CA2419332C - Article composite - Google Patents

Article composite Download PDF

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Publication number
CA2419332C
CA2419332C CA 2419332 CA2419332A CA2419332C CA 2419332 C CA2419332 C CA 2419332C CA 2419332 CA2419332 CA 2419332 CA 2419332 A CA2419332 A CA 2419332A CA 2419332 C CA2419332 C CA 2419332C
Authority
CA
Canada
Prior art keywords
curable composition
monomer
composite article
set forth
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA 2419332
Other languages
English (en)
Other versions
CA2419332A1 (fr
Inventor
Calvin T. Peeler
Micheal C. May
Theresa A. Howard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Corp
Original Assignee
BASF Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Corp filed Critical BASF Corp
Publication of CA2419332A1 publication Critical patent/CA2419332A1/fr
Application granted granted Critical
Publication of CA2419332C publication Critical patent/CA2419332C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/088—Removal of water or carbon dioxide from the reaction mixture or reaction components
    • C08G18/0885—Removal of water or carbon dioxide from the reaction mixture or reaction components using additives, e.g. absorbing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628—Nonplanar uniform thickness material
    • Y10T428/24736—Ornamental design or indicia
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
    • Y10T428/31576—Ester monomer type [polyvinylacetate, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Laminated Bodies (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

Un article composite comporte une couche d'acrylique, une couche durcie aux UV formée à partir d'une formulation polymérisable aux UV, ainsi qu'une couche dorsale de polyuréthane. Une méthode permettant de fabriquer l'article composite consiste à appliquer la formulation polymérisable aux UV sur la couche d'acrylique de manière à ce que la formulation se trouve entre la couche d'acrylique et la couche dorsale de polyuréthane pour renforcer l'adhésion entre ces deux dernières. La formulation polymérisable aux UV renferme au moins un monomère qui est soit un monomère de méthacrylate insaturé en éthylène, soit un monomère d'acrylate insaturé en éthylène, soit les deux. Le monomère possède un groupement hydroxyle. Il est compatible avec la couche d'acrylique, et le groupement fonctionnel hydroxyle du monomère réagit avec un polyisocyanate de la couche dorsale de polyuréthane. La formulation polymérisable aux UV contient aussi un initiateur de polymérisation qui réagit avec le monomère. Lorsque la formulation polymérisable aux UV est exposée à un rayonnement ultraviolet, l'initiateur de polymérisation permet à la formulation de se lier à la couche d'acrylique.
CA 2419332 2002-04-05 2003-02-17 Article composite Expired - Fee Related CA2419332C (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/116,972 US7087306B2 (en) 2002-04-05 2002-04-05 Composite article
US10/116,972 2002-04-05

Publications (2)

Publication Number Publication Date
CA2419332A1 CA2419332A1 (fr) 2003-10-05
CA2419332C true CA2419332C (fr) 2008-08-05

Family

ID=28674106

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2419332 Expired - Fee Related CA2419332C (fr) 2002-04-05 2003-02-17 Article composite

Country Status (3)

Country Link
US (2) US7087306B2 (fr)
CA (1) CA2419332C (fr)
MX (1) MXPA03001516A (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7117148B2 (en) 2002-04-05 2006-10-03 Microsoft Corporation Method of noise reduction using correction vectors based on dynamic aspects of speech and noise normalization
US7087306B2 (en) * 2002-04-05 2006-08-08 Basf Corporation Composite article
US20050282016A1 (en) * 2004-06-22 2005-12-22 Joseph Ogonowski Polyester-polyurethane composite structure
US7223026B1 (en) * 2005-01-18 2007-05-29 Alliance Fiber Optic Products, Inc. Solder-free packaging for integrated fiber optics device
US20070266662A1 (en) * 2006-05-16 2007-11-22 Arc Technologies, Llc Simulated stone or brick column and method of fabricating same
CL2007003131A1 (es) * 2006-11-01 2008-07-04 Lucite Int Inc Metodo para fabricar un articulo que comprende formular composicion acrilica que tiene un agente de transferencia con grupo que reacciona con isocianato y luego unir a una composicion que contiene isocianato; articulo; metodo que mejora la eficiencia
US8792008B2 (en) * 2011-09-08 2014-07-29 Maxlinear, Inc. Method and apparatus for spectrum monitoring

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3925283A (en) * 1970-06-29 1975-12-09 Continental Tapes Inc Polyurethane pressure-sensitive adhesive products and processes
US3743617A (en) * 1971-05-17 1973-07-03 D Kest Urethane base pressure sensitive adhesive
DE3014161A1 (de) 1980-04-12 1981-10-22 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von polyurethan-formkoerpern
US5118728A (en) 1988-10-24 1992-06-02 Texaco Chemical Company Spray polyurea elastomers using chopped glass roving
BE1002899A6 (nl) 1989-03-03 1991-07-16 Recticel Werkwijze voor het vervaardigen van voorwerpen met een elastomeren buitenwand en een kunststofschuim kern.
US5171818A (en) 1990-03-23 1992-12-15 Bruce Wilson Sprayable aliphatic polyurea-polyurethane coating compositions and methods
US5639546A (en) * 1991-09-03 1997-06-17 Minnesota Mining And Manufacturing Company Coated article having improved adhesion to organic coatings
DE4203217A1 (de) 1992-02-05 1993-08-12 Bayer Ag Verfahren zur herstellung von beschichtungen
US5232996A (en) * 1992-05-07 1993-08-03 Lord Corporation Acrylate-terminated polyurethane/epoxy adhesives
US5215796A (en) 1992-05-22 1993-06-01 Aqua Glass Corporation Multilayer polymeric shaped article
US5543225A (en) 1992-05-22 1996-08-06 Aqua Glass Corporation Multilayer fiber reinforced polymeric shaped article
US5595701A (en) 1995-05-12 1997-01-21 The Goodyear Tire & Rubber Company Process for making a polyurea backed product with a polyurethane skin
JP3769075B2 (ja) * 1996-07-08 2006-04-19 Ｊｓｒ株式会社 放射線硬化性樹脂組成物
US6026760A (en) 1998-01-09 2000-02-22 Innovative Coatings Corporation Floatation device
US6092343A (en) 1998-07-16 2000-07-25 Therma-Tru Corporation Compression molded door assembly
US7087306B2 (en) * 2002-04-05 2006-08-08 Basf Corporation Composite article

Also Published As

Publication number Publication date
US7691481B2 (en) 2010-04-06
US7087306B2 (en) 2006-08-08
US20060014025A1 (en) 2006-01-19
US20030190481A1 (en) 2003-10-09
MXPA03001516A (es) 2003-10-09
CA2419332A1 (fr) 2003-10-05

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Effective date: 20210217