CA2493463C - Procede et tube a ailettes pour la craquage thermique d'hydrocarbures - Google Patents
Procede et tube a ailettes pour la craquage thermique d'hydrocarbures Download PDFInfo
- Publication number
- CA2493463C CA2493463C CA2493463A CA2493463A CA2493463C CA 2493463 C CA2493463 C CA 2493463C CA 2493463 A CA2493463 A CA 2493463A CA 2493463 A CA2493463 A CA 2493463A CA 2493463 C CA2493463 C CA 2493463C
- Authority
- CA
- Canada
- Prior art keywords
- fins
- finned tube
- tube according
- tube
- profile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 9
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 9
- 238000004227 thermal cracking Methods 0.000 title claims abstract description 6
- 238000000034 method Methods 0.000 title abstract description 12
- 230000008569 process Effects 0.000 title abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 238000012360 testing method Methods 0.000 claims description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- 238000012546 transfer Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 238000003466 welding Methods 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229910052758 niobium Inorganic materials 0.000 claims description 4
- 239000010955 niobium Substances 0.000 claims description 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 238000007792 addition Methods 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims 2
- 229910045601 alloy Inorganic materials 0.000 claims 1
- 239000000956 alloy Substances 0.000 claims 1
- 239000003792 electrolyte Substances 0.000 claims 1
- 239000000571 coke Substances 0.000 abstract description 9
- 238000000197 pyrolysis Methods 0.000 abstract description 9
- 230000008021 deposition Effects 0.000 abstract 1
- 238000005336 cracking Methods 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000007789 gas Substances 0.000 description 8
- 239000010410 layer Substances 0.000 description 7
- 238000010586 diagram Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000001133 acceleration Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 238000004939 coking Methods 0.000 description 3
- 229910000851 Alloy steel Inorganic materials 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 238000005482 strain hardening Methods 0.000 description 2
- 241001589086 Bellapiscis medius Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010622 cold drawing Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/14—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils in pipes or coils with or without auxiliary means, e.g. digesters, soaking drums, expansion means
- C10G9/18—Apparatus
- C10G9/20—Tube furnaces
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/24—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by heating with electrical means
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/40—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only inside the tubular element
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/80—Additives
- C10G2300/805—Water
- C10G2300/807—Steam
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Geometry (AREA)
- General Engineering & Computer Science (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
L'invention concerne un procédé de séparation thermique d'hydrocarbures en présence de vapeur, selon lequel un mélange est guidé à travers des tubes munis d'ailettes intérieures hélicoïdales, qui sont chauffés depuis l'extérieur. Pour compenser la température dans la paroi des tubes et sur la section transversale des tubes, ainsi que pour réduire le dépôt de coke de pyrolyse au niveau de la paroi intérieure des tubes, un écoulement spiroïdal est produit dans le mélange gazeux et est introduit progressivement avec un écoulement essentiellement axial et avec un écart croissant par rapport aux ailettes, dans une zone nodale.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10233961A DE10233961A1 (de) | 2002-07-25 | 2002-07-25 | Verfahren zum thermischen Spalten von Kohlenwasserstoffen |
| DE10233961.9 | 2002-07-25 | ||
| PCT/EP2003/004827 WO2004015029A1 (fr) | 2002-07-25 | 2003-05-08 | Procede et tube a ailettes pour separation thermique d'hydrocarbures |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2493463A1 CA2493463A1 (fr) | 2004-02-19 |
| CA2493463C true CA2493463C (fr) | 2013-01-15 |
Family
ID=30128404
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2493463A Expired - Lifetime CA2493463C (fr) | 2002-07-25 | 2003-05-08 | Procede et tube a ailettes pour la craquage thermique d'hydrocarbures |
Country Status (22)
| Country | Link |
|---|---|
| EP (2) | EP2298850A1 (fr) |
| JP (2) | JP4536512B2 (fr) |
| KR (1) | KR101023668B1 (fr) |
| CN (1) | CN100523133C (fr) |
| AT (1) | ATE526385T1 (fr) |
| AU (1) | AU2003227737A1 (fr) |
| BR (1) | BR0312919B1 (fr) |
| CA (1) | CA2493463C (fr) |
| DE (1) | DE10233961A1 (fr) |
| EA (1) | EA010936B1 (fr) |
| ES (1) | ES2374568T3 (fr) |
| HR (1) | HRP20050072A2 (fr) |
| IL (1) | IL166229A (fr) |
| MA (1) | MA27325A1 (fr) |
| MX (1) | MXPA05001070A (fr) |
| NO (1) | NO337398B1 (fr) |
| NZ (1) | NZ537827A (fr) |
| PL (1) | PL204769B1 (fr) |
| PT (1) | PT1525289E (fr) |
| RS (1) | RS20050060A (fr) |
| UA (1) | UA85044C2 (fr) |
| WO (1) | WO2004015029A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11440106B2 (en) | 2016-10-26 | 2022-09-13 | Schmidt + Clemens Gmbh + Co. Kg | Deep hole drilling method as well as tool for a deep hole drilling machine and deep hole drilling machine |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK2037202T3 (en) | 2006-07-05 | 2018-11-19 | Nippon Steel & Sumitomo Metal Corp | Metal pipe for thermal cracking reaction |
| WO2010106070A1 (fr) * | 2009-03-17 | 2010-09-23 | Total Petrochemicals Research Feluy | Procédé pour le refroidissement brusque de l'effluent gazeux d'un four |
| EP2813286A1 (fr) * | 2013-06-11 | 2014-12-17 | Evonik Industries AG | Tube de réaction et procédé de fabrication de cyanure d'hydrogène |
| FR3033266B1 (fr) * | 2015-03-05 | 2017-03-03 | Ifp Energies Now | Ensemble de collecte d'un fluide gazeux pour reacteur radial |
| WO2017007649A1 (fr) | 2015-07-09 | 2017-01-12 | Sabic Global Technologies B.V. | Minimisation de la formation de coke dans un système de craquage d'hydrocarbures |
| JP6107905B2 (ja) * | 2015-09-09 | 2017-04-05 | 株式会社富士通ゼネラル | 熱交換器 |
| CN109072090B (zh) * | 2016-04-12 | 2021-03-16 | 巴斯夫安特卫普股份有限公司 | 用于裂解炉的反应器 |
| HUE066462T2 (hu) * | 2017-04-07 | 2024-08-28 | Schmidt Clemens Gmbh Co Kg | Csõ és berendezés szénhidrogének termikus krakkolásához |
| EP3606657A1 (fr) * | 2017-04-07 | 2020-02-12 | Schmidt + Clemens GmbH & Co. KG | Tuyau et dispositif pour réaliser une fission thermique d'hydrocarbures |
| DE102017003409B4 (de) | 2017-04-07 | 2023-08-10 | Schmidt + Clemens Gmbh + Co. Kg | Rohr und Vorrichtung zum thermischen Spalten von Kohlenwasserstoffen |
| US11053445B2 (en) * | 2017-05-05 | 2021-07-06 | Exxonmobil Chemical Patents Inc. | Heat transfer tube for hydrocarbon processing |
| MY201675A (en) * | 2017-10-27 | 2024-03-12 | China Petroleum & Chem Corp | Heat transfer enhancement pipe as well as cracking furnace and atmospheric and vacuum heating furnace including the same |
| GB2590363B (en) * | 2019-12-09 | 2023-06-28 | Paralloy Ltd | Internally profiled tubes |
| CN116026278B (zh) * | 2022-12-21 | 2025-10-31 | 湖南特种玻璃研究院有限公司 | 一种溢流砖寿命预测方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB969796A (en) | 1961-03-01 | 1964-09-16 | Exxon Research Engineering Co | Apparatus for heating fluids and tubes for disposal therein |
| JPS58132081A (ja) * | 1982-01-08 | 1983-08-06 | Idemitsu Petrochem Co Ltd | 炭化水素の熱分解方法 |
| DE3716665A1 (de) * | 1987-05-19 | 1988-12-08 | Vdm Nickel Tech | Korrosionsbestaendige legierung |
| JP3001181B2 (ja) | 1994-07-11 | 2000-01-24 | 株式会社クボタ | エチレン製造用反応管 |
| DE4427859A1 (de) * | 1994-08-05 | 1995-10-26 | Siemens Ag | Rohr mit auf seiner Innenseite ein mehrgängiges Gewinde bildenden Rippen sowie Dampferzeuger zu seiner Verwendung |
| DE19523280C2 (de) | 1995-06-27 | 2002-12-05 | Gfm Gmbh Steyr | Schmiedemaschine zum Innenprofilieren von rohrförmigen Werkstücken |
| DE19629977C2 (de) * | 1996-07-25 | 2002-09-19 | Schmidt & Clemens Gmbh & Co Ed | Werkstück aus einer austenitischen Nickel-Chrom-Stahllegierung |
| RU2211854C2 (ru) * | 1997-06-10 | 2003-09-10 | Эксон Кемикэл Пейтентс Инк. | Пиролизная печь с u-образным змеевиком с внутренним оребрением |
| JPH11199876A (ja) * | 1998-01-16 | 1999-07-27 | Kubota Corp | コーキング減少性能を有するエチレン製造用熱分解管 |
-
2002
- 2002-07-25 DE DE10233961A patent/DE10233961A1/de not_active Withdrawn
-
2003
- 2003-05-08 RS YUP-2005/0060A patent/RS20050060A/sr unknown
- 2003-05-08 KR KR1020057001384A patent/KR101023668B1/ko not_active Expired - Lifetime
- 2003-05-08 AT AT03725176T patent/ATE526385T1/de active
- 2003-05-08 CA CA2493463A patent/CA2493463C/fr not_active Expired - Lifetime
- 2003-05-08 ES ES03725176T patent/ES2374568T3/es not_active Expired - Lifetime
- 2003-05-08 UA UAA200501718A patent/UA85044C2/ru unknown
- 2003-05-08 PL PL373967A patent/PL204769B1/pl unknown
- 2003-05-08 MX MXPA05001070A patent/MXPA05001070A/es active IP Right Grant
- 2003-05-08 HR HR20050072A patent/HRP20050072A2/hr not_active Application Discontinuation
- 2003-05-08 NZ NZ537827A patent/NZ537827A/en not_active IP Right Cessation
- 2003-05-08 BR BRPI0312919-5A patent/BR0312919B1/pt active IP Right Grant
- 2003-05-08 EA EA200500258A patent/EA010936B1/ru not_active IP Right Cessation
- 2003-05-08 EP EP10012045A patent/EP2298850A1/fr not_active Withdrawn
- 2003-05-08 EP EP03725176A patent/EP1525289B9/fr not_active Expired - Lifetime
- 2003-05-08 PT PT03725176T patent/PT1525289E/pt unknown
- 2003-05-08 AU AU2003227737A patent/AU2003227737A1/en not_active Abandoned
- 2003-05-08 JP JP2004526658A patent/JP4536512B2/ja not_active Expired - Lifetime
- 2003-05-08 WO PCT/EP2003/004827 patent/WO2004015029A1/fr not_active Ceased
- 2003-05-08 CN CNB038178850A patent/CN100523133C/zh not_active Expired - Lifetime
-
2005
- 2005-01-11 IL IL166229A patent/IL166229A/en active IP Right Grant
- 2005-01-18 MA MA28048A patent/MA27325A1/fr unknown
- 2005-01-28 NO NO20050493A patent/NO337398B1/no not_active IP Right Cessation
-
2010
- 2010-02-18 JP JP2010034129A patent/JP2010150553A/ja not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11440106B2 (en) | 2016-10-26 | 2022-09-13 | Schmidt + Clemens Gmbh + Co. Kg | Deep hole drilling method as well as tool for a deep hole drilling machine and deep hole drilling machine |
Also Published As
| Publication number | Publication date |
|---|---|
| BR0312919A (pt) | 2005-07-05 |
| PL204769B1 (pl) | 2010-02-26 |
| KR101023668B1 (ko) | 2011-03-25 |
| CN100523133C (zh) | 2009-08-05 |
| EP1525289B9 (fr) | 2012-02-29 |
| PL373967A1 (en) | 2005-09-19 |
| NO20050493L (no) | 2005-03-17 |
| EP1525289B1 (fr) | 2011-09-28 |
| ATE526385T1 (de) | 2011-10-15 |
| UA85044C2 (ru) | 2008-12-25 |
| DE10233961A1 (de) | 2004-02-12 |
| PT1525289E (pt) | 2012-01-04 |
| EA010936B1 (ru) | 2008-12-30 |
| ES2374568T3 (es) | 2012-02-17 |
| NZ537827A (en) | 2007-04-27 |
| JP2010150553A (ja) | 2010-07-08 |
| CN1671824A (zh) | 2005-09-21 |
| JP4536512B2 (ja) | 2010-09-01 |
| EA200500258A1 (ru) | 2005-08-25 |
| NO337398B1 (no) | 2016-04-04 |
| CA2493463A1 (fr) | 2004-02-19 |
| AU2003227737A1 (en) | 2004-02-25 |
| MXPA05001070A (es) | 2005-10-05 |
| IL166229A (en) | 2008-11-26 |
| EP2298850A1 (fr) | 2011-03-23 |
| IL166229A0 (en) | 2006-01-15 |
| RS20050060A (sr) | 2007-09-21 |
| JP2005533917A (ja) | 2005-11-10 |
| EP1525289A1 (fr) | 2005-04-27 |
| MA27325A1 (fr) | 2005-05-02 |
| BR0312919B1 (pt) | 2014-06-24 |
| KR20050052457A (ko) | 2005-06-02 |
| WO2004015029A1 (fr) | 2004-02-19 |
| HRP20050072A2 (en) | 2005-08-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20230508 |