CA2004370C - Fibre carbone a module d'elasticite extra eleve - Google Patents

Fibre carbone a module d'elasticite extra eleve

Info

Publication number: CA2004370C
Authority: CA; Canada
Prior art keywords: pitch; fibers; fiber; carbon fiber; ohm
Prior art date: 1988-12-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA 2004370

Other languages

English (en)

Other versions

CA2004370A1 (fr

Inventor

David Arthur Schulz

Loren Carl Nelson

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BP Corp North America Inc

Original Assignee

BP Corp North America Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-12-07

Filing date

1989-12-01

Publication date

1995-11-21

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26960622&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2004370(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1989-12-01 Application filed by BP Corp North America Inc filed Critical BP Corp North America Inc

1990-06-07 Publication of CA2004370A1 publication Critical patent/CA2004370A1/fr

1995-11-21 Application granted granted Critical

1995-11-21 Publication of CA2004370C publication Critical patent/CA2004370C/fr

2009-12-01 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 93
239000004917 carbon fiber Substances 0.000 title claims abstract description 93
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 57
238000000034 method Methods 0.000 claims abstract description 36
239000000835 fiber Substances 0.000 claims description 128
239000011295 pitch Substances 0.000 claims description 89
238000010438 heat treatment Methods 0.000 claims description 41
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 18
229910017604 nitric acid Inorganic materials 0.000 claims description 18
239000011302 mesophase pitch Substances 0.000 claims description 11
238000010000 carbonizing Methods 0.000 claims description 10
239000012298 atmosphere Substances 0.000 claims description 9
238000007669 thermal treatment Methods 0.000 claims description 8
238000004804 winding Methods 0.000 claims description 7
238000002074 melt spinning Methods 0.000 claims description 6
238000011282 treatment Methods 0.000 claims description 5
239000011261 inert gas Substances 0.000 claims description 4
239000000203 mixture Substances 0.000 description 19
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 17
230000001590 oxidative effect Effects 0.000 description 15
238000009987 spinning Methods 0.000 description 15
229910002804 graphite Inorganic materials 0.000 description 14
239000010439 graphite Substances 0.000 description 14
239000002131 composite material Substances 0.000 description 10
239000007788 liquid Substances 0.000 description 9
229920002239 polyacrylonitrile Polymers 0.000 description 8
239000000463 material Substances 0.000 description 6
239000007789 gas Substances 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
239000012300 argon atmosphere Substances 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
230000006378 damage Effects 0.000 description 4
238000001035 drying Methods 0.000 description 4
238000001125 extrusion Methods 0.000 description 4
230000006698 induction Effects 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
239000002245 particle Substances 0.000 description 4
239000002243 precursor Substances 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
229920000297 Rayon Polymers 0.000 description 3
239000002253 acid Substances 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
239000006229 carbon black Substances 0.000 description 3
239000000155 melt Substances 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
230000000704 physical effect Effects 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000002964 rayon Substances 0.000 description 3
238000003860 storage Methods 0.000 description 3
RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
239000011260 aqueous acid Substances 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000011280 coal tar Substances 0.000 description 2
239000000356 contaminant Substances 0.000 description 2
238000001816 cooling Methods 0.000 description 2
238000007598 dipping method Methods 0.000 description 2
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
230000004927 fusion Effects 0.000 description 2
239000001307 helium Substances 0.000 description 2
229910052734 helium Inorganic materials 0.000 description 2
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
238000012545 processing Methods 0.000 description 2
238000004513 sizing Methods 0.000 description 2
239000002904 solvent Substances 0.000 description 2
238000005507 spraying Methods 0.000 description 2
238000004381 surface treatment Methods 0.000 description 2
239000004094 surface-active agent Substances 0.000 description 2
GCORYIZHFMJQMJ-YPKPFQOOSA-N (z)-2,2,3,3-tetramethyloctadec-9-enoic acid Chemical compound CCCCCCCC\C=C/CCCCCC(C)(C)C(C)(C)C(O)=O GCORYIZHFMJQMJ-YPKPFQOOSA-N 0.000 description 1
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
239000005639 Lauric acid Substances 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
229910003481 amorphous carbon Inorganic materials 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
238000013459 approach Methods 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
239000003575 carbonaceous material Substances 0.000 description 1
238000003763 carbonization Methods 0.000 description 1
239000000571 coke Substances 0.000 description 1
238000004939 coking Methods 0.000 description 1
229940000425 combination drug Drugs 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000007547 defect Effects 0.000 description 1
230000002950 deficient Effects 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
238000011161 development Methods 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000005265 energy consumption Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
239000002360 explosive Substances 0.000 description 1
239000003733 fiber-reinforced composite Substances 0.000 description 1
238000007380 fibre production Methods 0.000 description 1
238000005087 graphitization Methods 0.000 description 1
230000017525 heat dissipation Effects 0.000 description 1
238000007654 immersion Methods 0.000 description 1
238000013101 initial test Methods 0.000 description 1
238000011068 loading method Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000013081 microcrystal Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
239000013618 particulate matter Substances 0.000 description 1
239000003209 petroleum derivative Substances 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
238000000197 pyrolysis Methods 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
238000007789 sealing Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000010998 test method Methods 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
229920001187 thermosetting polymer Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
239000002759 woven fabric Substances 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/145—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from pitch or distillation residues

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Inorganic Fibers (AREA)

CA 2004370 1988-12-07 1989-12-01 Fibre carbone a module d'elasticite extra eleve Expired - Lifetime CA2004370C (fr)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date
US28094288A	1988-12-07	1988-12-07
US280,942		1988-12-07
US32440189A	1989-03-15	1989-03-15
US324,401		1989-03-15

Publications (2)

Publication Number	Publication Date
CA2004370A1 CA2004370A1 (fr)	1990-06-07
CA2004370C true CA2004370C (fr)	1995-11-21

Family

ID=26960622

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2004370 Expired - Lifetime CA2004370C (fr)	1988-12-07	1989-12-01	Fibre carbone a module d'elasticite extra eleve

Country Status (5)

Country	Link
EP (1)	EP0372931B1 (fr)
JP (1)	JP2769889B2 (fr)
CA (1)	CA2004370C (fr)
DE (1)	DE68922591T2 (fr)
HK (1)	HK1007176A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5169616A (en) *	1990-12-28	1992-12-08	E. I. Du Pont De Nemours And Company	High thermal conductivity carbon fibers
JP3125062B2 (ja) *	1993-02-24	2001-01-15	株式会社ペトカ	炭素繊維の製造方法
CA2124158C (fr) *	1993-06-14	2005-09-13	Daniel H. Hecht	Articles en carbone et graphite a module eleve et methode de fabrication
JP4772239B2 (ja)	2001-10-02	2011-09-14	ポリマテック株式会社	黒鉛化炭素粉末及び熱伝導性複合材料組成物
US7947362B2 (en)	2006-04-27	2011-05-24	Teijin Limited	Carbon fiber composite sheet
US7749479B2 (en)	2006-11-22	2010-07-06	Hexcel Corporation	Carbon fibers having improved strength and modulus and an associated method and apparatus for preparing same
JP6133091B2 (ja) *	2013-03-22	2017-05-24	株式会社クラレ	ピッチ系炭素繊維およびその製造方法
KR102109019B1 (ko) *	2019-12-26	2020-05-12	이성만	발열원단

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1055664A (fr) *	1974-12-24	1979-06-05	Union Carbide Corporation	Thermodurcissement rapide de fibres carbonees provenant de bitume a l'etat mesophase
US4351816A (en) *	1980-12-17	1982-09-28	Union Carbide Corporation	Method for producing a mesophase pitch derived carbon yarn and fiber
CA1219410A (fr) *	1982-09-27	1987-03-24	David A. Schulz	Amelioration des caracteristiques des fibres de carbone
CA1239512A (fr) *	1984-04-30	1988-07-26	Loren C. Nelson	Fibres de carbone, et leur production

1989
- 1989-12-01 CA CA 2004370 patent/CA2004370C/fr not_active Expired - Lifetime
- 1989-12-06 DE DE1989622591 patent/DE68922591T2/de not_active Expired - Lifetime
- 1989-12-06 EP EP19890312718 patent/EP0372931B1/fr not_active Expired - Lifetime
- 1989-12-06 JP JP1315512A patent/JP2769889B2/ja not_active Expired - Lifetime
1998
- 1998-06-24 HK HK98106400A patent/HK1007176A1/en not_active IP Right Cessation

Also Published As

Publication number	Publication date
JPH02242919A (ja)	1990-09-27
HK1007176A1 (en)	1999-04-01
JP2769889B2 (ja)	1998-06-25
DE68922591D1 (de)	1995-06-14
EP0372931A3 (fr)	1991-11-06
CA2004370A1 (fr)	1990-06-07
EP0372931A2 (fr)	1990-06-13
DE68922591T2 (de)	1995-09-28
EP0372931B1 (fr)	1995-05-10

Legal Events

Date	Code	Title	Description
1991-12-23	EEER	Examination request
2009-12-01	MKEX	Expiry

Publication	Publication Date	Title
US4014725A (en)	1977-03-29	Method of making carbon cloth from pitch based fiber
Chand	2000	Review carbon fibers for composites
US4005183A (en)	1977-01-25	High modulus, high strength carbon fibers produced from mesophase pitch
Ko	1996	Raman spectrum of modified PAN‐based carbon fibers during graphitization
US5552008A (en)	1996-09-03	Method for the preparation of high modulus carbon and graphite articles
US3919387A (en)	1975-11-11	Process for producing high mesophase content pitch fibers
US4138525A (en)	1979-02-06	Highly-handleable pitch-based fibers
Edie et al.	1993	Ribbon-shape carbon fibers for thermal management
US5266294A (en)	1993-11-30	Continuous, ultrahigh modulus carbon fiber
US4849200A (en)	1989-07-18	Process for fabricating carbon/carbon composite
CA2004370C (fr)	1995-11-21	Fibre carbone a module d'elasticite extra eleve
US4073869A (en)	1978-02-14	Internal chemical modification of carbon fibers to yield a product of reduced electrical conductivity
Newell et al.	1994	Direct carbonization of PBO fiber
JP3031197B2 (ja)	2000-04-10	ピッチ系炭素繊維
HK1007176B (en)	1999-04-01	Continuous, ultrahigh modulus carbon fiber
US5721308A (en)	1998-02-24	Pitch based carbon fiber and process for producing the same
US5556608A (en)	1996-09-17	Carbon thread and process for producing it
Zhang et al.	1994	Carbon fibers from polyethylene-based precursors
US3705236A (en)	1972-12-05	Method of producing carbon fibers
US5695816A (en)	1997-12-09	Process for the preparation of carbon fiber reinforced carbon composites
US3716331A (en)	1973-02-13	Process for producing carbon fibers having a high young's modulus of elasticity
CA1055664A (fr)	1979-06-05	Thermodurcissement rapide de fibres carbonees provenant de bitume a l'etat mesophase
US3652221A (en)	1972-03-28	Process for producing carbon fibers
JPS60246819A (ja)	1985-12-06	ピツチ系炭素繊維の製造方法
JP2985455B2 (ja)	1999-11-29	炭素繊維およびその製造方法