CA2267939C - Processus de traitement au chlorure pour la fabrication d'un catalyseur - Google Patents

Processus de traitement au chlorure pour la fabrication d'un catalyseur Download PDF

Info

Publication number: CA2267939C
Authority: CA; Canada
Prior art keywords: mole; process according; weight; catalyst; olefins
Prior art date: 1998-05-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA 2267939

Other languages

English (en)

Other versions

CA2267939A1 (fr

Inventor

Mark Kelly

Dusan Jeremic

Victoria Ker

Charles Russell

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Nova Chemicals Corp

Original Assignee

Nova Chemicals Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-05-12

Filing date

1999-04-06

Publication date

2007-06-05

1999-04-06 Application filed by Nova Chemicals Corp filed Critical Nova Chemicals Corp

1999-11-12 Publication of CA2267939A1 publication Critical patent/CA2267939A1/fr

2007-06-05 Application granted granted Critical

2007-06-05 Publication of CA2267939C publication Critical patent/CA2267939C/fr

2019-04-06 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 64
238000000034 method Methods 0.000 title claims description 39
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 title abstract description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 72
-1 alkylaluminum compound Chemical class 0.000 claims abstract description 31
239000010936 titanium Substances 0.000 claims abstract description 20
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 7
229910052719 titanium Inorganic materials 0.000 claims abstract description 7
238000012685 gas phase polymerization Methods 0.000 claims abstract description 6
229910052782 aluminium Inorganic materials 0.000 claims description 36
239000000377 silicon dioxide Substances 0.000 claims description 34
229920000642 polymer Polymers 0.000 claims description 21
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 19
239000005977 Ethylene Substances 0.000 claims description 19
239000004711 α-olefin Substances 0.000 claims description 19
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 16
239000002904 solvent Substances 0.000 claims description 16
239000007789 gas Substances 0.000 claims description 14
150000004820 halides Chemical class 0.000 claims description 14
239000011261 inert gas Substances 0.000 claims description 11
239000000203 mixture Substances 0.000 claims description 11
238000006116 polymerization reaction Methods 0.000 claims description 11
239000001257 hydrogen Substances 0.000 claims description 10
229910052739 hydrogen Inorganic materials 0.000 claims description 10
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 8
239000004215 Carbon black (E152) Substances 0.000 claims description 5
125000000217 alkyl group Chemical group 0.000 claims description 5
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
229930195733 hydrocarbon Natural products 0.000 claims description 5
150000002430 hydrocarbons Chemical class 0.000 claims description 5
150000003609 titanium compounds Chemical class 0.000 claims description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
150000005376 secondary alkyl halides Chemical class 0.000 claims description 2
150000005377 tertiary alkyl halides Chemical class 0.000 claims description 2
125000004435 hydrogen atom Chemical class [H]* 0.000 claims 5
125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 1
WPWHSFAFEBZWBB-UHFFFAOYSA-N 1-butyl radical Chemical group [CH2]CCC WPWHSFAFEBZWBB-UHFFFAOYSA-N 0.000 claims 1
150000001875 compounds Chemical class 0.000 abstract description 9
150000001336 alkenes Chemical class 0.000 abstract description 3
238000004519 manufacturing process Methods 0.000 abstract description 2
239000011777 magnesium Substances 0.000 description 26
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 10
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 9
229910052749 magnesium Inorganic materials 0.000 description 8
229910052799 carbon Inorganic materials 0.000 description 7
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 6
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
239000000178 monomer Substances 0.000 description 5
239000002245 particle Substances 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
238000009826 distribution Methods 0.000 description 4
150000002431 hydrogen Chemical class 0.000 description 4
238000003756 stirring Methods 0.000 description 4
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
238000001035 drying Methods 0.000 description 3
239000012530 fluid Substances 0.000 description 3
150000002681 magnesium compounds Chemical class 0.000 description 3
239000002002 slurry Substances 0.000 description 3
239000003381 stabilizer Substances 0.000 description 3
238000003786 synthesis reaction Methods 0.000 description 3
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
239000012018 catalyst precursor Substances 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
239000004611 light stabiliser Substances 0.000 description 2
229920000092 linear low density polyethylene Polymers 0.000 description 2
239000004707 linear low-density polyethylene Substances 0.000 description 2
UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
239000011148 porous material Substances 0.000 description 2
239000000376 reactant Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
NBRKLOOSMBRFMH-UHFFFAOYSA-N tert-butyl chloride Chemical compound CC(C)(C)Cl NBRKLOOSMBRFMH-UHFFFAOYSA-N 0.000 description 2
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
BSPCSKHALVHRSR-UHFFFAOYSA-N 2-chlorobutane Chemical compound CCC(C)Cl BSPCSKHALVHRSR-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
239000006057 Non-nutritive feed additive Substances 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
229910003074 TiCl4 Inorganic materials 0.000 description 1
239000012190 activator Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001350 alkyl halides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
150000004796 dialkyl magnesium compounds Chemical class 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
229920001973 fluoroelastomer Polymers 0.000 description 1
239000008246 gaseous mixture Substances 0.000 description 1
230000002140 halogenating effect Effects 0.000 description 1
239000012760 heat stabilizer Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000012433 hydrogen halide Substances 0.000 description 1
229910000039 hydrogen halide Inorganic materials 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
ULYZAYCEDJDHCC-UHFFFAOYSA-N isopropyl chloride Chemical compound CC(C)Cl ULYZAYCEDJDHCC-UHFFFAOYSA-N 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
YHNWUQFTJNJVNU-UHFFFAOYSA-N magnesium;butane;ethane Chemical compound [Mg+2].[CH2-]C.CCC[CH2-] YHNWUQFTJNJVNU-UHFFFAOYSA-N 0.000 description 1
239000000463 material Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
150000003961 organosilicon compounds Chemical class 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000010926 purge Methods 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000001175 rotational moulding Methods 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
150000003623 transition metal compounds Chemical class 0.000 description 1
238000005406 washing Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000001993 wax Substances 0.000 description 1

Landscapes

Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

CA 2267939 1998-05-12 1999-04-06 Processus de traitement au chlorure pour la fabrication d'un catalyseur Expired - Lifetime CA2267939C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US7628098A	1998-05-12	1998-05-12
US09/076,280		1998-05-12

Publications (2)

Publication Number	Publication Date
CA2267939A1 CA2267939A1 (fr)	1999-11-12
CA2267939C true CA2267939C (fr)	2007-06-05

Family

ID=29709288

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2267939 Expired - Lifetime CA2267939C (fr)	1998-05-12	1999-04-06	Processus de traitement au chlorure pour la fabrication d'un catalyseur

Country Status (1)

Country	Link
CA (1)	CA2267939C (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2006082048A1 (fr) *	2005-02-03	2006-08-10	Basell Polyolefine Gmbh	Systemes catalytiques de type ziegler-natta et procede pour les preparer
US10155831B2 (en) *	2013-09-05	2018-12-18	Univation Technologies, Llc	Process control for long chain branching control in polyethylene production

1999
- 1999-04-06 CA CA 2267939 patent/CA2267939C/fr not_active Expired - Lifetime

Also Published As

Publication number	Publication date
CA2267939A1 (fr)	1999-11-12

Legal Events

Date	Code	Title	Description
2004-03-12	EEER	Examination request
2019-06-10	MKEX	Expiry	Effective date: 20190408

Publication	Publication Date	Title
US4530912A (en)	1985-07-23	Polymerization catalyst and method
JP2557054B2 (ja)	1996-11-27	アルフア−オレフイン重合用触媒組成物
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JP4298794B2 (ja)	2009-07-22	高活性メタロセン重合法
CA2267937C (fr)	2008-12-09	Processus fractionne d'addition d'aluminium pour la fabrication d'un catalyseur
CA1163617A (fr)	1984-03-13	Catalyseur de polymerisation des olefines, et procede qui y fait appel
CA2109136C (fr)	2005-12-20	Methode de preparation d'un catalyseur de type ziegler-natta
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