CA2637614C - Additifs de copolymeres blocs pour mousses - Google Patents

Additifs de copolymeres blocs pour mousses Download PDF

Info

Publication number: CA2637614C
Authority: CA; Canada
Prior art keywords: block copolymer; blowing agent; block; thermoplastic; foam
Prior art date: 2006-01-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA2637614A

Other languages

English (en)

Other versions

CA2637614A1 (fr

Inventor

Brett L. Van Horn

Christopher A. Bertelo

Noah E. Macy

Scott C. Schmidt

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Arkema Inc

Original Assignee

Arkema Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2006-01-19

Filing date

2007-01-18

Publication date

2014-07-22

2007-01-18 Application filed by Arkema Inc filed Critical Arkema Inc

2007-07-26 Publication of CA2637614A1 publication Critical patent/CA2637614A1/fr

2014-07-22 Application granted granted Critical

2014-07-22 Publication of CA2637614C publication Critical patent/CA2637614C/fr

Status Expired - Fee Related legal-status Critical Current

2027-01-18 Anticipated expiration legal-status Critical

Links

229920001400 block copolymer Polymers 0.000 title claims abstract description 40
239000006260 foam Substances 0.000 title claims abstract description 35
239000000654 additive Substances 0.000 title abstract description 29
239000004604 Blowing Agent Substances 0.000 claims abstract description 27
239000000203 mixture Substances 0.000 claims abstract description 23
229920001169 thermoplastic Polymers 0.000 claims abstract description 19
229920005992 thermoplastic resin Polymers 0.000 claims abstract description 14
239000004416 thermosoftening plastic Substances 0.000 claims abstract description 14
239000004793 Polystyrene Substances 0.000 claims description 23
229920002223 polystyrene Polymers 0.000 claims description 22
-1 poly(butyl acrylate) Polymers 0.000 claims description 21
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 16
229920001485 poly(butyl acrylate) polymer Polymers 0.000 claims description 15
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 claims description 12
239000001569 carbon dioxide Substances 0.000 claims description 8
229910002092 carbon dioxide Inorganic materials 0.000 claims description 8
RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 claims description 8
238000000034 method Methods 0.000 claims description 7
YFMFNYKEUDLDTL-UHFFFAOYSA-N 1,1,1,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)C(F)(F)F YFMFNYKEUDLDTL-UHFFFAOYSA-N 0.000 claims description 4
UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 claims description 4
NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 claims description 4
GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 claims description 4
MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 claims description 4
WZLFPVPRZGTCKP-UHFFFAOYSA-N 1,1,1,3,3-pentafluorobutane Chemical compound CC(F)(F)CC(F)(F)F WZLFPVPRZGTCKP-UHFFFAOYSA-N 0.000 claims description 3
WGZYQOSEVSXDNI-UHFFFAOYSA-N 1,1,2-trifluoroethane Chemical compound FCC(F)F WGZYQOSEVSXDNI-UHFFFAOYSA-N 0.000 claims description 3
150000001335 aliphatic alkanes Chemical class 0.000 claims description 3
230000000996 additive effect Effects 0.000 abstract description 15
230000003247 decreasing effect Effects 0.000 abstract description 6
238000005187 foaming Methods 0.000 abstract description 5
238000004519 manufacturing process Methods 0.000 abstract description 5
239000002952 polymeric resin Substances 0.000 abstract description 2
229920005989 resin Polymers 0.000 description 20
239000011347 resin Substances 0.000 description 20
229920001577 copolymer Polymers 0.000 description 15
210000004027 cell Anatomy 0.000 description 13
230000009477 glass transition Effects 0.000 description 10
229920000642 polymer Polymers 0.000 description 10
229920001519 homopolymer Polymers 0.000 description 7
230000000704 physical effect Effects 0.000 description 7
230000000694 effects Effects 0.000 description 6
229920005604 random copolymer Polymers 0.000 description 6
238000003860 storage Methods 0.000 description 6
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 5
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
238000004630 atomic force microscopy Methods 0.000 description 3
230000006911 nucleation Effects 0.000 description 3
238000010899 nucleation Methods 0.000 description 3
229920002959 polymer blend Polymers 0.000 description 3
230000001627 detrimental effect Effects 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
238000005227 gel permeation chromatography Methods 0.000 description 2
239000000463 material Substances 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
238000010526 radical polymerization reaction Methods 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
238000000089 atomic force micrograph Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000002902 bimodal effect Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000001273 butane Substances 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
230000001413 cellular effect Effects 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000013329 compounding Methods 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
230000000779 depleting effect Effects 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
BXOUVIIITJXIKB-UHFFFAOYSA-N ethene;styrene Chemical compound C=C.C=CC1=CC=CC=C1 BXOUVIIITJXIKB-UHFFFAOYSA-N 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
210000000497 foam cell Anatomy 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000009413 insulation Methods 0.000 description 1
238000003990 inverse gas chromatography Methods 0.000 description 1
239000007788 liquid Substances 0.000 description 1
230000007774 longterm Effects 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
238000012634 optical imaging Methods 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
238000005191 phase separation Methods 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920006327 polystyrene foam Polymers 0.000 description 1
229920005990 polystyrene resin Polymers 0.000 description 1
238000010079 rubber tapping Methods 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
229920000428 triblock copolymer Polymers 0.000 description 1
239000002023 wood Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/06—CO2, N2 or noble gases
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2453/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA2637614A 2006-01-19 2007-01-18 Additifs de copolymeres blocs pour mousses Expired - Fee Related CA2637614C (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US76033006P	2006-01-19	2006-01-19
US60/760,330		2006-01-19
PCT/US2007/001436 WO2007084665A2 (fr)	2006-01-19	2007-01-18	Additifs de copolymères blocs pour mousses

Publications (2)

Publication Number	Publication Date
CA2637614A1 CA2637614A1 (fr)	2007-07-26
CA2637614C true CA2637614C (fr)	2014-07-22

Family

ID=38288261

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA2637614A Expired - Fee Related CA2637614C (fr)	2006-01-19	2007-01-18	Additifs de copolymeres blocs pour mousses

Country Status (6)

Country	Link
US (1)	US20080281012A1 (fr)
EP (1)	EP1973958A4 (fr)
JP (1)	JP5340744B2 (fr)
CN (1)	CN101370843A (fr)
CA (1)	CA2637614C (fr)
WO (1)	WO2007084665A2 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2011513538A (ja) *	2008-02-29	2011-04-28	アーケマ・インコーポレイテッド	ブロックコポリマー油リターン剤
CN102573818B (zh) *	2009-09-25	2016-08-03	阿科玛股份有限公司	具有改进的尺寸稳定性的生物可降解泡沫
AU2010101182A4 (en)	2010-07-14	2010-12-09	Basf Se	Polyester resin composition and a process for manufacturing the same
WO2013003254A1 (fr)	2011-06-27	2013-01-03	Owens Corning Intellectual Capital, Llc	Agents d'atténuation infrarouge organiques
JP6273001B2 (ja)	2013-10-30	2018-01-31	ダウグローバルテクノロジーズエルエルシー	臭素化スチレン−ブタジエンコポリマーを含有し、かつ向上したセルサイズ均一性を有する発泡スチレンポリマー
MY178771A (en) *	2014-02-20	2020-10-20	Asahi Chemical Ind	Thermoplastic resin composition, and molded product and method for producing same
JP6641745B2 (ja) *	2014-07-08	2020-02-05	宇部興産株式会社	相構造解析方法、ポリマー材料、ポリマー材料製造方法
EP3452537B1 (fr)	2016-05-06	2024-08-21	The Chemours Company FC, LLC	Expansion de polymère styrénique

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1109660B (it) *	1978-02-23	1985-12-23	Lavorazione Mat Plast	Perfezionamento all estrusione di schiume sintetiche
US4229396A (en) *	1979-03-21	1980-10-21	The Dow Chemical Company	Method of extruding thermoplastic resin foams having enlarged cell-sizes
US4616042A (en) *	1985-06-14	1986-10-07	General Electric Company	Low temperature impact modified thermoplastic foam
US5252664A (en) *	1989-07-21	1993-10-12	Polysar Limited	Transparent toughened thermoplastics
US5079296A (en) *	1989-07-21	1992-01-07	Polysar Limited	Transparent toughened thermoplastics
US5218006A (en) *	1992-06-01	1993-06-08	Reedy Michael E	Process for producing polystyrene foam
JP3338450B2 (ja) *	1993-01-26	2002-10-28	ザ・ダウ・ケミカル・カンパニー	気泡の大きな発泡体およびその製造法
US5389694A (en) *	1993-06-04	1995-02-14	The Dow Chemical Company	Foamable styrenic polymer gel having a carbon dioxide blowing agent and a process for making a foam structure therefrom
CA2205397A1 (fr) *	1994-11-18	1996-05-30	Itsuki Nakatani	Mousse en resine de polystyrene et procede pour produire la mousse
US5776389A (en) *	1996-06-20	1998-07-07	The Dow Chemical Company	Process for making an alkenyl aromatic polymer foam having enlarged cell size
US5993706A (en) *	1996-08-08	1999-11-30	Tenneco Protective Packaging, Inc.	Oxygenated hydrocarbon compatibilizing agent for carbon dioxide-blown polyolefinic foams
HUP0002619A3 (en) *	1997-06-11	2003-06-30	Dow Global Technologies Inc Mi	Extruded thermoplastic foams with absorbing effect
MX234819B (es) *	2000-10-24	2006-03-13	Dow Global Technologies Inc	Proceso de preparacion para espuma polimerica termoplastica multimodal.
JP2002179827A (ja) *	2000-12-14	2002-06-26	Mitsubishi Kagaku Form Plastic Kk	スチレン系樹脂発泡体及びその製造方法
US7358282B2 (en) *	2003-12-05	2008-04-15	Kimberly-Clark Worldwide, Inc.	Low-density, open-cell, soft, flexible, thermoplastic, absorbent foam and method of making foam
DE10358801A1 (de) *	2003-12-12	2005-07-14	Basf Ag	Partikelschaumformteile aus expandierbaren Styrolpolymeren und Mischungen mit thermoplastischen Polymeren

2007
- 2007-01-18 CA CA2637614A patent/CA2637614C/fr not_active Expired - Fee Related
- 2007-01-18 CN CNA2007800025666A patent/CN101370843A/zh active Pending
- 2007-01-18 EP EP07718118A patent/EP1973958A4/fr not_active Withdrawn
- 2007-01-18 WO PCT/US2007/001436 patent/WO2007084665A2/fr not_active Ceased
- 2007-01-18 US US12/160,824 patent/US20080281012A1/en not_active Abandoned
- 2007-01-18 JP JP2008551415A patent/JP5340744B2/ja not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA2637614A1 (fr)	2007-07-26
US20080281012A1 (en)	2008-11-13
WO2007084665A2 (fr)	2007-07-26
WO2007084665A3 (fr)	2008-01-24
EP1973958A4 (fr)	2011-07-06
JP2009523895A (ja)	2009-06-25
EP1973958A2 (fr)	2008-10-01
JP5340744B2 (ja)	2013-11-13
CN101370843A (zh)	2009-02-18

Legal Events

Date	Code	Title	Description
2011-12-29	EEER	Examination request
2016-02-29	MKLA	Lapsed	Effective date: 20160118

Publication	Publication Date	Title
CA2637614C (fr)	2014-07-22	Additifs de copolymeres blocs pour mousses
AU757026B2 (en)	2003-01-30	Process for producing extruded foam
CA2787937C (fr)	2019-01-15	Melange d'additifs pour renforcer la permeabilite a la vapeur d'eau et augmenter la taille des alveoles dans des mousses thermoplastiques
JP4794791B2 (ja)	2011-10-19	広い分子量分布のモノビニル芳香族ポリマーをもつ断熱用押出し発泡体
Mohamad et al.	2006	Characterization of epoxidized natural rubber/ethylene vinyl acetate (ENR‐50/EVA) blend: Effect of blend ratio
TW200906950A (en)	2009-02-16	Alkenyl-aromatic foam having good surface quality, high thermal insulating properties and low density
EP2734577B1 (fr)	2018-03-28	Nanomousse polymérique
Li et al.	2018	Rheological, crystallization and foaming behaviors of high melt strength polypropylene in the presence of polyvinyl acetate
Gong et al.	2012	The effect of interfacial miscibility on the cell morphology of polyethylene terephthalate/bisphenol a polycarbonate blend foams
AU5897599A (en)	2000-04-03	Process for producing extruded styrenic foam
EP0274410A2 (fr)	1988-07-13	Composition de chlorure de vinylidène expansible et mousse produite à partir de cette composition
EP2898007B1 (fr)	2016-12-28	Polymère greffé de silsesquioxane oligomérique polyédrique dans une mousse polymérique
WO1996016111A1 (fr)	1996-05-30	Mousse en resine de polystyrene et procede pour produire la mousse
Jin et al.	2011	The possible scalability of mesophase separation on macrophase separation and crystallization of iPP/OBC blends
TWI633144B (zh)	2018-08-21	極性添加劑在提高發泡劑於聚苯乙烯中之溶解度上的用途
JP3761310B2 (ja)	2006-03-29	スチレン系樹脂押出発泡体の製造方法及び発泡体
Tong et al.	2025	Supercritical CO2‐Assisted Foaming of PBST/PHBH Blends: Mechanisms of Morphological Control and Shrinkage Reduction
Jamalpour et al.	2018	Using supramolecular associations to create stable cellular structures in amorphous soft polymers
JPH02245007A (ja)	1990-09-28	ポリ（ビニル芳香族）ポリマー相とポリ（アルキレン）相とからなる安定な相互浸透性ポリマー配合物の製造方法
JP2024061223A (ja)	2024-05-07	ポリプロピレン系樹脂発泡粒子の製造方法
JPH11349724A (ja)	1999-12-21	発泡性ポリオレフィン系樹脂粒子、それから得られる発泡粒子および発泡成形体
Li et al.	2026	Non-Cross-Linked Foaming of Styrene–Ethylene–Butylene–Styrene Enabled by Long-Chain Branched Polypropylene with Triple Effects
US20090306261A1 (en)	2009-12-10	Compatibilizing Polymer Blends by Using Organoclay
Lin	1994	Effects of emulsifiers on properties of microemulsions and polymeric emulsions
Sugimoto et al.	0	EFFECT OF FLUORINATED HYPERBRANCHED POLYMER ON FOAMING OF PMMA