CA2040109A1 - Procede de production de sulfate de potassium et d'acide chlorhydrique - Google Patents

Procede de production de sulfate de potassium et d'acide chlorhydrique

Info

Publication number: CA2040109A1
Authority: CA; Canada
Prior art keywords: potassium; hydrochloric acid; solution; process according; chloride
Prior art date: 1990-04-10
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2040109

Other languages

English (en)

Inventor

Hirofumi Higuchi

Hiromi Nakamura

Yuji Takamizawa

Mariko Abe

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mitsubishi Gas Chemical Co Inc

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-04-10

Filing date

1991-04-09

Publication date

1991-10-11

1991-04-09 Application filed by Individual filed Critical Individual

1991-10-11 Publication of CA2040109A1 publication Critical patent/CA2040109A1/fr

Status Abandoned legal-status Critical Current

Links

VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 title claims abstract description 133
238000000034 method Methods 0.000 title claims abstract description 58
229910052939 potassium sulfate Inorganic materials 0.000 title claims abstract description 45
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 title claims abstract description 44
235000011151 potassium sulphates Nutrition 0.000 title claims abstract description 44
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 81
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 80
239000000243 solution Substances 0.000 claims abstract description 54
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 52
239000001103 potassium chloride Substances 0.000 claims abstract description 40
235000011164 potassium chloride Nutrition 0.000 claims abstract description 40
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
159000000001 potassium salts Chemical class 0.000 claims abstract description 29
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims abstract description 18
229910000041 hydrogen chloride Inorganic materials 0.000 claims abstract description 18
CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 claims abstract description 14
229910000343 potassium bisulfate Inorganic materials 0.000 claims abstract description 14
239000007864 aqueous solution Substances 0.000 claims abstract description 11
239000006185 dispersion Substances 0.000 claims abstract description 10
239000013078 crystal Substances 0.000 claims abstract description 6
230000001376 precipitating effect Effects 0.000 claims abstract description 3
238000006243 chemical reaction Methods 0.000 claims description 29
238000004821 distillation Methods 0.000 claims description 12
239000007788 liquid Substances 0.000 claims description 10
238000004519 manufacturing process Methods 0.000 description 7
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
239000007789 gas Substances 0.000 description 6
239000000203 mixture Substances 0.000 description 6
239000011591 potassium Substances 0.000 description 6
229910052700 potassium Inorganic materials 0.000 description 6
239000002002 slurry Substances 0.000 description 6
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
239000002253 acid Substances 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
229910052801 chlorine Inorganic materials 0.000 description 4
238000004508 fractional distillation Methods 0.000 description 4
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
238000010521 absorption reaction Methods 0.000 description 3
230000007423 decrease Effects 0.000 description 3
239000003337 fertilizer Substances 0.000 description 3
238000001556 precipitation Methods 0.000 description 3
239000011369 resultant mixture Substances 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
241000196324 Embryophyta Species 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
238000001944 continuous distillation Methods 0.000 description 2
238000011437 continuous method Methods 0.000 description 2
238000005194 fractionation Methods 0.000 description 2
238000009776 industrial production Methods 0.000 description 2
239000000047 product Substances 0.000 description 2
239000002994 raw material Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000005406 washing Methods 0.000 description 2
LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
240000008067 Cucumis sativus Species 0.000 description 1
ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 1
101100130497 Drosophila melanogaster Mical gene Proteins 0.000 description 1
241000243251 Hydra Species 0.000 description 1
101100345589 Mus musculus Mical1 gene Proteins 0.000 description 1
244000300264 Spinacia oleracea Species 0.000 description 1
235000009337 Spinacia oleracea Nutrition 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
238000010533 azeotropic distillation Methods 0.000 description 1
238000000998 batch distillation Methods 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
150000001720 carbohydrates Chemical class 0.000 description 1
235000014633 carbohydrates Nutrition 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
230000007547 defect Effects 0.000 description 1
MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
-1 etc. Chemical compound 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
QRXWMOHMRWLFEY-UHFFFAOYSA-N isoniazide Chemical compound NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 description 1
239000000463 material Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910001510 metal chloride Inorganic materials 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
TWXDDNPPQUTEOV-FVGYRXGTSA-N methamphetamine hydrochloride Chemical compound Cl.CN[C@@H](C)CC1=CC=CC=C1 TWXDDNPPQUTEOV-FVGYRXGTSA-N 0.000 description 1
239000011259 mixed solution Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
LMAZKPOSWVOFGY-FBAUPLQOSA-N orine Natural products CO[C@H]1C[C@H](O[C@H]2CC[C@]3(C)[C@H]4C[C@@H](OC(=O)C=Cc5ccccc5)[C@]6(C)[C@@](O)(CC[C@]6(O)[C@]4(O)CC=C3C2)[C@H](C)OC(=O)C=Cc7ccccc7)O[C@H](C)[C@H]1O LMAZKPOSWVOFGY-FBAUPLQOSA-N 0.000 description 1
230000007065 protein hydrolysis Effects 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000010992 reflux Methods 0.000 description 1
238000003746 solid phase reaction Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
- C01D5/02—Preparation of sulfates from alkali metal salts and sulfuric acid or bisulfates; Preparation of bisulfates
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/03—Preparation from chlorides
- C01B7/035—Preparation of hydrogen chloride from chlorides

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CA 2040109 1990-04-10 1991-04-09 Procede de production de sulfate de potassium et d'acide chlorhydrique Abandoned CA2040109A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
JP9316990		1990-04-10
JP93169/1990		1990-04-10

Publications (1)

Publication Number	Publication Date
CA2040109A1 true CA2040109A1 (fr)	1991-10-11

Family

ID=14075070

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2040109 Abandoned CA2040109A1 (fr)	1990-04-10	1991-04-09	Procede de production de sulfate de potassium et d'acide chlorhydrique

Country Status (2)

Country	Link
CA (1)	CA2040109A1 (fr)
DE (1)	DE4111718A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US8409542B2 (en)	2011-06-14	2013-04-02	Nichromet Extraction Inc.	Method and system for the production of potassium sulfate from potassium chloride
CN103396286A (zh) *	2013-07-19	2013-11-20	淮阴师范学院	以氯化钠与低浓度乙醇为原料生产氯乙烷的方法
CN107417307A (zh) *	2017-09-12	2017-12-01	化工部长沙设计研究院	一种水溶性滴灌用硫酸钾的制备工艺
US11021411B2 (en)	2017-05-24	2021-06-01	Ksm Inc.	Potassium magnesium fertilizer
CN116692901A (zh) *	2023-06-25	2023-09-05	江西金德锂新能源科技有限公司	一种锂云母提锂废渣中硫酸钾的分离方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP1889814B1 (fr) *	2006-08-07	2012-10-24	Grillo-Werke AG	Procédé destiné au retrait de chlorure

1991
- 1991-04-09 CA CA 2040109 patent/CA2040109A1/fr not_active Abandoned
- 1991-04-10 DE DE19914111718 patent/DE4111718A1/de not_active Withdrawn

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US8409542B2 (en)	2011-06-14	2013-04-02	Nichromet Extraction Inc.	Method and system for the production of potassium sulfate from potassium chloride
CN103396286A (zh) *	2013-07-19	2013-11-20	淮阴师范学院	以氯化钠与低浓度乙醇为原料生产氯乙烷的方法
US11021411B2 (en)	2017-05-24	2021-06-01	Ksm Inc.	Potassium magnesium fertilizer
CN107417307A (zh) *	2017-09-12	2017-12-01	化工部长沙设计研究院	一种水溶性滴灌用硫酸钾的制备工艺
CN116692901A (zh) *	2023-06-25	2023-09-05	江西金德锂新能源科技有限公司	一种锂云母提锂废渣中硫酸钾的分离方法

Also Published As

Publication number	Publication date
DE4111718A1 (de)	1991-10-17

Legal Events

Date	Code	Title	Description
1999-04-09	FZDE	Dead

Publication	Publication Date	Title
US4045543A (en)	1977-08-30	Production of potassium sulfate and hydrogen chloride
US3998935A (en)	1976-12-21	Manufacture of potassium sulfate
CA1217028A (fr)	1987-01-27	Preparation de sulfate de potassium a partir d'acide sulfurique et de chlorure de potassium
US4162270A (en)	1979-07-24	Process for producing 4,4'-dihydroxydiphenylsulfone of high purity
CA2157885C (fr)	1999-01-26	Methode de preparation de chlorure de magnesium anhydre
NO150151B (no)	1984-05-21	Fremgangsmaate for fremstilling av aluminiumfluorid ved absorpsjon av fluorholdig gass
SU489312A3 (ru)	1975-10-25	Способ получени тетрахлорфталонитрила
JPS60210515A (ja)	1985-10-23	シラン製造方法
US4052460A (en)	1977-10-04	Production of 3,3-dimethyl-2-oxo-butyric acid salt
CA2040109A1 (fr)	1991-10-11	Procede de production de sulfate de potassium et d'acide chlorhydrique
US3130010A (en)	1964-04-21	Process for production of high purity cesium metal and cesium compounds
JPS5829296B2 (ja)	1983-06-22	モノメチルヒドラジンの製造方法
US5540818A (en)	1996-07-30	Process for the production of high purity methanesulphonyl fluoride at an improved yield
US4062929A (en)	1977-12-13	Production of hydrogen fluoride
JPH05186216A (ja)	1993-07-27	硫酸カリウムと塩酸の製造方法
JP3182946B2 (ja)	2001-07-03	Ｎ−（α−アルコキシエチル）ホルムアミドの製造方法
JP2845745B2 (ja)	1999-01-13	高純度メタンスルホニルフロライドの製造法
US4394368A (en)	1983-07-19	High temperature hydrolysis of aluminum sulfate solutions
US2783130A (en)	1957-02-26	Process for the production of hydrazine
CA3111115A1 (fr)	2022-09-02	Procede industriel et systeme de production de potassium et engrais de potassium et de magnesium
US4898974A (en)	1990-02-06	Production of 3,3-dimethyl-2-oxo-butyric acid salt
JPS58157751A (ja)	1983-09-19	モノメチルヒドラジンの回収方法
US3043878A (en)	1962-07-10	Manufacture of guanidine nitrate
US4564704A (en)	1986-01-14	Production of 3,3-dimethyl-2-oxo-butyric acid salt
US2982617A (en)	1961-05-02	Preparation of perchloryl fluoride

CA2040109A1 - Procede de production de sulfate de potassium et d'acide chlorhydrique - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (2)

Publications (1)

Family

ID=14075070

Family Applications (1)

Country Status (2)

Cited By (5)

Families Citing this family (1)

Cited By (5)

Also Published As

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Legal Events