CA2306383A1 - Pastilles de detergent pour lave-vaisselle a rendement ameliore - Google Patents

Pastilles de detergent pour lave-vaisselle a rendement ameliore Download PDF

Info

Publication number: CA2306383A1
Authority: CA; Canada
Prior art keywords: tablet; weight; detergent; coating material; region
Prior art date: 1999-04-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002306383A

Other languages

English (en)

Inventor

Juergen Haerer

Christian Nitsch

Matthias Sunder

Thomas Holderbaum

Bernd Richter

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee

Henkel AG and Co KGaA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-04-23

Filing date

2000-04-20

Publication date

2000-10-23

2000-04-20 Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA

2000-10-23 Publication of CA2306383A1 publication Critical patent/CA2306383A1/fr

Status Abandoned legal-status Critical Current

Links

239000003599 detergent Substances 0.000 claims abstract description 124
102000004190 Enzymes Human genes 0.000 claims abstract description 82
108090000790 Enzymes Proteins 0.000 claims abstract description 82
239000011248 coating agent Substances 0.000 claims abstract description 65
238000000576 coating method Methods 0.000 claims abstract description 65
239000000463 material Substances 0.000 claims abstract description 63
239000007788 liquid Substances 0.000 claims abstract description 48
238000002844 melting Methods 0.000 claims abstract description 35
230000008018 melting Effects 0.000 claims abstract description 35
238000002360 preparation method Methods 0.000 claims abstract description 27
239000013543 active substance Substances 0.000 claims abstract description 22
230000005923 long-lasting effect Effects 0.000 claims abstract description 3
229940088598 enzyme Drugs 0.000 claims description 79
238000000034 method Methods 0.000 claims description 79
108091005804 Peptidases Proteins 0.000 claims description 59
239000004365 Protease Substances 0.000 claims description 54
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 53
239000006185 dispersion Substances 0.000 claims description 45
239000000203 mixture Substances 0.000 claims description 45
239000007844 bleaching agent Substances 0.000 claims description 40
102000013142 Amylases Human genes 0.000 claims description 38
108010065511 Amylases Proteins 0.000 claims description 38
235000019418 amylase Nutrition 0.000 claims description 35
239000000155 melt Substances 0.000 claims description 34
239000004382 Amylase Substances 0.000 claims description 30
239000002245 particle Substances 0.000 claims description 30
-1 siloxanes Chemical class 0.000 claims description 29
239000010410 layer Substances 0.000 claims description 25
229920001223 polyethylene glycol Polymers 0.000 claims description 25
239000004615 ingredient Substances 0.000 claims description 24
239000000126 substance Substances 0.000 claims description 19
229940079919 digestives enzyme preparation Drugs 0.000 claims description 18
239000002736 nonionic surfactant Substances 0.000 claims description 17
239000012190 activator Substances 0.000 claims description 16
239000003795 chemical substances by application Substances 0.000 claims description 16
238000009826 distribution Methods 0.000 claims description 13
238000004851 dishwashing Methods 0.000 claims description 12
239000004094 surface-active agent Substances 0.000 claims description 12
238000004519 manufacturing process Methods 0.000 claims description 11
235000014113 dietary fatty acids Nutrition 0.000 claims description 7
239000000194 fatty acid Chemical class 0.000 claims description 7
229930195729 fatty acid Chemical class 0.000 claims description 7
238000007493 shaping process Methods 0.000 claims description 7
150000002191 fatty alcohols Chemical class 0.000 claims description 6
229920001451 polypropylene glycol Polymers 0.000 claims description 6
150000002148 esters Chemical class 0.000 claims description 5
150000004665 fatty acids Chemical class 0.000 claims description 5
239000002270 dispersing agent Substances 0.000 claims description 4
239000003995 emulsifying agent Substances 0.000 claims description 4
238000011049 filling Methods 0.000 claims description 4
238000007667 floating Methods 0.000 claims description 4
238000007711 solidification Methods 0.000 claims description 4
230000008023 solidification Effects 0.000 claims description 4
238000002156 mixing Methods 0.000 claims description 3
239000000654 additive Substances 0.000 claims description 2
239000000470 constituent Substances 0.000 claims description 2
238000001816 cooling Methods 0.000 claims description 2
238000001125 extrusion Methods 0.000 claims description 2
238000005469 granulation Methods 0.000 claims description 2
230000003179 granulation Effects 0.000 claims description 2
229920000223 polyglycerol Chemical class 0.000 claims description 2
239000002356 single layer Substances 0.000 claims description 2
238000003825 pressing Methods 0.000 claims 1
239000003826 tablet Substances 0.000 description 163
235000019419 proteases Nutrition 0.000 description 44
239000002253 acid Substances 0.000 description 27
150000003839 salts Chemical class 0.000 description 23
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
108090001060 Lipase Proteins 0.000 description 21
102000004882 Lipase Human genes 0.000 description 21
239000004367 Lipase Substances 0.000 description 21
235000019421 lipase Nutrition 0.000 description 21
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 20
125000004432 carbon atom Chemical group C* 0.000 description 17
230000000694 effects Effects 0.000 description 17
235000019832 sodium triphosphate Nutrition 0.000 description 17
238000004140 cleaning Methods 0.000 description 16
235000019441 ethanol Nutrition 0.000 description 16
239000000047 product Substances 0.000 description 16
150000007513 acids Chemical class 0.000 description 15
239000002304 perfume Substances 0.000 description 14
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 13
229910052708 sodium Inorganic materials 0.000 description 13
239000011734 sodium Substances 0.000 description 12
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 11
150000001875 compounds Chemical class 0.000 description 11
239000003921 oil Substances 0.000 description 11
235000019198 oils Nutrition 0.000 description 11
239000010457 zeolite Substances 0.000 description 11
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
229920000642 polymer Polymers 0.000 description 10
229920002245 Dextrose equivalent Polymers 0.000 description 9
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
229910021536 Zeolite Inorganic materials 0.000 description 9
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 9
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 9
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 8
229920005646 polycarboxylate Polymers 0.000 description 8
239000011591 potassium Substances 0.000 description 8
229910052700 potassium Inorganic materials 0.000 description 8
150000004760 silicates Chemical class 0.000 description 8
239000000243 solution Substances 0.000 description 8
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 8
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 7
150000001298 alcohols Chemical class 0.000 description 7
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 7
238000005260 corrosion Methods 0.000 description 7
230000007797 corrosion Effects 0.000 description 7
239000004375 Dextrin Substances 0.000 description 6
229920001353 Dextrin Polymers 0.000 description 6
229910019142 PO4 Inorganic materials 0.000 description 6
102000035195 Peptidases Human genes 0.000 description 6
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 6
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
125000000217 alkyl group Chemical group 0.000 description 6
229940025131 amylases Drugs 0.000 description 6
238000004061 bleaching Methods 0.000 description 6
235000019425 dextrin Nutrition 0.000 description 6
230000002366 lipolytic effect Effects 0.000 description 6
229910052748 manganese Inorganic materials 0.000 description 6
239000011572 manganese Substances 0.000 description 6
235000021317 phosphate Nutrition 0.000 description 6
235000011007 phosphoric acid Nutrition 0.000 description 6
150000003013 phosphoric acid derivatives Chemical class 0.000 description 6
239000001488 sodium phosphate Substances 0.000 description 6
239000002689 soil Substances 0.000 description 6
239000001226 triphosphate Substances 0.000 description 6
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 5
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
150000001868 cobalt Chemical class 0.000 description 5
229910017052 cobalt Inorganic materials 0.000 description 5
239000010941 cobalt Substances 0.000 description 5
229920001577 copolymer Polymers 0.000 description 5
BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 5
239000000975 dye Substances 0.000 description 5
239000003112 inhibitor Substances 0.000 description 5
239000000178 monomer Substances 0.000 description 5
239000000843 powder Substances 0.000 description 5
235000013772 propylene glycol Nutrition 0.000 description 5
229910052723 transition metal Inorganic materials 0.000 description 5
ZGZHWIAQICBGKN-UHFFFAOYSA-N 1-nonanoylpyrrolidine-2,5-dione Chemical compound CCCCCCCCC(=O)N1C(=O)CCC1=O ZGZHWIAQICBGKN-UHFFFAOYSA-N 0.000 description 4
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 4
235000008733 Citrus aurantifolia Nutrition 0.000 description 4
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 4
SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 4
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 4
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
235000011941 Tilia x europaea Nutrition 0.000 description 4
UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
229910000147 aluminium phosphate Inorganic materials 0.000 description 4
150000001408 amides Chemical class 0.000 description 4
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 4
239000001177 diphosphate Substances 0.000 description 4
230000007062 hydrolysis Effects 0.000 description 4
238000006460 hydrolysis reaction Methods 0.000 description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
239000004571 lime Substances 0.000 description 4
235000013372 meat Nutrition 0.000 description 4
235000019796 monopotassium phosphate Nutrition 0.000 description 4
229910000402 monopotassium phosphate Inorganic materials 0.000 description 4
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 4
BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 4
238000003860 storage Methods 0.000 description 4
RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 3
101000740449 Bacillus subtilis (strain 168) Biotin/lipoyl attachment protein Proteins 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
102000004157 Hydrolases Human genes 0.000 description 3
108090000604 Hydrolases Proteins 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
239000004115 Sodium Silicate Substances 0.000 description 3
229920002472 Starch Polymers 0.000 description 3
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
239000001361 adipic acid Substances 0.000 description 3
235000011037 adipic acid Nutrition 0.000 description 3
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 3
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 3
150000001720 carbohydrates Chemical class 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
150000004691 decahydrates Chemical class 0.000 description 3
238000000354 decomposition reaction Methods 0.000 description 3
XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 3
235000011180 diphosphates Nutrition 0.000 description 3
ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 3
229910000397 disodium phosphate Inorganic materials 0.000 description 3
238000009472 formulation Methods 0.000 description 3
239000011521 glass Substances 0.000 description 3
239000008103 glucose Substances 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
150000002576 ketones Chemical class 0.000 description 3
229920006324 polyoxymethylene Polymers 0.000 description 3
235000011009 potassium phosphates Nutrition 0.000 description 3
235000019828 potassium polyphosphate Nutrition 0.000 description 3
230000001603 reducing effect Effects 0.000 description 3
229910052709 silver Inorganic materials 0.000 description 3
239000004332 silver Substances 0.000 description 3
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 3
AQMNWCRSESPIJM-UHFFFAOYSA-M sodium metaphosphate Chemical compound [Na+].[O-]P(=O)=O AQMNWCRSESPIJM-UHFFFAOYSA-M 0.000 description 3
229910000162 sodium phosphate Inorganic materials 0.000 description 3
159000000000 sodium salts Chemical class 0.000 description 3
235000019351 sodium silicates Nutrition 0.000 description 3
239000010936 titanium Substances 0.000 description 3
229910052719 titanium Inorganic materials 0.000 description 3
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 3
229910000406 trisodium phosphate Inorganic materials 0.000 description 3
229910052720 vanadium Inorganic materials 0.000 description 3
YPFNIPKMNMDDDB-UHFFFAOYSA-K 2-[2-[bis(carboxylatomethyl)amino]ethyl-(2-hydroxyethyl)amino]acetate;iron(3+) Chemical compound [Fe+3].OCCN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O YPFNIPKMNMDDDB-UHFFFAOYSA-K 0.000 description 2
WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 2
UYWQUFXKFGHYNT-UHFFFAOYSA-N Benzylformate Chemical compound O=COCC1=CC=CC=C1 UYWQUFXKFGHYNT-UHFFFAOYSA-N 0.000 description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
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FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
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BTJXBZZBBNNTOV-UHFFFAOYSA-N Linalyl benzoate Chemical compound CC(C)=CCCC(C)(C=C)OC(=O)C1=CC=CC=C1 BTJXBZZBBNNTOV-UHFFFAOYSA-N 0.000 description 2
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230000002378 acidificating effect Effects 0.000 description 2
150000001299 aldehydes Chemical class 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
229910000318 alkali metal phosphate Inorganic materials 0.000 description 2
125000005263 alkylenediamine group Polymers 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
239000003945 anionic surfactant Substances 0.000 description 2
PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
239000002585 base Substances 0.000 description 2
239000011324 bead Substances 0.000 description 2
GGNQRNBDZQJCCN-UHFFFAOYSA-N benzene-1,2,4-triol Chemical compound OC1=CC=C(O)C(O)=C1 GGNQRNBDZQJCCN-UHFFFAOYSA-N 0.000 description 2
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150000001735 carboxylic acids Chemical class 0.000 description 2
YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
239000003093 cationic surfactant Substances 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
150000001805 chlorine compounds Chemical class 0.000 description 2
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150000001412 amines Chemical class 0.000 description 1
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239000002280 amphoteric surfactant Substances 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
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239000012964 benzotriazole Substances 0.000 description 1
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239000012876 carrier material Substances 0.000 description 1
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239000000460 chlorine Substances 0.000 description 1
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230000005494 condensation Effects 0.000 description 1
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238000007598 dipping method Methods 0.000 description 1
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BRDYCNFHFWUBCZ-UHFFFAOYSA-N dodecaneperoxoic acid Chemical compound CCCCCCCCCCCC(=O)OO BRDYCNFHFWUBCZ-UHFFFAOYSA-N 0.000 description 1
235000013601 eggs Nutrition 0.000 description 1
238000002003 electron diffraction Methods 0.000 description 1
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238000001704 evaporation Methods 0.000 description 1
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239000004744 fabric Substances 0.000 description 1
235000019197 fats Nutrition 0.000 description 1
239000001148 ferula galbaniflua oil terpeneless Substances 0.000 description 1
238000005187 foaming Methods 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
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235000012209 glucono delta-lactone Nutrition 0.000 description 1
229960003681 gluconolactone Drugs 0.000 description 1
239000001087 glyceryl triacetate Substances 0.000 description 1
235000013773 glyceryl triacetate Nutrition 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 description 1
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229930182470 glycoside Natural products 0.000 description 1
125000003147 glycosyl group Chemical group 0.000 description 1
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125000000623 heterocyclic group Chemical group 0.000 description 1
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 1
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WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 description 1
150000002460 imidazoles Chemical class 0.000 description 1
150000003949 imides Chemical class 0.000 description 1
150000002484 inorganic compounds Chemical class 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000002563 ionic surfactant Substances 0.000 description 1
239000001851 juniperus communis l. berry oil Substances 0.000 description 1
150000003951 lactams Chemical class 0.000 description 1
150000002596 lactones Chemical group 0.000 description 1
239000003446 ligand Substances 0.000 description 1
SDQFDHOLCGWZPU-UHFFFAOYSA-N lilial Chemical compound O=CC(C)CC1=CC=C(C(C)(C)C)C=C1 SDQFDHOLCGWZPU-UHFFFAOYSA-N 0.000 description 1
235000001510 limonene Nutrition 0.000 description 1
229940087305 limonene Drugs 0.000 description 1
229930007744 linalool Natural products 0.000 description 1
UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
239000012263 liquid product Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
159000000003 magnesium salts Chemical class 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
239000001630 malic acid Substances 0.000 description 1
235000011090 malic acid Nutrition 0.000 description 1
239000000594 mannitol Substances 0.000 description 1
235000010355 mannitol Nutrition 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000001098 melissa officinalis l. leaf oil Substances 0.000 description 1
108010003855 mesentericopeptidase Proteins 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
RTWNYYOXLSILQN-UHFFFAOYSA-N methanediamine Chemical compound NCN RTWNYYOXLSILQN-UHFFFAOYSA-N 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
108010020132 microbial serine proteinases Proteins 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
229940111688 monobasic potassium phosphate Drugs 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
229910000403 monosodium phosphate Inorganic materials 0.000 description 1
235000019799 monosodium phosphate Nutrition 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
SXLLDUPXUVRMEE-UHFFFAOYSA-N nonanediperoxoic acid Chemical compound OOC(=O)CCCCCCCC(=O)OO SXLLDUPXUVRMEE-UHFFFAOYSA-N 0.000 description 1
229940055577 oleyl alcohol Drugs 0.000 description 1
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238000006384 oligomerization reaction Methods 0.000 description 1
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239000007800 oxidant agent Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
150000002923 oximes Chemical class 0.000 description 1
125000005429 oxyalkyl group Chemical group 0.000 description 1
239000002540 palm oil Substances 0.000 description 1
RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
239000008188 pellet Substances 0.000 description 1
XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 1
229960005382 phenolphthalein Drugs 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
229940067107 phenylethyl alcohol Drugs 0.000 description 1
QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
229960001553 phloroglucinol Drugs 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
150000003016 phosphoric acids Chemical class 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
239000004584 polyacrylic acid Substances 0.000 description 1
150000003109 potassium Chemical class 0.000 description 1
OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
229910052939 potassium sulfate Inorganic materials 0.000 description 1
235000011151 potassium sulphates Nutrition 0.000 description 1
WSHYKIAQCMIPTB-UHFFFAOYSA-M potassium;2-oxo-3-(3-oxo-1-phenylbutyl)chromen-4-olate Chemical compound [K+].[O-]C=1C2=CC=CC=C2OC(=O)C=1C(CC(=O)C)C1=CC=CC=C1 WSHYKIAQCMIPTB-UHFFFAOYSA-M 0.000 description 1
239000002243 precursor Substances 0.000 description 1
230000002028 premature Effects 0.000 description 1
150000003138 primary alcohols Chemical class 0.000 description 1
238000012545 processing Methods 0.000 description 1
POSICDHOUBKJKP-UHFFFAOYSA-N prop-2-enoxybenzene Chemical compound C=CCOC1=CC=CC=C1 POSICDHOUBKJKP-UHFFFAOYSA-N 0.000 description 1
235000018102 proteins Nutrition 0.000 description 1
102000004169 proteins and genes Human genes 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
229940079877 pyrogallol Drugs 0.000 description 1
230000002829 reductive effect Effects 0.000 description 1
230000011514 reflex Effects 0.000 description 1
229940100486 rice starch Drugs 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
239000010671 sandalwood oil Substances 0.000 description 1
239000002455 scale inhibitor Substances 0.000 description 1
239000002893 slag Substances 0.000 description 1
239000000344 soap Substances 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
150000003388 sodium compounds Chemical class 0.000 description 1
AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
235000019830 sodium polyphosphate Nutrition 0.000 description 1
229940048086 sodium pyrophosphate Drugs 0.000 description 1
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000013042 solid detergent Substances 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
238000004381 surface treatment Methods 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229950009390 symclosene Drugs 0.000 description 1
235000020357 syrup Nutrition 0.000 description 1
KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
150000003505 terpenes Chemical class 0.000 description 1
235000007586 terpenes Nutrition 0.000 description 1
229940116411 terpineol Drugs 0.000 description 1
RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 1
229960002622 triacetin Drugs 0.000 description 1
150000003918 triazines Chemical class 0.000 description 1
150000003852 triazoles Chemical class 0.000 description 1
229940062627 tribasic potassium phosphate Drugs 0.000 description 1
ZKWDCFPLNQTHSH-UHFFFAOYSA-N tribromoisocyanuric acid Chemical compound BrN1C(=O)N(Br)C(=O)N(Br)C1=O ZKWDCFPLNQTHSH-UHFFFAOYSA-N 0.000 description 1
150000004684 trihydrates Chemical class 0.000 description 1
235000019798 tripotassium phosphate Nutrition 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
239000010679 vetiver oil Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1
238000005303 weighing Methods 0.000 description 1
ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
150000003752 zinc compounds Chemical class 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0091—Dishwashing tablets
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0078—Multilayered tablets
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38672—Granulated or coated enzymes

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

CA002306383A 1999-04-23 2000-04-20 Pastilles de detergent pour lave-vaisselle a rendement ameliore Abandoned CA2306383A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19918458.5		1999-04-23
DE19918458A DE19918458A1 (de)	1999-04-23	1999-04-23	Leistungsgesteigerte Reinigungsmitteltabletten für das maschinelle Geschirrspülen

Publications (1)

Publication Number	Publication Date
CA2306383A1 true CA2306383A1 (fr)	2000-10-23

Family

ID=7905615

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002306383A Abandoned CA2306383A1 (fr)	1999-04-23	2000-04-20	Pastilles de detergent pour lave-vaisselle a rendement ameliore

Country Status (7)

Country	Link
EP (1)	EP1173538B1 (fr)
AR (1)	AR023554A1 (fr)
AT (1)	ATE275623T1 (fr)
AU (1)	AU4549900A (fr)
CA (1)	CA2306383A1 (fr)
DE (2)	DE19918458A1 (fr)
WO (1)	WO2000065021A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ATE303431T1 (de) *	2001-03-05	2005-09-15	Unilever Nv	Wasch- oder reinigungsmittel
DE10313457A1 (de) *	2003-03-25	2004-10-14	Henkel Kgaa	Wasch- oder Reinigungsmittel
DE10313458A1 (de) *	2003-03-25	2004-11-18	Henkel Kgaa	Wasch- oder Reinigungsmittel

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB8727135D0 (en) *	1987-11-19	1987-12-23	Unilever Plc	Machine dishwashing composition
US5133892A (en) *	1990-10-17	1992-07-28	Lever Brothers Company, Division Of Conopco, Inc.	Machine dishwashing detergent tablets
DE19851426A1 (de) *	1998-07-15	2000-01-20	Henkel Kgaa	Verfahren zur Herstellung mehrphasiger Wasch- und Reinigungsmittelformkörper

1999
- 1999-04-23 DE DE19918458A patent/DE19918458A1/de not_active Withdrawn
2000
- 2000-04-14 EP EP00926937A patent/EP1173538B1/fr not_active Expired - Lifetime
- 2000-04-14 AU AU45499/00A patent/AU4549900A/en not_active Abandoned
- 2000-04-14 WO PCT/EP2000/003387 patent/WO2000065021A1/fr not_active Ceased
- 2000-04-14 DE DE50007687T patent/DE50007687D1/de not_active Expired - Fee Related
- 2000-04-14 AT AT00926937T patent/ATE275623T1/de not_active IP Right Cessation
- 2000-04-19 AR ARP000101851A patent/AR023554A1/es unknown
- 2000-04-20 CA CA002306383A patent/CA2306383A1/fr not_active Abandoned

Also Published As

Publication number	Publication date
DE50007687D1 (de)	2004-10-14
EP1173538A1 (fr)	2002-01-23
EP1173538B1 (fr)	2004-09-08
DE19918458A1 (de)	2000-10-26
AR023554A1 (es)	2002-09-04
WO2000065021A1 (fr)	2000-11-02
AU4549900A (en)	2000-11-10
ATE275623T1 (de)	2004-09-15

Legal Events

Date	Code	Title	Description
2002-07-23	FZDE	Discontinued

Publication	Publication Date	Title
US6962898B2 (en)	2005-11-08	Machine dishwasher rinsing agent
US7205266B2 (en)	2007-04-17	Laundry or dishwasher detergent tablet having at least one cavity
US6462006B1 (en)	2002-10-08	Solid machine dishwashing detergent with phosphate and crystalline lamellar silicates
US20020010123A1 (en)	2002-01-24	Laundry detergents and cleaning products
JP2007534808A (ja)	2007-11-29	洗浄剤もしくは清浄化用生成物を製造する方法
US20040116319A1 (en)	2004-06-17	Dishwashing agent and method for production thereof
US20070203047A1 (en)	2007-08-30	Dishwasher Detergent
US20060122089A1 (en)	2006-06-08	Detergent or cleaning agent
US20060116309A1 (en)	2006-06-01	Detergent or cleaning agent
US20050225003A1 (en)	2005-10-13	Method for producing washing and cleaning agents in the form of filled moulded bodies II
CA2313875A1 (fr)	2001-01-14	Tablette de detergent remplie
EP0839906B1 (fr)	2004-01-14	Composition détergente
CA2327536A1 (fr)	2001-06-04	Materiau particulaire composite pour la liberation controlee d'un ingredient actif
CA2303578A1 (fr)	2000-09-30	Detersif pour lave-vaisselle renfermant un produit de rincage sous forme de particules
CA2306383A1 (fr)	2000-10-23	Pastilles de detergent pour lave-vaisselle a rendement ameliore
CA2303638A1 (fr)	2000-09-30	Pastilles de detersif a une ou plusieurs phases renfermant des activateurs de blanchiment particuliers
CA2306388A1 (fr)	2000-10-23	Detergents particulaires a rendement ameliore, pour lave-vaisselle
US20030166493A1 (en)	2003-09-04	Shaped bodies with subsequent addition of surfactants
CA2302141A1 (fr)	2000-09-25	Pastille contenant un adjuvant
US20090029897A1 (en)	2009-01-29	Detergent or Cleaning Agent
CA2307276A1 (fr)	2000-10-29	Comprimes effervescents renfermant des agents facilitant leur fabrication et un procede pour leur production
CA2324070A1 (fr)	2001-04-21	Pastilles de detergent ayant une meilleure resistance a l'abrasion
CA2304316A1 (fr)	2000-09-30	Pastilles de detersif renfermant des activateurs de blanchiment particuliers
CA2300494A1 (fr)	2000-09-11	Procede de granulation
CA2311173A1 (fr)	2000-12-10	Detergents pour lave-vaisselle contenant des phosphates speciaux