CA2245144A1 - Procede d'electrolyse d'une saumure - Google Patents
Procede d'electrolyse d'une saumureInfo
- Publication number
- CA2245144A1 CA2245144A1 CA002245144A CA2245144A CA2245144A1 CA 2245144 A1 CA2245144 A1 CA 2245144A1 CA 002245144 A CA002245144 A CA 002245144A CA 2245144 A CA2245144 A CA 2245144A CA 2245144 A1 CA2245144 A1 CA 2245144A1
- Authority
- CA
- Canada
- Prior art keywords
- cathode
- electrolysis
- cation exchange
- cell
- exchange membrane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
- C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B13/00—Diaphragms; Spacing elements
- C25B13/04—Diaphragms; Spacing elements characterised by the material
- C25B13/08—Diaphragms; Spacing elements characterised by the material based on organic materials
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/02—Process control or regulation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Automation & Control Theory (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
L'invention concerne un procédé d'électrolyse d'une solution de chlorure de sodium au moyen d'une cellule d'électrolyse à membrane et à
cathode à réduction d'oxygène.
Ce procédé consiste à effectuer l'électrolyse d'une solution aqueuse de chlorure de sodium au moyen d'une cellule comprenant une membrane échangeuse de cations qui divise la cellule en un compartiment anodique et un compartiment cathodique dans lequel ladite cathode est placée directement contre la membrane échangeuse de cations, ledit compartiment cathodique étant alimenté par un gaz humidifié contenant de l'oxygène, caractérisé en ce que, pour obtenir une concentration pondérale en soude entre la membrane échangeuse de cations et la cathode inférieure à 38,8 %, on utilise une solution aqueuse de chlorure de sodium (anolyte) ayant une concentration pondérale en chlorure de sodium inférieure à 200 g/l et que l'eau humidifiant le gaz contenant de l'oxygène est sous forme de vapeur d'eau.
Le rendement en soude est supérieur à celui obtenu dans les procédés traditionnels.
cathode à réduction d'oxygène.
Ce procédé consiste à effectuer l'électrolyse d'une solution aqueuse de chlorure de sodium au moyen d'une cellule comprenant une membrane échangeuse de cations qui divise la cellule en un compartiment anodique et un compartiment cathodique dans lequel ladite cathode est placée directement contre la membrane échangeuse de cations, ledit compartiment cathodique étant alimenté par un gaz humidifié contenant de l'oxygène, caractérisé en ce que, pour obtenir une concentration pondérale en soude entre la membrane échangeuse de cations et la cathode inférieure à 38,8 %, on utilise une solution aqueuse de chlorure de sodium (anolyte) ayant une concentration pondérale en chlorure de sodium inférieure à 200 g/l et que l'eau humidifiant le gaz contenant de l'oxygène est sous forme de vapeur d'eau.
Le rendement en soude est supérieur à celui obtenu dans les procédés traditionnels.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9711795A FR2768751B1 (fr) | 1997-09-23 | 1997-09-23 | Procede d'electrolyse d'une saumure |
| FR9711795 | 1997-09-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2245144A1 true CA2245144A1 (fr) | 1999-03-23 |
| CA2245144C CA2245144C (fr) | 2002-08-13 |
Family
ID=9511354
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002245144A Expired - Fee Related CA2245144C (fr) | 1997-09-23 | 1998-09-22 | Procede d'electrolyse d'une saumure |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6080298A (fr) |
| EP (1) | EP0903425B1 (fr) |
| JP (1) | JP3073968B2 (fr) |
| KR (1) | KR100313259B1 (fr) |
| CN (1) | CN1107744C (fr) |
| AT (1) | ATE377100T1 (fr) |
| BR (1) | BR9803590A (fr) |
| CA (1) | CA2245144C (fr) |
| DE (1) | DE69838632T2 (fr) |
| ES (1) | ES2296325T3 (fr) |
| FR (1) | FR2768751B1 (fr) |
| NO (1) | NO322395B1 (fr) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050011753A1 (en) * | 2003-06-23 | 2005-01-20 | Jackson John R. | Low energy chlorate electrolytic cell and process |
| FR2930541B1 (fr) | 2008-04-29 | 2010-05-21 | Solvay | Procede d'epuration de solutions aqueuses |
| KR101239145B1 (ko) | 2009-03-17 | 2013-03-06 | 김영준 | 음식물 쓰레기에 포함된 염화나트륨 수용액을 전기 분해하는 장치 |
| CN102134724B (zh) * | 2010-12-31 | 2012-06-20 | 北京化工大学 | 阴离子膜电解槽装置用于纯碱生产中废液脱盐的方法 |
| CN106148992A (zh) * | 2015-04-20 | 2016-11-23 | 李坚 | 离子膜催化法或电渗析催化法水制氢及其应用 |
| EP3608444B1 (fr) | 2017-03-30 | 2025-01-01 | Kaneka Corporation | Procédé de fabrication d'hydroxyde de sodium et/ou de chlore et cellule d'électrolyse d'eau salée à deux chambres |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4221644A (en) * | 1979-08-14 | 1980-09-09 | Diamond Shamrock Corporation | Air-depolarized chlor-alkali cell operation methods |
| JPS5641392A (en) * | 1979-09-11 | 1981-04-18 | Toyo Soda Mfg Co Ltd | Electrolytic method of alkali chloride aqueous solution |
| JP3400508B2 (ja) * | 1993-10-27 | 2003-04-28 | ペルメレック電極株式会社 | 塩水電解方法及び電解槽 |
| JP3344828B2 (ja) * | 1994-06-06 | 2002-11-18 | ペルメレック電極株式会社 | 塩水の電解方法 |
| JPH08333693A (ja) * | 1995-06-05 | 1996-12-17 | Permelec Electrode Ltd | 電解槽 |
-
1997
- 1997-09-23 FR FR9711795A patent/FR2768751B1/fr not_active Expired - Fee Related
-
1998
- 1998-09-15 DE DE69838632T patent/DE69838632T2/de not_active Expired - Lifetime
- 1998-09-15 EP EP98402268A patent/EP0903425B1/fr not_active Expired - Lifetime
- 1998-09-15 AT AT98402268T patent/ATE377100T1/de not_active IP Right Cessation
- 1998-09-15 ES ES98402268T patent/ES2296325T3/es not_active Expired - Lifetime
- 1998-09-17 NO NO19984306A patent/NO322395B1/no not_active IP Right Cessation
- 1998-09-21 KR KR1019980038977A patent/KR100313259B1/ko not_active Expired - Fee Related
- 1998-09-21 JP JP10266805A patent/JP3073968B2/ja not_active Expired - Fee Related
- 1998-09-22 BR BR9803590-8A patent/BR9803590A/pt not_active IP Right Cessation
- 1998-09-22 CA CA002245144A patent/CA2245144C/fr not_active Expired - Fee Related
- 1998-09-23 US US09/158,889 patent/US6080298A/en not_active Expired - Lifetime
- 1998-09-23 CN CN98120557A patent/CN1107744C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE69838632T2 (de) | 2008-08-28 |
| EP0903425A1 (fr) | 1999-03-24 |
| ES2296325T3 (es) | 2008-04-16 |
| KR19990029993A (ko) | 1999-04-26 |
| FR2768751B1 (fr) | 1999-10-29 |
| CA2245144C (fr) | 2002-08-13 |
| JPH11152591A (ja) | 1999-06-08 |
| JP3073968B2 (ja) | 2000-08-07 |
| FR2768751A1 (fr) | 1999-03-26 |
| NO984306L (no) | 1999-03-24 |
| DE69838632D1 (de) | 2007-12-13 |
| EP0903425B1 (fr) | 2007-10-31 |
| NO984306D0 (no) | 1998-09-17 |
| KR100313259B1 (ko) | 2002-02-19 |
| BR9803590A (pt) | 1999-12-14 |
| ATE377100T1 (de) | 2007-11-15 |
| US6080298A (en) | 2000-06-27 |
| NO322395B1 (no) | 2006-10-02 |
| CN1107744C (zh) | 2003-05-07 |
| CN1219610A (zh) | 1999-06-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20130924 |