CA2024596A1 - Catalyseurs a base de compose organique de l'etain, utilisables dans des systemes de polyurethane - Google Patents

Catalyseurs a base de compose organique de l'etain, utilisables dans des systemes de polyurethane

Info

Publication number
CA2024596A1
CA2024596A1 CA2024596A CA2024596A CA2024596A1 CA 2024596 A1 CA2024596 A1 CA 2024596A1 CA 2024596 A CA2024596 A CA 2024596A CA 2024596 A CA2024596 A CA 2024596A CA 2024596 A1 CA2024596 A1 CA 2024596A1
Authority
CA
Canada
Prior art keywords
polyurethane systems
organotin catalysts
catalysts
polyisocyanate
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2024596A
Other languages
English (en)
Other versions
CA2024596C (fr
Inventor
James D. Nichols
John B. Dickenson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Products and Chemicals Inc
Original Assignee
Air Products and Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/405,362 external-priority patent/US4981924A/en
Priority claimed from US07/405,700 external-priority patent/US4987244A/en
Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc
Publication of CA2024596A1 publication Critical patent/CA2024596A1/fr
Application granted granted Critical
Publication of CA2024596C publication Critical patent/CA2024596C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/443—Polyepoxides
    • C09D5/4457—Polyepoxides containing special additives, e.g. pigments, polymeric particles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0228—Sulfur-containing compounds with a metal-sulfur link, e.g. mercaptides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22—Tin compounds
    • C07F7/2224—Compounds having one or more tin-oxygen linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22—Tin compounds
    • C07F7/226—Compounds with one or more Sn-S linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C08G18/242—Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • C08G18/6415—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63 having nitrogen
    • C08G18/643—Reaction products of epoxy resins with at least equivalent amounts of amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/10—Non-coordinating groups comprising only oxygen beside carbon or hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)

Abstract

es organoétains de formule R2Sn?X-R1-OH]2, où R est un groupement alkyle ou aryle en C1-C8, R1 est un groupement hydrocarbylique divalent en C2-C9 pouvant renfermer un substituant hydroxyle et X est un groupement de liaison pouvant être -5- ou -O2C-, sont utiles comme catalyseurs pour la réaction d'un polyisocyanate ou d'un polyisocyanate partiellement séquencé avec un composé hydroxylé.
CA002024596A 1989-09-11 1990-09-04 Catalyseurs a base de compose organique de l'etain, utilisables dans des systemes de polyurethane Expired - Fee Related CA2024596C (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US07/405,362 US4981924A (en) 1989-09-11 1989-09-11 Cationic electrodepositable compositions of blocked polyisocyanates and amine-epoxy resins containing diorganotin bis-mercaptides and bis-carboxylates as catalysts
US07/405,700 US4987244A (en) 1989-09-11 1989-09-11 Organotin catalysts for use in polyurethane systems
US405,362 1989-09-11
US405,700 1989-09-11

Publications (2)

Publication Number Publication Date
CA2024596A1 true CA2024596A1 (fr) 1991-03-12
CA2024596C CA2024596C (fr) 1997-08-19

Family

ID=27019047

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002024596A Expired - Fee Related CA2024596C (fr) 1989-09-11 1990-09-04 Catalyseurs a base de compose organique de l'etain, utilisables dans des systemes de polyurethane

Country Status (10)

Country Link
EP (1) EP0417605B1 (fr)
JP (1) JPH075701B2 (fr)
KR (1) KR930006915B1 (fr)
AR (1) AR246562A1 (fr)
AU (1) AU627929B2 (fr)
BR (1) BR9004481A (fr)
CA (1) CA2024596C (fr)
DE (1) DE69021303T2 (fr)
ES (1) ES2088930T3 (fr)
MX (1) MX164444B (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5089645A (en) * 1989-09-11 1992-02-18 Air Products And Chemicals, Inc. Hydroxyl-containing organotin catalysts for making polyurethanes
EP0490278B1 (fr) * 1990-12-12 1996-02-14 Air Products And Chemicals, Inc. Elastomères de polyuréthane rim obtenu à partir de catalyseurs d'étain organique contenant hydroxyle
US5256704A (en) * 1990-12-12 1993-10-26 Air Products And Chemicals, Inc. Polyurethane RIM elastomers obtained with hydroxyl-containing organotin catalysts
AU652991B2 (en) * 1991-02-21 1994-09-15 Morton International Limited Isocyanate-cured polysulphide polymers
US5356529A (en) * 1993-05-03 1994-10-18 Ppg Industries, Inc. Electrodepositable compositions containing triorganotin catalysts
US8389653B2 (en) * 2006-03-30 2013-03-05 Basf Corporation Method of catalyzing a reaction to form a urethane coating and a complex for use in the method

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3799854A (en) * 1970-06-19 1974-03-26 Ppg Industries Inc Method of electrodepositing cationic compositions
US4310454A (en) * 1979-04-03 1982-01-12 Ciba-Geigy Corporation Novel organo-tin compounds
US4395528A (en) * 1981-03-02 1983-07-26 M&T Chemicals Inc. Catalyst composition and curable polymer compositions containing same
GB8712988D0 (en) * 1987-06-03 1987-07-08 Ici Plc Polyurethane foams
EP0423642A3 (en) * 1989-10-20 1991-07-03 Air Products And Chemicals, Inc. Polymeric diorganotin catalysts for use in polyurethane systems

Also Published As

Publication number Publication date
EP0417605A2 (fr) 1991-03-20
ES2088930T3 (es) 1996-10-01
KR910006362A (ko) 1991-04-29
CA2024596C (fr) 1997-08-19
AU627929B2 (en) 1992-09-03
DE69021303D1 (de) 1995-09-07
AR246562A1 (es) 1994-08-31
JPH075701B2 (ja) 1995-01-25
KR930006915B1 (ko) 1993-07-24
BR9004481A (pt) 1991-09-10
DE69021303T2 (de) 1996-01-11
JPH03106919A (ja) 1991-05-07
EP0417605B1 (fr) 1995-08-02
EP0417605A3 (en) 1992-03-11
MX164444B (es) 1992-08-13
AU6217990A (en) 1991-03-14

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Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed
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Effective date: 19990907