CA2041312C - Catalyseur renfermant de grandes quantites de metal precieux en dispersion sur des tamis moleculaires hydrophobes - Google Patents

Catalyseur renfermant de grandes quantites de metal precieux en dispersion sur des tamis moleculaires hydrophobes

Info

Publication number: CA2041312C
Authority: CA; Canada
Prior art keywords: noble metal; silicalite; mass; water; hydrogen
Prior art date: 1989-09-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA 2041312

Other languages

English (en)

Other versions

CA2041312A1 (fr

Inventor

Mark T. Staniulis

Douglas E. Crozier

Alan P. Risch

Jenny L. Pai

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Honeywell UOP LLC

Original Assignee

UOP LLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-09-05

Filing date

1991-04-26

Publication date

1997-09-30

1989-09-05 Priority claimed from US07/402,745 external-priority patent/US5013703A/en

1991-04-26 Application filed by UOP LLC filed Critical UOP LLC

1991-04-26 Priority to CA 2041312 priority Critical patent/CA2041312C/fr

1992-10-27 Publication of CA2041312A1 publication Critical patent/CA2041312A1/fr

1997-09-30 Application granted granted Critical

1997-09-30 Publication of CA2041312C publication Critical patent/CA2041312C/fr

2011-04-26 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

229910000510 noble metal Inorganic materials 0.000 title claims abstract description 40
239000003054 catalyst Substances 0.000 title claims abstract description 23
230000002209 hydrophobic effect Effects 0.000 title description 8
239000002808 molecular sieve Substances 0.000 title description 4
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 24
239000001257 hydrogen Substances 0.000 claims abstract description 24
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 23
239000006185 dispersion Substances 0.000 claims abstract description 18
238000001354 calcination Methods 0.000 claims abstract description 12
239000007788 liquid Substances 0.000 claims abstract description 11
230000000155 isotopic effect Effects 0.000 claims abstract description 9
150000002736 metal compounds Chemical class 0.000 claims abstract description 8
230000003197 catalytic effect Effects 0.000 claims abstract description 7
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 46
238000000034 method Methods 0.000 claims description 27
229910052697 platinum Inorganic materials 0.000 claims description 19
239000002585 base Substances 0.000 claims description 18
230000008569 process Effects 0.000 claims description 15
239000002131 composite material Substances 0.000 claims description 10
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 8
239000007864 aqueous solution Substances 0.000 claims description 5
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 4
230000006872 improvement Effects 0.000 claims description 4
229910052763 palladium Inorganic materials 0.000 claims description 4
229910052703 rhodium Inorganic materials 0.000 claims description 4
239000010948 rhodium Substances 0.000 claims description 4
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 4
229910052707 ruthenium Inorganic materials 0.000 claims description 4
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
229910052737 gold Inorganic materials 0.000 claims description 3
239000010931 gold Substances 0.000 claims description 3
229910052741 iridium Inorganic materials 0.000 claims description 3
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 3
229910052762 osmium Inorganic materials 0.000 claims description 3
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 3
229910052702 rhenium Inorganic materials 0.000 claims description 3
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 3
238000004519 manufacturing process Methods 0.000 claims description 2
150000008044 alkali metal hydroxides Chemical class 0.000 claims 1
238000011068 loading method Methods 0.000 abstract description 10
239000000203 mixture Substances 0.000 abstract description 4
-1 poly(tetrafluoroethylene) Polymers 0.000 abstract description 3
239000011159 matrix material Substances 0.000 abstract description 2
229920001343 polytetrafluoroethylene Polymers 0.000 abstract description 2
238000005470 impregnation Methods 0.000 description 18
229910052751 metal Inorganic materials 0.000 description 10
239000002184 metal Substances 0.000 description 10
XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 8
150000001875 compounds Chemical class 0.000 description 6
239000000243 solution Substances 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
238000011161 development Methods 0.000 description 3
230000018109 developmental process Effects 0.000 description 3
238000000926 separation method Methods 0.000 description 3
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical class [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
YFONKFDEZLYQDH-OPQQBVKSSA-N N-[(1R,2S)-2,6-dimethyindan-1-yl]-6-[(1R)-1-fluoroethyl]-1,3,5-triazine-2,4-diamine Chemical compound C[C@@H](F)C1=NC(N)=NC(N[C@H]2C3=CC(C)=CC=C3C[C@@H]2C)=N1 YFONKFDEZLYQDH-OPQQBVKSSA-N 0.000 description 2
235000011114 ammonium hydroxide Nutrition 0.000 description 2
230000008901 benefit Effects 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
230000009849 deactivation Effects 0.000 description 2
239000000463 material Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
239000012071 phase Substances 0.000 description 2
239000012808 vapor phase Substances 0.000 description 2
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
206010053317 Hydrophobia Diseases 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
241000282320 Panthera leo Species 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
229940045985 antineoplastic platinum compound Drugs 0.000 description 1
238000013459 approach Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000003518 caustics Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000012612 commercial material Substances 0.000 description 1
230000002860 competitive effect Effects 0.000 description 1
230000000875 corresponding effect Effects 0.000 description 1
229910002026 crystalline silica Inorganic materials 0.000 description 1
BCAARMUWIRURQS-UHFFFAOYSA-N dicalcium;oxocalcium;silicate Chemical compound [Ca+2].[Ca+2].[Ca]=O.[O-][Si]([O-])([O-])[O-] BCAARMUWIRURQS-UHFFFAOYSA-N 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
239000010410 layer Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
150000003058 platinum compounds Chemical class 0.000 description 1
CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
229920000136 polysorbate Polymers 0.000 description 1
239000011148 porous material Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000011160 research Methods 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000002356 single layer Substances 0.000 description 1
238000002791 soaking Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Landscapes

Silicates, Zeolites, And Molecular Sieves (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)

CA 2041312 1989-09-05 1991-04-26 Catalyseur renfermant de grandes quantites de metal precieux en dispersion sur des tamis moleculaires hydrophobes Expired - Fee Related CA2041312C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA 2041312 CA2041312C (fr)	1989-09-05	1991-04-26	Catalyseur renfermant de grandes quantites de metal precieux en dispersion sur des tamis moleculaires hydrophobes

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US07/402,745 US5013703A (en)	1989-09-05	1989-09-05	Noble metal exchange of hydrophobic molecular sieves
CA 2041312 CA2041312C (fr)	1989-09-05	1991-04-26	Catalyseur renfermant de grandes quantites de metal precieux en dispersion sur des tamis moleculaires hydrophobes

Publications (2)

Publication Number	Publication Date
CA2041312A1 CA2041312A1 (fr)	1992-10-27
CA2041312C true CA2041312C (fr)	1997-09-30

Family

ID=25674577

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2041312 Expired - Fee Related CA2041312C (fr)	1989-09-05	1991-04-26	Catalyseur renfermant de grandes quantites de metal precieux en dispersion sur des tamis moleculaires hydrophobes

Country Status (1)

Country	Link
CA (1)	CA2041312C (fr)

1991
- 1991-04-26 CA CA 2041312 patent/CA2041312C/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA2041312A1 (fr)	1992-10-27

Legal Events

Date	Code	Title	Description
1994-11-08	EEER	Examination request
2003-04-28	MKLA	Lapsed

Publication	Publication Date	Title
CA2063123C (fr)	1996-12-10	Mode de preparation de peroxyde d'hydrogene
KR100460249B1 (ko)	2004-12-08	암모니아의 산화 반응 방법
CN109985654B (zh)	2021-07-13	一种碱金属离子修饰的氮化碳催化剂及其制备方法和应用
US5871707A (en)	1999-02-16	Process for producing chlorine
KR960002189B1 (ko)	1996-02-13	루테늄에 의해 촉진된 할로겐 함유의 수소화 및/또는 탈수소화 촉매의 제조방법
JPS5916816B2 (ja)	1984-04-18	アンモニアの製造方法
JPWO1994012428A1 (ja)	1995-01-05	過酸化水素の製造方法
JPH05330802A (ja)	1993-12-14	アンモニア分解ガスの製造法および水素の製造法
EP0339640A1 (fr)	1989-11-02	Composition d'oxyde de titane et d'alumine
EP0272332A1 (fr)	1988-06-29	Procede de production de chlore
WO1999002258A1 (fr)	1999-01-21	Reduction catalytique selective pour l'elimination d'oxydes d'azote et corps catalytique correspondant
JPWO1988000171A1 (ja)	1988-04-07	塩素の製造方法
KR100761512B1 (ko)	2007-10-04	금속 촉매를 이용한 디메틸나프탈렌의 탈수소화 공정
JPH0679177A (ja)	1994-03-22	アンモニア合成触媒および合成方法
EP3903933B1 (fr)	2025-03-19	Catalyseur pour décomposition d'ammoniac et procédé de traitement de gaz d'échappement
CA2041312C (fr)	1997-09-30	Catalyseur renfermant de grandes quantites de metal precieux en dispersion sur des tamis moleculaires hydrophobes
JPS5929633B2 (ja)	1984-07-21	炭化水素の低温水蒸気改質法
JPH08141399A (ja)	1996-06-04	アンモニア合成触媒およびその調製法
US5013703A (en)	1991-05-07	Noble metal exchange of hydrophobic molecular sieves
JP3672367B2 (ja)	2005-07-20	アンモニア合成触媒およびその製造法
JP3302402B2 (ja)	2002-07-15	アンモニア分解触媒
CN114471643B (zh)	2023-09-01	一种制氢的催化剂及其制备方法和应用
JP3485622B2 (ja)	2004-01-13	アンモニア合成触媒およびアンモニア合成方法
JPH05329370A (ja)	1993-12-14	アンモニア分解触媒
GB2033776A (en)	1980-05-29	Catalyst for the production of ammonia