CA2014475A1 - Compositions pour le moulage comprenant les elements suivants: polycarbonate, copolymere greffe nitrile aromatique butadiene-vinyle et copolymere greffe methylacrylate-butadiene-styrene; procedes de moulage par soufflage et de formage a chaud utilisant lesdites compositions - Google Patents

Compositions pour le moulage comprenant les elements suivants: polycarbonate, copolymere greffe nitrile aromatique butadiene-vinyle et copolymere greffe methylacrylate-butadiene-styrene; procedes de moulage par soufflage et de formage a chaud utilisant lesdites compositions

Info

Publication number: CA2014475A1
Authority: CA; Canada
Prior art keywords: weight; percent; butadiene; polymer; rubber
Prior art date: 1989-10-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2014475

Other languages

English (en)

Inventor

Michael K. Laughner

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Chemical Co

Original Assignee

Dow Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-10-27

Filing date

1990-04-12

Publication date

1991-04-27

1989-10-27 Priority claimed from US07/428,284 external-priority patent/US5087663A/en

1990-04-12 Application filed by Dow Chemical Co filed Critical Dow Chemical Co

1991-04-27 Publication of CA2014475A1 publication Critical patent/CA2014475A1/fr

Status Abandoned legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 77
229920000642 polymer Polymers 0.000 title claims abstract description 70
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 title claims abstract description 44
238000000071 blow moulding Methods 0.000 title claims abstract description 17
238000003856 thermoforming Methods 0.000 title claims abstract description 5
229920000578 graft copolymer Polymers 0.000 title claims description 32
238000000465 moulding Methods 0.000 title description 6
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 title 1
229920001971 elastomer Polymers 0.000 claims abstract description 63
239000005060 rubber Substances 0.000 claims abstract description 60
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 19
239000000155 melt Substances 0.000 claims abstract description 18
125000000217 alkyl group Chemical group 0.000 claims abstract description 6
229920002554 vinyl polymer Polymers 0.000 claims description 32
239000000178 monomer Substances 0.000 claims description 31
238000000034 method Methods 0.000 claims description 19
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 18
-1 vinyl aromatic hydrocarbon Chemical class 0.000 claims description 18
150000002825 nitriles Chemical class 0.000 claims description 15
239000003795 chemical substances by application Substances 0.000 claims description 13
230000002708 enhancing effect Effects 0.000 claims description 13
229920001577 copolymer Polymers 0.000 claims description 12
230000008569 process Effects 0.000 claims description 8
239000005062 Polybutadiene Substances 0.000 claims description 7
229920002857 polybutadiene Polymers 0.000 claims description 7
229920002587 poly(1,3-butadiene) polymer Polymers 0.000 claims description 6
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
229920002959 polymer blend Polymers 0.000 claims description 2
238000002360 preparation method Methods 0.000 claims 1
229920007019 PC/ABS Polymers 0.000 abstract description 7
150000001252 acrylic acid derivatives Chemical class 0.000 abstract 1
239000003607 modifier Substances 0.000 abstract 1
229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 47
238000002474 experimental method Methods 0.000 description 44
239000004417 polycarbonate Substances 0.000 description 44
XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 43
239000004676 acrylonitrile butadiene styrene Substances 0.000 description 40
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 24
229920000515 polycarbonate Polymers 0.000 description 17
229920005989 resin Polymers 0.000 description 17
239000011347 resin Substances 0.000 description 17
229920000126 latex Polymers 0.000 description 8
239000000758 substrate Substances 0.000 description 8
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 7
239000004816 latex Substances 0.000 description 7
239000002245 particle Substances 0.000 description 7
229920001169 thermoplastic Polymers 0.000 description 7
239000004416 thermosoftening plastic Substances 0.000 description 7
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
239000011159 matrix material Substances 0.000 description 6
239000004431 polycarbonate resin Substances 0.000 description 5
SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 5
229920000638 styrene acrylonitrile Polymers 0.000 description 5
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
239000000839 emulsion Substances 0.000 description 4
229920005668 polycarbonate resin Polymers 0.000 description 4
239000011342 resin composition Substances 0.000 description 4
239000000126 substance Substances 0.000 description 4
229920005992 thermoplastic resin Polymers 0.000 description 4
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
229940106691 bisphenol a Drugs 0.000 description 3
150000001993 dienes Chemical class 0.000 description 3
238000001746 injection moulding Methods 0.000 description 3
239000000243 solution Substances 0.000 description 3
239000004429 Calibre Substances 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000000654 additive Substances 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
230000003078 antioxidant effect Effects 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
230000008901 benefit Effects 0.000 description 2
WWNGFHNQODFIEX-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;styrene Chemical compound C=CC=C.COC(=O)C(C)=C.C=CC1=CC=CC=C1 WWNGFHNQODFIEX-UHFFFAOYSA-N 0.000 description 2
239000002131 composite material Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
150000005673 monoalkenes Chemical class 0.000 description 2
235000012424 soybean oil Nutrition 0.000 description 2
239000003549 soybean oil Substances 0.000 description 2
239000011145 styrene acrylonitrile resin Substances 0.000 description 2
229920003048 styrene butadiene rubber Polymers 0.000 description 2
239000000725 suspension Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
VDYWHVQKENANGY-UHFFFAOYSA-N 1,3-Butyleneglycol dimethacrylate Chemical compound CC(=C)C(=O)OC(C)CCOC(=O)C(C)=C VDYWHVQKENANGY-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
BCHLTFOMLWCYIS-UHFFFAOYSA-N 4-amino-5-chloro-n-[2-(diethylamino)ethyl]-2-methoxybenzamide;n-(4-hydroxyphenyl)acetamide;hydrochloride Chemical compound Cl.CC(=O)NC1=CC=C(O)C=C1.CCN(CC)CCNC(=O)C1=CC(Cl)=C(N)C=C1OC BCHLTFOMLWCYIS-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
239000004609 Impact Modifier Substances 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
208000013201 Stress fracture Diseases 0.000 description 1
208000000260 Warts Diseases 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000008360 acrylonitriles Chemical class 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
230000004075 alteration Effects 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000011258 core-shell material Substances 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
238000009863 impact test Methods 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical class [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 1
239000010445 mica Substances 0.000 description 1
229910052618 mica group Inorganic materials 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000008188 pellet Substances 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
230000005501 phase interface Effects 0.000 description 1
239000002530 phenolic antioxidant Substances 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
238000007665 sagging Methods 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
201000010153 skin papilloma Diseases 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
230000008961 swelling Effects 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
238000005303 weighing Methods 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

CA 2014475 1989-10-27 1990-04-12 Compositions pour le moulage comprenant les elements suivants: polycarbonate, copolymere greffe nitrile aromatique butadiene-vinyle et copolymere greffe methylacrylate-butadiene-styrene; procedes de moulage par soufflage et de formage a chaud utilisant lesdites compositions Abandoned CA2014475A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US428,284		1989-10-27
US07/428,284 US5087663A (en)	1989-03-08	1989-10-27	Molding compositions with methyl (meth)acrylate-butadiene-styrene graft copolymers

Publications (1)

Publication Number	Publication Date
CA2014475A1 true CA2014475A1 (fr)	1991-04-27

Family

ID=23698251

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2014475 Abandoned CA2014475A1 (fr)	1989-10-27	1990-04-12	Compositions pour le moulage comprenant les elements suivants: polycarbonate, copolymere greffe nitrile aromatique butadiene-vinyle et copolymere greffe methylacrylate-butadiene-styrene; procedes de moulage par soufflage et de formage a chaud utilisant lesdites compositions

Country Status (1)

Country	Link
CA (1)	CA2014475A1 (fr)

1990
- 1990-04-12 CA CA 2014475 patent/CA2014475A1/fr not_active Abandoned

Legal Events

Date	Code	Title	Description
1992-10-12	FZDE	Dead

Publication	Publication Date	Title
US5068285A (en)	1991-11-26	Molding compositions with acrylonitrile-styrene-acrylate rubber copolymers
US5087663A (en)	1992-02-11	Molding compositions with methyl (meth)acrylate-butadiene-styrene graft copolymers
US4742104A (en)	1988-05-03	Thermoplastic moulding compositions based on polycarbonate/graft polymer mixtures
US4530965A (en)	1985-07-23	Polymeric molding composition containing styrenic copolymer, polycarbonate and MBS polymer
US4792585A (en)	1988-12-20	Thermoplastic resin composition
US4696972A (en)	1987-09-29	Polymeric molding composition containing styrenic copolymer, polycarbonate and MBS polymer
US4496690A (en)	1985-01-29	Alloys of styrenic resins and polyamides
EP0375648A2 (fr)	1990-06-27	Compositions de résines
US5159003A (en)	1992-10-27	Polyester-compatible alloys of polycarbonate
KR100243750B1 (ko)	2000-03-02	열가소성수지조성물
JPS6044545A (ja)	1985-03-09	組成物
EP0328273B1 (fr)	1994-01-05	Usage des modificateurs de la rhéologie de la masse fondue dans les compositions de polymères thermoplstiques
EP0681002A2 (fr)	1995-11-08	Compositions de polycarbonate et de polymère greffé de faible brillance
US5008330A (en)	1991-04-16	Molding compositions with acrylonitrile-EPDM-styrene copolymers
US4937280A (en)	1990-06-26	Blends based on vinyl-aromatic polymers having high tenacity and impact strength
US5049614A (en)	1991-09-17	Blends based on vinyl-aromatic polymers having high tenacity and impact strength
US4906688A (en)	1990-03-06	Thermoplastic moulding compositions of the ABS type of improved toughness and processability
EP0381358B1 (fr)	1994-12-14	Agents délustrants, procédé de leur production, compositions thermoplastiques matées et articles en forme
AU5187490A (en)	1990-10-09	Molding compositions comprising carbonate polymer, rubber modified vinyl aromatic-nitrile graft copolymer and methyl(meth)acrylate-butadiene-styrene graft copolymer and blow molding and thermoforming processes using such compositions
CA1304856C (fr)	1992-07-07	Composition de resine de polycarbonate avec adjuvants dieniques, ameliorant la resistance a l'impact
US5516842A (en)	1996-05-14	Polycarbonate resin composition and molded product thereof
JP2001279049A (ja)	2001-10-10	ブロー成形用ａｂｓ系樹脂組成物およびそのブロー成形品
CA1165037A (fr)	1984-04-03	Melanges de polycarbonate aromatique et de copolymeres statistiques d'un monovinylidene aromatique et d'un acide carboxylique non sature
US4439582A (en)	1984-03-27	Blends of aromatic polycarbonate with random copolymers of a monovinylidene aromatic and an unsaturated carboxylic acid
CA2014476A1 (fr)	1991-03-22	Compositions pour le moulage comprenant les elements suivants: polycarbonate, copolymere greffe nitrile aromatique-vinyle, modifie par du caoutchouc, et copolymere greffe methylacrylate-butadiene-styrene; procedes de moulage par soufflage et de formage a chaud utilisant lesdites compositions