CA1239512A - Fibres de carbone, et leur production - Google Patents

Fibres de carbone, et leur production

Info

Publication number: CA1239512A
Authority: CA; Canada
Prior art keywords: yarn; pitch; fibers; carbon; nitric acid
Prior art date: 1984-04-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000479045A

Other languages

English (en)

Inventor

Loren C. Nelson

David A. Schulz

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BP Corp North America Inc

Original Assignee

BP Corp North America Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-04-30

Filing date

1985-04-12

Publication date

1988-07-26

1985-04-12 Application filed by BP Corp North America Inc filed Critical BP Corp North America Inc

1988-07-26 Application granted granted Critical

1988-07-26 Publication of CA1239512A publication Critical patent/CA1239512A/fr

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims description 32
229920000049 Carbon (fiber) Polymers 0.000 title description 39
239000004917 carbon fiber Substances 0.000 title description 39
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 69
229910052799 carbon Inorganic materials 0.000 claims abstract description 56
238000010438 heat treatment Methods 0.000 claims abstract description 43
239000000203 mixture Substances 0.000 claims abstract description 41
230000001590 oxidative effect Effects 0.000 claims abstract description 35
239000012298 atmosphere Substances 0.000 claims abstract description 23
238000009987 spinning Methods 0.000 claims abstract description 20
239000011295 pitch Substances 0.000 claims description 145
239000000835 fiber Substances 0.000 claims description 130
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 39
229910017604 nitric acid Inorganic materials 0.000 claims description 39
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 26
230000008569 process Effects 0.000 claims description 26
238000004519 manufacturing process Methods 0.000 claims description 24
239000011302 mesophase pitch Substances 0.000 claims description 22
239000007788 liquid Substances 0.000 claims description 20
229910002804 graphite Inorganic materials 0.000 claims description 13
239000010439 graphite Substances 0.000 claims description 13
229910052757 nitrogen Inorganic materials 0.000 claims description 13
239000004094 surface-active agent Substances 0.000 claims description 9
239000007789 gas Substances 0.000 claims description 8
239000006229 carbon black Substances 0.000 claims description 7
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
239000006185 dispersion Substances 0.000 claims description 4
229910052786 argon Inorganic materials 0.000 claims description 3
239000001307 helium Substances 0.000 claims description 3
229910052734 helium Inorganic materials 0.000 claims description 3
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 3
229940000425 combination drug Drugs 0.000 claims 1
238000010000 carbonizing Methods 0.000 description 19
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 17
239000001301 oxygen Substances 0.000 description 17
229910052760 oxygen Inorganic materials 0.000 description 17
239000000243 solution Substances 0.000 description 15
239000003245 coal Substances 0.000 description 12
239000000463 material Substances 0.000 description 10
238000011282 treatment Methods 0.000 description 10
230000004927 fusion Effects 0.000 description 8
238000004513 sizing Methods 0.000 description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
238000004804 winding Methods 0.000 description 8
239000000284 extract Substances 0.000 description 7
239000007800 oxidant agent Substances 0.000 description 7
230000003647 oxidation Effects 0.000 description 7
238000007254 oxidation reaction Methods 0.000 description 7
239000002131 composite material Substances 0.000 description 6
239000011368 organic material Substances 0.000 description 5
238000012360 testing method Methods 0.000 description 5
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
239000002245 particle Substances 0.000 description 4
239000002243 precursor Substances 0.000 description 4
238000010926 purge Methods 0.000 description 4
239000011734 sodium Substances 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
-1 ammonium peroxide Chemical class 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
238000009826 distribution Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000003860 storage Methods 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
238000010306 acid treatment Methods 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
230000008901 benefit Effects 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
238000003763 carbonization Methods 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
230000006866 deterioration Effects 0.000 description 2
239000008246 gaseous mixture Substances 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
239000006193 liquid solution Substances 0.000 description 2
239000003595 mist Substances 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
239000003208 petroleum Substances 0.000 description 2
239000004033 plastic Substances 0.000 description 2
XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 2
239000010802 sludge Substances 0.000 description 2
VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
230000000087 stabilizing effect Effects 0.000 description 2
229910052717 sulfur Inorganic materials 0.000 description 2
239000011593 sulfur Substances 0.000 description 2
238000004381 surface treatment Methods 0.000 description 2
QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 2
229920001187 thermosetting polymer Polymers 0.000 description 2
LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
229910052582 BN Inorganic materials 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
OGIIWTRTOXDWEH-UHFFFAOYSA-N [O].[O-][O+]=O Chemical compound [O].[O-][O+]=O OGIIWTRTOXDWEH-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
229910001870 ammonium persulfate Inorganic materials 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000011260 aqueous acid Substances 0.000 description 1
238000010420 art technique Methods 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
238000012512 characterization method Methods 0.000 description 1
230000001684 chronic effect Effects 0.000 description 1
238000012777 commercial manufacturing Methods 0.000 description 1
238000010276 construction Methods 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
238000013461 design Methods 0.000 description 1
230000002542 deteriorative effect Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
238000002050 diffraction method Methods 0.000 description 1
230000003467 diminishing effect Effects 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
239000007770 graphite material Substances 0.000 description 1
239000011316 heat-treated pitch Substances 0.000 description 1
230000006698 induction Effects 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
150000002605 large molecules Chemical class 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
238000005461 lubrication Methods 0.000 description 1
229920002521 macromolecule Polymers 0.000 description 1
238000002074 melt spinning Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
238000012856 packing Methods 0.000 description 1
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
238000012545 processing Methods 0.000 description 1
238000010791 quenching Methods 0.000 description 1
229910000753 refractory alloy Inorganic materials 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000002791 soaking Methods 0.000 description 1
235000010344 sodium nitrate Nutrition 0.000 description 1
239000004317 sodium nitrate Substances 0.000 description 1
PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
239000007921 spray Substances 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000004753 textile Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/145—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from pitch or distillation residues

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Inorganic Fibers (AREA)

CA000479045A 1984-04-30 1985-04-12 Fibres de carbone, et leur production Expired CA1239512A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US60506484A	1984-04-30	1984-04-30
US605,064		1984-04-30

Publications (1)

Publication Number	Publication Date
CA1239512A true CA1239512A (fr)	1988-07-26

Family

ID=24422113

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000479045A Expired CA1239512A (fr)	1984-04-30	1985-04-12	Fibres de carbone, et leur production

Country Status (4)

Country	Link
EP (1)	EP0163339B1 (fr)
JP (1)	JPS60231825A (fr)
CA (1)	CA1239512A (fr)
DE (1)	DE3572847D1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA2004370C (fr) *	1988-12-07	1995-11-21	David Arthur Schulz	Fibre carbone a module d'elasticite extra eleve
JP3125062B2 (ja) *	1993-02-24	2001-01-15	株式会社ペトカ	炭素繊維の製造方法
CA2124158C (fr) *	1993-06-14	2005-09-13	Daniel H. Hecht	Articles en carbone et graphite a module eleve et methode de fabrication
US12371821B2 (en) *	2019-10-17	2025-07-29	Thread Innovations Inc.	Fabrication of carbon fibers with high mechanical properties

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3639953A (en) *	1969-08-07	1972-02-08	Kanegafuchi Spinning Co Ltd	Method of producing carbon fibers
GB1356569A (en) *	1970-12-22	1974-06-12	Coal Industry Patents Ltd	Manufacture of carbon fibres
US4055583A (en) *	1974-04-24	1977-10-25	Bergwerksverband Gmbh	Method for the production of carbonaceous articles, particularly strands
FR2392144A1 (fr) *	1977-05-25	1978-12-22	British Petroleum Co	Procede de fabrication de fibres de carbone et de graphite a partir de brais de petrole
US4276278A (en) *	1979-01-29	1981-06-30	Union Carbide Corporation	Spin size and thermosetting aid for pitch fibers
US4275051A (en) *	1979-01-29	1981-06-23	Union Carbide Corporation	Spin size and thermosetting aid for pitch fibers
US4351816A (en) *	1980-12-17	1982-09-28	Union Carbide Corporation	Method for producing a mesophase pitch derived carbon yarn and fiber

1985
- 1985-04-12 CA CA000479045A patent/CA1239512A/fr not_active Expired
- 1985-04-26 JP JP8905785A patent/JPS60231825A/ja active Granted
- 1985-04-29 EP EP19850200687 patent/EP0163339B1/fr not_active Expired
- 1985-04-29 DE DE8585200687T patent/DE3572847D1/de not_active Expired

Also Published As

Publication number	Publication date
EP0163339A3 (en)	1986-09-17
JPS60231825A (ja)	1985-11-18
EP0163339A2 (fr)	1985-12-04
JPH0250211B2 (fr)	1990-11-01
EP0163339B1 (fr)	1989-09-06
DE3572847D1 (en)	1989-10-12

Legal Events

Date	Code	Title	Description
2005-07-26	MKEX	Expiry

Publication	Publication Date	Title
EP0190222B1 (fr)	1989-11-23	Fibres de carbone hachees et methodes pour leur production
US4275051A (en)	1981-06-23	Spin size and thermosetting aid for pitch fibers
EP1130140B1 (fr)	2005-11-16	Fibre precurseur a base d'acrylonitrile destinee a former une fibre de carbone et procede de production
US4284615A (en)	1981-08-18	Process for the production of carbon fibers
EP0226819B1 (fr)	1994-02-02	Procédé pour la fabrication d'écheveaux coupés de fibres de carbone
US4582662A (en)	1986-04-15	Process for producing a carbon fiber from pitch material
US4276278A (en)	1981-06-30	Spin size and thermosetting aid for pitch fibers
US4576810A (en)	1986-03-18	Carbon fiber production
CA1239512A (fr)	1988-07-26	Fibres de carbone, et leur production
EP0297702A2 (fr)	1989-01-04	Fibres de carbone ou de graphite à base de brai
EP0014161B1 (fr)	1983-03-30	Méthode de traitement d'un faisceau multifilament de fibres de brai et composition d'ensimage pour ce traitement
US5595720A (en)	1997-01-21	Method for producing carbon fiber
US4840762A (en)	1989-06-20	Process for preparation of high-performance grade carbon fibers
JPH02242919A (ja)	1990-09-27	連続超高モジュラス炭素繊維
JPS60126324A (ja)	1985-07-05	フィラメントの揃いの良い炭素繊維束を製造する方法
CA1311883C (fr)	1992-12-29	Fibres de carbone a base de brai, et methode de production connexe
JPS5930918A (ja)	1984-02-18	炭素繊維の製造方法
US20240240366A1 (en)	2024-07-18	Carbon fiber derived from pedot:pss fiber
JP2930166B2 (ja)	1999-08-03	炭素繊維の製造方法
JPH0491229A (ja)	1992-03-24	ピッチ系炭素繊維の製造方法
JPH0617319A (ja)	1994-01-25	ピッチ系炭素繊維の製造方法
JPH043453B2 (fr)	1992-01-23
JPH08246250A (ja)	1996-09-24	炭素繊維の製造方法
JPS6321922A (ja)	1988-01-29	ピツチ系炭素繊維の製造方法
JPS6081320A (ja)	1985-05-09	炭素繊維の製造方法