CA2195511C - Detergent liquide isotropique contenant des hydrotropes et des polymeres modifies hydrophobes - Google Patents

Detergent liquide isotropique contenant des hydrotropes et des polymeres modifies hydrophobes Download PDF

Info

Publication number: CA2195511C
Authority: CA; Canada
Prior art keywords: hazy; polymer; hydrophobic; group; monomer
Prior art date: 1996-01-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA 2195511

Other languages

English (en)

Other versions

CA2195511A1 (fr

Inventor

Nancy Ann Falk

Barbara Helen Bory

Tamara Padron

Tirucherai Varahan Vasudevan

Diane Wolf

Jeanie Lum

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Sun Products Canada Corp

Original Assignee

Unilever PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-01-25

Filing date

1997-01-20

Publication date

2006-06-20

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27081033&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2195511(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1996-01-25 Priority claimed from US08/591,789 external-priority patent/US5723434A/en

1996-01-25 Priority claimed from US08/591,058 external-priority patent/US5719117A/en

1997-01-20 Application filed by Unilever PLC filed Critical Unilever PLC

1997-07-26 Publication of CA2195511A1 publication Critical patent/CA2195511A1/fr

2006-06-20 Application granted granted Critical

2006-06-20 Publication of CA2195511C publication Critical patent/CA2195511C/fr

2017-01-20 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

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239000003599 detergent Substances 0.000 title claims abstract description 26
239000003752 hydrotrope Substances 0.000 title claims description 53
239000000203 mixture Substances 0.000 claims abstract description 187
230000002209 hydrophobic effect Effects 0.000 claims abstract description 79
239000000178 monomer Substances 0.000 claims abstract description 71
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 94
239000004094 surface-active agent Substances 0.000 claims description 59
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 39
-1 hydroxy, carboxyl Chemical group 0.000 claims description 38
QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 36
125000000129 anionic group Chemical group 0.000 claims description 33
125000000217 alkyl group Chemical group 0.000 claims description 28
125000004432 carbon atom Chemical group C* 0.000 claims description 28
NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 26
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NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 11
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239000011591 potassium Substances 0.000 description 10
229910021538 borax Inorganic materials 0.000 description 9
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239000003795 chemical substances by application Substances 0.000 description 9
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BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 8
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AOVQVJXCILXRRU-UHFFFAOYSA-M sodium;2-(dodecylamino)ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCNCCOS([O-])(=O)=O AOVQVJXCILXRRU-UHFFFAOYSA-M 0.000 description 1
HWCHICTXVOMIIF-UHFFFAOYSA-M sodium;3-(dodecylamino)propanoate Chemical compound [Na+].CCCCCCCCCCCCNCCC([O-])=O HWCHICTXVOMIIF-UHFFFAOYSA-M 0.000 description 1
QEKATQBVVAZOAY-UHFFFAOYSA-M sodium;4-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=C(S([O-])(=O)=O)C=C1 QEKATQBVVAZOAY-UHFFFAOYSA-M 0.000 description 1
238000009987 spinning Methods 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000000758 substrate Substances 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
DIORMHZUUKOISG-UHFFFAOYSA-N sulfoformic acid Chemical compound OC(=O)S(O)(=O)=O DIORMHZUUKOISG-UHFFFAOYSA-N 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
150000003457 sulfones Chemical class 0.000 description 1
150000003505 terpenes Chemical class 0.000 description 1
235000007586 terpenes Nutrition 0.000 description 1
150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
BDOBMVIEWHZYDL-UHFFFAOYSA-N tetrachlorosalicylanilide Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C(=O)NC1=CC=CC=C1 BDOBMVIEWHZYDL-UHFFFAOYSA-N 0.000 description 1
UGODCLHJOJPPHP-AZGWGOJFSA-J tetralithium;[(2r,3s,4r,5r)-5-(6-aminopurin-9-yl)-4-hydroxy-2-[[oxido(sulfonatooxy)phosphoryl]oxymethyl]oxolan-3-yl] phosphate;hydrate Chemical compound [Li+].[Li+].[Li+].[Li+].O.C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP([O-])(=O)OS([O-])(=O)=O)[C@@H](OP([O-])([O-])=O)[C@H]1O UGODCLHJOJPPHP-AZGWGOJFSA-J 0.000 description 1
JZBRFIUYUGTUGG-UHFFFAOYSA-J tetrapotassium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical class [K+].[K+].[K+].[K+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O JZBRFIUYUGTUGG-UHFFFAOYSA-J 0.000 description 1
LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
ZCXUWYGUGJQPPR-UHFFFAOYSA-N trisodium;borate;pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].[Na+].[O-]B([O-])[O-] ZCXUWYGUGJQPPR-UHFFFAOYSA-N 0.000 description 1
235000013799 ultramarine blue Nutrition 0.000 description 1
KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 1
125000004417 unsaturated alkyl group Chemical group 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
238000004383 yellowing Methods 0.000 description 1
239000010457 zeolite Substances 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

CA 2195511 1996-01-25 1997-01-20 Detergent liquide isotropique contenant des hydrotropes et des polymeres modifies hydrophobes Expired - Fee Related CA2195511C (fr)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US08/591058		1996-01-25
US08/591789		1996-01-25
US08/591,789 US5723434A (en)	1996-01-25	1996-01-25	Isotropic liquids comprising hydrophobically modified polar polymer
US08/591,058 US5719117A (en)	1996-01-25	1996-01-25	Isotropic liquids comprising hydrophobically modified polar polymers plus aliphatic hydrocarbon oils

Publications (2)

Publication Number	Publication Date
CA2195511A1 CA2195511A1 (fr)	1997-07-26
CA2195511C true CA2195511C (fr)	2006-06-20

Family

ID=27081033

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2195511 Expired - Fee Related CA2195511C (fr)	1996-01-25	1997-01-20	Detergent liquide isotropique contenant des hydrotropes et des polymeres modifies hydrophobes

Country Status (4)

Country	Link
EP (1)	EP0786516B1 (fr)
CA (1)	CA2195511C (fr)
DE (1)	DE69728701T2 (fr)
ES (1)	ES2218636T3 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19752163A1 (de) *	1997-11-26	1999-05-27	Henkel Kgaa	Niedrigkonzentrierte höherviskose Flüssigwaschmittel
US6462013B1 (en) *	1998-06-26	2002-10-08	National Starch And Chemical Investment Holding Corporation	Isotropic liquid detergent comprising ethylenically unsaturated acid monomer-C1 to C24 chain transfer agent polymerization product
AU5355599A (en) *	1998-10-22	2000-05-04	Rohm And Haas Company	Polymer compositions and a method of promoting soil release from fabrics using said polymer compositions
AU2495400A (en)	1999-01-11	2000-08-01	Huntsman Petrochemical Corporation	Surfactant compositions containing alkoxylated amines
BR0012199A (pt) *	1999-06-30	2002-04-02	Huntsman Spec Chem Corp	Misturas surfactantes concentradas
KR100485941B1 (ko) *	2002-08-06	2005-05-03	(주) 청도정밀화학	폴리 카본산계 고성능 콘크리트 분산제의 새로운 조성물
JP5543490B2 (ja) *	2008-12-29	2014-07-09	エコラボインコーポレイティド	高粘性洗剤エマルジョン
US8216989B2 (en)	2009-08-26	2012-07-10	Ecolab Usa Inc.	Cleaning composition for removing/preventing redeposition of protein soils

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GB401413A (en)	1932-06-29	1933-11-16	Robert Henry Marriott	Compositions particularly suitable for use as shampoos or for washing purposes
GB461221A (en)	1936-04-17	1937-02-12	Robert Henry Marriott	Compositions suitable for use in the washing of textile materials or for other washing purposes
US2379942A (en)	1942-12-31	1945-07-10	Bell Telephone Labor Inc	Cable terminating means
US2503280A (en)	1947-10-24	1950-04-11	Du Pont	Azo catalysts in preparation of sulfonic acids
US2507088A (en)	1948-01-08	1950-05-09	Du Pont	Sulfoxidation process
US3260741A (en)	1962-11-09	1966-07-12	Exxon Research Engineering Co	Sulfoxidation process
US3308067A (en)	1963-04-01	1967-03-07	Procter & Gamble	Polyelectrolyte builders and detergent compositions
US3372188A (en)	1965-03-12	1968-03-05	Union Oil Co	Sulfoxidation process in the presence of sulfur trioxide
JPS4629787B1 (fr)	1968-07-02	1971-08-30
DK129804A (fr)	1969-01-17
ZA734721B (en)	1972-07-14	1974-03-27	Procter & Gamble	Detergent compositions
US4605509A (en)	1973-05-11	1986-08-12	The Procter & Gamble Company	Detergent compositions containing sodium aluminosilicate builders
DE2433485A1 (de)	1973-07-16	1975-02-06	Procter & Gamble	Zur verwendung in waschmitteln geeignete aluminosilikat-ionenaustauscher
GB1600981A (en)	1977-06-09	1981-10-21	Ici Ltd	Detergent composition
US4353806A (en)	1980-04-03	1982-10-12	Exxon Research And Engineering Company	Polymer-microemulsion complexes for the enhanced recovery of oil
US4497718A (en)	1983-04-20	1985-02-05	Lever Brothers Company	Homogeneous aqueous fabric softening composition with stilbene sulfonic acid fluorescent whitener
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GB8609806D0 (en)	1986-04-22	1986-05-29	Unilever Plc	Cleaning composition
DE3750450T2 (de)	1986-08-29	1995-01-05	Novo Industri As	Enzymhaltiger Reinigungsmittelzusatz.
GB8813978D0 (en) *	1988-06-13	1988-07-20	Unilever Plc	Liquid detergents
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IL91362A0 (en)	1989-08-20	1990-03-19	Yissum Res Dev Co	Bisphosphonates,process for preparing them and pharmaceutical compositions containing them
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US5389279A (en)	1991-12-31	1995-02-14	Lever Brothers Company, Division Of Conopco, Inc.	Compositions comprising nonionic glycolipid surfactants
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US5486307A (en)	1993-11-22	1996-01-23	Colgate-Palmolive Co.	Liquid cleaning compositions with grease release agent
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JPH09507695A (ja) *	1994-05-13	1997-08-05	ユニリーバー・ナームローゼ・ベンノートシヤープ	洗剤組成物
JPH10500442A (ja) *	1994-05-17	1998-01-13	エス．シー．ジョンソンアンドサン，インコーポレーテッド	会合性ポリマーシックナーを含む洗濯用予備しみ抜き剤

1997
- 1997-01-16 DE DE1997628701 patent/DE69728701T2/de not_active Revoked
- 1997-01-16 ES ES97200106T patent/ES2218636T3/es not_active Expired - Lifetime
- 1997-01-16 EP EP19970200106 patent/EP0786516B1/fr not_active Revoked
- 1997-01-20 CA CA 2195511 patent/CA2195511C/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
DE69728701T2 (de)	2004-10-07
EP0786516A2 (fr)	1997-07-30
CA2195511A1 (fr)	1997-07-26
ES2218636T3 (es)	2004-11-16
EP0786516A3 (fr)	1999-08-18
EP0786516B1 (fr)	2004-04-21
DE69728701D1 (de)	2004-05-27

Legal Events

Date	Code	Title	Description
2001-11-23	EEER	Examination request
2015-03-03	MKLA	Lapsed	Effective date: 20150120

Publication	Publication Date	Title
US5385959A (en)	1995-01-31	Capsule which comprises a component subject to degradation and a composite polymer
US5281355A (en)	1994-01-25	Heavy duty liquid detergent compositions containing a capsule which comprises a component subject to degradation and a composite polymer
US5281356A (en)	1994-01-25	Heavy duty liquid detergent compositions containing non-proteolytic enzymes comprising capsules comprising proteolytic enzyme and composite polymer
US5723434A (en)	1998-03-03	Isotropic liquids comprising hydrophobically modified polar polymer
US6258771B1 (en)	2001-07-10	Process for preparing pourable, transparent/translucent liquid detergent with non-continuous suspending system
US5281357A (en)	1994-01-25	Protease containing heavy duty liquid detergent compositions comprising capsules comprising non-proteolytic enzyme and composite polymer
US6051541A (en)	2000-04-18	Process for preparing pourable, transparent/translucent liquid detergent with continuous suspending system
AU746074B2 (en)	2002-04-11	Pourable transparent/translucent liquid detergent composition with suspended particles
EP0672102B1 (fr)	1996-06-19	Capsule comprenant un composant soumis a une degradation et polymere composite
US5264142A (en)	1993-11-23	Stabilization of peroxygen bleach in enzyme-containing heavy duty liquids
US7387992B2 (en)	2008-06-17	Laundry detergent with polyamine mono-anionic surfactant
WO2007057085A1 (fr)	2007-05-24	Procédé et kit de lavage du linge respectueux de l’environnement
US5719117A (en)	1998-02-17	Isotropic liquids comprising hydrophobically modified polar polymers plus aliphatic hydrocarbon oils
US20050197275A1 (en)	2005-09-08	Solid laundry detergents with polyanionic ammonium surfactant
CA2195511C (fr)	2006-06-20	Detergent liquide isotropique contenant des hydrotropes et des polymeres modifies hydrophobes
US5071586A (en)	1991-12-10	Protease-containing compositions stabilized by propionic acid or salt thereof
US5776882A (en)	1998-07-07	Isotropic liquids incorporating hydrophobically modified polar polymers with high ratios of hydrophile to hydrophobe
US20030186832A1 (en)	2003-10-02	Isotropic liquid detergents with improved anti-redeposition
CA2041716A1 (fr)	1991-11-09	Detergent d'adoucissement non ionique et anti-statique contenant un copolymere pet-poet facilitant le nettoyage
US5962398A (en)	1999-10-05	Isotropic liquids incorporating anionic polymers which are not hydrophobically modified
US20050197274A1 (en)	2005-09-08	Solid laundry detergent granules with polyanionic ammonium surfactant and non-aqueous binder
US6969700B2 (en)	2005-11-29	Liquid detergent with polyanionic ammonium surfactant and a high pKa solid inorganic base
WO2010079023A1 (fr)	2010-07-15	Système de dosage mesuré anti-pulvérisation pour liquides de lessive à réduction de cisaillement visqueux