CA2462612C - Adhesifs sans danger pour l'environnement destines au collage de caoutchouc vulcanise - Google Patents

Adhesifs sans danger pour l'environnement destines au collage de caoutchouc vulcanise Download PDF

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Publication number
CA2462612C
CA2462612C CA2462612A CA2462612A CA2462612C CA 2462612 C CA2462612 C CA 2462612C CA 2462612 A CA2462612 A CA 2462612A CA 2462612 A CA2462612 A CA 2462612A CA 2462612 C CA2462612 C CA 2462612C
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Canada
Prior art keywords
phr
parts
rubber
adhesive composition
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2462612A
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English (en)
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CA2462612A1 (fr
Inventor
Christian C. Green
Douglas H. Mowrey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lord Corp
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Lord Corp
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Filing date
Publication date
Priority claimed from US10/222,545 external-priority patent/US20040033374A1/en
Application filed by Lord Corp filed Critical Lord Corp
Publication of CA2462612A1 publication Critical patent/CA2462612A1/fr
Application granted granted Critical
Publication of CA2462612C publication Critical patent/CA2462612C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00—Compositions of rubber derivatives
    • C08L15/02—Rubber derivatives containing halogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/26—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers modified by chemical after-treatment
    • C09J123/28—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
    • C08L23/0892—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with monomers containing atoms other than carbon, hydrogen or oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/32—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur
    • C08L23/34—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur by chlorosulfonation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking
    • C08L2312/08—Crosslinking by silane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

L'invention a trait à des compositions d'adhésifs permettant de coller efficacement du caoutchouc à un métal, ne contenant pas plus d'environ 1000 ppm de plomb, et convenant particulièrement au collage d'élastomères vulcanisés à des substrats rigides, tels que le métal. Lesdits adhésifs sont avantageusement utilisés en combinaison avec des couches primaires et en tant qu'adhésifs à couche unique, et permettent d'obtenir des liaisons durables entre le caoutchouc et le substrat, présentant une bonne adhérence primaire et une bonne résistance au déchirement après exposition à des conditions extrêmes. Lesdits adhésifs sont polyvalents et présentent une stabilité dans le moule et une stabilité de stockage en boîte excellentes. Dans un mode de réalisation, les compositions d'adhésifs de la présente invention sont essentiellement constituées de moins de 1000 ppm de plomb, d'au moins un diluant tel que l'eau ou un solvant organique, d'un filmogène contenant un halogène, éventuellement d'un composé nitreux, de dichlorobutadiène bromé, et/ou d'un promoteur d'adhérence, et d'un fixateur d'acide contenant du phosphate de zinc.
CA2462612A 2001-10-17 2002-10-17 Adhesifs sans danger pour l'environnement destines au collage de caoutchouc vulcanise Expired - Fee Related CA2462612C (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US33003301P 2001-10-17 2001-10-17
US60/330,033 2001-10-17
US10/222,545 US20040033374A1 (en) 2002-08-16 2002-08-16 Phenolic adhesives for bonding peroxide-cured elastomers
US10/222,545 2002-08-16
PCT/US2002/033362 WO2003033613A1 (fr) 2001-10-17 2002-10-17 Adhesifs sans danger pour l'environnement destines au collage de caoutchouc vulcanise

Publications (2)

Publication Number Publication Date
CA2462612A1 CA2462612A1 (fr) 2003-04-24
CA2462612C true CA2462612C (fr) 2011-08-02

Family

ID=26916919

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2462612A Expired - Fee Related CA2462612C (fr) 2001-10-17 2002-10-17 Adhesifs sans danger pour l'environnement destines au collage de caoutchouc vulcanise

Country Status (3)

Country Link
CA (1) CA2462612C (fr)
MX (1) MXPA04003502A (fr)
WO (1) WO2003033613A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CZ2003155A3 (cs) 2002-01-30 2003-09-17 Rohm And Haas Company Vodné lepicí přípravky pro lepení elastomerů
NZ551502A (en) * 2004-06-16 2010-08-27 Lord Corp Adhesive composition, method for bonding to a metal surface and rubber to metal adhesive
US9328270B2 (en) 2006-11-15 2016-05-03 Rohm And Haas Company Waterborne adhesives for elastomers
RU2378310C1 (ru) * 2008-06-16 2010-01-10 Государственное образовательное учреждение высшего профессионального образования Волгоградский государственный технический университет (ВолгГТУ) Способ крепления резин друг к другу
JP6905046B2 (ja) * 2016-04-04 2021-07-21 ダウ グローバル テクノロジーズ エルエルシー 金属にゴムを結合するための改善された接着剤組成物
CN110437769B (zh) * 2019-09-18 2021-03-02 青岛科技大学 一种可硫化交联的卤化橡胶胶黏剂及其制备方法
CN110511300B (zh) * 2019-09-18 2021-09-14 青岛科技大学 一种卤化的反式丁二烯-异戊二烯共聚橡胶及其制备方法和用途
EP3950800A1 (fr) * 2020-08-03 2022-02-09 Henkel AG & Co. KGaA Amélioration de la résistance à la corrosion d'adhésifs et de produits d'étanchéité à base de caoutchouc

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3830784A (en) * 1972-03-22 1974-08-20 Lord Corp Shelf-stable adhesive compositions for laminating elastomers to metal and textile substrates and such laminates
US4119587A (en) * 1977-02-25 1978-10-10 Lord Corporation Adhesive compositions comprising (a) halogenated polyolefin (b) aromatic nitroso compound and (c) lead salts
IN162673B (fr) * 1984-03-07 1988-06-25 Lord Corp
US5268404A (en) * 1989-12-04 1993-12-07 Lord Corporation One-coat rubber-to-metal bonding adhesive

Also Published As

Publication number Publication date
MXPA04003502A (es) 2004-09-10
WO2003033613A1 (fr) 2003-04-24
CA2462612A1 (fr) 2003-04-24

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