CA2048462C - Compositions thermoplastiques - Google Patents

Compositions thermoplastiques Download PDF

Info

Publication number: CA2048462C
Authority: CA; Canada
Prior art keywords: composition; thermoplastic composition; para; halogen; copolymer
Prior art date: 1991-01-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA 2048462

Other languages

English (en)

Other versions

CA2048462A1 (fr

Inventor

Narayanaswami R. Dharmarajan

Donald R. Hazelton

Kenneth W. Powers

Robert C. Puydak

Hsien-Chang Wang

Thomas C. Yu

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ExxonMobil Chemical Patents Inc

Original Assignee

Exxon Chemical Patents Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-01-31

Filing date

1991-08-06

Publication date

2004-06-29

1991-01-31 Priority claimed from US07/648,267 external-priority patent/US6013727A/en

1991-08-06 Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc

1992-08-01 Publication of CA2048462A1 publication Critical patent/CA2048462A1/fr

2004-06-29 Application granted granted Critical

2004-06-29 Publication of CA2048462C publication Critical patent/CA2048462C/fr

2011-08-06 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 186
229920001169 thermoplastic Polymers 0.000 title claims abstract description 66
239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 63
229920001577 copolymer Polymers 0.000 claims abstract description 101
229920005989 resin Polymers 0.000 claims abstract description 73
239000011347 resin Substances 0.000 claims abstract description 73
229910052736 halogen Inorganic materials 0.000 claims abstract description 41
150000002367 halogens Chemical class 0.000 claims abstract description 41
229920002959 polymer blend Polymers 0.000 claims abstract description 16
238000004519 manufacturing process Methods 0.000 claims abstract description 4
229920001971 elastomer Polymers 0.000 claims description 89
239000005060 rubber Substances 0.000 claims description 67
-1 polybutylene terephthalate Polymers 0.000 claims description 41
238000004073 vulcanization Methods 0.000 claims description 31
238000000034 method Methods 0.000 claims description 25
229920000728 polyester Polymers 0.000 claims description 22
239000004952 Polyamide Substances 0.000 claims description 21
229920002647 polyamide Polymers 0.000 claims description 21
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 19
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 19
229910052794 bromium Inorganic materials 0.000 claims description 19
239000003921 oil Substances 0.000 claims description 19
230000008569 process Effects 0.000 claims description 19
239000003795 chemical substances by application Substances 0.000 claims description 13
238000002156 mixing Methods 0.000 claims description 13
239000004721 Polyphenylene oxide Substances 0.000 claims description 12
239000000945 filler Substances 0.000 claims description 11
238000002844 melting Methods 0.000 claims description 11
230000008018 melting Effects 0.000 claims description 11
125000003118 aryl group Chemical group 0.000 claims description 10
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 9
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical group CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 8
229920002292 Nylon 6 Polymers 0.000 claims description 8
229920001778 nylon Polymers 0.000 claims description 8
239000004734 Polyphenylene sulfide Substances 0.000 claims description 7
XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 7
229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 7
239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 7
239000004417 polycarbonate Substances 0.000 claims description 7
229920006380 polyphenylene oxide Polymers 0.000 claims description 7
229920000069 polyphenylene sulfide Polymers 0.000 claims description 7
239000011145 styrene acrylonitrile resin Substances 0.000 claims description 7
239000004677 Nylon Substances 0.000 claims description 6
239000004642 Polyimide Substances 0.000 claims description 6
150000001408 amides Chemical class 0.000 claims description 6
229920002492 poly(sulfone) Polymers 0.000 claims description 6
229920001707 polybutylene terephthalate Polymers 0.000 claims description 6
229920000515 polycarbonate Polymers 0.000 claims description 6
229920001721 polyimide Polymers 0.000 claims description 6
229920001470 polyketone Polymers 0.000 claims description 6
229920006324 polyoxymethylene Polymers 0.000 claims description 6
229920000570 polyether Polymers 0.000 claims description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
229920002302 Nylon 6,6 Polymers 0.000 claims description 4
239000000654 additive Substances 0.000 claims description 4
229920001400 block copolymer Polymers 0.000 claims description 4
239000000460 chlorine Substances 0.000 claims description 4
229910052801 chlorine Inorganic materials 0.000 claims description 4
239000004014 plasticizer Substances 0.000 claims description 4
SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 claims description 4
229920000638 styrene acrylonitrile Polymers 0.000 claims description 4
JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims description 3
229920000299 Nylon 12 Polymers 0.000 claims description 3
238000010057 rubber processing Methods 0.000 claims description 3
238000010058 rubber compounding Methods 0.000 claims description 2
238000010008 shearing Methods 0.000 claims description 2
PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims 5
229920000147 Styrene maleic anhydride Polymers 0.000 claims 5
239000002245 particle Substances 0.000 claims 2
230000000996 additive effect Effects 0.000 claims 1
229920000642 polymer Polymers 0.000 description 30
XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 30
239000000306 component Substances 0.000 description 26
239000000806 elastomer Substances 0.000 description 22
235000019198 oils Nutrition 0.000 description 18
238000006243 chemical reaction Methods 0.000 description 15
230000026030 halogenation Effects 0.000 description 12
238000005658 halogenation reaction Methods 0.000 description 12
238000006116 polymerization reaction Methods 0.000 description 12
239000010734 process oil Substances 0.000 description 11
239000002904 solvent Substances 0.000 description 10
239000008117 stearic acid Substances 0.000 description 10
239000011787 zinc oxide Substances 0.000 description 10
235000021355 Stearic acid Nutrition 0.000 description 9
239000003999 initiator Substances 0.000 description 9
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 9
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 9
RKQOSDAEEGPRER-UHFFFAOYSA-L zinc diethyldithiocarbamate Chemical compound [Zn+2].CCN(CC)C([S-])=S.CCN(CC)C([S-])=S RKQOSDAEEGPRER-UHFFFAOYSA-L 0.000 description 9
238000004132 cross linking Methods 0.000 description 8
239000003085 diluting agent Substances 0.000 description 8
238000009826 distribution Methods 0.000 description 8
239000011159 matrix material Substances 0.000 description 8
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 7
239000003963 antioxidant agent Substances 0.000 description 7
239000003054 catalyst Substances 0.000 description 7
239000012632 extractable Substances 0.000 description 7
239000000463 material Substances 0.000 description 7
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
238000005893 bromination reaction Methods 0.000 description 6
239000000243 solution Substances 0.000 description 6
230000006835 compression Effects 0.000 description 5
238000007906 compression Methods 0.000 description 5
JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 5
239000000178 monomer Substances 0.000 description 5
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
230000000704 physical effect Effects 0.000 description 5
239000000049 pigment Substances 0.000 description 5
239000002002 slurry Substances 0.000 description 5
239000000126 substance Substances 0.000 description 5
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 5
BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 4
239000000956 alloy Substances 0.000 description 4
229910045601 alloy Inorganic materials 0.000 description 4
XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 4
229920005557 bromobutyl Polymers 0.000 description 4
239000003518 caustics Substances 0.000 description 4
229920001198 elastomeric copolymer Polymers 0.000 description 4
125000001188 haloalkyl group Chemical group 0.000 description 4
239000012535 impurity Substances 0.000 description 4
239000004615 ingredient Substances 0.000 description 4
239000008188 pellet Substances 0.000 description 4
238000010791 quenching Methods 0.000 description 4
238000007086 side reaction Methods 0.000 description 4
239000004636 vulcanized rubber Substances 0.000 description 4
JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 4
229920006051 Capron® Polymers 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
229920000181 Ethylene propylene rubber Polymers 0.000 description 3
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
229920000571 Nylon 11 Polymers 0.000 description 3
229920002614 Polyether block amide Polymers 0.000 description 3
239000004743 Polypropylene Substances 0.000 description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
150000008064 anhydrides Chemical class 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
230000031709 bromination Effects 0.000 description 3
125000001246 bromo group Chemical group Br* 0.000 description 3
229920005549 butyl rubber Polymers 0.000 description 3
229910000019 calcium carbonate Inorganic materials 0.000 description 3
125000004432 carbon atom Chemical group C* 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
238000001816 cooling Methods 0.000 description 3
238000007334 copolymerization reaction Methods 0.000 description 3
238000005516 engineering process Methods 0.000 description 3
125000004970 halomethyl group Chemical group 0.000 description 3
230000006872 improvement Effects 0.000 description 3
ORECYURYFJYPKY-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine;2,4,6-trichloro-1,3,5-triazine;2,4,4-trimethylpentan-2-amine Chemical compound CC(C)(C)CC(C)(C)N.ClC1=NC(Cl)=NC(Cl)=N1.C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 ORECYURYFJYPKY-UHFFFAOYSA-N 0.000 description 3
239000003208 petroleum Substances 0.000 description 3
150000003022 phthalic acids Chemical class 0.000 description 3
229920006122 polyamide resin Polymers 0.000 description 3
229920001155 polypropylene Polymers 0.000 description 3
238000012545 processing Methods 0.000 description 3
239000000047 product Substances 0.000 description 3
230000009467 reduction Effects 0.000 description 3
YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 3
229920006395 saturated elastomer Polymers 0.000 description 3
239000003381 stabilizer Substances 0.000 description 3
229910052717 sulfur Inorganic materials 0.000 description 3
239000011593 sulfur Substances 0.000 description 3
238000012360 testing method Methods 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
239000001993 wax Substances 0.000 description 3
229910052725 zinc Inorganic materials 0.000 description 3
125000006681 (C2-C10) alkylene group Chemical group 0.000 description 2
IPJGAEWUPXWFPL-UHFFFAOYSA-N 1-[3-(2,5-dioxopyrrol-1-yl)phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC(N2C(C=CC2=O)=O)=C1 IPJGAEWUPXWFPL-UHFFFAOYSA-N 0.000 description 2
GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
AIBRSVLEQRWAEG-UHFFFAOYSA-N 3,9-bis(2,4-ditert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP1OCC2(COP(OC=3C(=CC(=CC=3)C(C)(C)C)C(C)(C)C)OC2)CO1 AIBRSVLEQRWAEG-UHFFFAOYSA-N 0.000 description 2
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
229920013683 Celanese Polymers 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
238000005481 NMR spectroscopy Methods 0.000 description 2
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 2
JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
229920002367 Polyisobutene Polymers 0.000 description 2
208000037062 Polyps Diseases 0.000 description 2
239000004614 Process Aid Substances 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
150000001335 aliphatic alkanes Chemical class 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
238000005275 alloying Methods 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
238000009835 boiling Methods 0.000 description 2
239000006229 carbon black Substances 0.000 description 2
229920005556 chlorobutyl Polymers 0.000 description 2
NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
239000004927 clay Substances 0.000 description 2
239000007859 condensation product Substances 0.000 description 2
238000012937 correction Methods 0.000 description 2
238000006356 dehydrogenation reaction Methods 0.000 description 2
125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 2
DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
239000012990 dithiocarbamate Substances 0.000 description 2
150000004659 dithiocarbamates Chemical class 0.000 description 2
238000001035 drying Methods 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
238000005227 gel permeation chromatography Methods 0.000 description 2
150000002334 glycols Chemical class 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
238000001746 injection moulding Methods 0.000 description 2
239000011968 lewis acid catalyst Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
229910044991 metal oxide Inorganic materials 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
238000000465 moulding Methods 0.000 description 2
238000006386 neutralization reaction Methods 0.000 description 2
150000002825 nitriles Chemical class 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
239000010690 paraffinic oil Substances 0.000 description 2
230000037361 pathway Effects 0.000 description 2
150000002978 peroxides Chemical class 0.000 description 2
239000012169 petroleum derived wax Substances 0.000 description 2
235000019381 petroleum wax Nutrition 0.000 description 2
229920001568 phenolic resin Polymers 0.000 description 2
231100000572 poisoning Toxicity 0.000 description 2
230000000607 poisoning effect Effects 0.000 description 2
229920000139 polyethylene terephthalate Polymers 0.000 description 2
239000005020 polyethylene terephthalate Substances 0.000 description 2
229920005672 polyolefin resin Polymers 0.000 description 2
229920000874 polytetramethylene terephthalate Polymers 0.000 description 2
230000001012 protector Effects 0.000 description 2
230000000171 quenching effect Effects 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000006467 substitution reaction Methods 0.000 description 2
229920001897 terpolymer Polymers 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
229920006345 thermoplastic polyamide Polymers 0.000 description 2
229920005992 thermoplastic resin Polymers 0.000 description 2
229960002447 thiram Drugs 0.000 description 2
KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 2
239000004408 titanium dioxide Substances 0.000 description 2
238000003466 welding Methods 0.000 description 2
239000011701 zinc Substances 0.000 description 2
OPNUROKCUBTKLF-UHFFFAOYSA-N 1,2-bis(2-methylphenyl)guanidine Chemical class CC1=CC=CC=C1N\C(N)=N\C1=CC=CC=C1C OPNUROKCUBTKLF-UHFFFAOYSA-N 0.000 description 1
150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 1
GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 description 1
FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical group CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 description 1
BYLSIPUARIZAHZ-UHFFFAOYSA-N 2,4,6-tris(1-phenylethyl)phenol Chemical compound C=1C(C(C)C=2C=CC=CC=2)=C(O)C(C(C)C=2C=CC=CC=2)=CC=1C(C)C1=CC=CC=C1 BYLSIPUARIZAHZ-UHFFFAOYSA-N 0.000 description 1
WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 1
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239000012434 nucleophilic reagent Substances 0.000 description 1
SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
150000002895 organic esters Chemical class 0.000 description 1
NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
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AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
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239000011297 pine tar Substances 0.000 description 1
229940068124 pine tar Drugs 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920001084 poly(chloroprene) Polymers 0.000 description 1
229920001643 poly(ether ketone) Polymers 0.000 description 1
229920001652 poly(etherketoneketone) Polymers 0.000 description 1
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
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239000004632 polycaprolactone Substances 0.000 description 1
229920002530 polyetherether ketone Polymers 0.000 description 1
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235000013824 polyphenols Nutrition 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000001294 propane Substances 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
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230000006798 recombination Effects 0.000 description 1
238000005215 recombination Methods 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000012552 review Methods 0.000 description 1
239000007965 rubber solvent Substances 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
238000010517 secondary reaction Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
238000002791 soaking Methods 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
235000012424 soybean oil Nutrition 0.000 description 1
239000003549 soybean oil Substances 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
230000008961 swelling Effects 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
238000010998 test method Methods 0.000 description 1
125000005407 trans-1,4-cyclohexylene group Chemical group [H]C1([H])C([H])([H])[C@]([H])([*:2])C([H])([H])C([H])([H])[C@@]1([H])[*:1] 0.000 description 1
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
229920006305 unsaturated polyester Polymers 0.000 description 1
UIYCHXAGWOYNNA-UHFFFAOYSA-N vinyl sulfide Chemical group C=CSC=C UIYCHXAGWOYNNA-UHFFFAOYSA-N 0.000 description 1
238000005303 weighing Methods 0.000 description 1
230000004580 weight loss Effects 0.000 description 1
230000002087 whitening effect Effects 0.000 description 1
239000002023 wood Substances 0.000 description 1
238000004876 x-ray fluorescence Methods 0.000 description 1
239000008096 xylene Substances 0.000 description 1
IPSRAFUHLHIWAR-UHFFFAOYSA-N zinc;ethane Chemical group [Zn+2].[CH2-]C.[CH2-]C IPSRAFUHLHIWAR-UHFFFAOYSA-N 0.000 description 1
ZUBNXRHITOZMOO-UHFFFAOYSA-N zinc;octadecanoic acid;oxygen(2-) Chemical compound [O-2].[Zn+2].CCCCCCCCCCCCCCCCCC(O)=O ZUBNXRHITOZMOO-UHFFFAOYSA-N 0.000 description 1
150000003955 ε-lactams Chemical class 0.000 description 1

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Compositions Of Macromolecular Compounds (AREA)

CA 2048462 1991-01-31 1991-08-06 Compositions thermoplastiques Expired - Lifetime CA2048462C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US07/648,267 US6013727A (en)	1988-05-27	1991-01-31	Thermoplastic blend containing engineering resin
US07/648,267		1991-01-31

Publications (2)

Publication Number	Publication Date
CA2048462A1 CA2048462A1 (fr)	1992-08-01
CA2048462C true CA2048462C (fr)	2004-06-29

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CA 2048462 Expired - Lifetime CA2048462C (fr)	1991-01-31	1991-08-06	Compositions thermoplastiques

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CN114181490B (zh) *	2021-11-19	2023-02-24	金旸（厦门）新材料科技有限公司	一种阻燃抗静电abs/sma/pa复合材料及其制备方法

1991
- 1991-08-06 CA CA 2048462 patent/CA2048462C/fr not_active Expired - Lifetime

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Publication	Publication Date	Title
US6013727A (en)	2000-01-11	Thermoplastic blend containing engineering resin
US5013793A (en)	1991-05-07	Dynamically cured thermoplastic olefin polymers and process for producing the same
EP0604579B1 (fr)	1996-11-06	Compositions thermoplastiques et leur procede de preparation
US6843292B2 (en)	2005-01-18	Thermoplastic blend
CA2627970C (fr)	2010-10-26	Compositions elastomeres thermoplastiques et leur procede de fabrication
WO2002031048A1 (fr)	2002-04-18	Compositions thermoplastiques d'elastomeres halogenes
WO1992001744A1 (fr)	1992-02-06	Composition pour carcasse de pneu
EP1465947A1 (fr)	2004-10-13	Vulcanisats thermoplastiques pour pneus pour roulage a plat
CA2048462C (fr)	2004-06-29	Compositions thermoplastiques
USH1922H (en)	2000-11-07	Coating composition
CZ13993A3 (cs)	1993-09-15	Termoplastické umělé hmoty
MXPA02012383A (es)	2008-10-03	Mezcla fisica termoplastica