CA2205592C - Heavy duty liquid detergent compositions comprising salts of alpha sulfonated fatty acid methyl esters and use of alpha-sulfonated fatty acid salts to inhibit redeposition of soilon fabric - Google Patents

Heavy duty liquid detergent compositions comprising salts of alpha sulfonated fatty acid methyl esters and use of alpha-sulfonated fatty acid salts to inhibit redeposition of soilon fabric Download PDF

Info

Publication number: CA2205592C
Authority: CA; Canada
Prior art keywords: alkyl; weight; fatty acid; alpha; sulfonated
Prior art date: 1995-09-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA002205592A

Other languages

English (en)

French (fr)

Other versions

CA2205592A1 (en

Inventor

Branko Sajic

Irma Ryklin

Arshad Malik

Y. Kameshwer Rao

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Stepan Co

Original Assignee

Stepan Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-09-18

Filing date

1996-09-17

Publication date

2001-12-11

1996-09-17 Application filed by Stepan Co filed Critical Stepan Co

1997-03-27 Publication of CA2205592A1 publication Critical patent/CA2205592A1/en

2001-12-11 Application granted granted Critical

2001-12-11 Publication of CA2205592C publication Critical patent/CA2205592C/en

2016-09-17 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 200
239000003599 detergent Substances 0.000 title claims abstract description 119
235000014113 dietary fatty acids Nutrition 0.000 title claims abstract description 79
239000000194 fatty acid Substances 0.000 title claims abstract description 79
229930195729 fatty acid Natural products 0.000 title claims abstract description 79
239000004744 fabric Substances 0.000 title claims abstract description 58
150000003839 salts Chemical class 0.000 title claims abstract description 36
-1 fatty acid salts Chemical class 0.000 title claims description 83
239000007788 liquid Substances 0.000 title claims description 26
235000019387 fatty acid methyl ester Nutrition 0.000 title description 2
150000004665 fatty acids Chemical class 0.000 claims abstract description 72
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 63
239000002689 soil Substances 0.000 claims abstract description 53
125000005907 alkyl ester group Chemical group 0.000 claims abstract description 35
239000002736 nonionic surfactant Substances 0.000 claims abstract description 35
239000003945 anionic surfactant Substances 0.000 claims abstract description 34
238000000034 method Methods 0.000 claims abstract description 25
230000002401 inhibitory effect Effects 0.000 claims abstract description 7
125000000217 alkyl group Chemical group 0.000 claims description 42
238000005406 washing Methods 0.000 claims description 28
150000004702 methyl esters Chemical class 0.000 claims description 17
150000004996 alkyl benzenes Chemical class 0.000 claims description 14
238000009472 formulation Methods 0.000 claims description 14
150000008051 alkyl sulfates Chemical class 0.000 claims description 11
150000002191 fatty alcohols Chemical class 0.000 claims description 5
239000012141 concentrate Substances 0.000 claims description 4
229940077388 benzenesulfonate Drugs 0.000 claims description 3
238000007865 diluting Methods 0.000 claims description 2
239000004094 surface-active agent Substances 0.000 description 54
239000003795 chemical substances by application Substances 0.000 description 48
239000000463 material Substances 0.000 description 38
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 31
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 26
238000004140 cleaning Methods 0.000 description 26
235000019441 ethanol Nutrition 0.000 description 25
239000007844 bleaching agent Substances 0.000 description 24
229920000742 Cotton Polymers 0.000 description 23
241000219146 Gossypium Species 0.000 description 23
229940117927 ethylene oxide Drugs 0.000 description 23
239000011734 sodium Substances 0.000 description 22
229910052708 sodium Inorganic materials 0.000 description 22
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 21
235000015424 sodium Nutrition 0.000 description 20
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 19
150000001875 compounds Chemical class 0.000 description 18
239000000047 product Substances 0.000 description 16
229920003171 Poly (ethylene oxide) Chemical group 0.000 description 15
239000002253 acid Substances 0.000 description 15
239000007859 condensation product Substances 0.000 description 15
229920000728 polyester Polymers 0.000 description 14
239000004367 Lipase Substances 0.000 description 13
102000004882 Lipase Human genes 0.000 description 13
108090001060 Lipase Proteins 0.000 description 13
150000001412 amines Chemical class 0.000 description 13
150000002148 esters Chemical class 0.000 description 13
235000019421 lipase Nutrition 0.000 description 13
229920000642 polymer Polymers 0.000 description 13
102000004190 Enzymes Human genes 0.000 description 11
108090000790 Enzymes Proteins 0.000 description 11
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 11
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 11
229940088598 enzyme Drugs 0.000 description 10
230000002209 hydrophobic effect Effects 0.000 description 10
239000003752 hydrotrope Substances 0.000 description 10
229920001296 polysiloxane Polymers 0.000 description 10
239000000243 solution Substances 0.000 description 10
239000002738 chelating agent Substances 0.000 description 9
229920001577 copolymer Polymers 0.000 description 9
229930195733 hydrocarbon Natural products 0.000 description 9
150000002430 hydrocarbons Chemical class 0.000 description 9
239000012188 paraffin wax Substances 0.000 description 9
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 8
229910052783 alkali metal Inorganic materials 0.000 description 8
238000007046 ethoxylation reaction Methods 0.000 description 8
150000003871 sulfonates Chemical class 0.000 description 8
HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 7
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 7
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 7
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 7
238000013019 agitation Methods 0.000 description 7
150000001298 alcohols Chemical class 0.000 description 7
125000000129 anionic group Chemical group 0.000 description 7
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical group OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 7
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 7
125000002768 hydroxyalkyl group Chemical group 0.000 description 7
229920005646 polycarboxylate Polymers 0.000 description 7
229910052700 potassium Inorganic materials 0.000 description 7
239000002904 solvent Substances 0.000 description 7
239000000758 substrate Substances 0.000 description 7
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 7
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 6
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 6
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 6
125000002947 alkylene group Chemical group 0.000 description 6
150000001408 amides Chemical class 0.000 description 6
238000004061 bleaching Methods 0.000 description 6
239000004927 clay Substances 0.000 description 6
239000008103 glucose Substances 0.000 description 6
239000004615 ingredient Substances 0.000 description 6
230000003287 optical effect Effects 0.000 description 6
229920001223 polyethylene glycol Polymers 0.000 description 6
239000011591 potassium Substances 0.000 description 6
235000007686 potassium Nutrition 0.000 description 6
229960003975 potassium Drugs 0.000 description 6
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 5
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 5
108091005804 Peptidases Proteins 0.000 description 5
239000002202 Polyethylene glycol Substances 0.000 description 5
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical group OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 5
239000012190 activator Substances 0.000 description 5
150000001340 alkali metals Chemical class 0.000 description 5
150000003863 ammonium salts Chemical class 0.000 description 5
150000001768 cations Chemical class 0.000 description 5
229920002678 cellulose Polymers 0.000 description 5
239000001913 cellulose Substances 0.000 description 5
230000008859 change Effects 0.000 description 5
239000002270 dispersing agent Substances 0.000 description 5
239000012530 fluid Substances 0.000 description 5
239000006260 foam Substances 0.000 description 5
125000000623 heterocyclic group Chemical group 0.000 description 5
125000001183 hydrocarbyl group Chemical group 0.000 description 5
229910052760 oxygen Inorganic materials 0.000 description 5
239000001301 oxygen Substances 0.000 description 5
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 5
238000012360 testing method Methods 0.000 description 5
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
BCXBKOQDEOJNRH-UHFFFAOYSA-N NOP(O)=O Chemical class NOP(O)=O BCXBKOQDEOJNRH-UHFFFAOYSA-N 0.000 description 4
239000004365 Protease Substances 0.000 description 4
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
125000003342 alkenyl group Chemical group 0.000 description 4
125000003118 aryl group Chemical class 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
239000002585 base Substances 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
239000011575 calcium Substances 0.000 description 4
150000001720 carbohydrates Chemical group 0.000 description 4
125000001309 chloro group Chemical group Cl* 0.000 description 4
238000009826 distribution Methods 0.000 description 4
239000000835 fiber Substances 0.000 description 4
238000010348 incorporation Methods 0.000 description 4
239000011777 magnesium Substances 0.000 description 4
229910052749 magnesium Inorganic materials 0.000 description 4
235000001055 magnesium Nutrition 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
239000003921 oil Substances 0.000 description 4
235000019198 oils Nutrition 0.000 description 4
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
125000006353 oxyethylene group Chemical group 0.000 description 4
229920001983 poloxamer Polymers 0.000 description 4
238000006116 polymerization reaction Methods 0.000 description 4
230000008569 process Effects 0.000 description 4
229910052938 sodium sulfate Inorganic materials 0.000 description 4
235000011152 sodium sulphate Nutrition 0.000 description 4
PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 4
239000000126 substance Substances 0.000 description 4
235000000346 sugar Nutrition 0.000 description 4
229920002994 synthetic fiber Polymers 0.000 description 4
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical group O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 description 3
108010065511 Amylases Proteins 0.000 description 3
102000013142 Amylases Human genes 0.000 description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
239000004215 Carbon black (E152) Substances 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
229910019142 PO4 Inorganic materials 0.000 description 3
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 3
PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 3
240000008042 Zea mays Species 0.000 description 3
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 3
235000002017 Zea mays subsp mays Nutrition 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
125000005227 alkyl sulfonate group Chemical group 0.000 description 3
WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical group OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 3
235000019418 amylase Nutrition 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
235000001465 calcium Nutrition 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
150000001851 cinnamic acid derivatives Chemical class 0.000 description 3
239000003240 coconut oil Substances 0.000 description 3
235000019864 coconut oil Nutrition 0.000 description 3
235000005822 corn Nutrition 0.000 description 3
239000008367 deionised water Substances 0.000 description 3
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239000003085 diluting agent Substances 0.000 description 3
239000004205 dimethyl polysiloxane Substances 0.000 description 3
SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
229930182830 galactose Chemical group 0.000 description 3
125000003147 glycosyl group Chemical group 0.000 description 3
125000001165 hydrophobic group Chemical group 0.000 description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
238000010412 laundry washing Methods 0.000 description 3
235000021317 phosphate Nutrition 0.000 description 3
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150000003138 primary alcohols Chemical class 0.000 description 3
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239000000377 silicon dioxide Substances 0.000 description 3
229940083542 sodium Drugs 0.000 description 3
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235000021286 stilbenes Nutrition 0.000 description 3
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 3
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235000020357 syrup Nutrition 0.000 description 3
239000006188 syrup Substances 0.000 description 3
239000011800 void material Substances 0.000 description 3
239000004711 α-olefin Substances 0.000 description 3
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HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
NKVJCKOMRJVZLO-UHFFFAOYSA-N 3,6,7-trioxabicyclo[7.2.2]trideca-1(11),9,12-triene-2,8-dione Chemical compound O=C1OCCOOC(=O)C2=CC=C1C=C2 NKVJCKOMRJVZLO-UHFFFAOYSA-N 0.000 description 2
LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 description 2
SFHBJXIEBWOOFA-UHFFFAOYSA-N 5-methyl-3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical compound O=C1OC(C)COC(=O)C2=CC=C1C=C2 SFHBJXIEBWOOFA-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
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239000004382 Amylase Substances 0.000 description 2
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
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239000012445 acidic reagent Substances 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
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GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 2
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159000000003 magnesium salts Chemical class 0.000 description 1
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VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
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LULAYUGMBFYYEX-UHFFFAOYSA-N metachloroperbenzoic acid Natural products OC(=O)C1=CC=CC(Cl)=C1 LULAYUGMBFYYEX-UHFFFAOYSA-N 0.000 description 1
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239000011736 potassium bicarbonate Substances 0.000 description 1
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MYGBBCKCTXSGOB-UHFFFAOYSA-M potassium;2-propan-2-ylbenzenesulfonate Chemical compound [K+].CC(C)C1=CC=CC=C1S([O-])(=O)=O MYGBBCKCTXSGOB-UHFFFAOYSA-M 0.000 description 1
GHKGUEZUGFJUEJ-UHFFFAOYSA-M potassium;4-methylbenzenesulfonate Chemical compound [K+].CC1=CC=C(S([O-])(=O)=O)C=C1 GHKGUEZUGFJUEJ-UHFFFAOYSA-M 0.000 description 1
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RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
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125000001424 substituent group Chemical group 0.000 description 1
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125000000542 sulfonic acid group Chemical group 0.000 description 1
150000003462 sulfoxides Chemical class 0.000 description 1
YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical class ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 1
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239000008399 tap water Substances 0.000 description 1
235000020679 tap water Nutrition 0.000 description 1
108010075550 termamyl Proteins 0.000 description 1
AABMAPVNIQIMKZ-UHFFFAOYSA-J tetrapotassium 2-(1,2-dicarboxylatoethoxy)butanedioate Chemical class [K+].[K+].[K+].[K+].[O-]C(=O)CC(C([O-])=O)OC(C([O-])=O)CC([O-])=O AABMAPVNIQIMKZ-UHFFFAOYSA-J 0.000 description 1
JZBRFIUYUGTUGG-UHFFFAOYSA-J tetrapotassium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [K+].[K+].[K+].[K+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O JZBRFIUYUGTUGG-UHFFFAOYSA-J 0.000 description 1
RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
239000004753 textile Substances 0.000 description 1
GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
150000003626 triacylglycerols Chemical class 0.000 description 1
QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
229960004418 trolamine Drugs 0.000 description 1
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Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols

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Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

CA002205592A 1995-09-18 1996-09-17 Heavy duty liquid detergent compositions comprising salts of alpha sulfonated fatty acid methyl esters and use of alpha-sulfonated fatty acid salts to inhibit redeposition of soilon fabric Expired - Lifetime CA2205592C (en)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
US52950195A	1995-09-18	1995-09-18
US08/529,501		1995-09-18
US59174896A	1996-01-25	1996-01-25
US08/591,748		1996-01-25
PCT/US1996/014889 WO1997011143A2 (en)	1995-09-18	1996-09-17	Heavy duty liquid detergent compositions comprising salts of alpha sulfonated fatty acid methyl esters and use of alpha-sulfonatedfatty acid salts to inhibit redeposition of soil on fabric

Publications (2)

Publication Number	Publication Date
CA2205592A1 CA2205592A1 (en)	1997-03-27
CA2205592C true CA2205592C (en)	2001-12-11

Family

ID=27063032

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002205592A Expired - Lifetime CA2205592C (en)	1995-09-18	1996-09-17	Heavy duty liquid detergent compositions comprising salts of alpha sulfonated fatty acid methyl esters and use of alpha-sulfonated fatty acid salts to inhibit redeposition of soilon fabric

Country Status (10)

Country	Link
EP (1)	EP0792336A2 (de)
JP (1)	JPH10502969A (de)
AR (1)	AR003618A1 (de)
AU (1)	AU699950B2 (de)
BR (1)	BR9606651A (de)
CA (1)	CA2205592C (de)
CO (1)	CO5040238A1 (de)
MX (1)	MX9703647A (de)
NZ (1)	NZ318989A (de)
WO (1)	WO1997011143A2 (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA2595940A1 (en) *	2005-02-14	2006-08-24	The Dial Corporation	Improved detergent composition with enhanced whitening power
JP5481720B2 (ja) *	2007-12-28	2014-04-23	ライオン株式会社	粒状洗剤組成物
JP5481719B2 (ja) *	2007-12-28	2014-04-23	ライオン株式会社	粒状洗剤組成物
PL2295530T3 (pl) *	2009-09-14	2012-04-30	Procter & Gamble	Kompozycja detergentu
CN102575195B (zh)	2009-10-15	2014-06-04	狮王株式会社	液体清洗剂组合物
JP5793563B2 (ja) *	2011-04-18	2015-10-14	ライオン株式会社	液体洗浄剤
DE102013226260A1 (de) *	2013-12-17	2015-06-18	Henkel Ag & Co. Kgaa	Waschmittel enthaltend Methylestersulfonate (MES) und Methylesterethoxylate (MEE)
WO2016160407A1 (en) *	2015-03-31	2016-10-06	Stepan Company	Detergents based on alpha-sulfonated fatty ester surfactants
CN106047529A (zh) *	2016-06-30	2016-10-26	安徽泰隆成亚集团股份有限公司	环保浓缩型衣料用液体洗涤剂
EP3441447A1 (de) *	2017-08-09	2019-02-13	Henkel AG & Co. KGaA	Nichtionisches celluloseether als schmutzentfernungsverstärker bei der reinigung harter oberflächen
US20220364020A1 (en)	2019-06-28	2022-11-17	Conopco, Inc., D/B/A Unilever	Detergent composition

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA795748A (en) *		1968-10-01	Stepan Chemical Company	Heavy-duty synthetic detergent compositions
BE631335A (de) *	1962-04-24
GB1368736A (en) *	1970-09-09	1974-10-02	Unilever Ltd	Detergent compositions
DE2333356C3 (de) *	1973-06-30	1982-03-11	Henkel KGaA, 4000 Düsseldorf	Waschmittel
JPS6059960B2 (ja) *	1980-11-28	1985-12-27	ライオン株式会社	粉セツケン組成物
DE3726326A1 (de) *	1987-08-07	1989-02-16	Henkel Kgaa	Verbesserte wasch- und reinigungsmittel fuer textilien (ii)
GB8808041D0 (en) *	1988-04-06	1988-05-05	Unilever Plc	Detergent composition
JPH0637639B2 (ja) *	1988-10-12	1994-05-18	ライオン株式会社	高嵩密度粒状洗剤組成物
US5118440A (en) *	1990-03-05	1992-06-02	The Procter & Gamble Company	Light-duty liquid dishwashing detergent composition containing alkyl polysaccharide and alpha-sulfonated fatty acid alkyl ester surfactants
JPH06330084A (ja) *	1993-05-21	1994-11-29	Lion Corp	洗浄剤組成物
WO1995010585A1 (en) *	1993-10-12	1995-04-20	Stepan Company	Liquid detergent compositions comprising salts of alpha sulfonated fatty acid methyl esters, and anionic surfactants

1996
- 1996-09-17 CA CA002205592A patent/CA2205592C/en not_active Expired - Lifetime
- 1996-09-17 BR BR9606651A patent/BR9606651A/pt not_active Application Discontinuation
- 1996-09-17 WO PCT/US1996/014889 patent/WO1997011143A2/en not_active Ceased
- 1996-09-17 AU AU71112/96A patent/AU699950B2/en not_active Ceased
- 1996-09-17 EP EP96932244A patent/EP0792336A2/de not_active Withdrawn
- 1996-09-17 MX MX9703647A patent/MX9703647A/es unknown
- 1996-09-17 NZ NZ318989A patent/NZ318989A/en unknown
- 1996-09-17 JP JP9512836A patent/JPH10502969A/ja active Pending
- 1996-09-18 AR ARP960104404A patent/AR003618A1/es unknown
- 1996-09-18 CO CO96049859A patent/CO5040238A1/es unknown

Also Published As

Publication number	Publication date
EP0792336A2 (de)	1997-09-03
AR003618A1 (es)	1998-08-05
JPH10502969A (ja)	1998-03-17
CO5040238A1 (es)	2001-05-29
MX9703647A (es)	1997-08-30
AU699950B2 (en)	1998-12-17
NZ318989A (en)	1999-10-28
WO1997011143A3 (en)	1997-04-24
WO1997011143A2 (en)	1997-03-27
BR9606651A (pt)	1997-09-30
AU7111296A (en)	1997-04-09
CA2205592A1 (en)	1997-03-27

Legal Events

Date	Code	Title	Description
1997-05-16	EEER	Examination request
2016-11-21	MKEX	Expiry	Effective date: 20160919

Publication	Publication Date	Title
US5945394A (en)	1999-08-31	Heavy duty liquid detergent compositions comprising salts of α-sulfonated fatty acid methyl esters and use of α-sulphonated fatty acid salts to inhibit redeposition of soil on fabric
KR100209789B1 (ko)	1999-07-15	알파-술폰화 지방산 메틸에스테르 및 음이온성 계면활성제를 포함하는 액체세제 조성물
JP3267618B2 (ja)	2002-03-18	グリセロールアミドを有するクリーニング組成物
JP3046070B2 (ja)	2000-05-29	ポリヒドロキシ脂肪酸アミドと増泡剤とを含有する洗剤組成物
JP3046071B2 (ja)	2000-05-29	ポリヒドロキシ脂肪酸アミド界面活性剤とアルキルエステルスルホネート界面活性剤とを含有する洗剤組成物
FI105341B (fi)	2000-07-31	Polyhydroksirasvahappoamidit valkaisuainetta sisältävissä nestemäisissä pesuainekoostumuksissa
RU2112784C1 (ru)	1998-06-10	Жидкая или твердая моющая композиция с контролируемым пенообразованием для стирки тканей, способ стирки тканей и моющие частицы
CZ283033B6 (cs)	1997-12-17	Detergenční kompozice aktivovaná zeolitem a/nebo vrstevnatým silikátem a způsob zlepšování její schopnosti čištění textilie
CZ281623B6 (cs)	1996-11-13	Čistící prostředky obsahující aniontová povrchově aktivní činidla, polyhydroxyamidy mastné kyseliny a hořčík
CA2092187C (en)	1998-01-20	Detergent compositions with polyhydroxy fatty acid amide surfactant and polymeric dispersing agent
SK25293A3 (en)	1994-01-12	Polyhydroxy fatty acid amides in soil release agent-containing detergent compositions
JPH08503732A (ja)	1996-04-23	特選の石鹸を含有する高起泡性洗剤組成物
CA2205592C (en)	2001-12-11	Heavy duty liquid detergent compositions comprising salts of alpha sulfonated fatty acid methyl esters and use of alpha-sulfonated fatty acid salts to inhibit redeposition of soilon fabric
NZ240031A (en)	1995-07-26	Detergent containing polyhydroxy fatty acid amide and alkyl benzene sulphonate
JPH08503733A (ja)	1996-04-23	カルシウムイオンとポリヒドロキシ脂肪酸アミド非イオン界面活性剤／所定の陰イオン界面活性剤／石鹸界面活性剤混合物とを含有する洗剤組成物
AU682668B2 (en)	1997-10-16	Detergent composition with suds suppressing system
WO1997000930A1 (en)	1997-01-09	Manual dishwashing compositions
CA2191136C (en)	1999-12-28	Manual dishwashing compositions
GB2298211A (en)	1996-08-28	Liquid detergent compositions comprising anionic surfactant, nonionic surfactant and proteolytic enzyme
IE64994B1 (en)	1995-09-20	Detergent compositions containing anionic surfactants polyhydroxy fatty acid amides and a critically selected suds enhancing agent
EP0591397A1 (de)	1994-04-13	Waschmittel enthaltend Polyhydroxyfettsäureamide und unlöslichen ethoxylierten Alkohol.
JPH08503735A (ja)	1996-04-23	ポリヒドロキシ脂肪酸アミドと硫酸化ポリヒドロキシ脂肪酸アミドと石鹸とを含有する洗剤組成物
CZ38896A3 (en)	1996-08-14	Preparation containing lipase enzymes for hand washing of dishes
CZ38793A3 (cs)	1993-10-13	Detergenční kompozice obsahující amidy polyhydroxy-mastných kyselin a alkylestersulfonatová povrchově aktivní činidla
KR20010001053A (ko)	2001-01-05	알킬벤젠설폰산마그네슘염을 함유하는 알카리성 액체세제 조성물