CA2306388A1 - Detergents particulaires a rendement ameliore, pour lave-vaisselle - Google Patents

Detergents particulaires a rendement ameliore, pour lave-vaisselle Download PDF

Info

Publication number: CA2306388A1
Authority: CA; Canada
Prior art keywords: weight; enzyme particles; enzyme; coating material; auxiliaries
Prior art date: 1999-04-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2306388

Other languages

English (en)

Inventor

Matthias Sunder

Thomas Holderbaum

Bernd Richter

Christian Nitsch

Juergen Haerer

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee

Henkel AG and Co KGaA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-04-23

Filing date

2000-04-20

Publication date

2000-10-23

2000-04-20 Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA

2000-10-23 Publication of CA2306388A1 publication Critical patent/CA2306388A1/fr

Status Abandoned legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title claims abstract description 118
102000004190 Enzymes Human genes 0.000 claims abstract description 173
108090000790 Enzymes Proteins 0.000 claims abstract description 173
239000002245 particle Substances 0.000 claims abstract description 123
239000011248 coating agent Substances 0.000 claims abstract description 70
238000000576 coating method Methods 0.000 claims abstract description 70
239000000463 material Substances 0.000 claims abstract description 69
239000012876 carrier material Substances 0.000 claims abstract description 53
239000007788 liquid Substances 0.000 claims abstract description 38
230000008018 melting Effects 0.000 claims abstract description 35
238000002844 melting Methods 0.000 claims abstract description 35
238000002360 preparation method Methods 0.000 claims abstract description 20
230000005923 long-lasting effect Effects 0.000 claims abstract description 5
108091005804 Peptidases Proteins 0.000 claims description 53
239000004365 Protease Substances 0.000 claims description 48
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 47
239000007844 bleaching agent Substances 0.000 claims description 37
238000000034 method Methods 0.000 claims description 36
239000000203 mixture Substances 0.000 claims description 35
102000013142 Amylases Human genes 0.000 claims description 34
108010065511 Amylases Proteins 0.000 claims description 34
239000013543 active substance Substances 0.000 claims description 30
235000019418 amylase Nutrition 0.000 claims description 30
239000002253 acid Substances 0.000 claims description 29
-1 siloxanes Chemical class 0.000 claims description 28
239000004382 Amylase Substances 0.000 claims description 25
239000000155 melt Substances 0.000 claims description 25
239000004615 ingredient Substances 0.000 claims description 22
229920001223 polyethylene glycol Polymers 0.000 claims description 22
239000006185 dispersion Substances 0.000 claims description 21
239000000126 substance Substances 0.000 claims description 20
239000002304 perfume Substances 0.000 claims description 19
150000007513 acids Chemical class 0.000 claims description 17
239000012190 activator Substances 0.000 claims description 16
238000007493 shaping process Methods 0.000 claims description 13
239000003795 chemical substances by application Substances 0.000 claims description 12
229920000642 polymer Polymers 0.000 claims description 12
238000005260 corrosion Methods 0.000 claims description 11
230000007797 corrosion Effects 0.000 claims description 11
239000000975 dye Substances 0.000 claims description 10
239000004094 surface-active agent Substances 0.000 claims description 10
239000003112 inhibitor Substances 0.000 claims description 9
229910019142 PO4 Inorganic materials 0.000 claims description 8
235000021317 phosphate Nutrition 0.000 claims description 8
150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 8
229920001451 polypropylene glycol Polymers 0.000 claims description 8
235000014113 dietary fatty acids Nutrition 0.000 claims description 7
238000004851 dishwashing Methods 0.000 claims description 7
239000000194 fatty acid Chemical class 0.000 claims description 7
229930195729 fatty acid Chemical class 0.000 claims description 7
150000002191 fatty alcohols Chemical class 0.000 claims description 6
239000003054 catalyst Substances 0.000 claims description 5
150000002148 esters Chemical class 0.000 claims description 5
150000004665 fatty acids Chemical class 0.000 claims description 5
238000004519 manufacturing process Methods 0.000 claims description 5
239000003995 emulsifying agent Substances 0.000 claims description 4
239000007787 solid Substances 0.000 claims description 4
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 3
150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
239000002270 dispersing agent Substances 0.000 claims description 3
238000001125 extrusion Methods 0.000 claims description 2
238000005469 granulation Methods 0.000 claims description 2
230000003179 granulation Effects 0.000 claims description 2
229920000223 polyglycerol Chemical class 0.000 claims description 2
238000007711 solidification Methods 0.000 claims description 2
230000008023 solidification Effects 0.000 claims description 2
150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
230000000694 effects Effects 0.000 abstract description 20
239000000654 additive Substances 0.000 abstract 1
229940088598 enzyme Drugs 0.000 description 108
235000019419 proteases Nutrition 0.000 description 41
239000000843 powder Substances 0.000 description 38
150000003839 salts Chemical class 0.000 description 23
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 23
108090001060 Lipase Proteins 0.000 description 21
102000004882 Lipase Human genes 0.000 description 21
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 20
239000004367 Lipase Substances 0.000 description 20
235000019421 lipase Nutrition 0.000 description 20
125000004432 carbon atom Chemical group C* 0.000 description 17
235000019832 sodium triphosphate Nutrition 0.000 description 17
235000019441 ethanol Nutrition 0.000 description 16
229940079919 digestives enzyme preparation Drugs 0.000 description 15
239000002736 nonionic surfactant Substances 0.000 description 14
239000000047 product Substances 0.000 description 14
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical class CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 13
229910052708 sodium Inorganic materials 0.000 description 13
238000004140 cleaning Methods 0.000 description 12
150000001875 compounds Chemical class 0.000 description 12
239000011734 sodium Substances 0.000 description 12
229920002245 Dextrose equivalent Polymers 0.000 description 11
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 11
239000003921 oil Substances 0.000 description 11
235000019198 oils Nutrition 0.000 description 11
239000010457 zeolite Substances 0.000 description 11
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
229910021536 Zeolite Inorganic materials 0.000 description 9
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 9
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 9
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 8
229920005646 polycarboxylate Polymers 0.000 description 8
150000004760 silicates Chemical class 0.000 description 8
239000000243 solution Substances 0.000 description 8
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 8
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
150000001298 alcohols Chemical class 0.000 description 7
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 7
239000011591 potassium Substances 0.000 description 7
229910052700 potassium Inorganic materials 0.000 description 7
239000004375 Dextrin Substances 0.000 description 6
229920001353 Dextrin Polymers 0.000 description 6
102000035195 Peptidases Human genes 0.000 description 6
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 6
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
125000000217 alkyl group Chemical group 0.000 description 6
229940025131 amylases Drugs 0.000 description 6
235000019425 dextrin Nutrition 0.000 description 6
230000002366 lipolytic effect Effects 0.000 description 6
229910052748 manganese Inorganic materials 0.000 description 6
239000011572 manganese Substances 0.000 description 6
235000011007 phosphoric acid Nutrition 0.000 description 6
239000001488 sodium phosphate Substances 0.000 description 6
239000002689 soil Substances 0.000 description 6
239000001226 triphosphate Substances 0.000 description 6
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
150000001868 cobalt Chemical class 0.000 description 5
229910017052 cobalt Inorganic materials 0.000 description 5
239000010941 cobalt Substances 0.000 description 5
229920001577 copolymer Polymers 0.000 description 5
BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 5
239000000178 monomer Substances 0.000 description 5
235000013772 propylene glycol Nutrition 0.000 description 5
229910052723 transition metal Inorganic materials 0.000 description 5
ZGZHWIAQICBGKN-UHFFFAOYSA-N 1-nonanoylpyrrolidine-2,5-dione Chemical compound CCCCCCCCC(=O)N1C(=O)CCC1=O ZGZHWIAQICBGKN-UHFFFAOYSA-N 0.000 description 4
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 4
235000008733 Citrus aurantifolia Nutrition 0.000 description 4
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 4
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 4
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
235000011941 Tilia x europaea Nutrition 0.000 description 4
UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
229910000147 aluminium phosphate Inorganic materials 0.000 description 4
150000001408 amides Chemical class 0.000 description 4
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 4
238000013270 controlled release Methods 0.000 description 4
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238000009826 distribution Methods 0.000 description 4
230000007062 hydrolysis Effects 0.000 description 4
238000006460 hydrolysis reaction Methods 0.000 description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
239000004571 lime Substances 0.000 description 4
235000013372 meat Nutrition 0.000 description 4
235000019796 monopotassium phosphate Nutrition 0.000 description 4
229910000402 monopotassium phosphate Inorganic materials 0.000 description 4
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 4
BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 4
RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 3
101000740449 Bacillus subtilis (strain 168) Biotin/lipoyl attachment protein Proteins 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
102000004157 Hydrolases Human genes 0.000 description 3
108090000604 Hydrolases Proteins 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
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KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
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239000001361 adipic acid Substances 0.000 description 3
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150000001720 carbohydrates Chemical class 0.000 description 3
150000004691 decahydrates Chemical class 0.000 description 3
238000000354 decomposition reaction Methods 0.000 description 3
XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 3
235000011180 diphosphates Nutrition 0.000 description 3
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239000000839 emulsion Substances 0.000 description 3
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230000001603 reducing effect Effects 0.000 description 3
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FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 3
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229910000406 trisodium phosphate Inorganic materials 0.000 description 3
229910052720 vanadium Inorganic materials 0.000 description 3
YPFNIPKMNMDDDB-UHFFFAOYSA-K 2-[2-[bis(carboxylatomethyl)amino]ethyl-(2-hydroxyethyl)amino]acetate;iron(3+) Chemical compound [Fe+3].OCCN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O YPFNIPKMNMDDDB-UHFFFAOYSA-K 0.000 description 2
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230000001580 bacterial effect Effects 0.000 description 1
239000011324 bead Substances 0.000 description 1
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
239000012964 benzotriazole Substances 0.000 description 1
150000001565 benzotriazoles Chemical class 0.000 description 1
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
229940007550 benzyl acetate Drugs 0.000 description 1
SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 1
OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
229920002988 biodegradable polymer Polymers 0.000 description 1
239000004621 biodegradable polymer Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
108010064866 biozym Proteins 0.000 description 1
238000004061 bleaching Methods 0.000 description 1
FZJUFJKVIYFBSY-UHFFFAOYSA-N bourgeonal Chemical compound CC(C)(C)C1=CC=C(CCC=O)C=C1 FZJUFJKVIYFBSY-UHFFFAOYSA-N 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
WQZQEUCNSUNRRW-UHFFFAOYSA-N butanedioic acid propane-1,2,3-triol Chemical class OCC(O)CO.OC(=O)CCC(O)=O.OC(=O)CCC(O)=O WQZQEUCNSUNRRW-UHFFFAOYSA-N 0.000 description 1
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
235000014633 carbohydrates Nutrition 0.000 description 1
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
150000001732 carboxylic acid derivatives Chemical group 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
235000017803 cinnamon Nutrition 0.000 description 1
239000001507 cistus ladaniferus l. oil Substances 0.000 description 1
229940043350 citral Drugs 0.000 description 1
229930003633 citronellal Natural products 0.000 description 1
235000000983 citronellal Nutrition 0.000 description 1
235000000484 citronellol Nutrition 0.000 description 1
239000001524 citrus aurantium oil Substances 0.000 description 1
235000020971 citrus fruits Nutrition 0.000 description 1
239000010634 clove oil Substances 0.000 description 1
239000003245 coal Substances 0.000 description 1
QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical class [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 1
239000003240 coconut oil Substances 0.000 description 1
235000019864 coconut oil Nutrition 0.000 description 1
238000013329 compounding Methods 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
150000001879 copper Chemical class 0.000 description 1
239000010949 copper Substances 0.000 description 1
108010005400 cutinase Proteins 0.000 description 1
229940019836 cyclamen aldehyde Drugs 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
UNWDCFHEVIWFCW-UHFFFAOYSA-N decanediperoxoic acid Chemical compound OOC(=O)CCCCCCCCC(=O)OO UNWDCFHEVIWFCW-UHFFFAOYSA-N 0.000 description 1
SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
239000008121 dextrose Substances 0.000 description 1
239000012933 diacyl peroxide Substances 0.000 description 1
229940111685 dibasic potassium phosphate Drugs 0.000 description 1
229940095104 dimethyl benzyl carbinyl acetate Drugs 0.000 description 1
XQRLCLUYWUNEEH-UHFFFAOYSA-L diphosphonate(2-) Chemical compound [O-]P(=O)OP([O-])=O XQRLCLUYWUNEEH-UHFFFAOYSA-L 0.000 description 1
229910000396 dipotassium phosphate Inorganic materials 0.000 description 1
GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 description 1
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
BRDYCNFHFWUBCZ-UHFFFAOYSA-N dodecaneperoxoic acid Chemical compound CCCCCCCCCCCC(=O)OO BRDYCNFHFWUBCZ-UHFFFAOYSA-N 0.000 description 1
235000013345 egg yolk Nutrition 0.000 description 1
238000002003 electron diffraction Methods 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000007046 ethoxylation reaction Methods 0.000 description 1
229940071087 ethylenediamine disuccinate Drugs 0.000 description 1
229960002217 eugenol Drugs 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
239000004744 fabric Substances 0.000 description 1
235000019197 fats Nutrition 0.000 description 1
239000001148 ferula galbaniflua oil terpeneless Substances 0.000 description 1
238000005187 foaming Methods 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
229930182830 galactose Natural products 0.000 description 1
229940074391 gallic acid Drugs 0.000 description 1
235000004515 gallic acid Nutrition 0.000 description 1
WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
229940113087 geraniol Drugs 0.000 description 1
235000012209 glucono delta-lactone Nutrition 0.000 description 1
229960003681 gluconolactone Drugs 0.000 description 1
239000001087 glyceryl triacetate Substances 0.000 description 1
235000013773 glyceryl triacetate Nutrition 0.000 description 1
VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 description 1
125000001046 glycoluril group Chemical group [H]C12N(*)C(=O)N(*)C1([H])N(*)C(=O)N2* 0.000 description 1
229930182470 glycoside Natural products 0.000 description 1
125000003147 glycosyl group Chemical group 0.000 description 1
229940015043 glyoxal Drugs 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
108010002430 hemicellulase Proteins 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 1
PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 description 1
150000001469 hydantoins Chemical class 0.000 description 1
125000002768 hydroxyalkyl group Chemical group 0.000 description 1
WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 description 1
150000002460 imidazoles Chemical class 0.000 description 1
150000003949 imides Chemical class 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
150000002484 inorganic compounds Chemical class 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000002563 ionic surfactant Substances 0.000 description 1
239000001851 juniperus communis l. berry oil Substances 0.000 description 1
150000003951 lactams Chemical class 0.000 description 1
150000002596 lactones Chemical group 0.000 description 1
239000003446 ligand Substances 0.000 description 1
SDQFDHOLCGWZPU-UHFFFAOYSA-N lilial Chemical compound O=CC(C)CC1=CC=C(C(C)(C)C)C=C1 SDQFDHOLCGWZPU-UHFFFAOYSA-N 0.000 description 1
235000001510 limonene Nutrition 0.000 description 1
229940087305 limonene Drugs 0.000 description 1
229930007744 linalool Natural products 0.000 description 1
UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
159000000003 magnesium salts Chemical class 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
239000001630 malic acid Substances 0.000 description 1
235000011090 malic acid Nutrition 0.000 description 1
239000000594 mannitol Substances 0.000 description 1
235000010355 mannitol Nutrition 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000001098 melissa officinalis l. leaf oil Substances 0.000 description 1
239000000289 melt material Substances 0.000 description 1
108010003855 mesentericopeptidase Proteins 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
RTWNYYOXLSILQN-UHFFFAOYSA-N methanediamine Chemical compound NCN RTWNYYOXLSILQN-UHFFFAOYSA-N 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
108010020132 microbial serine proteinases Proteins 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
229940111688 monobasic potassium phosphate Drugs 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
229910000403 monosodium phosphate Inorganic materials 0.000 description 1
235000019799 monosodium phosphate Nutrition 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
SXLLDUPXUVRMEE-UHFFFAOYSA-N nonanediperoxoic acid Chemical compound OOC(=O)CCCCCCCC(=O)OO SXLLDUPXUVRMEE-UHFFFAOYSA-N 0.000 description 1
229940055577 oleyl alcohol Drugs 0.000 description 1
XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
238000006384 oligomerization reaction Methods 0.000 description 1
229920001542 oligosaccharide Polymers 0.000 description 1
150000002482 oligosaccharides Chemical class 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
150000002923 oximes Chemical class 0.000 description 1
125000005429 oxyalkyl group Chemical group 0.000 description 1
239000002540 palm oil Substances 0.000 description 1
RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
239000008188 pellet Substances 0.000 description 1
XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 1
229960005382 phenolphthalein Drugs 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
229940067107 phenylethyl alcohol Drugs 0.000 description 1
QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
229960001553 phloroglucinol Drugs 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
150000003016 phosphoric acids Chemical class 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
239000004584 polyacrylic acid Substances 0.000 description 1
150000003109 potassium Chemical class 0.000 description 1
OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
229910052939 potassium sulfate Inorganic materials 0.000 description 1
235000011151 potassium sulphates Nutrition 0.000 description 1
WSHYKIAQCMIPTB-UHFFFAOYSA-M potassium;2-oxo-3-(3-oxo-1-phenylbutyl)chromen-4-olate Chemical compound [K+].[O-]C=1C2=CC=CC=C2OC(=O)C=1C(CC(=O)C)C1=CC=CC=C1 WSHYKIAQCMIPTB-UHFFFAOYSA-M 0.000 description 1
239000002243 precursor Substances 0.000 description 1
230000002028 premature Effects 0.000 description 1
150000003138 primary alcohols Chemical class 0.000 description 1
238000012545 processing Methods 0.000 description 1
POSICDHOUBKJKP-UHFFFAOYSA-N prop-2-enoxybenzene Chemical compound C=CCOC1=CC=CC=C1 POSICDHOUBKJKP-UHFFFAOYSA-N 0.000 description 1
235000018102 proteins Nutrition 0.000 description 1
102000004169 proteins and genes Human genes 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
229940079877 pyrogallol Drugs 0.000 description 1
230000002829 reductive effect Effects 0.000 description 1
230000011514 reflex Effects 0.000 description 1
229940100486 rice starch Drugs 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
239000010671 sandalwood oil Substances 0.000 description 1
239000002455 scale inhibitor Substances 0.000 description 1
239000002893 slag Substances 0.000 description 1
239000000344 soap Substances 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
150000003388 sodium compounds Chemical class 0.000 description 1
AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
235000019830 sodium polyphosphate Nutrition 0.000 description 1
229940048086 sodium pyrophosphate Drugs 0.000 description 1
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000013042 solid detergent Substances 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
239000012798 spherical particle Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
238000004381 surface treatment Methods 0.000 description 1
229950009390 symclosene Drugs 0.000 description 1
235000020357 syrup Nutrition 0.000 description 1
KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
150000003505 terpenes Chemical class 0.000 description 1
235000007586 terpenes Nutrition 0.000 description 1
229940116411 terpineol Drugs 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 1
229960002622 triacetin Drugs 0.000 description 1
150000003918 triazines Chemical class 0.000 description 1
150000003852 triazoles Chemical class 0.000 description 1
229940062627 tribasic potassium phosphate Drugs 0.000 description 1
ZKWDCFPLNQTHSH-UHFFFAOYSA-N tribromoisocyanuric acid Chemical compound BrN1C(=O)N(Br)C(=O)N(Br)C1=O ZKWDCFPLNQTHSH-UHFFFAOYSA-N 0.000 description 1
150000004684 trihydrates Chemical class 0.000 description 1
235000019798 tripotassium phosphate Nutrition 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
239000010679 vetiver oil Substances 0.000 description 1
ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
150000003752 zinc compounds Chemical class 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

CA 2306388 1999-04-23 2000-04-20 Detergents particulaires a rendement ameliore, pour lave-vaisselle Abandoned CA2306388A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE1999118457 DE19918457A1 (de)	1999-04-23	1999-04-23	Leistungsgesteigerte teilchenförmige Reinigungsmittel für das maschinelle Geschirrspülen
DE19918457.7		1999-04-23

Publications (1)

Publication Number	Publication Date
CA2306388A1 true CA2306388A1 (fr)	2000-10-23

Family

ID=7905614

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2306388 Abandoned CA2306388A1 (fr)	1999-04-23	2000-04-20	Detergents particulaires a rendement ameliore, pour lave-vaisselle

Country Status (5)

Country	Link
AR (1)	AR023550A1 (fr)
AU (1)	AU4549800A (fr)
CA (1)	CA2306388A1 (fr)
DE (1)	DE19918457A1 (fr)
WO (1)	WO2000065016A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE102006036895A1 (de) *	2006-08-04	2008-02-07	Henkel Kgaa	Teilchenförmiges Wasch- oder Reinigunsmittel
DE102014212643A1 (de) *	2014-06-30	2015-12-31	Henkel Ag & Co. Kgaa	Flüssiges Reinigungsmittel enthaltend flüssige und feste Enzymformulierungen

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3823090A (en) *	1968-06-20	1974-07-09	Nippon Oils & Fats Co Ltd	Production of powdered detergent
DE19727073A1 (de) *	1997-06-25	1999-01-07	Henkel Kgaa	Umhüllte Reinigungsmittelkomponente
DE19817964A1 (de) *	1998-04-22	1999-10-28	Henkel Kgaa	Umhüllte Reinigungsmittelkomponente
DE19851426A1 (de) *	1998-07-15	2000-01-20	Henkel Kgaa	Verfahren zur Herstellung mehrphasiger Wasch- und Reinigungsmittelformkörper

1999
- 1999-04-23 DE DE1999118457 patent/DE19918457A1/de not_active Withdrawn
2000
- 2000-04-14 WO PCT/EP2000/003384 patent/WO2000065016A1/fr not_active Ceased
- 2000-04-14 AU AU45498/00A patent/AU4549800A/en not_active Abandoned
- 2000-04-19 AR ARP000101847 patent/AR023550A1/es unknown
- 2000-04-20 CA CA 2306388 patent/CA2306388A1/fr not_active Abandoned

Also Published As

Publication number	Publication date
AU4549800A (en)	2000-11-10
WO2000065016A1 (fr)	2000-11-02
DE19918457A1 (de)	2000-10-26
AR023550A1 (es)	2002-09-04

Legal Events

Date	Code	Title	Description
2002-07-23	FZDE	Dead

Publication	Publication Date	Title
US6962898B2 (en)	2005-11-08	Machine dishwasher rinsing agent
US6462006B1 (en)	2002-10-08	Solid machine dishwashing detergent with phosphate and crystalline lamellar silicates
US5854189A (en)	1998-12-29	Process for the production of break-resistant, storable multifunctional detergent tablets
EP2380961B1 (fr)	2018-05-23	Composition de détergent
US20020010123A1 (en)	2002-01-24	Laundry detergents and cleaning products
US20070203047A1 (en)	2007-08-30	Dishwasher Detergent
US20060122089A1 (en)	2006-06-08	Detergent or cleaning agent
US20060116309A1 (en)	2006-06-01	Detergent or cleaning agent
US11220660B2 (en)	2022-01-11	Portion bag having bleach activator/complexing agent compound
EP2931864B1 (fr)	2016-08-17	Composition de nettoyage
CA2312157A1 (fr)	2000-12-25	Emballage-portion de substance active
US20020013252A1 (en)	2002-01-31	Particulate composite material for the controlled release of an active ingredient
EP2584028B1 (fr)	2017-05-10	Particule
CA2303578A1 (fr)	2000-09-30	Detersif pour lave-vaisselle renfermant un produit de rincage sous forme de particules
JP2007528921A (ja)	2007-10-18	漂白活性剤およびその製造方法
CA2306388A1 (fr)	2000-10-23	Detergents particulaires a rendement ameliore, pour lave-vaisselle
US7041632B2 (en)	2006-05-09	Perfumed detergent shaped bodies
CA2306383A1 (fr)	2000-10-23	Pastilles de detergent pour lave-vaisselle a rendement ameliore
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