CA2389081C - Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres - Google Patents

Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres Download PDF

Info

Publication number: CA2389081C
Authority: CA; Canada
Prior art keywords: acid; percarboxylic; composition; solution; composition according
Prior art date: 1999-10-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002389081A

Other languages

English (en)

French (fr)

Other versions

CA2389081A1 (fr

Inventor

Jean-Pierre Schirmann

Christian Pralus

Claude Lion

Louis Da Conceicao

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Arkema France SA

Original Assignee

Atofina SA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-10-29

Filing date

2000-10-25

Publication date

2009-12-22

2000-10-25 Application filed by Atofina SA filed Critical Atofina SA

2001-05-03 Publication of CA2389081A1 publication Critical patent/CA2389081A1/fr

2009-12-22 Application granted granted Critical

2009-12-22 Publication of CA2389081C publication Critical patent/CA2389081C/fr

2020-10-25 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims description 42
238000000034 method Methods 0.000 title claims description 9
239000003344 environmental pollutant Substances 0.000 title description 6
231100000719 pollutant Toxicity 0.000 title description 5
SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 claims abstract description 28
239000002253 acid Substances 0.000 claims abstract description 26
239000000463 material Substances 0.000 claims abstract description 22
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 12
150000007513 acids Chemical class 0.000 claims abstract description 8
150000001875 compounds Chemical class 0.000 claims abstract description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
239000003054 catalyst Substances 0.000 claims abstract description 7
150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 4
239000003960 organic solvent Substances 0.000 claims abstract description 4
239000012429 reaction media Substances 0.000 claims abstract description 4
239000000243 solution Substances 0.000 claims description 33
CZPZWMPYEINMCF-UHFFFAOYSA-N propaneperoxoic acid Chemical compound CCC(=O)OO CZPZWMPYEINMCF-UHFFFAOYSA-N 0.000 claims description 17
239000004094 surface-active agent Substances 0.000 claims description 16
239000007864 aqueous solution Substances 0.000 claims description 15
238000005202 decontamination Methods 0.000 claims description 13
230000003588 decontaminative effect Effects 0.000 claims description 13
150000004965 peroxy acids Chemical class 0.000 claims description 11
FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 claims description 10
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 8
150000002903 organophosphorus compounds Chemical class 0.000 claims description 8
125000001453 quaternary ammonium group Chemical group 0.000 claims description 7
WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 claims description 6
239000002904 solvent Substances 0.000 claims description 6
-1 (hydroxy-2 ethyl) bromide ammonium Chemical compound 0.000 claims description 5
239000003153 chemical reaction reagent Substances 0.000 claims description 5
150000002898 organic sulfur compounds Chemical class 0.000 claims description 5
125000000217 alkyl group Chemical group 0.000 claims description 4
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 4
239000004327 boric acid Substances 0.000 claims description 4
239000003093 cationic surfactant Substances 0.000 claims description 4
229910052736 halogen Inorganic materials 0.000 claims description 4
235000019260 propionic acid Nutrition 0.000 claims description 4
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 4
150000002978 peroxides Chemical class 0.000 claims description 3
239000003381 stabilizer Substances 0.000 claims description 3
125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 2
125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 claims description 2
DCGMMDKJUJDGRR-UHFFFAOYSA-N azane 1-bromooctane Chemical compound N.CCCCCCCCBr DCGMMDKJUJDGRR-UHFFFAOYSA-N 0.000 claims description 2
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
125000002091 cationic group Chemical group 0.000 claims description 2
TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical group [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 claims description 2
238000005507 spraying Methods 0.000 claims description 2
238000005406 washing Methods 0.000 claims description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
238000004821 distillation Methods 0.000 claims 2
125000005843 halogen group Chemical group 0.000 claims 2
229910052739 hydrogen Inorganic materials 0.000 claims 2
239000001257 hydrogen Substances 0.000 claims 2
239000000376 reactant Substances 0.000 claims 2
238000010533 azeotropic distillation Methods 0.000 abstract description 2
231100000167 toxic agent Toxicity 0.000 description 11
239000003440 toxic substance Substances 0.000 description 10
230000006378 damage Effects 0.000 description 8
230000015556 catabolic process Effects 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 7
238000006731 degradation reaction Methods 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
WYMSBXTXOHUIGT-UHFFFAOYSA-N paraoxon Chemical compound CCOP(=O)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 WYMSBXTXOHUIGT-UHFFFAOYSA-N 0.000 description 6
229960004623 paraoxon Drugs 0.000 description 6
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 5
239000003795 chemical substances by application Substances 0.000 description 5
ZONYXWQDUYMKFB-UHFFFAOYSA-N flavanone Chemical compound O1C2=CC=CC=C2C(=O)CC1C1=CC=CC=C1 ZONYXWQDUYMKFB-UHFFFAOYSA-N 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 3
229910019142 PO4 Inorganic materials 0.000 description 3
229910052760 oxygen Inorganic materials 0.000 description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
239000010452 phosphate Substances 0.000 description 3
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
UUZYBYIOAZTMGC-UHFFFAOYSA-M benzyl(trimethyl)azanium;bromide Chemical compound [Br-].C[N+](C)(C)CC1=CC=CC=C1 UUZYBYIOAZTMGC-UHFFFAOYSA-M 0.000 description 2
WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 2
238000004587 chromatography analysis Methods 0.000 description 2
150000002367 halogens Chemical group 0.000 description 2
239000002917 insecticide Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
230000000269 nucleophilic effect Effects 0.000 description 2
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
239000000575 pesticide Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
150000003457 sulfones Chemical class 0.000 description 2
231100000331 toxic Toxicity 0.000 description 2
230000002588 toxic effect Effects 0.000 description 2
XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
FMPKLEQNIRQNON-UHFFFAOYSA-N N.OCCBr Chemical compound N.OCCBr FMPKLEQNIRQNON-UHFFFAOYSA-N 0.000 description 1
AXPZGGIIXCYPQK-UHFFFAOYSA-N OS(=O)P(O)(O)=O Chemical class OS(=O)P(O)(O)=O AXPZGGIIXCYPQK-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000013543 active substance Substances 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
239000000872 buffer Substances 0.000 description 1
RLGQACBPNDBWTB-UHFFFAOYSA-N cetyltrimethylammonium ion Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)C RLGQACBPNDBWTB-UHFFFAOYSA-N 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
230000008021 deposition Effects 0.000 description 1
FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
GGDGVDMTSZPOIB-UHFFFAOYSA-M hexadecyl-(2-hydroxyethyl)-dimethylazanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)CCO GGDGVDMTSZPOIB-UHFFFAOYSA-M 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
229910001234 light alloy Inorganic materials 0.000 description 1
USSBDBZGEDUBHE-UHFFFAOYSA-L magnesium;2-oxidooxycarbonylbenzoate Chemical compound [Mg+2].[O-]OC(=O)C1=CC=CC=C1C([O-])=O USSBDBZGEDUBHE-UHFFFAOYSA-L 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
238000012544 monitoring process Methods 0.000 description 1
231100000252 nontoxic Toxicity 0.000 description 1
230000003000 nontoxic effect Effects 0.000 description 1
IOQPZZOEVPZRBK-UHFFFAOYSA-O octylazanium Chemical compound CCCCCCCC[NH3+] IOQPZZOEVPZRBK-UHFFFAOYSA-O 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
150000004967 organic peroxy acids Chemical class 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
LCCNCVORNKJIRZ-UHFFFAOYSA-N parathion Chemical compound CCOP(=S)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 LCCNCVORNKJIRZ-UHFFFAOYSA-N 0.000 description 1
239000012071 phase Substances 0.000 description 1
FUWGSUOSJRCEIV-UHFFFAOYSA-N phosphonothioic O,O-acid Chemical compound OP(O)=S FUWGSUOSJRCEIV-UHFFFAOYSA-N 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
239000001103 potassium chloride Substances 0.000 description 1
235000011164 potassium chloride Nutrition 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
150000003242 quaternary ammonium salts Chemical class 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
238000005070 sampling Methods 0.000 description 1
238000002791 soaking Methods 0.000 description 1
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
235000019345 sodium thiosulphate Nutrition 0.000 description 1
238000004611 spectroscopical analysis Methods 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
150000003464 sulfur compounds Chemical class 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
238000003466 welding Methods 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/38—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by oxidation; by combustion
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/02—Chemical warfare substances, e.g. cholinesterase inhibitors
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/04—Pesticides, e.g. insecticides, herbicides, fungicides or nematocides
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/22—Organic substances containing halogen
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/26—Organic substances containing nitrogen or phosphorus
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/28—Organic substances containing oxygen, sulfur, selenium or tellurium, i.e. chalcogen

Landscapes

Business, Economics & Management (AREA)
General Health & Medical Sciences (AREA)
Toxicology (AREA)
Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Emergency Management (AREA)
Detergent Compositions (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Processing Of Solid Wastes (AREA)
Compounds Of Unknown Constitution (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CA002389081A 1999-10-29 2000-10-25 Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres Expired - Fee Related CA2389081C (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
FR99/13571		1999-10-29
FR9913571A FR2800291B1 (fr)	1999-10-29	1999-10-29	Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres
PCT/FR2000/002967 WO2001030452A1 (fr)	1999-10-29	2000-10-25	Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres

Publications (2)

Publication Number	Publication Date
CA2389081A1 CA2389081A1 (fr)	2001-05-03
CA2389081C true CA2389081C (fr)	2009-12-22

Family

ID=9551526

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002389081A Expired - Fee Related CA2389081C (fr)	1999-10-29	2000-10-25	Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres

Country Status (7)

Country	Link
EP (1)	EP1237628B1 (de)
AT (1)	ATE395106T1 (de)
AU (1)	AU1034401A (de)
CA (1)	CA2389081C (de)
DE (1)	DE60038896D1 (de)
FR (1)	FR2800291B1 (de)
WO (1)	WO2001030452A1 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2004080543A2 (en)	2003-03-12	2004-09-23	Queen's University At Kingston	Method of decomposing organophosphorus compounds
FR2930732B1 (fr) *	2008-04-30	2010-05-14	Arkema France	Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres
JP6423365B2 (ja)	2013-12-20	2018-11-14	三井化学株式会社	半芳香族ポリアミド樹脂組成物およびその成型品

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2464947A1 (fr) *	1979-09-07	1981-03-20	Ugine Kuhlmann	Procede de fabrication d'acides percarboxyliques
FR2519634B1 (fr) *	1982-01-13	1986-09-12	Ugine Kuhlmann	Perfectionnement aux procedes de synthese des acides percaboxyliques
FR2651133B1 (fr) *	1989-08-22	1992-10-23	France Etat Armement	Procede de decontamination par des solutions de peracides de materiaux contamines par des agents toxiques.
FR2676368B1 (fr) *	1991-05-15	1994-10-28	France Etat Armement	Composition de decontamination a base de monoperoxyphtalate de magnesium et procede de decontamination de materiaux contamines par des agents toxiques utilisant cette composition.
GB9213059D0 (en) *	1992-06-19	1992-08-05	Laporte Esd Ltd	Compositions
FR2761080B1 (fr) *	1997-03-21	2002-07-19	Quadrimex	Composition a base de peracides pour le nettoyage, la desinfection et la decontamination de surfaces souillees par des agents toxiques

1999
- 1999-10-29 FR FR9913571A patent/FR2800291B1/fr not_active Expired - Fee Related
2000
- 2000-10-25 DE DE60038896T patent/DE60038896D1/de not_active Expired - Lifetime
- 2000-10-25 EP EP00971499A patent/EP1237628B1/de not_active Expired - Lifetime
- 2000-10-25 AU AU10344/01A patent/AU1034401A/en not_active Abandoned
- 2000-10-25 AT AT00971499T patent/ATE395106T1/de not_active IP Right Cessation
- 2000-10-25 CA CA002389081A patent/CA2389081C/fr not_active Expired - Fee Related
- 2000-10-25 WO PCT/FR2000/002967 patent/WO2001030452A1/fr not_active Ceased

Also Published As

Publication number	Publication date
DE60038896D1 (de)	2008-06-26
EP1237628A1 (de)	2002-09-11
AU1034401A (en)	2001-05-08
FR2800291B1 (fr)	2004-07-09
ATE395106T1 (de)	2008-05-15
FR2800291A1 (fr)	2001-05-04
CA2389081A1 (fr)	2001-05-03
WO2001030452A1 (fr)	2001-05-03
EP1237628B1 (de)	2008-05-14

Legal Events

Date	Code	Title	Description
2005-07-14	EEER	Examination request
2015-12-07	MKLA	Lapsed	Effective date: 20151026

Publication	Publication Date	Title
EP2271410B1 (de)	2011-10-12	Zusammensetzung und verfahren zur zersetzung von organophosphor- und/oder organoschwefel-schadstoffen
AU693563B2 (en)	1998-07-02	Peroxygen compositions
WO1988000795A1 (fr)	1988-02-11	Composition antiseptique incorporant des huiles essentielles
EP3676423A1 (de)	2020-07-08	Metallkorrosionshemmer
CA2389081C (fr)	2009-12-22	Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres
FR2766724A1 (fr)	1999-02-05	Compositions decontaminantes non agressives
CA2725293C (fr)	2017-03-07	Solution aqueuse decontaminante et moussante
FR2676368A1 (fr)	1992-11-20	Composition de decontamination a base de monoperoxyphtalate de magnesium et procede de decontamination de materiaux contamines par des agents toxiques utilisant cette composition.
EP0848628B1 (de)	2003-04-23	Verfahren zur dekontaminierung, mit einer persäure enthaltenden zusammensetzung, von materialien die durch toxische mittel kontaminiert sind
FR2761080A1 (fr)	1998-09-25	Composition a base de peracides pour le nettoyage, la desinfection et la decontamination de surfaces souillees par des agents toxiques
FR2766725A1 (fr)	1999-02-05	Compositions decontaminantes stabilisees
EP0906773A1 (de)	1999-04-07	Dekontaminierungmittel
US7910537B1 (en)	2011-03-22	Decontamination of chemical warfare agents using benign household chemicals
FR2689021A1 (fr)	1993-10-01	Procédé de décontamination de substrats contaminés par des agents toxiques à l'aide d'une composition à base de persulfate.
Cassagne et al.	2001	Reactions of N, N-diisopropyl-2-aminoethylp-fluorobenzene thiosulfonate with oxidising agents
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