-07-27 |
| ATE118837T1 (de) | 1995-03-15 |
| JPH03500307A (ja) | 1991-01-24 |
| WO1989002949A1 (en) | 1989-04-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |