CA2014476A1 - Compositions pour le moulage comprenant les elements suivants: polycarbonate, copolymere greffe nitrile aromatique-vinyle, modifie par du caoutchouc, et copolymere greffe methylacrylate-butadiene-styrene; procedes de moulage par soufflage et de formage a chaud utilisant lesdites compositions - Google Patents

Compositions pour le moulage comprenant les elements suivants: polycarbonate, copolymere greffe nitrile aromatique-vinyle, modifie par du caoutchouc, et copolymere greffe methylacrylate-butadiene-styrene; procedes de moulage par soufflage et de formage a chaud utilisant lesdites compositions

Info

Publication number: CA2014476A1
Authority: CA; Canada
Prior art keywords: polymer; graft copolymer; weight; rubber; percent
Prior art date: 1989-09-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2014476

Other languages

English (en)

Inventor

Michael K. Laughner

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Chemical Co

Original Assignee

Dow Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-09-22

Filing date

1990-04-12

Publication date

1991-03-22

1989-09-22 Priority claimed from US07/411,279 external-priority patent/US5008330A/en

1989-09-22 Priority claimed from US07/411,278 external-priority patent/US5068285A/en

1990-04-12 Application filed by Dow Chemical Co filed Critical Dow Chemical Co

1991-03-22 Publication of CA2014476A1 publication Critical patent/CA2014476A1/fr

Status Abandoned legal-status Critical Current

Links

229920001971 elastomer Polymers 0.000 title claims abstract description 95
239000000203 mixture Substances 0.000 title claims abstract description 65
229920000642 polymer Polymers 0.000 title claims abstract description 60
229920000578 graft copolymer Polymers 0.000 title claims abstract description 47
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 title claims abstract description 39
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title claims abstract description 27
238000000071 blow moulding Methods 0.000 title claims abstract description 15
238000003856 thermoforming Methods 0.000 title claims description 9
238000000465 moulding Methods 0.000 title claims description 8
239000005060 rubber Substances 0.000 title abstract description 79
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 title 1
229920001577 copolymer Polymers 0.000 claims abstract description 31
229920002554 vinyl polymer Polymers 0.000 claims abstract description 29
150000001993 dienes Chemical class 0.000 claims abstract description 16
239000000178 monomer Substances 0.000 claims description 27
238000000034 method Methods 0.000 claims description 21
125000000217 alkyl group Chemical group 0.000 claims description 19
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 14
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 11
229920000058 polyacrylate Polymers 0.000 claims description 8
238000002360 preparation method Methods 0.000 claims description 3
239000011258 core-shell material Substances 0.000 claims description 2
239000004609 Impact Modifier Substances 0.000 abstract description 3
229920005989 resin Polymers 0.000 description 37
239000011347 resin Substances 0.000 description 37
238000002474 experimental method Methods 0.000 description 33
239000004417 polycarbonate Substances 0.000 description 30
229920000515 polycarbonate Polymers 0.000 description 30
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 28
229920001898 acrylonitrile–EPDM–styrene Polymers 0.000 description 15
-1 vinyl aromatic hydrocarbon Chemical class 0.000 description 13
229920001169 thermoplastic Polymers 0.000 description 11
239000004416 thermosoftening plastic Substances 0.000 description 11
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 9
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 9
239000004816 latex Substances 0.000 description 9
229920000126 latex Polymers 0.000 description 9
239000011159 matrix material Substances 0.000 description 9
239000000758 substrate Substances 0.000 description 9
229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 8
150000002825 nitriles Chemical class 0.000 description 8
XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 7
239000004676 acrylonitrile butadiene styrene Substances 0.000 description 7
125000005250 alkyl acrylate group Chemical group 0.000 description 6
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 6
SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 6
229920000638 styrene acrylonitrile Polymers 0.000 description 6
239000000126 substance Substances 0.000 description 6
239000000463 material Substances 0.000 description 5
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 4
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
238000001746 injection moulding Methods 0.000 description 4
239000000155 melt Substances 0.000 description 4
239000002245 particle Substances 0.000 description 4
230000000704 physical effect Effects 0.000 description 4
229920005992 thermoplastic resin Polymers 0.000 description 4
239000004429 Calibre Substances 0.000 description 3
229920002943 EPDM rubber Polymers 0.000 description 3
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 3
239000003963 antioxidant agent Substances 0.000 description 3
230000003078 antioxidant effect Effects 0.000 description 3
WWNGFHNQODFIEX-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;styrene Chemical compound C=CC=C.COC(=O)C(C)=C.C=CC1=CC=CC=C1 WWNGFHNQODFIEX-UHFFFAOYSA-N 0.000 description 3
229920001519 homopolymer Polymers 0.000 description 3
PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
YAAQEISEHDUIFO-UHFFFAOYSA-N C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 Chemical compound C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 YAAQEISEHDUIFO-UHFFFAOYSA-N 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
238000003917 TEM image Methods 0.000 description 2
239000002253 acid Substances 0.000 description 2
229920002877 acrylic styrene acrylonitrile Polymers 0.000 description 2
239000000654 additive Substances 0.000 description 2
229940106691 bisphenol a Drugs 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 2
238000010102 injection blow moulding Methods 0.000 description 2
150000005673 monoalkenes Chemical class 0.000 description 2
229920005668 polycarbonate resin Polymers 0.000 description 2
239000004431 polycarbonate resin Substances 0.000 description 2
229920002959 polymer blend Polymers 0.000 description 2
230000000379 polymerizing effect Effects 0.000 description 2
239000000243 solution Substances 0.000 description 2
235000012424 soybean oil Nutrition 0.000 description 2
239000003549 soybean oil Substances 0.000 description 2
239000011145 styrene acrylonitrile resin Substances 0.000 description 2
PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
229940058015 1,3-butylene glycol Drugs 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
239000005062 Polybutadiene Substances 0.000 description 1
208000000260 Warts Diseases 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
229920000800 acrylic rubber Polymers 0.000 description 1
150000008360 acrylonitriles Chemical class 0.000 description 1
230000004075 alteration Effects 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
235000019437 butane-1,3-diol Nutrition 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
229920006026 co-polymeric resin Polymers 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
239000002131 composite material Substances 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
239000000975 dye Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000004945 emulsification Methods 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000000835 fiber Substances 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical class [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 1
239000010445 mica Substances 0.000 description 1
229910052618 mica group Inorganic materials 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000008188 pellet Substances 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
239000000049 pigment Substances 0.000 description 1
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
229920002857 polybutadiene Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
239000011342 resin composition Substances 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
201000010153 skin papilloma Diseases 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
230000008961 swelling Effects 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical class C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
238000005303 weighing Methods 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

CA 2014476 1989-09-22 1990-04-12 Compositions pour le moulage comprenant les elements suivants: polycarbonate, copolymere greffe nitrile aromatique-vinyle, modifie par du caoutchouc, et copolymere greffe methylacrylate-butadiene-styrene; procedes de moulage par soufflage et de formage a chaud utilisant lesdites compositions Abandoned CA2014476A1 (fr)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US411,279		1989-09-22
US07/411,279 US5008330A (en)	1989-03-08	1989-09-22	Molding compositions with acrylonitrile-EPDM-styrene copolymers
US07/411,278 US5068285A (en)	1989-03-08	1989-09-22	Molding compositions with acrylonitrile-styrene-acrylate rubber copolymers
US411,278		1989-09-22

Publications (1)

Publication Number	Publication Date
CA2014476A1 true CA2014476A1 (fr)	1991-03-22

Family

ID=27021341

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2014476 Abandoned CA2014476A1 (fr)	1989-09-22	1990-04-12	Compositions pour le moulage comprenant les elements suivants: polycarbonate, copolymere greffe nitrile aromatique-vinyle, modifie par du caoutchouc, et copolymere greffe methylacrylate-butadiene-styrene; procedes de moulage par soufflage et de formage a chaud utilisant lesdites compositions

Country Status (1)

Country	Link
CA (1)	CA2014476A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN112724636A (zh) *	2020-12-29	2021-04-30	金旸（厦门）新材料科技有限公司	一种耐候、耐溶剂腐蚀、降噪的pc/abs合金材料及其制备方法

1990
- 1990-04-12 CA CA 2014476 patent/CA2014476A1/fr not_active Abandoned

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN112724636A (zh) *	2020-12-29	2021-04-30	金旸（厦门）新材料科技有限公司	一种耐候、耐溶剂腐蚀、降噪的pc/abs合金材料及其制备方法

Legal Events

Date	Code	Title	Description
1992-10-12	FZDE	Dead

Publication	Publication Date	Title
US5068285A (en)	1991-11-26	Molding compositions with acrylonitrile-styrene-acrylate rubber copolymers
US5087663A (en)	1992-02-11	Molding compositions with methyl (meth)acrylate-butadiene-styrene graft copolymers
US4605699A (en)	1986-08-12	Thermoplastic molding compositions containing polycarbonate and an acrylate graft copolymer
US5162423A (en)	1992-11-10	Thermoplastic molding materials having good low-temperature impact strength
US20010011116A1 (en)	2001-08-02	Thermoplastic resin composition having excellent long-term heat-aging properties
JPH0733473B2 (ja)	1995-04-12	充填剤入りポリマーブレンド
US4624986A (en)	1986-11-25	Low temperature impact resistant carbonate polymer blends
US4218544A (en)	1980-08-19	Blends of polycarbonate with rubber and monovinylidene aromatic copolymers
US4792585A (en)	1988-12-20	Thermoplastic resin composition
US4530965A (en)	1985-07-23	Polymeric molding composition containing styrenic copolymer, polycarbonate and MBS polymer
US4367310A (en)	1983-01-04	Blends of polycarbonate with rubber and monovinylidene aromatic copolymers
US4696972A (en)	1987-09-29	Polymeric molding composition containing styrenic copolymer, polycarbonate and MBS polymer
US5061754A (en)	1991-10-29	Low gloss polycarbonate/abs blends
KR100243750B1 (ko)	2000-03-02	열가소성수지조성물
US5574099A (en)	1996-11-12	Rubber-reinforced styrene resin composition and process for producing the same
US4163762A (en)	1979-08-07	Blends of phenolphthalein polycarbonates with rubber-modified monovinylidene aromatic copolymers
US5747587A (en)	1998-05-05	HCFC resistant resin composition
US5008330A (en)	1991-04-16	Molding compositions with acrylonitrile-EPDM-styrene copolymers
CA1296823C (fr)	1992-03-03	Composition de resine a base de copolymeres greffes et de styrene
EP0381358B1 (fr)	1994-12-14	Agents délustrants, procédé de leur production, compositions thermoplastiques matées et articles en forme
AU5187490A (en)	1990-10-09	Molding compositions comprising carbonate polymer, rubber modified vinyl aromatic-nitrile graft copolymer and methyl(meth)acrylate-butadiene-styrene graft copolymer and blow molding and thermoforming processes using such compositions
US4937280A (en)	1990-06-26	Blends based on vinyl-aromatic polymers having high tenacity and impact strength
US4906688A (en)	1990-03-06	Thermoplastic moulding compositions of the ABS type of improved toughness and processability
US5049614A (en)	1991-09-17	Blends based on vinyl-aromatic polymers having high tenacity and impact strength
US5516842A (en)	1996-05-14	Polycarbonate resin composition and molded product thereof

Info

Links

Landscapes

Applications Claiming Priority (4)

Publications (1)

Family

ID=27021341

Family Applications (1)

Country Status (1)

Cited By (1)

Cited By (1)

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