CA1333622C - Composition de verre fritte exempt de plomb - Google Patents

Composition de verre fritte exempt de plomb

Info

Publication number: CA1333622C
Authority: CA; Canada
Prior art keywords: zro2; tio2; composition; alkali metal; lead
Prior art date: 1988-06-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000602278A

Other languages

English (en)

Inventor

Barry P. Reinherz

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Vibrantz GmbH

Original Assignee

Ciba Geigy AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-06-13

Filing date

1989-06-09

Publication date

1994-12-20

1989-06-09 Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG

1994-12-20 Application granted granted Critical

1994-12-20 Publication of CA1333622C publication Critical patent/CA1333622C/fr

2011-12-20 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000011521 glass Substances 0.000 title claims abstract description 34
239000000203 mixture Substances 0.000 title claims abstract description 27
MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 31
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 28
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(iii) oxide Chemical compound O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 claims description 12
239000000377 silicon dioxide Substances 0.000 claims description 11
229910000272 alkali metal oxide Inorganic materials 0.000 claims description 10
229910052681 coesite Inorganic materials 0.000 claims description 10
229910052906 cristobalite Inorganic materials 0.000 claims description 10
235000012239 silicon dioxide Nutrition 0.000 claims description 10
229910052682 stishovite Inorganic materials 0.000 claims description 10
229910052905 tridymite Inorganic materials 0.000 claims description 10
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 8
229910011255 B2O3 Inorganic materials 0.000 claims description 7
FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical class [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 7
QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 6
JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 5
XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims description 4
238000002844 melting Methods 0.000 claims description 4
230000008018 melting Effects 0.000 claims description 4
239000002994 raw material Substances 0.000 claims description 3
229910000421 cerium(III) oxide Inorganic materials 0.000 claims 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
229910001947 lithium oxide Inorganic materials 0.000 claims 1
238000004519 manufacturing process Methods 0.000 claims 1
239000011591 potassium Substances 0.000 claims 1
229910001950 potassium oxide Inorganic materials 0.000 claims 1
239000011734 sodium Substances 0.000 claims 1
229910001948 sodium oxide Inorganic materials 0.000 claims 1
238000000576 coating method Methods 0.000 abstract description 25
229910052783 alkali metal Inorganic materials 0.000 abstract 1
239000011248 coating agent Substances 0.000 description 15
210000003298 dental enamel Anatomy 0.000 description 14
238000000034 method Methods 0.000 description 12
238000012360 testing method Methods 0.000 description 11
239000000049 pigment Substances 0.000 description 10
238000005034 decoration Methods 0.000 description 8
229910052793 cadmium Inorganic materials 0.000 description 7
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 7
239000000919 ceramic Substances 0.000 description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
239000003599 detergent Substances 0.000 description 6
238000010304 firing Methods 0.000 description 6
238000009472 formulation Methods 0.000 description 6
239000000463 material Substances 0.000 description 6
229910052573 porcelain Inorganic materials 0.000 description 6
230000035882 stress Effects 0.000 description 5
239000002253 acid Substances 0.000 description 4
239000003086 colorant Substances 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
239000010665 pine oil Substances 0.000 description 3
NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 description 3
239000000843 powder Substances 0.000 description 3
238000007650 screen-printing Methods 0.000 description 3
239000000126 substance Substances 0.000 description 3
239000000758 substrate Substances 0.000 description 3
230000002411 adverse Effects 0.000 description 2
239000003513 alkali Substances 0.000 description 2
FRLJSGOEGLARCA-UHFFFAOYSA-N cadmium sulfide Chemical class [S-2].[Cd+2] FRLJSGOEGLARCA-UHFFFAOYSA-N 0.000 description 2
238000007598 dipping method Methods 0.000 description 2
238000011156 evaluation Methods 0.000 description 2
239000002241 glass-ceramic Substances 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
239000003605 opacifier Substances 0.000 description 2
229910001404 rare earth metal oxide Inorganic materials 0.000 description 2
239000002002 slurry Substances 0.000 description 2
239000005361 soda-lime glass Substances 0.000 description 2
230000008646 thermal stress Effects 0.000 description 2
230000003313 weakening effect Effects 0.000 description 2
229910001018 Cast iron Inorganic materials 0.000 description 1
BKQMNPVDJIHLPD-UHFFFAOYSA-N OS(=O)(=O)[Se]S(O)(=O)=O Chemical class OS(=O)(=O)[Se]S(O)(=O)=O BKQMNPVDJIHLPD-UHFFFAOYSA-N 0.000 description 1
238000003853 Pinholing Methods 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
238000007792 addition Methods 0.000 description 1
239000000654 additive Substances 0.000 description 1
QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
229910000416 bismuth oxide Inorganic materials 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000007906 compression Methods 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
PGWFQHBXMJMAPN-UHFFFAOYSA-N ctk4b5078 Chemical class [Cd].OS(=O)(=O)[Se]S(O)(=O)=O PGWFQHBXMJMAPN-UHFFFAOYSA-N 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
238000004534 enameling Methods 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
239000005357 flat glass Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
235000011389 fruit/vegetable juice Nutrition 0.000 description 1
238000000227 grinding Methods 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
230000019612 pigmentation Effects 0.000 description 1
238000007639 printing Methods 0.000 description 1
238000006722 reduction reaction Methods 0.000 description 1
238000006748 scratching Methods 0.000 description 1
230000002393 scratching effect Effects 0.000 description 1
HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000010998 test method Methods 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
230000002110 toxicologic effect Effects 0.000 description 1
231100000759 toxicological effect Toxicity 0.000 description 1
239000000037 vitreous enamel Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Geochemistry & Mineralogy (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Glass Compositions (AREA)

CA000602278A 1988-06-13 1989-06-09 Composition de verre fritte exempt de plomb Expired - Fee Related CA1333622C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US07/206,250 US4892847A (en)	1988-06-13	1988-06-13	Lead-free glass frit compositions
US206,250		1988-06-13

Publications (1)

Publication Number	Publication Date
CA1333622C true CA1333622C (fr)	1994-12-20

Family

ID=22765576

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000602278A Expired - Fee Related CA1333622C (fr)	1988-06-13	1989-06-09	Composition de verre fritte exempt de plomb

Country Status (7)

Country	Link
US (1)	US4892847A (fr)
EP (1)	EP0347379B1 (fr)
JP (1)	JP2707527B2 (fr)
KR (1)	KR960015146B1 (fr)
CA (1)	CA1333622C (fr)
DE (1)	DE58904863D1 (fr)
MX (1)	MX16410A (fr)

Families Citing this family (54)

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US5203902A (en) *	1988-11-19	1993-04-20	Johnson Matthey Public Limited Company	Glass composition for use in glazes or enamels
ZW13689A1 (en) *	1988-11-19	1989-12-12	Johnson Matthey Plc	Glass composition for use in glazes or enamels
US5350718A (en) *	1991-03-25	1994-09-27	Degussa Aktiengesellschaft	Glass frits, a process for their production and their use in enamel barrier layers for stopping the migration of silver
ATE129222T1 (de) *	1991-06-14	1995-11-15	Cookson Group Plc	Glaszusammensetzungen.
FR2687997B1 (fr) *	1992-03-02	1996-07-05	Degussa Prod Ceramiques	Frittes de verre contenant du zinc, exemptes de plomb et de cadmium - procede de fabrication et utilisation.
US5204291A (en) *	1992-04-17	1993-04-20	Corning Incorporated	Transparent lead-free glazes
ES2110570T3 (es) *	1992-07-01	1998-02-16	Proceram	Composiciones y articulos ceramicos vitreos transparentes y exentos de plomo.
US5306674A (en) *	1992-09-04	1994-04-26	Ferro Corporation	Lead-free glass coatings
US5252521A (en) *	1992-10-19	1993-10-12	Ferro Corporation	Bismuth-containing lead-free glass enamels and glazes of low silica content
US5378408A (en) *	1993-07-29	1995-01-03	E. I. Du Pont De Nemours And Company	Lead-free thick film paste composition
GB9319971D0 (en) *	1993-09-28	1993-11-17	Cookson Group Plc	Cobalt glass compositions for coatings
FR2712881B1 (fr) *	1993-11-25	1996-05-15	Cerdec France Sa	Composition de frittes de verre exempte de plomb et de cadmium, en particulier pour la fabrication d'émaux pour l'émaillage des pare-brise et/ou toits panoramiques.
GB9401818D0 (en) *	1994-01-31	1994-03-23	Cookson Group Plc	Glass compositions
US5725919A (en) *	1994-03-16	1998-03-10	Ferro Corporation	Lead-free glass enamels for decorating glass beverage containers and methods for using the same
US5439852A (en) *	1994-08-01	1995-08-08	E. I. Du Pont De Nemours And Company	Cadmium-free and lead-free thick film conductor composition
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US5647901A (en) *	1994-12-14	1997-07-15	Cerdec Corporation	High loading, low viscosity medium for ceramic coating composition
US5559059A (en) *	1995-05-22	1996-09-24	Cerdec Corporation	Lead-free glass frits for ceramics enamels
US5714420A (en)	1995-12-08	1998-02-03	Cerdec Corporation - Drakenfeld Products	Partially crystallizing ceramic enamel composition containing bismuth silicate, and use thereof
US5629247A (en) *	1996-05-08	1997-05-13	The O'hommel Company	High bismuth oxide based flux and paint compositions for glass substrates
DE19744803C1 (de) *	1997-10-10	1999-01-28	Heraeus Gmbh W C	Kobalthaltige keramische Dekorfarbe und ihre Verwendung
US5998037A (en) *	1997-12-22	1999-12-07	Ferro Corporation	Porcelain enamel composition for electronic applications
US6171987B1 (en)	1997-12-29	2001-01-09	Ben-Gurion University Of The Negev	Cadmium-free and lead-free glass compositions, thick film formulations containing them and uses thereof
US6360562B1 (en) *	1998-02-24	2002-03-26	Superior Micropowders Llc	Methods for producing glass powders
DE19921925A1 (de) *	1999-05-12	2000-11-16	Dmc2 Degussa Metals Catalysts	Verfahren zur Dekoration fester Materialien
EP1138641A1 (fr) *	2000-03-30	2001-10-04	Schott Glas	Verres de silicate sans plomb contenant du bismuth et leurs utilisations
JP2002020186A (ja) *	2000-06-29	2002-01-23	Noritake Co Ltd	イングレーズ絵付け盛装飾陶磁器及び転写紙
US7507453B2 (en) *	2000-10-31	2009-03-24	International Imaging Materials, Inc	Digital decoration and marking of glass and ceramic substrates
KR20030010415A (ko) *	2001-07-27	2003-02-05	학교법인대우학원	무연 무알칼리 저융점 유리
US6936556B2 (en) *	2002-05-15	2005-08-30	Ferro Corporation	Durable glass enamel composition
US7740899B2 (en) *	2002-05-15	2010-06-22	Ferro Corporation	Electronic device having lead and cadmium free electronic overglaze applied thereto
US7030048B2 (en) *	2003-08-05	2006-04-18	E. I. Du Pont De Nemours And Company	Thick film dielectric compositions for use on aluminum nitride substrates
US7138347B2 (en) *	2003-08-14	2006-11-21	E. I. Du Pont De Nemours And Company	Thick-film conductor paste for automotive glass
JP4453355B2 (ja) *	2003-12-12	2010-04-21	旭硝子株式会社	導体付き車両用窓ガラスおよびその製造方法
CN100368330C (zh) *	2005-06-21	2008-02-13	沈阳工业大学	一种高温钛合金的表面防护方法
CN1298794C (zh) *	2005-06-21	2007-02-07	沈阳工业大学	一种电泳涂覆用搪瓷粉料及其制备
RU2302387C1 (ru) *	2005-11-24	2007-07-10	Институт химии и технологии редких элементов и минерального сырья им. И.В. Тананаева Кольского научного центра Российской академии наук	Глазурь
US20090131239A1 (en) *	2006-03-03	2009-05-21	Tsuyoshi Kotake	Base glass composition for graded-refractive-index rod lens and graded-refractive-index rod lens produced from the same
WO2007116511A1 (fr) *	2006-04-07	2007-10-18	Hitachi Plasma Display Limited	Panneau d'affichage plasma
US7560401B2 (en) *	2007-04-20	2009-07-14	Johnson Matthey Public Limited Company	Frits and obscuration enamels for automotive applications
JP5309629B2 (ja) *	2008-03-13	2013-10-09	セントラル硝子株式会社	耐酸性を有する無鉛ガラス組成物
ES2658167T3 (es) *	2009-06-19	2018-03-08	Ferro Corporation	Fritas y pigmentos rojos de cobre
ES2360781B1 (es)	2009-11-13	2012-05-25	Vidres S.A.	Composición y procedimiento para la obtención de materiales para el recubrimiento de cuerpos cerámicos y los artículos así obtenidos.
US8772189B2 (en)	2011-05-04	2014-07-08	Ferro Corporation	Glass frit compositions for enamels
KR20140134565A (ko)	2013-05-14	2014-11-24	삼성디스플레이 주식회사	표시 장치 및 그 제조 방법
KR102078356B1 (ko)	2013-05-16	2020-04-08	삼성디스플레이 주식회사	유기 발광 표시 장치 및 그 제조 방법
US9340449B1 (en)	2014-11-03	2016-05-17	Nazim Muhammad	Ceramic frits incorporating CRT glass
CN105016616B (zh) *	2015-07-10	2018-02-06	山东省淄博市博山长虹陶瓷装饰材料厂	高抗蚀无铅无镉钢化玻璃颜料熔剂
KR102059804B1 (ko)	2015-08-05	2019-12-27	페로 코포레이션	고유전 상수-k ltcc 유전성 조성물 및 장치
KR101581645B1 (ko) *	2015-09-08	2016-01-04	한국세라믹기술원	태양전지 전극용 무연 도전성 조성물
CN114590999B (zh) *	2022-01-20	2023-05-05	广西科技大学	一种低熔点无铅玻璃粉及其制备方法
GB202201111D0 (en) *	2022-01-28	2022-03-16	Johnson Matthey Advanced Glass Tech B V	Inkjet printable inks for fabricating enamel coatings
US12467308B2 (en) *	2022-11-23	2025-11-11	LuxWall, Inc.	Vacuum insulated panel with tellurium oxide and/or vanadium oxide inclusive seal
CN117185660A (zh) *	2023-08-08	2023-12-08	上海宝银电子材料有限公司	一种环保耐酸遮蔽汽车后档玻璃黑釉及其制备方法

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FR627067A (fr) *	1927-01-04	1927-09-26		Procédé d'émaillage de la tôle et de la fonte, au moyen d'émaux fluoboratés à base d'oxyde de bismuth ou d'oxydes de bismuth et de zinc mélangés, exempts de tout composé de plomb
US2942992A (en) *	1957-05-03	1960-06-28	Du Pont	Vitrifiable inorganic ceramic binder and silver compositions containing same
US4084976A (en) *	1977-07-20	1978-04-18	Champion Spark Plug Company	Lead-free glaze for alumina bodies
US4312951A (en) *	1979-09-07	1982-01-26	Mobay Chemical Corporation	Low-melting, lead-free ceramic frits
US4224074A (en) *	1979-10-01	1980-09-23	Corning Glass Works	Non-toxic frits for decorating glass, glass-ceramic and ceramic articles
JPS6025379B2 (ja) *	1980-09-29	1985-06-18	日本碍子株式会社	鋼板ホ−ロ−用下釉フリツト組成物
US4340645A (en) *	1981-05-11	1982-07-20	Mobay Chemical Corporation	Leadless glazes for whiteware
US4376169A (en) *	1982-04-28	1983-03-08	Mobay Chemical Corporation	Low-melting, lead-free ceramic frits
US4446241A (en) *	1982-06-28	1984-05-01	Owens-Illinois, Inc.	Lead-free and cadmium-free glass frit compositions for glazing, enameling and decorating
US4537862A (en) *	1982-06-28	1985-08-27	Owens-Illinois, Inc.	Lead-free and cadmium-free glass frit compositions for glazing, enameling and decorating
US4554258A (en) *	1984-06-28	1985-11-19	Owens-Illinois, Inc.	Chemical resistant lead-free glass frit compositions
US4590171A (en) *	1985-05-29	1986-05-20	Corning Glass Works	Low temperature lead and cadmium-free frits

1988
- 1988-06-13 US US07/206,250 patent/US4892847A/en not_active Expired - Lifetime
1989
- 1989-06-05 EP EP89810424A patent/EP0347379B1/fr not_active Expired - Lifetime
- 1989-06-05 DE DE8989810424T patent/DE58904863D1/de not_active Expired - Lifetime
- 1989-06-09 CA CA000602278A patent/CA1333622C/fr not_active Expired - Fee Related
- 1989-06-12 MX MX1641089A patent/MX16410A/es unknown
- 1989-06-12 JP JP1146905A patent/JP2707527B2/ja not_active Expired - Lifetime
- 1989-06-12 KR KR1019890008052A patent/KR960015146B1/ko not_active Expired - Lifetime

Also Published As

Publication number	Publication date
JP2707527B2 (ja)	1998-01-28
MX16410A (es)	1994-02-28
JPH0234537A (ja)	1990-02-05
EP0347379A1 (fr)	1989-12-20
EP0347379B1 (fr)	1993-07-07
DE58904863D1 (de)	1993-08-12
KR960015146B1 (ko)	1996-11-01
US4892847A (en)	1990-01-09
KR900000306A (ko)	1990-01-30

Legal Events

Date	Code	Title	Description
2007-12-20	MKLA	Lapsed

Publication	Publication Date	Title
CA1333622C (fr)	1994-12-20	Composition de verre fritte exempt de plomb
CA1274857A (fr)	1990-10-02	Compositions pour frettes de verres sans plomb
JP4251582B2 (ja)	2009-04-08	ガラス又はガラスセラミックのつや出し、エナメル質化及び加飾用無鉛及び無カドミウムのガラス組成物
US4970178A (en)	1990-11-13	Lead-free glass frit compositions
EP0452065B1 (fr)	1994-05-25	Compositions de glaçure
CA2291502C (fr)	2008-04-08	Compositions de verres sans plomb et sans metaux alcalins
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