CA2127373A1 - Utilisation de copolymeres greffes en emulsion pour former des films dans les agents de mise en pli, et preparation des copolymeres greffes en emulsion - Google Patents

Utilisation de copolymeres greffes en emulsion pour former des films dans les agents de mise en pli, et preparation des copolymeres greffes en emulsion

Info

Publication number: CA2127373A1
Authority: CA; Canada
Prior art keywords: monomers; grafted; emulsion graft; graft copolymers; water
Prior art date: 1992-01-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2127373

Other languages

English (en)

Inventor

Sven Grabowski

Axel Sanner

Karin Sperling-Vietmeier

Volker Buehler

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF SE

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-01-28

Filing date

1993-01-20

Publication date

1993-08-05

1993-01-20 Application filed by Individual filed Critical Individual

1993-08-05 Publication of CA2127373A1 publication Critical patent/CA2127373A1/fr

Status Abandoned legal-status Critical Current

Links

229920000578 graft copolymer Polymers 0.000 title claims abstract description 27
239000000839 emulsion Substances 0.000 title claims abstract description 18
238000002360 preparation method Methods 0.000 title claims description 8
239000000178 monomer Substances 0.000 claims abstract description 38
239000000203 mixture Substances 0.000 claims abstract description 27
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 14
229920001577 copolymer Polymers 0.000 claims abstract description 12
239000003795 chemical substances by application Substances 0.000 claims abstract description 11
229920001567 vinyl ester resin Polymers 0.000 claims abstract description 7
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 3
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 3
150000001735 carboxylic acids Chemical class 0.000 claims abstract 2
239000003999 initiator Substances 0.000 claims description 28
238000006116 polymerization reaction Methods 0.000 claims description 22
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
239000001267 polyvinylpyrrolidone Substances 0.000 claims description 13
235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 13
238000000034 method Methods 0.000 claims description 12
229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 11
IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 9
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
150000002734 metacrylic acid derivatives Chemical class 0.000 claims description 6
125000000217 alkyl group Chemical group 0.000 claims description 5
229910052757 nitrogen Inorganic materials 0.000 claims description 5
238000007334 copolymerization reaction Methods 0.000 claims description 4
125000000129 anionic group Chemical group 0.000 claims description 3
125000002091 cationic group Chemical group 0.000 claims description 3
150000002148 esters Chemical class 0.000 claims description 3
238000010438 heat treatment Methods 0.000 claims description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
239000000084 colloidal system Substances 0.000 claims description 2
239000003995 emulsifying agent Substances 0.000 claims description 2
125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 2
125000006702 (C1-C18) alkyl group Chemical group 0.000 claims 3
125000000623 heterocyclic group Chemical group 0.000 claims 1
230000001681 protective effect Effects 0.000 claims 1
229920002554 vinyl polymer Polymers 0.000 abstract description 7
239000002537 cosmetic Substances 0.000 abstract description 2
125000005907 alkyl ester group Chemical group 0.000 abstract 1
150000003951 lactams Chemical class 0.000 abstract 1
229940063559 methacrylic acid Drugs 0.000 abstract 1
239000000825 pharmaceutical preparation Substances 0.000 abstract 1
239000000758 substrate Substances 0.000 abstract 1
150000002500 ions Chemical class 0.000 description 20
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 15
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 11
229920000642 polymer Polymers 0.000 description 10
239000006185 dispersion Substances 0.000 description 9
ZFXYFBGIUFBOJW-UHFFFAOYSA-N theophylline Chemical compound O=C1N(C)C(=O)N(C)C2=C1NC=N2 ZFXYFBGIUFBOJW-UHFFFAOYSA-N 0.000 description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
239000000843 powder Substances 0.000 description 6
239000000243 solution Substances 0.000 description 6
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 5
239000002585 base Substances 0.000 description 5
-1 cyclic carbox-amides Chemical class 0.000 description 5
229940063557 methacrylate Drugs 0.000 description 5
239000007787 solid Substances 0.000 description 5
239000007921 spray Substances 0.000 description 5
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 4
239000011248 coating agent Substances 0.000 description 4
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 4
229960000278 theophylline Drugs 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
229940048053 acrylate Drugs 0.000 description 3
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
239000011159 matrix material Substances 0.000 description 3
238000001694 spray drying Methods 0.000 description 3
238000005507 spraying Methods 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
UCTLHLZWKJIXJI-LXIBVNSESA-N [(3s,8r,9s,10r,13s,14s)-17-chloro-16-formyl-10,13-dimethyl-2,3,4,7,8,9,11,12,14,15-decahydro-1h-cyclopenta[a]phenanthren-3-yl] acetate Chemical compound C([C@@H]12)C[C@]3(C)C(Cl)=C(C=O)C[C@H]3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)C)C1 UCTLHLZWKJIXJI-LXIBVNSESA-N 0.000 description 2
150000001252 acrylic acid derivatives Chemical class 0.000 description 2
239000003513 alkali Substances 0.000 description 2
230000000903 blocking effect Effects 0.000 description 2
238000000576 coating method Methods 0.000 description 2
238000010790 dilution Methods 0.000 description 2
239000012895 dilution Substances 0.000 description 2
238000001035 drying Methods 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
238000009472 formulation Methods 0.000 description 2
BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
239000000463 material Substances 0.000 description 2
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
235000019333 sodium laurylsulphate Nutrition 0.000 description 2
238000003860 storage Methods 0.000 description 2
239000000454 talc Substances 0.000 description 2
229910052623 talc Inorganic materials 0.000 description 2
HQGPZXPTJWUDQR-UHFFFAOYSA-N 1-ethenyl-5-methylpyrrolidin-2-one Chemical compound CC1CCC(=O)N1C=C HQGPZXPTJWUDQR-UHFFFAOYSA-N 0.000 description 1
PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 1
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
KFTHUBZIEMOORC-UHFFFAOYSA-N 2-methylbut-2-enamide Chemical compound CC=C(C)C(N)=O KFTHUBZIEMOORC-UHFFFAOYSA-N 0.000 description 1
NDAJNMAAXXIADY-UHFFFAOYSA-N 2-methylpropanimidamide Chemical compound CC(C)C(N)=N NDAJNMAAXXIADY-UHFFFAOYSA-N 0.000 description 1
QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
SXIFAEWFOJETOA-UHFFFAOYSA-N 4-hydroxy-butyl Chemical group [CH2]CCCO SXIFAEWFOJETOA-UHFFFAOYSA-N 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
239000002000 Electrolyte additive Substances 0.000 description 1
239000004908 Emulsion polymer Substances 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
241000282326 Felis catus Species 0.000 description 1
241000257303 Hymenoptera Species 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
241000183024 Populus tremula Species 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
PGGSRKRIHKFHBZ-UHFFFAOYSA-N [Br+].CCCCCCCCCCCCCCCC[N+](C)(C)C Chemical compound [Br+].CCCCCCCCCCCCCCCC[N+](C)(C)C PGGSRKRIHKFHBZ-UHFFFAOYSA-N 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000005250 alkyl acrylate group Chemical group 0.000 description 1
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
239000012935 ammoniumperoxodisulfate Substances 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
229960000541 cetyl alcohol Drugs 0.000 description 1
238000007385 chemical modification Methods 0.000 description 1
XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 1
229940005991 chloric acid Drugs 0.000 description 1
239000004927 clay Substances 0.000 description 1
230000001609 comparable effect Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
230000002844 continuous effect Effects 0.000 description 1
235000019700 dicalcium phosphate Nutrition 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
229940043264 dodecyl sulfate Drugs 0.000 description 1
125000003700 epoxy group Chemical group 0.000 description 1
239000006260 foam Substances 0.000 description 1
ISXSFOPKZQZDAO-UHFFFAOYSA-N formaldehyde;sodium Chemical compound [Na].O=C ISXSFOPKZQZDAO-UHFFFAOYSA-N 0.000 description 1
239000003205 fragrance Substances 0.000 description 1
238000004108 freeze drying Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000008266 hair spray Substances 0.000 description 1
IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Substances C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
WFKDPJRCBCBQNT-UHFFFAOYSA-N n,2-dimethylprop-2-enamide Chemical compound CNC(=O)C(C)=C WFKDPJRCBCBQNT-UHFFFAOYSA-N 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
239000003973 paint Substances 0.000 description 1
125000005385 peroxodisulfate group Chemical group 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
239000003380 propellant Substances 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
102000004169 proteins and genes Human genes 0.000 description 1
HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
IOVGROKTTNBUGK-SJCJKPOMSA-N ritodrine Chemical compound N([C@@H](C)[C@H](O)C=1C=CC(O)=CC=1)CCC1=CC=C(O)C=C1 IOVGROKTTNBUGK-SJCJKPOMSA-N 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
239000002453 shampoo Substances 0.000 description 1
239000000344 soap Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
235000012976 tarts Nutrition 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical class CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
101150019895 thiE gene Proteins 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1
230000007704 transition Effects 0.000 description 1
229940070710 valerate Drugs 0.000 description 1
NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/91—Graft copolymers
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/20—Pills, tablets, discs, rods
- A61K9/2004—Excipients; Inactive ingredients
- A61K9/2022—Organic macromolecular compounds
- A61K9/2027—Organic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polyvinyl pyrrolidone, poly(meth)acrylates
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F271/00—Macromolecular compounds obtained by polymerising monomers on to polymers of nitrogen-containing monomers as defined in group C08F26/00
- C08F271/02—Macromolecular compounds obtained by polymerising monomers on to polymers of nitrogen-containing monomers as defined in group C08F26/00 on to polymers of monomers containing heterocyclic nitrogen

Landscapes

Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Animal Behavior & Ethology (AREA)
Chemical & Material Sciences (AREA)
Veterinary Medicine (AREA)
Public Health (AREA)
General Health & Medical Sciences (AREA)
Epidemiology (AREA)
Medicinal Chemistry (AREA)
Organic Chemistry (AREA)
Polymers & Plastics (AREA)
Pharmacology & Pharmacy (AREA)
Chemical Kinetics & Catalysis (AREA)
Birds (AREA)
Graft Or Block Polymers (AREA)
Cosmetics (AREA)
Medicinal Preparation (AREA)

CA 2127373 1992-01-28 1993-01-20 Utilisation de copolymeres greffes en emulsion pour former des films dans les agents de mise en pli, et preparation des copolymeres greffes en emulsion Abandoned CA2127373A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19924202193 DE4202193A1 (de)	1992-01-28	1992-01-28	Verwendung von emulsionspfropfcopolymerisaten als filmbildner in kosmetischen und pharmazeutischen zubereitungen und verfahren zur herstellung der emulsionspfropfcopolymerisate
DEP4202193.6		1992-01-28

Publications (1)

Publication Number	Publication Date
CA2127373A1 true CA2127373A1 (fr)	1993-08-05

Family

ID=6450353

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2127373 Abandoned CA2127373A1 (fr)	1992-01-28	1993-01-20	Utilisation de copolymeres greffes en emulsion pour former des films dans les agents de mise en pli, et preparation des copolymeres greffes en emulsion

Country Status (5)

Country	Link
EP (1)	EP0624169A1 (fr)
JP (1)	JPH07503036A (fr)
CA (1)	CA2127373A1 (fr)
DE (1)	DE4202193A1 (fr)
WO (1)	WO1993015120A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6107397A (en) *	1997-03-24	2000-08-22	Basf Aktiengesellschaft	Aqueous copolymer dispersions of water-soluble monomers with N-vinyl groups and hydrophobic monomers
DE19853046A1 (de) *	1998-11-18	2000-05-25	Basf Ag	Wasserlösliche oder wasserdispergierbare Pfropfcopolymerisate auf der Basis eines Polyvinyllactams, deren Herstellung und Verwendung
WO2013096206A1 (fr) *	2011-12-21	2013-06-27	Lubrizol Advanced Materials, Inc.	Procédé de préparation de polymères acryliques et produits obtenus par ce procédé

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1174991B (de) *	1962-03-21	1964-07-30	Hoechst Ag	Verfahren zur Herstellung von Polyvinylalkohol
US3468832A (en) *	1966-11-17	1969-09-23	Gaf Corp	Stable aqueous emulsions
US3652481A (en) *	1970-01-29	1972-03-28	Gaf Corp	Stable aqueous emulsions of graft copolymers
US3770683A (en) *	1972-02-14	1973-11-06	Gaf Corp	Graft copolymers of poly(vinylpyrrolidone) with acrylic acid and acrylic ester

1992
- 1992-01-28 DE DE19924202193 patent/DE4202193A1/de not_active Withdrawn
1993
- 1993-01-20 JP JP5512903A patent/JPH07503036A/ja active Pending
- 1993-01-20 EP EP93903203A patent/EP0624169A1/fr not_active Withdrawn
- 1993-01-20 WO PCT/EP1993/000118 patent/WO1993015120A1/fr not_active Ceased
- 1993-01-20 CA CA 2127373 patent/CA2127373A1/fr not_active Abandoned

Also Published As

Publication number	Publication date
JPH07503036A (ja)	1995-03-30
EP0624169A1 (fr)	1994-11-17
DE4202193A1 (de)	1993-07-29
WO1993015120A1 (fr)	1993-08-05

Legal Events

Date	Code	Title	Description
1998-01-20	FZDE	Dead

Publication	Publication Date	Title
US5426163A (en)	1995-06-20	Redispersible powder composed of n-vinylpyrrolidone/vinyl acetate copolymer the preparation and use thereof
JP2807016B2 (ja)	1998-09-30	毛髪固定剤
CA2098667C (fr)	2003-10-28	Production de formes pharmaceutiques solides a action prolongee
US6482393B1 (en)	2002-11-19	Hairsetting compositions
CZ289663B6 (cs)	2002-03-13	Materiály pro povlaky a pojiva pro lékové formy, jejich pouľití a lékové formy
US5948396A (en)	1999-09-07	Hair fixative amphoteric polymer composition
JP2002521511A (ja)	2002-07-16	（共）重合体の水性分散液の製造方法、この方法によって得られる分散液、これら分散液から得られる再分散性粉末、およびこれらの利用
HU203968B (en)	1991-11-28	Aqueous dispersions for coating drug forms
JP2933655B2 (ja)	1999-08-16	第三ブチルアクリレート、第三ブチルメタクリレートまたはこれらの混合物を基礎とする共重合体溶液
WO1998018454A1 (fr)	1998-05-07	Compositions aqueuses de revetement gastro-resistant
JP2002521507A (ja)	2002-07-16	不均質形態を有するラテックス粒子の水性分散液の製造方法、この方法によって得られるラテックス粒子、分散液、再分散性粉末、およびこれらの利用
JP4018363B2 (ja)	2007-12-05	ヒドロキシアルキル（メタ）アクリレートの水溶性または水分散性（コ）ポリマー、その製造方法、ならびに医薬投与剤形における被覆剤、結合剤および／またはフィルム形成性賦形剤としてのその使用
JP3442407B2 (ja)	2003-09-02	髪セット剤、調髪剤、新規の共重合体、髪セット剤および調髪剤におけるフィルム形成剤、およびスプレー配合物の形の髪セット剤
CA1071789A (fr)	1980-02-12	Methode pour produire un email a base aqueuse, exempt de solvant
JP3847870B2 (ja)	2006-11-22	アクリル毛髪固定剤組成物およびその製造方法
CA2127373A1 (fr)	1993-08-05	Utilisation de copolymeres greffes en emulsion pour former des films dans les agents de mise en pli, et preparation des copolymeres greffes en emulsion
US20080262104A1 (en)	2008-10-23	Aqueous Polyvinyl Acetate Dispersions Having High Shearing Stability
EP0536595B1 (fr)	1995-07-05	Procédé pour enrober des formes pharmaceutiques
JPH0819174B2 (ja)	1996-02-28	ビニルピロリドン重合体の製法
JP3251418B2 (ja)	2002-01-28	整髪剤用基剤
US5416157A (en)	1995-05-16	Process for improving mechanical shear stability of acrylic enteric polymers
US4117853A (en)	1978-10-03	Film-forming vinyl acetate copolymerizates in an improved process for setting hair and as hair setting agents
JPH11255622A (ja)	1999-09-21	毛髪化粧料組成物
JP2947896B2 (ja)	1999-09-13	ネイルエナメル用下地剤
JPH04306250A (ja)	1992-10-29	整髪用樹脂組成物