CA2444460C - Feuille d'acier plaquee a chaud avec du zinc, ayant d'excellentes proprietes de conservation de son brillant et methode pour la produire - Google Patents
Feuille d'acier plaquee a chaud avec du zinc, ayant d'excellentes proprietes de conservation de son brillant et methode pour la produire Download PDFInfo
- Publication number
- CA2444460C CA2444460C CA002444460A CA2444460A CA2444460C CA 2444460 C CA2444460 C CA 2444460C CA 002444460 A CA002444460 A CA 002444460A CA 2444460 A CA2444460 A CA 2444460A CA 2444460 C CA2444460 C CA 2444460C
- Authority
- CA
- Canada
- Prior art keywords
- dip
- hot
- plating layer
- luster
- plating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 112
- 239000010959 steel Substances 0.000 title claims abstract description 112
- 238000000034 method Methods 0.000 title claims description 20
- 238000007747 plating Methods 0.000 claims abstract description 148
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 126
- 239000010410 layer Substances 0.000 claims abstract description 83
- 238000001816 cooling Methods 0.000 claims abstract description 57
- 239000002932 luster Substances 0.000 claims abstract description 40
- 230000015556 catabolic process Effects 0.000 claims abstract description 38
- 238000006731 degradation reaction Methods 0.000 claims abstract description 38
- 230000001590 oxidative effect Effects 0.000 claims abstract description 33
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 18
- 239000002344 surface layer Substances 0.000 claims abstract description 13
- 238000010791 quenching Methods 0.000 claims description 61
- 230000000171 quenching effect Effects 0.000 claims description 61
- 239000013078 crystal Substances 0.000 claims description 33
- 230000005496 eutectics Effects 0.000 claims description 20
- 230000000694 effects Effects 0.000 claims description 14
- 239000011159 matrix material Substances 0.000 claims description 14
- 229910052710 silicon Inorganic materials 0.000 claims description 14
- 229910052727 yttrium Inorganic materials 0.000 claims description 14
- 229910052726 zirconium Inorganic materials 0.000 claims description 14
- 239000012535 impurity Substances 0.000 claims description 13
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 10
- 238000007711 solidification Methods 0.000 abstract description 11
- 230000008023 solidification Effects 0.000 abstract description 11
- 229910018134 Al-Mg Inorganic materials 0.000 abstract description 7
- 229910018467 Al—Mg Inorganic materials 0.000 abstract description 7
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 239000011701 zinc Substances 0.000 description 58
- 239000011777 magnesium Substances 0.000 description 55
- 238000000576 coating method Methods 0.000 description 14
- 238000004519 manufacturing process Methods 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 11
- 238000005260 corrosion Methods 0.000 description 11
- 230000007797 corrosion Effects 0.000 description 11
- 239000003595 mist Substances 0.000 description 10
- 230000007423 decrease Effects 0.000 description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 8
- 229910052804 chromium Inorganic materials 0.000 description 8
- 239000011651 chromium Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000012530 fluid Substances 0.000 description 7
- 230000001276 controlling effect Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 230000002401 inhibitory effect Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 238000004532 chromating Methods 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 230000003405 preventing effect Effects 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 229910000521 B alloy Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 238000007739 conversion coating Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- RXCBCUJUGULOGC-UHFFFAOYSA-H dipotassium;tetrafluorotitanium;difluoride Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[K+].[K+].[Ti+4] RXCBCUJUGULOGC-UHFFFAOYSA-H 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 229960002261 magnesium phosphate Drugs 0.000 description 1
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 1
- 239000004137 magnesium phosphate Substances 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C18/00—Alloys based on zinc
- C22C18/04—Alloys based on zinc with aluminium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/14—Removing excess of molten coatings; Controlling or regulating the coating thickness
- C23C2/24—Removing excess of molten coatings; Controlling or regulating the coating thickness using magnetic or electric fields
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coating With Molten Metal (AREA)
- Laminated Bodies (AREA)
Abstract
Cette invention se rapporte à un procédé qui permet de produire une tôle d'acier par immersion à chaud à base de Zn-Al-Mg ayant un excellent maintien du brillant et qui consiste à cet effet à régler de façon appropriée, dans une étape consistant à refroidir le produit avec de l'eau après coagulation d'une couche de plaquage, la température à laquelle la couche de plaquage est mise en contact avec l'écoulement d'eau, c'est-à-dire à régler de façon appropriée dans cette étape la température du matériau à plaquer, lorsque celui-ci est mis en contact avec l'écoulement d'eau, et à utiliser de préférence un bain de plaquage dans lequel est incorporée une petite quantité d'un élément hautement oxydable. Ce procédé permet de stabiliser les états d'oxydation des éléments Al et Mg présents dans la partie de surface de la couche de plaquage, ce qui entraîne la suppression de la détérioration du brillant de surface d'une telle tôle d'acier à immersion à chaud à base de Zn-Al-Mg.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2002/007485 WO2004009863A1 (fr) | 2002-07-24 | 2002-07-24 | Tole d'acier galvanisee par immersion a chaud a base de zinc, ayant un excellent maintien du brillant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2444460A1 CA2444460A1 (fr) | 2004-01-24 |
| CA2444460C true CA2444460C (fr) | 2008-01-22 |
Family
ID=30490773
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002444460A Expired - Lifetime CA2444460C (fr) | 2002-07-24 | 2002-07-24 | Feuille d'acier plaquee a chaud avec du zinc, ayant d'excellentes proprietes de conservation de son brillant et methode pour la produire |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP1524326B1 (fr) |
| CN (1) | CN1276990C (fr) |
| AT (1) | ATE484605T1 (fr) |
| AU (1) | AU2002323927B2 (fr) |
| CA (1) | CA2444460C (fr) |
| DE (1) | DE60238001D1 (fr) |
| ES (1) | ES2350921T3 (fr) |
| NZ (1) | NZ528816A (fr) |
| WO (1) | WO2004009863A1 (fr) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100666693B1 (ko) | 2004-11-23 | 2007-01-11 | 삼성전자주식회사 | 모놀리식 듀플렉서 |
| CN102330043B (zh) * | 2011-08-03 | 2013-03-13 | 马鞍山鼎泰稀土新材料股份有限公司 | 一种钢丝热浸镀稀土锌合金及热浸镀方法 |
| CN103361588B (zh) * | 2012-03-30 | 2016-04-06 | 鞍钢股份有限公司 | 低铝低镁系锌铝镁镀层钢板生产方法及其镀层钢板 |
| WO2013160566A1 (fr) | 2012-04-25 | 2013-10-31 | Arcelormittal Investigacion Y Desarrollo, S.L. | Procédé de réalisation d'une tôle à revêtements znalmg huilés et tôle correspondante. |
| JP5097305B1 (ja) | 2012-04-25 | 2012-12-12 | 日新製鋼株式会社 | 黒色めっき鋼板 |
| AU2013332257A1 (en) | 2012-10-17 | 2015-04-09 | Bluescope Steel Limited | Method of producing metal-coated steel strip |
| TWI653362B (zh) | 2012-10-17 | 2019-03-11 | 澳大利亞商布魯史寇普鋼鐵有限公司 | 金屬被覆鋼帶的製造方法 |
| ES2807509T3 (es) | 2012-10-18 | 2021-02-23 | Bluescope Steel Ltd | Procedimiento de producción de banda de acero revestida con metal |
| EP2824213A1 (fr) * | 2013-07-12 | 2015-01-14 | Voestalpine Stahl GmbH | Procédé d'amélioration de l'adhérence sur une tôle d'acier dotée d'un revêtement de protection |
| US10138538B2 (en) | 2013-12-20 | 2018-11-27 | Arcelormittal | ZnAlMg-coated metal sheet produced by optimized wiping |
| KR101767788B1 (ko) * | 2015-12-24 | 2017-08-14 | 주식회사 포스코 | 내마찰성 및 내백청성이 우수한 도금 강재 및 그 제조방법 |
| TW201804008A (zh) * | 2016-03-31 | 2018-02-01 | 日新製鋼股份有限公司 | 熔融鋁鍍鋼線的製造方法 |
| KR102031466B1 (ko) | 2017-12-26 | 2019-10-11 | 주식회사 포스코 | 표면품질 및 내식성이 우수한 아연합금도금강재 및 그 제조방법 |
| CN111989420B (zh) * | 2018-05-16 | 2022-11-08 | 日本制铁株式会社 | 镀覆钢材 |
| CN108977695B (zh) * | 2018-09-30 | 2020-12-01 | 济南大学 | 一种含钛和锑的热浸镀锌铝镁合金及其制备方法 |
| TWI691615B (zh) * | 2019-04-10 | 2020-04-21 | 中國鋼鐵股份有限公司 | 鍍鋅鋼片及其製造方法 |
| CN113025937B (zh) * | 2021-02-07 | 2023-03-17 | 首钢集团有限公司 | 一种热浸镀锌钢板及其制备方法 |
| CN112941417A (zh) * | 2021-03-03 | 2021-06-11 | 靖江新舟合金材料有限公司 | 一种合金镀层钢板及其生产方法 |
| CN113512691B (zh) * | 2021-03-11 | 2023-05-09 | 首钢集团有限公司 | 一种锌铝镁镀层钢及其制备方法 |
| CN113604765B (zh) * | 2021-10-09 | 2022-01-04 | 天津市弘仁金属材料有限公司 | 一种钢带热浸镀方法 |
| CN115261703A (zh) * | 2022-06-08 | 2022-11-01 | 日照宝华新材料有限公司 | 一种高耐蚀光伏支架用钢板的制造方法 |
| CN117265328A (zh) * | 2023-09-25 | 2023-12-22 | 常州大学 | 一种含B和Zr的SuperDyma合金及其制备方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2754126B2 (ja) * | 1992-11-26 | 1998-05-20 | 新日本製鐵株式会社 | 外観、耐経時黒変性、耐食性に優れる溶融Ｚｎ−Ａｌめっき鋼板 |
| JP3148542B2 (ja) * | 1995-01-11 | 2001-03-19 | 新日本製鐵株式会社 | 耐眩性の優れた溶融Ｚｎめっき鋼板 |
| JPH10265926A (ja) * | 1997-03-25 | 1998-10-06 | Nisshin Steel Co Ltd | 耐食性および表面外観の良好な溶融Ｚｎ−Ａｌ−Ｍｇめっき鋼帯の製造法 |
| JP3888784B2 (ja) * | 1998-09-21 | 2007-03-07 | 日新製鋼株式会社 | 溶融Ｚｎ基めっき鋼板のエッジしわ防止法 |
| JP2001295015A (ja) * | 2000-02-09 | 2001-10-26 | Nisshin Steel Co Ltd | 高Ａｌ含有溶融Ｚｎ−Ａｌ−Ｍｇ系めっき鋼板 |
| JP2002080952A (ja) * | 2000-06-29 | 2002-03-22 | Nisshin Steel Co Ltd | 耐食性に優れた住宅用資材および住宅部材 |
| JP2002146504A (ja) * | 2000-08-22 | 2002-05-22 | Nisshin Steel Co Ltd | 耐食性及び耐ホイスカ性に優れた電装用資材及び電装用部材 |
| JP2002187234A (ja) * | 2000-12-21 | 2002-07-02 | Nisshin Steel Co Ltd | 耐食性に優れた非クロム系塗装鋼板 |
| JP4064634B2 (ja) * | 2001-02-02 | 2008-03-19 | 日新製鋼株式会社 | 光沢保持性の良好な溶融Ｚｎ基めっき鋼板およびその製造法 |
-
2002
- 2002-07-24 ES ES02755638T patent/ES2350921T3/es not_active Expired - Lifetime
- 2002-07-24 CA CA002444460A patent/CA2444460C/fr not_active Expired - Lifetime
- 2002-07-24 NZ NZ528816A patent/NZ528816A/en not_active IP Right Cessation
- 2002-07-24 AU AU2002323927A patent/AU2002323927B2/en not_active Expired
- 2002-07-24 WO PCT/JP2002/007485 patent/WO2004009863A1/fr not_active Ceased
- 2002-07-24 EP EP02755638A patent/EP1524326B1/fr not_active Expired - Lifetime
- 2002-07-24 AT AT02755638T patent/ATE484605T1/de not_active IP Right Cessation
- 2002-07-24 CN CN02808369.5A patent/CN1276990C/zh not_active Expired - Lifetime
- 2002-07-24 DE DE60238001T patent/DE60238001D1/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004009863A1 (fr) | 2004-01-29 |
| ATE484605T1 (de) | 2010-10-15 |
| EP1524326B1 (fr) | 2010-10-13 |
| ES2350921T3 (es) | 2011-01-28 |
| DE60238001D1 (de) | 2010-11-25 |
| CN1503853A (zh) | 2004-06-09 |
| CA2444460A1 (fr) | 2004-01-24 |
| EP1524326A4 (fr) | 2006-09-13 |
| NZ528816A (en) | 2005-10-28 |
| AU2002323927A1 (en) | 2004-02-09 |
| AU2002323927B2 (en) | 2005-08-25 |
| EP1524326A1 (fr) | 2005-04-20 |
| CN1276990C (zh) | 2006-09-27 |
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