CA2353614A1 - Composition de thermoplastique et de caoutchouc - Google Patents
Composition de thermoplastique et de caoutchouc Download PDFInfo
- Publication number
- CA2353614A1 CA2353614A1 CA002353614A CA2353614A CA2353614A1 CA 2353614 A1 CA2353614 A1 CA 2353614A1 CA 002353614 A CA002353614 A CA 002353614A CA 2353614 A CA2353614 A CA 2353614A CA 2353614 A1 CA2353614 A1 CA 2353614A1
- Authority
- CA
- Canada
- Prior art keywords
- rubber matrix
- rubber
- natural rubber
- matrix
- compatabiliser
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims description 79
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims description 11
- 229920001971 elastomer Polymers 0.000 claims abstract description 218
- 239000005060 rubber Substances 0.000 claims abstract description 217
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 131
- 229920001194 natural rubber Polymers 0.000 claims abstract description 131
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 129
- 239000011159 matrix material Substances 0.000 claims abstract description 121
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 115
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 115
- 239000002131 composite material Substances 0.000 claims abstract description 85
- 229920000642 polymer Polymers 0.000 claims abstract description 33
- 229920000098 polyolefin Polymers 0.000 claims abstract description 32
- 229920000728 polyester Polymers 0.000 claims abstract description 27
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 26
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- 239000004952 Polyamide Substances 0.000 claims abstract description 23
- 229920002647 polyamide Polymers 0.000 claims abstract description 23
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 19
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 18
- 229920003192 poly(bis maleimide) Polymers 0.000 claims abstract description 18
- XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 claims abstract description 16
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- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 13
- 150000002367 halogens Chemical class 0.000 claims abstract description 13
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- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims abstract description 11
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- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 7
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims abstract description 7
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- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 7
- 125000002560 nitrile group Chemical group 0.000 claims abstract description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract 4
- 229920003023 plastic Polymers 0.000 claims description 64
- 239000004033 plastic Substances 0.000 claims description 64
- IOVCWXUNBOPUCH-UHFFFAOYSA-M nitrite group Chemical group N(=O)[O-] IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 52
- 238000002156 mixing Methods 0.000 claims description 43
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- 239000000654 additive Substances 0.000 claims description 8
- 238000013329 compounding Methods 0.000 claims description 8
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 8
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 8
- 229920001155 polypropylene Polymers 0.000 claims description 8
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 7
- 238000004073 vulcanization Methods 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 6
- 150000008064 anhydrides Chemical class 0.000 claims description 6
- TVEOPXGOFVVUHS-UHFFFAOYSA-N buta-1,3-diene;nitrous acid Chemical compound ON=O.C=CC=C TVEOPXGOFVVUHS-UHFFFAOYSA-N 0.000 claims description 6
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 6
- 229920003049 isoprene rubber Polymers 0.000 claims description 6
- 229920002857 polybutadiene Polymers 0.000 claims description 6
- 239000004800 polyvinyl chloride Substances 0.000 claims description 6
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000004606 Fillers/Extenders Substances 0.000 claims description 5
- 239000005662 Paraffin oil Substances 0.000 claims description 5
- 239000005062 Polybutadiene Substances 0.000 claims description 5
- 239000004793 Polystyrene Substances 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims description 5
- 229920002223 polystyrene Polymers 0.000 claims description 5
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 4
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 239000005864 Sulphur Substances 0.000 claims description 4
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims description 4
- 229920003244 diene elastomer Polymers 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 108090000623 proteins and genes Proteins 0.000 claims description 4
- 102000004169 proteins and genes Human genes 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 229920006345 thermoplastic polyamide Polymers 0.000 claims description 4
- KCQMAAHONSBGTH-UHFFFAOYSA-N 2-methylbuta-1,3-diene nitrous acid Chemical group C=CC(C)=C.N(=O)O KCQMAAHONSBGTH-UHFFFAOYSA-N 0.000 claims description 3
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 3
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 3
- 229920000299 Nylon 12 Polymers 0.000 claims description 3
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims description 3
- 239000004904 UV filter Substances 0.000 claims description 3
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- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000000748 compression moulding Methods 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 3
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 238000011065 in-situ storage Methods 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 3
- 230000003019 stabilising effect Effects 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- HGDULKQRXBSKHL-UHFFFAOYSA-N 1,1-bis(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(CC)(OC(=O)C(C)=C)OC(=O)C(C)=C HGDULKQRXBSKHL-UHFFFAOYSA-N 0.000 claims description 2
- ZBSGNEYIENETRW-UHFFFAOYSA-N 2,3-bis(hydroxymethyl)phenol Chemical compound OCC1=CC=CC(O)=C1CO ZBSGNEYIENETRW-UHFFFAOYSA-N 0.000 claims description 2
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 claims description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 2
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 claims description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 2
- 229920000800 acrylic rubber Polymers 0.000 claims description 2
- 229910000085 borane Inorganic materials 0.000 claims description 2
- 229920002301 cellulose acetate Polymers 0.000 claims description 2
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- 239000007859 condensation product Substances 0.000 claims description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 2
- 150000001993 dienes Chemical class 0.000 claims description 2
- 150000002009 diols Chemical class 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
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- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
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- 229910052623 talc Inorganic materials 0.000 description 2
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 2
- NOBYOEQUFMGXBP-UHFFFAOYSA-N (4-tert-butylcyclohexyl) (4-tert-butylcyclohexyl)oxycarbonyloxy carbonate Chemical compound C1CC(C(C)(C)C)CCC1OC(=O)OOC(=O)OC1CCC(C(C)(C)C)CC1 NOBYOEQUFMGXBP-UHFFFAOYSA-N 0.000 description 1
- UDYXMTORTDACTG-UHFFFAOYSA-N 1,1,3-tributylthiourea Chemical compound CCCCNC(=S)N(CCCC)CCCC UDYXMTORTDACTG-UHFFFAOYSA-N 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 1
- VETPHHXZEJAYOB-UHFFFAOYSA-N 1-n,4-n-dinaphthalen-2-ylbenzene-1,4-diamine Chemical compound C1=CC=CC2=CC(NC=3C=CC(NC=4C=C5C=CC=CC5=CC=4)=CC=3)=CC=C21 VETPHHXZEJAYOB-UHFFFAOYSA-N 0.000 description 1
- KNCZPLRYWQLPQT-UHFFFAOYSA-N 1-tert-butyl-2-propan-2-ylbenzene Chemical compound CC(C)C1=CC=CC=C1C(C)(C)C KNCZPLRYWQLPQT-UHFFFAOYSA-N 0.000 description 1
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 1
- ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- BYLSIPUARIZAHZ-UHFFFAOYSA-N 2,4,6-tris(1-phenylethyl)phenol Chemical compound C=1C(C(C)C=2C=CC=CC=2)=C(O)C(C(C)C=2C=CC=CC=2)=CC=1C(C)C1=CC=CC=C1 BYLSIPUARIZAHZ-UHFFFAOYSA-N 0.000 description 1
- CFCWODSWPMKRNT-UHFFFAOYSA-N 6-oxo-6-propoxyhexanoic acid Chemical compound CCCOC(=O)CCCCC(O)=O CFCWODSWPMKRNT-UHFFFAOYSA-N 0.000 description 1
- 241000531891 Alburnus alburnus Species 0.000 description 1
- 229920001824 Barex® Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004610 Internal Lubricant Substances 0.000 description 1
- 229920002633 Kraton (polymer) Polymers 0.000 description 1
- 229920006063 Lamide® Polymers 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 101100208473 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) lcm-2 gene Proteins 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000012317 TBTU Substances 0.000 description 1
- 241000375392 Tana Species 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- SULYZTDOTDBHFD-UHFFFAOYSA-N buta-1,3-diene;methyl prop-2-enoate;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N.COC(=O)C=C SULYZTDOTDBHFD-UHFFFAOYSA-N 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229920005669 high impact polystyrene Polymers 0.000 description 1
- 229920006178 high molecular weight high density polyethylene Polymers 0.000 description 1
- 239000004797 high-impact polystyrene Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000012858 resilient material Substances 0.000 description 1
- 238000013040 rubber vulcanization Methods 0.000 description 1
- 238000000646 scanning calorimetry Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/04—Oxidation
- C08C19/06—Epoxidation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Cette invention se rapporte à une matrice de caoutchouc contenant: (a) 10 à 90 % (en volume) de caoutchouc naturel, (b) un ou plusieurs agents de compatibilisation choisis dans un groupe de polymères contenant: (i) soit un groupe nitrile, (ii) soit un halogène, (iii) soit un groupe acétate, (iv) soit un époxyde, (v) soit un styrène, (vi) soit un acrylate, et (c) un ou plusieurs seconds agents de compatibilisation qui constituent des copromoteurs interfaciaux choisis dans un groupe contenant: (i) soit un acétate de polyvinyle, (ii) soit de l'éthylène-acétate de vinyle, (iii) soit un polyacrylonitrile ou une résine à forte teneur en nitrile, (iv) soit un acrylamide ou un polyacrylamide, (v) soit une résine phénolique, (vi) soit un polymère d'acrylate, (vii) soit un polymère halogéné, (viii) soit un anhydride maléique ou un anhydride polymaléique, (ix) soit un bismaléimide. Cette matrice de caoutchouc peut être mélangée à un ou plusieurs thermoplastiques choisis dans un groupe comprenant: (i) soit des polyuréthanes, (ii) soit des polyesters, (iii) soit des polyamides, (iv) soit des acrylates, (v) soit de l'acrylonitrile-butadiène-styrène, (vi) soit des polyoléfines, (vii) soit des esters cellulosiques, afin de former un composite de caoutchouc et de thermoplastiques.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPP7505 | 1998-12-04 | ||
| AUPP7505A AUPP750598A0 (en) | 1998-12-04 | 1998-12-04 | Thermoplastic rubber composition |
| PCT/AU1999/001074 WO2000034383A1 (fr) | 1998-12-04 | 1999-12-03 | Composition de thermoplastique et de caoutchouc |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2353614A1 true CA2353614A1 (fr) | 2000-06-15 |
Family
ID=3811715
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002353614A Abandoned CA2353614A1 (fr) | 1998-12-04 | 1999-12-03 | Composition de thermoplastique et de caoutchouc |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP1171524A1 (fr) |
| CN (1) | CN1337979A (fr) |
| AU (1) | AUPP750598A0 (fr) |
| BR (1) | BR9915932A (fr) |
| CA (1) | CA2353614A1 (fr) |
| ID (1) | ID29940A (fr) |
| MX (1) | MXPA01005606A (fr) |
| WO (1) | WO2000034383A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020014759A1 (fr) * | 2018-07-16 | 2020-01-23 | Nasser Sidnei Winston | Composition polymère de caoutchouc injectable à froid |
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6656582B2 (en) | 2000-06-16 | 2003-12-02 | Tokai Rubber Industries, Ltd. | Rubber product with metallic structure and method of producing the same |
| JP3799968B2 (ja) | 2000-06-16 | 2006-07-19 | 東海ゴム工業株式会社 | 耐久性に優れた防振ゴムの製造方法 |
| WO2003018078A1 (fr) * | 2001-08-31 | 2003-03-06 | Mihai Curtescu | Compositions durcissables contenant des hydrogels polymeres et procede de fabrication d'articles techniques et de produits de consommation courante a partir de ces compositions |
| CN100467533C (zh) * | 2003-09-29 | 2009-03-11 | 日本瑞翁株式会社 | 热塑性弹性体组合物和成形体 |
| WO2006121141A1 (fr) * | 2005-05-10 | 2006-11-16 | The Yokohama Rubber Co., Ltd. | Composition elastomere themoplastique |
| CN100392038C (zh) * | 2006-03-13 | 2008-06-04 | 株洲市宏大高分子材料厂 | 改性tpu耐磨密封材料及其制备方法与用途 |
| US20070238833A1 (en) * | 2006-04-10 | 2007-10-11 | Christian Leboeuf | Polyamide composition comprising a modifier |
| US7897662B2 (en) * | 2007-09-20 | 2011-03-01 | The Goodyear Tire & Rubber Company | Tire with component containing cellulose |
| US9068063B2 (en) | 2010-06-29 | 2015-06-30 | Eastman Chemical Company | Cellulose ester/elastomer compositions |
| US9273195B2 (en) | 2010-06-29 | 2016-03-01 | Eastman Chemical Company | Tires comprising cellulose ester/elastomer compositions |
| US9708474B2 (en) | 2011-12-07 | 2017-07-18 | Eastman Chemical Company | Cellulose esters in pneumatic tires |
| ES2718374T3 (es) * | 2013-11-20 | 2019-07-01 | Basf Se | Artículos celulares de poliuretano termoplástico que comprenden una composición de poliuretano termoplástico y un copolímero de estireno-acrílico con funcionalidad epoxi |
| CN103657014B (zh) * | 2013-12-09 | 2016-02-17 | 成都动能健身服务有限公司 | 一种健身球及其制造方法 |
| US20160075866A1 (en) * | 2014-09-12 | 2016-03-17 | Teknor Apex Company | Compositions for capstock applications |
| CN104373501B (zh) * | 2014-10-08 | 2016-02-03 | 安徽奥丰汽车配件有限公司 | 汽车减振器托盘 |
| FR3033573B1 (fr) * | 2015-03-10 | 2018-03-23 | Arkema France | Composition et pre-impregne thermoplastiques, materiau composite a base dudit pre-impregne et utilisations dudit materiau composite |
| DE102015215327B4 (de) * | 2015-08-11 | 2025-08-21 | Continental Reifen Deutschland Gmbh | Vulkanisat, Verwendung dessen und Fahrzeugreifen |
| CN105131492A (zh) * | 2015-08-18 | 2015-12-09 | 合肥市再德高分子材料有限公司 | 一种复合改性高性能天然橡胶材料 |
| CN105131206A (zh) * | 2015-09-23 | 2015-12-09 | 江苏蓝湾生物科技有限公司 | 一种医用除臭橡胶材料的制备方法 |
| US10077343B2 (en) | 2016-01-21 | 2018-09-18 | Eastman Chemical Company | Process to produce elastomeric compositions comprising cellulose ester additives |
| CN105860020A (zh) * | 2016-04-19 | 2016-08-17 | 滁州环球聚氨酯科技有限公司 | 一种高强度疏水阻燃聚氨酯电缆外护套 |
| CN105968491A (zh) * | 2016-05-20 | 2016-09-28 | 温州泓呈祥科技有限公司 | 一种包含阻燃复配剂ldhs/sba-15的电缆绝缘材料及用途 |
| CN106009449B (zh) * | 2016-05-25 | 2020-06-02 | 北京化工大学 | 一种耐高温耐油热塑性硫化胶及其制备方法 |
| KR101862058B1 (ko) | 2016-10-06 | 2018-06-29 | 넥쌍 | 에틸렌 비닐 아세테이트 공중합체 및 니트릴 고무를 포함하는 가교된 조성물 |
| FR3060592A1 (fr) * | 2016-12-15 | 2018-06-22 | Compagnie Generale Des Etablissements Michelin | Pneumatique comportant une composition de caoutchouc comprenant un polymere porteur d'un groupement diene conjugue reticule par un dienophile |
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| EP3456763A1 (fr) * | 2017-09-19 | 2019-03-20 | Feng Tay Enterprises Co., Ltd. | Composition de vulcanisat thermoplastique |
| US10364336B2 (en) | 2017-09-22 | 2019-07-30 | Feng Tay Enterprises Co., Ltd. | Thermoplastic vulcanizate composition, method of forming the same and product thereof |
| CN107674269A (zh) * | 2017-11-06 | 2018-02-09 | 张永宏 | 静电吸附膜生产模具表面材料的制备方法 |
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| CN117167484B (zh) * | 2023-08-31 | 2024-03-19 | 广东东方管业有限公司 | 一种动态密封橡胶圈及其制备方法和应用 |
| CN117402418B (zh) * | 2023-12-11 | 2024-02-27 | 河北润驰流体科技有限公司 | 一种高耐磨橡胶软管及其制备方法 |
| CN119752170A (zh) * | 2025-03-06 | 2025-04-04 | 河南工学院 | 一种耐温型热塑性弹性体电缆绝缘料及其制备方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1473241A (en) * | 1974-01-25 | 1977-05-11 | Dunlop Ltd | 3-dimensional patterned articles of moulded rubber |
| US4515851A (en) * | 1982-10-25 | 1985-05-07 | Becton, Dickinson And Company | Slip resistant surfaces |
| JPS60162628A (ja) * | 1984-02-02 | 1985-08-24 | Chiriyuu Takaron Kk | 複合プラスチツクシ−トの製造方法 |
| JPS61188138A (ja) * | 1985-02-15 | 1986-08-21 | 株式会社ブリヂストン | 防食構造体 |
| JPS63152471A (ja) * | 1986-12-13 | 1988-06-24 | 池田物産株式会社 | カ−ペツトの製造方法 |
| JPH0813907B2 (ja) * | 1987-11-27 | 1996-02-14 | 日本合成ゴム株式会社 | 防振・防音・遮音材用ゴム組成物 |
| JP2518012B2 (ja) * | 1988-05-25 | 1996-07-24 | 日本合成ゴム株式会社 | 積層体 |
| JP3056316B2 (ja) * | 1992-02-06 | 2000-06-26 | 積水化学工業株式会社 | 積層用シート及びその製造方法 |
| US5641562A (en) * | 1994-12-30 | 1997-06-24 | Kimberly-Clark Worldwide Inc. | Water-shrinkable film |
-
1998
- 1998-12-04 AU AUPP7505A patent/AUPP750598A0/en not_active Abandoned
-
1999
- 1999-12-03 BR BR9915932-5A patent/BR9915932A/pt not_active Application Discontinuation
- 1999-12-03 MX MXPA01005606A patent/MXPA01005606A/es unknown
- 1999-12-03 CA CA002353614A patent/CA2353614A1/fr not_active Abandoned
- 1999-12-03 EP EP99960711A patent/EP1171524A1/fr not_active Withdrawn
- 1999-12-03 WO PCT/AU1999/001074 patent/WO2000034383A1/fr not_active Ceased
- 1999-12-03 CN CN99816015A patent/CN1337979A/zh active Pending
- 1999-12-03 ID IDW00200101188A patent/ID29940A/id unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020014759A1 (fr) * | 2018-07-16 | 2020-01-23 | Nasser Sidnei Winston | Composition polymère de caoutchouc injectable à froid |
Also Published As
| Publication number | Publication date |
|---|---|
| AUPP750598A0 (en) | 1999-01-07 |
| CN1337979A (zh) | 2002-02-27 |
| MXPA01005606A (es) | 2003-07-14 |
| EP1171524A1 (fr) | 2002-01-16 |
| BR9915932A (pt) | 2001-12-18 |
| ID29940A (id) | 2001-10-25 |
| WO2000034383A1 (fr) | 2000-06-15 |
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