CA2040202A1 - Enzyme stabilizing composition and stabilized enzyme containing built detergent compositions - Google Patents

Enzyme stabilizing composition and stabilized enzyme containing built detergent compositions

Info

Publication number: CA2040202A1
Authority: CA; Canada
Prior art keywords: enzyme; weight; composition; acid; detergent composition
Prior art date: 1990-04-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002040202A

Other languages

English (en)

French (fr)

Inventor

Hoai-Chau Cao

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Colgate Palmolive Co

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-04-13

Filing date

1991-04-10

Publication date

1991-10-14

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=24027097&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2040202(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1991-04-10 Application filed by Individual filed Critical Individual

1991-10-14 Publication of CA2040202A1 publication Critical patent/CA2040202A1/en

Status Abandoned legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 159
102000004190 Enzymes Human genes 0.000 title claims abstract description 108
108090000790 Enzymes Proteins 0.000 title claims abstract description 108
239000003599 detergent Substances 0.000 title claims abstract description 97
230000000087 stabilizing effect Effects 0.000 title claims abstract description 16
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 52
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims abstract description 24
230000006641 stabilisation Effects 0.000 claims abstract description 23
238000011105 stabilization Methods 0.000 claims abstract description 23
229910001424 calcium ion Inorganic materials 0.000 claims abstract description 22
239000004327 boric acid Substances 0.000 claims abstract description 19
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 18
239000004927 clay Substances 0.000 claims abstract description 14
125000000129 anionic group Chemical group 0.000 claims abstract description 13
229940088598 enzyme Drugs 0.000 claims description 102
239000007788 liquid Substances 0.000 claims description 48
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 36
-1 alkali metal borates Chemical class 0.000 claims description 34
125000004432 carbon atom Chemical group C* 0.000 claims description 28
239000002253 acid Substances 0.000 claims description 25
229910052783 alkali metal Inorganic materials 0.000 claims description 20
125000000217 alkyl group Chemical group 0.000 claims description 19
229910021538 borax Inorganic materials 0.000 claims description 19
235000010339 sodium tetraborate Nutrition 0.000 claims description 19
150000003839 salts Chemical class 0.000 claims description 17
150000001875 compounds Chemical class 0.000 claims description 16
238000002360 preparation method Methods 0.000 claims description 16
239000004328 sodium tetraborate Substances 0.000 claims description 16
108091005804 Peptidases Proteins 0.000 claims description 13
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239000007859 condensation product Substances 0.000 claims description 11
108010065511 Amylases Proteins 0.000 claims description 10
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150000001340 alkali metals Chemical class 0.000 claims description 10
239000002304 perfume Substances 0.000 claims description 10
239000004094 surface-active agent Substances 0.000 claims description 10
102000035195 Peptidases Human genes 0.000 claims description 9
239000002518 antifoaming agent Substances 0.000 claims description 9
159000000007 calcium salts Chemical class 0.000 claims description 9
JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 9
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 8
239000004365 Protease Substances 0.000 claims description 8
239000001110 calcium chloride Substances 0.000 claims description 8
229910001628 calcium chloride Inorganic materials 0.000 claims description 8
239000004902 Softening Agent Substances 0.000 claims description 7
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 7
235000019418 amylase Nutrition 0.000 claims description 7
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238000000034 method Methods 0.000 claims description 7
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235000019832 sodium triphosphate Nutrition 0.000 claims description 6
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102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 4
229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 4
150000008041 alkali metal carbonates Chemical class 0.000 claims description 4
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239000007864 aqueous solution Substances 0.000 claims description 4
229910052810 boron oxide Inorganic materials 0.000 claims description 4
238000004140 cleaning Methods 0.000 claims description 4
238000004900 laundering Methods 0.000 claims description 4
229920006324 polyoxymethylene Polymers 0.000 claims description 4
239000001205 polyphosphate Substances 0.000 claims description 4
235000011176 polyphosphates Nutrition 0.000 claims description 4
239000000344 soap Substances 0.000 claims description 4
150000007942 carboxylates Chemical class 0.000 claims description 3
239000000975 dye Substances 0.000 claims description 3
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 3
238000005260 corrosion Methods 0.000 claims description 2
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230000002070 germicidal effect Effects 0.000 claims description 2
239000003752 hydrotrope Substances 0.000 claims description 2
239000003112 inhibitor Substances 0.000 claims description 2
239000003002 pH adjusting agent Substances 0.000 claims description 2
150000004760 silicates Chemical class 0.000 claims description 2
239000000375 suspending agent Substances 0.000 claims description 2
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238000006731 degradation reaction Methods 0.000 claims 1
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230000000694 effects Effects 0.000 abstract description 10
230000032683 aging Effects 0.000 abstract description 8
239000002280 amphoteric surfactant Substances 0.000 abstract description 6
239000002736 nonionic surfactant Substances 0.000 abstract description 5
239000003945 anionic surfactant Substances 0.000 abstract description 3
235000012216 bentonite Nutrition 0.000 description 23
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DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 19
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 16
150000002191 fatty alcohols Chemical class 0.000 description 15
239000000440 bentonite Substances 0.000 description 13
229910000278 bentonite Inorganic materials 0.000 description 13
229940092782 bentonite Drugs 0.000 description 13
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 13
239000004615 ingredient Substances 0.000 description 12
239000000463 material Substances 0.000 description 11
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
238000002156 mixing Methods 0.000 description 9
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 8
239000011575 calcium Substances 0.000 description 8
229910052791 calcium Inorganic materials 0.000 description 8
239000000243 solution Substances 0.000 description 8
229920002125 Sokalan® Polymers 0.000 description 7
238000009472 formulation Methods 0.000 description 7
229920001296 polysiloxane Polymers 0.000 description 7
239000000047 product Substances 0.000 description 7
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
238000013019 agitation Methods 0.000 description 6
235000011148 calcium chloride Nutrition 0.000 description 6
239000003381 stabilizer Substances 0.000 description 6
230000008961 swelling Effects 0.000 description 6
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 5
150000002500 ions Chemical class 0.000 description 5
229910052751 metal Inorganic materials 0.000 description 5
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239000004584 polyacrylic acid Substances 0.000 description 5
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150000003077 polyols Chemical class 0.000 description 5
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
239000005977 Ethylene Substances 0.000 description 4
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
239000000084 colloidal system Substances 0.000 description 4
UKHVLWKBNNSRRR-ODZAUARKSA-M dowicil 200 Chemical compound [Cl-].C1N(C2)CN3CN2C[N+]1(C\C=C/Cl)C3 UKHVLWKBNNSRRR-ODZAUARKSA-M 0.000 description 4
235000011187 glycerol Nutrition 0.000 description 4
229910052739 hydrogen Inorganic materials 0.000 description 4
239000001257 hydrogen Substances 0.000 description 4
125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 4
229920000058 polyacrylate Polymers 0.000 description 4
229920005646 polycarboxylate Polymers 0.000 description 4
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 4
239000000126 substance Substances 0.000 description 4
239000003760 tallow Substances 0.000 description 4
YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
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229910019142 PO4 Inorganic materials 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
108010056079 Subtilisins Proteins 0.000 description 3
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150000007513 acids Chemical class 0.000 description 3
239000003513 alkali Substances 0.000 description 3
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239000012736 aqueous medium Substances 0.000 description 3
125000004429 atom Chemical group 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
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239000002609 medium Substances 0.000 description 3
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NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
239000010452 phosphate Substances 0.000 description 3
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229940096792 quaternium-15 Drugs 0.000 description 3
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235000017550 sodium carbonate Nutrition 0.000 description 3
238000003860 storage Methods 0.000 description 3
239000002562 thickening agent Substances 0.000 description 3
RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 3
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
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235000013162 Cocos nucifera Nutrition 0.000 description 2
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KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
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WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
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FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
DSLZVSRJTYRBFB-UHFFFAOYSA-N Galactaric acid Natural products OC(=O)C(O)C(O)C(O)C(O)C(O)=O DSLZVSRJTYRBFB-UHFFFAOYSA-N 0.000 description 1
108010010803 Gelatin Proteins 0.000 description 1
ODBLHEXUDAPZAU-FONMRSAGSA-N Isocitric acid Natural products OC(=O)[C@@H](O)[C@H](C(O)=O)CC(O)=O ODBLHEXUDAPZAU-FONMRSAGSA-N 0.000 description 1
241001397173 Kali <angiosperm> Species 0.000 description 1
239000005639 Lauric acid Substances 0.000 description 1
241001068914 Melicope knudsenii Species 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
241000208474 Protea Species 0.000 description 1
101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
NPTTZSYLTYJCPR-UHFFFAOYSA-N Trihydroxy-glutarsaeure Natural products OC(=O)C(O)C(O)C(O)C(O)=O NPTTZSYLTYJCPR-UHFFFAOYSA-N 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
KIDJHPQACZGFTI-UHFFFAOYSA-N [6-[bis(phosphonomethyl)amino]hexyl-(phosphonomethyl)amino]methylphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCCCCCN(CP(O)(O)=O)CP(O)(O)=O KIDJHPQACZGFTI-UHFFFAOYSA-N 0.000 description 1
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical group 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
108090000637 alpha-Amylases Proteins 0.000 description 1
102000004139 alpha-Amylases Human genes 0.000 description 1
229940024171 alpha-amylase Drugs 0.000 description 1
BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
230000003254 anti-foaming effect Effects 0.000 description 1
239000002585 base Substances 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
239000008280 blood Substances 0.000 description 1
210000004369 blood Anatomy 0.000 description 1
150000001642 boronic acid derivatives Chemical class 0.000 description 1
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
239000001639 calcium acetate Substances 0.000 description 1
235000011092 calcium acetate Nutrition 0.000 description 1
229960005147 calcium acetate Drugs 0.000 description 1
229940043430 calcium compound Drugs 0.000 description 1
150000001674 calcium compounds Chemical class 0.000 description 1
239000004281 calcium formate Substances 0.000 description 1
235000019255 calcium formate Nutrition 0.000 description 1
229940044172 calcium formate Drugs 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
125000002843 carboxylic acid group Chemical group 0.000 description 1
150000001734 carboxylic acid salts Chemical class 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000008112 carboxymethyl-cellulose Substances 0.000 description 1
238000005341 cation exchange Methods 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003518 caustics Substances 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
235000019219 chocolate Nutrition 0.000 description 1
150000001860 citric acid derivatives Chemical class 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
239000008119 colloidal silica Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
230000001461 cytolytic effect Effects 0.000 description 1
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 description 1
229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 description 1
UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 1
230000002255 enzymatic effect Effects 0.000 description 1
229940012017 ethylenediamine Drugs 0.000 description 1
239000012467 final product Substances 0.000 description 1
238000005187 foaming Methods 0.000 description 1
239000004088 foaming agent Substances 0.000 description 1
229940044170 formate Drugs 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
DSLZVSRJTYRBFB-DUHBMQHGSA-N galactaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)C(O)=O DSLZVSRJTYRBFB-DUHBMQHGSA-N 0.000 description 1
229920000159 gelatin Polymers 0.000 description 1
239000008273 gelatin Substances 0.000 description 1
235000019322 gelatine Nutrition 0.000 description 1
235000011852 gelatine desserts Nutrition 0.000 description 1
230000005484 gravity Effects 0.000 description 1
235000013882 gravy Nutrition 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000004310 lactic acid Substances 0.000 description 1
235000014655 lactic acid Nutrition 0.000 description 1
230000002366 lipolytic effect Effects 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
239000001630 malic acid Substances 0.000 description 1
235000011090 malic acid Nutrition 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
125000005341 metaphosphate group Chemical group 0.000 description 1
229920003145 methacrylic acid copolymer Polymers 0.000 description 1
229940117841 methacrylic acid copolymer Drugs 0.000 description 1
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
108010020132 microbial serine proteinases Proteins 0.000 description 1
239000003607 modifier Substances 0.000 description 1
150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
229910052901 montmorillonite Inorganic materials 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
239000002674 ointment Substances 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000003605 opacifier Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
238000010979 pH adjustment Methods 0.000 description 1
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
235000012736 patent blue V Nutrition 0.000 description 1
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
HCTVWSOKIJULET-LQDWTQKMSA-M phenoxymethylpenicillin potassium Chemical compound [K+].N([C@H]1[C@H]2SC([C@@H](N2C1=O)C([O-])=O)(C)C)C(=O)COC1=CC=CC=C1 HCTVWSOKIJULET-LQDWTQKMSA-M 0.000 description 1
229920003214 poly(methacrylonitrile) Polymers 0.000 description 1
229920002401 polyacrylamide Polymers 0.000 description 1
229920002239 polyacrylonitrile Polymers 0.000 description 1
GHTWQCXOBQMUHR-UHFFFAOYSA-M potassium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetate Chemical compound [K+].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC([O-])=O GHTWQCXOBQMUHR-UHFFFAOYSA-M 0.000 description 1
239000003755 preservative agent Substances 0.000 description 1
238000002203 pretreatment Methods 0.000 description 1
150000003138 primary alcohols Chemical class 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
230000003252 repetitive effect Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000003352 sequestering agent Substances 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
229910021647 smectite Inorganic materials 0.000 description 1
HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
229910000280 sodium bentonite Inorganic materials 0.000 description 1
229940080314 sodium bentonite Drugs 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
239000001433 sodium tartrate Substances 0.000 description 1
229960002167 sodium tartrate Drugs 0.000 description 1
235000011004 sodium tartrates Nutrition 0.000 description 1
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000002689 soil Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
238000005494 tarnishing Methods 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
108010075550 termamyl Proteins 0.000 description 1
RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
230000008719 thickening Effects 0.000 description 1
ODBLHEXUDAPZAU-UHFFFAOYSA-N threo-D-isocitric acid Natural products OC(=O)C(O)C(C(O)=O)CC(O)=O ODBLHEXUDAPZAU-UHFFFAOYSA-N 0.000 description 1
KRTNITDCKAVIFI-UHFFFAOYSA-N tridecyl benzenesulfonate Chemical compound CCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 KRTNITDCKAVIFI-UHFFFAOYSA-N 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

CA002040202A 1990-04-13 1991-04-10 Enzyme stabilizing composition and stabilized enzyme containing built detergent compositions Abandoned CA2040202A1 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US509,549		1983-06-30
US50954990A	1990-04-13	1990-04-13

Publications (1)

Publication Number	Publication Date
CA2040202A1 true CA2040202A1 (en)	1991-10-14

Family

ID=24027097

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002040202A Abandoned CA2040202A1 (en)	1990-04-13	1991-04-10	Enzyme stabilizing composition and stabilized enzyme containing built detergent compositions

Country Status (18)

Country	Link
EP (1)	EP0451924B1 (da)
AT (1)	ATE176682T1 (da)
AU (1)	AU651090B2 (da)
BR (1)	BR9101486A (da)
CA (1)	CA2040202A1 (da)
DE (1)	DE69130880D1 (da)
DK (1)	DK0451924T3 (da)
ES (1)	ES2130131T3 (da)
FI (1)	FI911800A7 (da)
GR (1)	GR1001040B (da)
IE (1)	IE911245A1 (da)
MX (1)	MX173751B (da)
MY (1)	MY105503A (da)
NO (1)	NO911448L (da)
NZ (1)	NZ237570A (da)
PT (1)	PT97325A (da)
TR (1)	TR25788A (da)
ZA (1)	ZA912598B (da)

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DE4037764A1 (de) *	1990-11-28	1992-06-04	Behringwerke Ag	Waschloesung fuer festphasen-immunometrische verfahren, die stabilisatoren fuer das markierungssystem enthaelt und ihre verwendung
CZ285148B6 (cs) *	1991-04-30	1999-05-12	The Procter And Gamble Company	Kapalné detergentní směsi s borito-polyolovým komplexem k inhibici proteolytického enzymu
AU669900B2 (en) *	1992-07-20	1996-06-27	Colgate-Palmolive Company, The	Stabilized built aqueous liquid softergent compositions
WO1996021716A1 (en) *	1995-01-09	1996-07-18	Novo Nordisk A/S	Stabilization of liquid enzyme compositions
DE19515072A1 (de) *	1995-04-28	1996-10-31	Cognis Bio Umwelt	Cellulasehaltiges Waschmittel
DE19605688A1 (de) *	1996-02-16	1997-08-21	Henkel Kgaa	Übergangsmetallkomplexe als Aktivatoren für Persauerstoffverbindungen
US6537958B1 (en)	1999-11-10	2003-03-25	The Procter & Gamble Company	Bleaching compositions
US7795199B2 (en)	2000-06-29	2010-09-14	Ecolab Inc.	Stable antimicrobial compositions including spore, bacteria, fungi, and/or enzyme
US6624132B1 (en)	2000-06-29	2003-09-23	Ecolab Inc.	Stable liquid enzyme compositions with enhanced activity
GB2367065B (en) *	2000-09-20	2002-11-20	Reckitt Benckiser Inc	Enzyme containing laundry booster compositions
WO2003070823A2 (en) *	2002-02-20	2003-08-28	The General Hospital Corporation	Conjugates comprising a biodegradable polymer and uses therefor
WO2005113147A2 (en)	2004-04-08	2005-12-01	Biomatrica, Inc.	Integration of sample storage and sample management for life science
DE102007011236A1 (de)	2007-03-06	2008-09-11	Henkel Ag & Co. Kgaa	Carboxylgruppen tragende Benzophenon-oderBenzoesäureanilid-Derivate als Enzymstabilisatoren
DE102007041754A1 (de)	2007-09-04	2009-03-05	Henkel Ag & Co. Kgaa	Polycyclische Verbindungen als Enzymstabilisatoren
DE102008010429A1 (de)	2008-02-21	2009-08-27	Henkel Ag & Co. Kgaa	Harnstoff-Derivate als Enzymstabilisatoren
DE102008014760A1 (de)	2008-03-18	2009-09-24	Henkel Ag & Co. Kgaa	Imidazolium-Salze als Enzymstabilisatoren
US7964548B2 (en)	2009-01-20	2011-06-21	Ecolab Usa Inc.	Stable aqueous antimicrobial enzyme compositions
US7723281B1 (en)	2009-01-20	2010-05-25	Ecolab Inc.	Stable aqueous antimicrobial enzyme compositions comprising a tertiary amine antimicrobial
EP2430195B1 (en) *	2009-05-11	2019-01-23	Biomatrica, INC.	Compositions and methods for biological sample storage
WO2012018639A2 (en)	2010-07-26	2012-02-09	Biomatrica, Inc.	Compositions for stabilizing dna, rna and proteins in saliva and other biological samples during shipping and storage at ambient temperatures
EP2598660B1 (en)	2010-07-26	2017-03-15	Biomatrica, INC.	Compositions for stabilizing dna, rna and proteins in blood and other biological samples during shipping and storage at ambient temperatures
US9133424B2 (en) *	2011-12-16	2015-09-15	Ecolab Usa Inc.	Stabilization and activation of protease for use at high temperature
US9725703B2 (en)	2012-12-20	2017-08-08	Biomatrica, Inc.	Formulations and methods for stabilizing PCR reagents
ES2786373T3 (es)	2014-06-10	2020-10-09	Biomatrica Inc	Estabilización de trombocitos a temperaturas ambiente
DE102014218507A1 (de)	2014-09-16	2016-03-17	Henkel Ag & Co. Kgaa	Spinnenseidenproteine als Enzymstabilisatoren
KR20250047404A (ko)	2015-12-08	2025-04-03	바이오매트리카 인코포레이티드	적혈구 침강 속도의 감소
IT202300009750A1 (it) *	2023-05-15	2024-11-15	Univ Degli Studi Milano	Composizione biologica per l’uso contro le infezioni fungine delle piante

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Publication number	Priority date	Publication date	Assignee	Title
IT1106254B (it) *	1976-03-08	1985-11-11	Procter & Gamble Europ	Composizione detergente liquida contenente enzimi
ATE77649T1 (de) *	1985-04-15	1992-07-15	Procter & Gamble	Fluessige reinigungsmittel mit einer oberflaechenaktiven verbindung, einem proteolytischen enzym und borsaeure.
SE468518B (sv) *	1985-07-26	1993-02-01	Colgate Palmolive Co	Stabiliserad textilmjukgoerande enzyminnehaallande foerstaerkt flytande detergentkomposition och dess anvaendning vid tvaett av textilier
US4842758A (en) *	1986-10-31	1989-06-27	Colgate-Palmolive Company	Stabilized enzyme system for use in aqueous liquid built detergent compositions

1991
- 1991-03-25 NZ NZ237570A patent/NZ237570A/xx unknown
- 1991-03-28 AU AU74007/91A patent/AU651090B2/en not_active Ceased
- 1991-04-04 MY MYPI91000556A patent/MY105503A/en unknown
- 1991-04-08 ZA ZA912598A patent/ZA912598B/xx unknown
- 1991-04-09 MX MX025281A patent/MX173751B/es unknown
- 1991-04-10 CA CA002040202A patent/CA2040202A1/en not_active Abandoned
- 1991-04-11 PT PT97325A patent/PT97325A/pt not_active Application Discontinuation
- 1991-04-12 AT AT91200871T patent/ATE176682T1/de not_active IP Right Cessation
- 1991-04-12 IE IE124591A patent/IE911245A1/en unknown
- 1991-04-12 ES ES91200871T patent/ES2130131T3/es not_active Expired - Lifetime
- 1991-04-12 EP EP91200871A patent/EP0451924B1/en not_active Revoked
- 1991-04-12 FI FI911800A patent/FI911800A7/fi not_active Application Discontinuation
- 1991-04-12 DE DE69130880T patent/DE69130880D1/de not_active Expired - Lifetime
- 1991-04-12 BR BR919101486A patent/BR9101486A/pt not_active Application Discontinuation
- 1991-04-12 DK DK91200871T patent/DK0451924T3/da active
- 1991-04-12 NO NO91911448A patent/NO911448L/no unknown
- 1991-04-12 GR GR910100154A patent/GR1001040B/el unknown
- 1991-04-15 TR TR91/0415A patent/TR25788A/xx unknown

Also Published As

Publication number	Publication date
GR1001040B (el)	1993-03-31
AU651090B2 (en)	1994-07-14
FI911800L (fi)	1991-10-14
MX173751B (es)	1994-03-25
ZA912598B (en)	1992-12-30
FI911800A0 (fi)	1991-04-12
AU7400791A (en)	1991-10-17
FI911800A7 (fi)	1991-10-14
NO911448L (no)	1991-10-14
NZ237570A (en)	1993-09-27
IE911245A1 (en)	1991-10-23
EP0451924B1 (en)	1999-02-10
EP0451924A2 (en)	1991-10-16
NO911448D0 (no)	1991-04-12
DE69130880D1 (de)	1999-03-25
HK1014026A1 (en)	1999-09-17
DK0451924T3 (da)	1999-09-20
TR25788A (tr)	1993-09-01
PT97325A (pt)	1992-01-31
GR910100154A (en)	1992-07-30
MY105503A (en)	1994-10-31
EP0451924A3 (en)	1992-03-11
ATE176682T1 (de)	1999-02-15
BR9101486A (pt)	1991-12-03
ES2130131T3 (es)	1999-07-01

Legal Events

Date	Code	Title	Description
1999-04-12	FZDE	Discontinued

Publication	Publication Date	Title
US5221495A (en)	1993-06-22	Enzyme stabilizing composition and stabilized enzyme containing built detergent compositions
EP0451924B1 (en)	1999-02-10	Enzyme stabilizing composition and the use thereof in stabilized enzyme containing built detergent compositions
US4842758A (en)	1989-06-27	Stabilized enzyme system for use in aqueous liquid built detergent compositions
US5364553A (en)	1994-11-15	Stabilized built aqueous liquid softergent compositions
AU669900B2 (en)	1996-06-27	Stabilized built aqueous liquid softergent compositions
US4900475A (en)	1990-02-13	Stabilized built liquid detergent composition containing enzyme
US5587356A (en)	1996-12-24	Thickened, highly aqueous, cost effective liquid detergent compositions
USH1776H (en)	1999-01-05	Enzyme-containing heavy duty liquid detergent
US5500151A (en)	1996-03-19	Heavy duty fabric softening laundry detergent composition
US4842769A (en)	1989-06-27	Stabilized fabric softening built detergent composition containing enzymes
CA1297440C (en)	1992-03-17	Fabric softening liquid detergent
JP2749415B2 (ja)	1998-05-13	酵素と酵素安定化系を含む液体洗剤組成物
EP0946698A1 (en)	1999-10-06	Mildly acidic laundry detergent composition
US5156761A (en)	1992-10-20	Method of stabilizing an enzymatic liquid detergent composition
AU618036B2 (en)	1991-12-12	Machine dishwashing compositions
US4842767A (en)	1989-06-27	Heavy duty built aqueous liquid detergent composition containing stabilized enzymes
US4272396A (en)	1981-06-09	Enzyme-containing detergent composition
CA2119362A1 (en)	1993-04-29	Aqueous enzymatic detergent compositions
GB2178054A (en)	1987-02-04	Stabilized built liquid detergent composition containing enzymes
US5948745A (en)	1999-09-07	Detergent composition having improved cleaning power
EP0426906B1 (en)	1998-01-28	Heavy duty fabric softening laundry detergent composition
HK1014026B (en)	2000-05-19	Enzyme stabilizing composition and the use thereof in stabilized enzyme containing built detergent compositions
HK1014730A (en)	1999-09-30	Stabilized built aqueous liquid softergent compositions
JPS6232196A (ja)	1987-02-12	布帛　柔軟化用　液体洗剤
CA2001762A1 (en)	1991-04-30	Heavy duty fabric softening laundry detergent compositions