CA2842396A1 - Procede destine a blanchir de la vaisselle dans un lave-vaisselle - Google Patents

Procede destine a blanchir de la vaisselle dans un lave-vaisselle Download PDF

Info

Publication number: CA2842396A1
Authority: CA; Canada
Prior art keywords: electrolysis; dishwasher; range; aqueous solution; electrolysis cell
Prior art date: 2011-09-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA2842396A

Other languages

English (en)

Inventor

Florian Stecker

Steffen Maas

Ulrich Griesbach

Andreas Fischer

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF SE

Original Assignee

BASF SE

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2011-09-05

Filing date

2012-09-04

Publication date

2013-03-14

2012-09-04 Application filed by BASF SE filed Critical BASF SE

2013-03-14 Publication of CA2842396A1 publication Critical patent/CA2842396A1/fr

Status Abandoned legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 49
238000004061 bleaching Methods 0.000 title claims abstract description 13
238000005868 electrolysis reaction Methods 0.000 claims abstract description 69
239000007864 aqueous solution Substances 0.000 claims abstract description 44
239000007844 bleaching agent Substances 0.000 claims abstract description 37
239000012190 activator Substances 0.000 claims abstract description 29
239000003642 reactive oxygen metabolite Substances 0.000 claims abstract description 16
238000011065 in-situ storage Methods 0.000 claims abstract description 7
230000004913 activation Effects 0.000 claims abstract description 3
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 57
229910003460 diamond Inorganic materials 0.000 claims description 39
239000010432 diamond Substances 0.000 claims description 39
-1 hydrogen peroxide anions Chemical class 0.000 claims description 37
125000002252 acyl group Chemical group 0.000 claims description 11
239000000654 additive Substances 0.000 claims description 8
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 6
229910052796 boron Inorganic materials 0.000 claims description 6
229920000768 polyamine Polymers 0.000 claims description 4
125000006585 (C6-C10) arylene group Chemical group 0.000 claims description 3
230000003647 oxidation Effects 0.000 claims description 3
238000007254 oxidation reaction Methods 0.000 claims description 3
125000004430 oxygen atom Chemical group O* 0.000 claims description 3
230000000996 additive effect Effects 0.000 claims description 2
FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical group CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 claims 2
125000003837 (C1-C20) alkyl group Chemical group 0.000 claims 1
125000000041 C6-C10 aryl group Chemical group 0.000 claims 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 35
239000000758 substrate Substances 0.000 description 22
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 19
238000004140 cleaning Methods 0.000 description 19
238000005406 washing Methods 0.000 description 17
239000002689 soil Substances 0.000 description 16
238000012360 testing method Methods 0.000 description 15
239000002253 acid Substances 0.000 description 13
239000012876 carrier material Substances 0.000 description 10
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 10
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
150000007513 acids Chemical class 0.000 description 9
229920000877 Melamine resin Polymers 0.000 description 8
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 8
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 8
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 8
239000010936 titanium Substances 0.000 description 8
229910052719 titanium Inorganic materials 0.000 description 8
239000004640 Melamine resin Substances 0.000 description 7
239000003599 detergent Substances 0.000 description 7
238000004851 dishwashing Methods 0.000 description 7
239000007788 liquid Substances 0.000 description 7
229910052757 nitrogen Inorganic materials 0.000 description 7
238000005086 pumping Methods 0.000 description 7
239000000243 solution Substances 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
229910052758 niobium Inorganic materials 0.000 description 6
239000010955 niobium Substances 0.000 description 6
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 6
239000001301 oxygen Substances 0.000 description 6
229910052760 oxygen Inorganic materials 0.000 description 6
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 5
229910052783 alkali metal Inorganic materials 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
238000005260 corrosion Methods 0.000 description 5
230000007797 corrosion Effects 0.000 description 5
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 5
239000003792 electrolyte Substances 0.000 description 5
230000007717 exclusion Effects 0.000 description 5
239000011521 glass Substances 0.000 description 5
229910002804 graphite Inorganic materials 0.000 description 5
239000010439 graphite Substances 0.000 description 5
238000005259 measurement Methods 0.000 description 5
229910052697 platinum Inorganic materials 0.000 description 5
229910052710 silicon Inorganic materials 0.000 description 5
239000010703 silicon Substances 0.000 description 5
229940045872 sodium percarbonate Drugs 0.000 description 5
239000004094 surface-active agent Substances 0.000 description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
229910052801 chlorine Inorganic materials 0.000 description 4
230000000694 effects Effects 0.000 description 4
239000003112 inhibitor Substances 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
239000000463 material Substances 0.000 description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
239000010970 precious metal Substances 0.000 description 4
230000001172 regenerating effect Effects 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
229910000030 sodium bicarbonate Inorganic materials 0.000 description 4
235000017557 sodium bicarbonate Nutrition 0.000 description 4
230000001954 sterilising effect Effects 0.000 description 4
238000004659 sterilization and disinfection Methods 0.000 description 4
102000004190 Enzymes Human genes 0.000 description 3
108090000790 Enzymes Proteins 0.000 description 3
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
229910000831 Steel Inorganic materials 0.000 description 3
150000001340 alkali metals Chemical class 0.000 description 3
125000004429 atom Chemical group 0.000 description 3
229940088598 enzyme Drugs 0.000 description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 3
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
239000000203 mixture Substances 0.000 description 3
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
230000001590 oxidative effect Effects 0.000 description 3
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 3
229960001922 sodium perborate Drugs 0.000 description 3
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 3
229910001220 stainless steel Inorganic materials 0.000 description 3
239000010959 steel Substances 0.000 description 3
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
239000005708 Sodium hypochlorite Substances 0.000 description 2
241001122767 Theaceae Species 0.000 description 2
239000004904 UV filter Substances 0.000 description 2
150000001408 amides Chemical class 0.000 description 2
125000002490 anilino group Chemical class [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
150000001244 carboxylic acid anhydrides Chemical class 0.000 description 2
239000000919 ceramic Substances 0.000 description 2
238000005229 chemical vapour deposition Methods 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000000576 coating method Methods 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
239000000470 constituent Substances 0.000 description 2
150000007973 cyanuric acids Chemical class 0.000 description 2
230000000249 desinfective effect Effects 0.000 description 2
230000005611 electricity Effects 0.000 description 2
239000000945 filler Substances 0.000 description 2
239000006260 foam Substances 0.000 description 2
125000000623 heterocyclic group Polymers 0.000 description 2
150000002443 hydroxylamines Chemical class 0.000 description 2
150000003949 imides Chemical class 0.000 description 2
238000009434 installation Methods 0.000 description 2
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
229910044991 metal oxide Inorganic materials 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 2
125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
238000006386 neutralization reaction Methods 0.000 description 2
150000002989 phenols Chemical class 0.000 description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
229920005862 polyol Polymers 0.000 description 2
150000003077 polyols Chemical class 0.000 description 2
IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
239000002243 precursor Substances 0.000 description 2
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
229910010271 silicon carbide Inorganic materials 0.000 description 2
JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
229910000029 sodium carbonate Inorganic materials 0.000 description 2
235000017550 sodium carbonate Nutrition 0.000 description 2
239000011780 sodium chloride Substances 0.000 description 2
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
229910052938 sodium sulfate Inorganic materials 0.000 description 2
235000011152 sodium sulphate Nutrition 0.000 description 2
KVSYNOOPFSVLNF-UHFFFAOYSA-M sodium;4-nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=C(S([O-])(=O)=O)C=C1 KVSYNOOPFSVLNF-UHFFFAOYSA-M 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
238000003860 storage Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
235000000346 sugar Nutrition 0.000 description 2
150000003456 sulfonamides Chemical class 0.000 description 2
229910052715 tantalum Inorganic materials 0.000 description 2
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
239000008399 tap water Substances 0.000 description 2
235000020679 tap water Nutrition 0.000 description 2
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
239000001226 triphosphate Substances 0.000 description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
229910052721 tungsten Inorganic materials 0.000 description 2
239000010937 tungsten Substances 0.000 description 2
150000003672 ureas Chemical class 0.000 description 2
239000010457 zeolite Substances 0.000 description 2
XPAXGQCVXSSEEQ-RANZSIQMSA-N (4R,5S,6R,7R)-3,4,5,6-tetraacetyl-3,4,5,6,7-pentahydroxy-7-(hydroxymethyl)nonane-2,8-dione Chemical compound C(C)(=O)[C@@]([C@]([C@@]([C@](C(O)(C(C)=O)C(C)=O)(O)C(C)=O)(O)C(C)=O)(O)C(C)=O)(O)CO XPAXGQCVXSSEEQ-RANZSIQMSA-N 0.000 description 1
XPAXGQCVXSSEEQ-HPBDAGMYSA-N (4S,5S,6R,7R)-3,4,5,6-tetraacetyl-3,4,5,6,7-pentahydroxy-7-(hydroxymethyl)nonane-2,8-dione Chemical compound C(C)(=O)[C@@]([C@]([C@@]([C@@](C(O)(C(C)=O)C(C)=O)(O)C(C)=O)(O)C(C)=O)(O)C(C)=O)(O)CO XPAXGQCVXSSEEQ-HPBDAGMYSA-N 0.000 description 1
VAVZXZURPCYUHS-RQOWECAXSA-N (z)-3-(hydrazinecarbonyl)-4-oxopent-2-enoic acid Chemical compound OC(=O)/C=C(C(=O)C)\C(=O)NN VAVZXZURPCYUHS-RQOWECAXSA-N 0.000 description 1
ZDBXRGDPBFTHEC-UHFFFAOYSA-N 1,3,5-triacetyl-1,3,5-triazinane-2,4,6-trione Chemical compound CC(=O)N1C(=O)N(C(C)=O)C(=O)N(C(C)=O)C1=O ZDBXRGDPBFTHEC-UHFFFAOYSA-N 0.000 description 1
ZGZHWIAQICBGKN-UHFFFAOYSA-N 1-nonanoylpyrrolidine-2,5-dione Chemical group CCCCCCCCC(=O)N1C(=O)CCC1=O ZGZHWIAQICBGKN-UHFFFAOYSA-N 0.000 description 1
NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 description 1
FAGGUIDTQQXDSJ-UHFFFAOYSA-N 3-benzoylazepan-2-one Chemical group C=1C=CC=CC=1C(=O)C1CCCCNC1=O FAGGUIDTQQXDSJ-UHFFFAOYSA-N 0.000 description 1
102000013142 Amylases Human genes 0.000 description 1
108010065511 Amylases Proteins 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
239000004367 Lipase Substances 0.000 description 1
102000004882 Lipase Human genes 0.000 description 1
108090001060 Lipase Proteins 0.000 description 1
102000035195 Peptidases Human genes 0.000 description 1
108091005804 Peptidases Proteins 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
239000004365 Protease Substances 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 1
POSYINLTKMTQCC-UHFFFAOYSA-M [O-]C(O)=O.OC(O)=O.[Na+].P Chemical compound [O-]C(O)=O.OC(O)=O.[Na+].P POSYINLTKMTQCC-UHFFFAOYSA-M 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
YFYRUYRLCFMHNF-UHFFFAOYSA-N acetonitrile;hydrogen sulfate;4-methylmorpholin-4-ium Chemical compound CC#N.OS([O-])(=O)=O.C[NH+]1CCOCC1 YFYRUYRLCFMHNF-UHFFFAOYSA-N 0.000 description 1
CASILXPBIXAEHM-UHFFFAOYSA-N acetonitrile;hydrogen sulfate;trimethylazanium Chemical compound CC#N.C[NH+](C)C.OS([O-])(=O)=O CASILXPBIXAEHM-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
239000013543 active substance Substances 0.000 description 1
235000019418 amylase Nutrition 0.000 description 1
229940025131 amylases Drugs 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
230000000845 anti-microbial effect Effects 0.000 description 1
239000004599 antimicrobial Substances 0.000 description 1
230000008901 benefit Effects 0.000 description 1
NDTSRXAMMQDVSW-UHFFFAOYSA-N benzthiazide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(S(N2)(=O)=O)=C1N=C2CSCC1=CC=CC=C1 NDTSRXAMMQDVSW-UHFFFAOYSA-N 0.000 description 1
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
229910000423 chromium oxide Inorganic materials 0.000 description 1
238000012733 comparative method Methods 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
HTXDPTMKBJXEOW-UHFFFAOYSA-N dioxoiridium Chemical compound O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
239000007772 electrode material Substances 0.000 description 1
239000008151 electrolyte solution Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
239000013505 freshwater Substances 0.000 description 1
239000001087 glyceryl triacetate Substances 0.000 description 1
235000013773 glyceryl triacetate Nutrition 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
239000010931 gold Substances 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000003014 ion exchange membrane Substances 0.000 description 1
229910000457 iridium oxide Inorganic materials 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
229910000464 lead oxide Inorganic materials 0.000 description 1
235000019421 lipase Nutrition 0.000 description 1
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
239000012528 membrane Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
229910003455 mixed metal oxide Inorganic materials 0.000 description 1
KBDYPDHUODKDRK-UHFFFAOYSA-N n-acetyl-n-phenylacetamide Chemical group CC(=O)N(C(C)=O)C1=CC=CC=C1 KBDYPDHUODKDRK-UHFFFAOYSA-N 0.000 description 1
DDNVNUWFESEAHN-UHFFFAOYSA-N n-methyl-n-methylsulfonylacetamide Chemical compound CC(=O)N(C)S(C)(=O)=O DDNVNUWFESEAHN-UHFFFAOYSA-N 0.000 description 1
FVCXXYLGLXGBDR-UHFFFAOYSA-N n-methyl-n-methylsulfonylbenzamide Chemical compound CS(=O)(=O)N(C)C(=O)C1=CC=CC=C1 FVCXXYLGLXGBDR-UHFFFAOYSA-N 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
125000004957 naphthylene group Chemical group 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
NQNBVCBUOCNRFZ-UHFFFAOYSA-N nickel ferrite Chemical compound [Ni]=O.O=[Fe]O[Fe]=O NQNBVCBUOCNRFZ-UHFFFAOYSA-N 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
239000003921 oil Substances 0.000 description 1
YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
HBEQXAKJSGXAIQ-UHFFFAOYSA-N oxopalladium Chemical compound [Pd]=O HBEQXAKJSGXAIQ-UHFFFAOYSA-N 0.000 description 1
229910003445 palladium oxide Inorganic materials 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
239000010695 polyglycol Substances 0.000 description 1
229920000151 polyglycol Polymers 0.000 description 1
239000004810 polytetrafluoroethylene Substances 0.000 description 1
229920001343 polytetrafluoroethylene Polymers 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
239000001103 potassium chloride Substances 0.000 description 1
235000011164 potassium chloride Nutrition 0.000 description 1
SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
229910001925 ruthenium oxide Inorganic materials 0.000 description 1
WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
238000011012 sanitization Methods 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
239000000344 soap Substances 0.000 description 1
UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 description 1
229960002218 sodium chlorite Drugs 0.000 description 1
235000019795 sodium metasilicate Nutrition 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
NJWINEJWPSVGQC-UHFFFAOYSA-M sodium;4-(7-methyloctanoyloxy)benzenesulfonate Chemical compound [Na+].CC(C)CCCCCC(=O)OC1=CC=C(S([O-])(=O)=O)C=C1 NJWINEJWPSVGQC-UHFFFAOYSA-M 0.000 description 1
OVONNAXAHAIEDF-UHFFFAOYSA-M sodium;4-benzoyloxybenzenesulfonate Chemical compound [Na+].C1=CC(S(=O)(=O)[O-])=CC=C1OC(=O)C1=CC=CC=C1 OVONNAXAHAIEDF-UHFFFAOYSA-M 0.000 description 1
MDZNLTJGGBVOAO-UHFFFAOYSA-M sodium;4-decanoyloxybenzoate Chemical compound [Na+].CCCCCCCCCC(=O)OC1=CC=C(C([O-])=O)C=C1 MDZNLTJGGBVOAO-UHFFFAOYSA-M 0.000 description 1
YJZUZSVGUFVSRA-UHFFFAOYSA-M sodium;4-nonanoyloxybenzoate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=C(C([O-])=O)C=C1 YJZUZSVGUFVSRA-UHFFFAOYSA-M 0.000 description 1
241000894007 species Species 0.000 description 1
150000005846 sugar alcohols Chemical class 0.000 description 1
150000008163 sugars Chemical class 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
239000004753 textile Substances 0.000 description 1
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
229910001887 tin oxide Inorganic materials 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
229960002622 triacetin Drugs 0.000 description 1
235000011178 triphosphate Nutrition 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
238000010626 work up procedure Methods 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L15/00—Washing or rinsing machines for crockery or tableware
- A47L15/0002—Washing processes, i.e. machine working principles characterised by phases or operational steps
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L15/00—Washing or rinsing machines for crockery or tableware
- A47L15/42—Details
- A47L15/4236—Arrangements to sterilize or disinfect dishes or washing liquids
- A47L15/4238—Arrangements to sterilize or disinfect dishes or washing liquids by using electrolytic cells
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L2601/00—Washing methods characterised by the use of a particular treatment
- A47L2601/06—Electrolysed water

Landscapes

Detergent Compositions (AREA)
Washing And Drying Of Tableware (AREA)
Water Treatment By Electricity Or Magnetism (AREA)
Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

CA2842396A 2011-09-05 2012-09-04 Procede destine a blanchir de la vaisselle dans un lave-vaisselle Abandoned CA2842396A1 (fr)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
US201161531015P	2011-09-05	2011-09-05
EP11179980.5		2011-09-05
US61/531015		2011-09-05
EP11179980		2011-09-05
PCT/EP2012/067220 WO2013034548A1 (fr)	2011-09-05	2012-09-04	Procédé destiné à blanchir de la vaisselle dans un lave-vaisselle

Publications (1)

Publication Number	Publication Date
CA2842396A1 true CA2842396A1 (fr)	2013-03-14

Family

ID=47752288

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA2842396A Abandoned CA2842396A1 (fr)	2011-09-05	2012-09-04	Procede destine a blanchir de la vaisselle dans un lave-vaisselle

Country Status (10)

Country	Link
US (1)	US20130056364A1 (fr)
EP (1)	EP2753226A1 (fr)
JP (1)	JP2014529455A (fr)
KR (1)	KR20140072064A (fr)
CN (1)	CN103781392A (fr)
BR (1)	BR112014003043A2 (fr)
CA (1)	CA2842396A1 (fr)
MX (1)	MX2014001739A (fr)
RU (1)	RU2014113179A (fr)
WO (1)	WO2013034548A1 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE102011080099A1 (de) *	2011-07-29	2013-01-31	Henkel Ag & Co. Kgaa	Wasch- oder Reinigungsmittel mit elektrochemisch aktivierbarer Mediatorverbindung
AT512689A1 (de) *	2012-03-29	2013-10-15	Pro Aqua Diamantelektroden Produktion Gmbh & Co Kg	Flüssigkeit auf der Basis von Wasser zur Verwendung als Reinigungs- und/oder Desinfektionsmittel, Substanz zur Auflösung in Wasser zur Herstellung eines Reinigungs- und/oder Desinfektionsmittels und Verfahren zur Herstellung eines Reinigungs- und/oder Desinfektionsmittels
DE102014213311A1 (de) *	2014-07-09	2016-01-14	Henkel Ag & Co. Kgaa	Neuartiges Waschverfahren mit elektrochemisch aktivierbarer Mediatorverbindung
CN104593170A (zh) *	2014-12-15	2015-05-06	深圳市中健科技产业投资有限公司	一种强碱性电解水洗衣液及其制备方法
GB2557260A (en) *	2016-12-02	2018-06-20	Reckitt Benckiser Finish Bv	Electrolytic system for automatic dishwashing
CN108852238B (zh) *	2018-06-20	2023-09-05	佛山市顺德区美的洗涤电器制造有限公司	洗碗机和控制洗碗机洗涤耗材投放的方法以及存储介质
CN108888212A (zh) *	2018-07-18	2018-11-27	浙江欧琳生活健康科技有限公司	一种洗碗机水槽水羟基预处理的方法及系统
EP3689217B1 (fr) *	2019-02-01	2024-10-09	BSH Hausgeräte GmbH	Procédé et dispositif de production d'un composé de nettoyage
DE102020103632A1 (de) *	2020-02-12	2021-08-12	Miele & Cie. Kg	Verwendung einer Komponente als Elektrolyt für eine elektrochemische Zelle, Verfahren zum Betreiben eines wasserführenden elektrischen Geräts und wasserführendes elektrisches Gerät

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO1994027970A1 (fr) *	1993-05-20	1994-12-08	The Procter & Gamble Company	Composes de blanchiment comprenant des adjuvants de blanchiment a base de benzoyl caprolactame substitue
BR0013008A (pt)	1999-08-05	2002-12-03	Steris Inc	Método e sistema de descontaminação antimicrobiana de itens
AR027014A1 (es) *	1999-12-20	2003-03-12	Procter & Gamble	Particula de acitvador de blanqueo, composicion detergente que la comrende y metodo de incremento de la hidroligancia promedio de una molecula de sal
US7015184B2 (en) *	2000-03-10	2006-03-21	Sharp Kabushiki Kaisha	Cleaning solution, and method and apparatus for cleaning using the same
US20020023847A1 (en)	2000-06-23	2002-02-28	Shinichi Natsume	Cleansing system and method using water electrolysis
DE10104470A1 (de)	2001-02-01	2002-08-08	Basf Ag	Reinigerformulierungen zur Verhinderung der Verfärbung von Kunststoffgegenständen
US6921743B2 (en) *	2001-04-02	2005-07-26	The Procter & Gamble Company	Automatic dishwashing compositions containing a halogen dioxide salt and methods for use with electrochemical cells and/or electrolytic devices
JP2003251355A (ja)	2001-12-28	2003-09-09	Omega:Kk	用水等の浄化殺菌方法と其の装置
JP2003211104A (ja) *	2002-01-28	2003-07-29	Permelec Electrode Ltd	洗浄装置
US7413637B2 (en) *	2002-05-17	2008-08-19	The Procter And Gamble Company	Self-contained, self-powered electrolytic devices for improved performance in automatic dishwashing
US20030213505A1 (en) *	2002-05-17	2003-11-20	Price Kenneth Nathan	Energy-efficient automatic dishwashing appliances
US20030213503A1 (en) *	2002-05-17	2003-11-20	The Procter & Gamble Company	Signal-based electrochemical methods for automatic dishwashing
DE10336588A1 (de)	2003-08-08	2005-02-24	Hunger, Marc, Dr.	Verfahren zu Entfernung/Entfärbung von farbigen Substanzen/Rückständen in Flüssigkeiten und von Oberflächen aller Art
AT502499B1 (de) *	2005-05-03	2007-04-15	Juan Horn	Integrierte vorrichtung zum reinigen von küchengeschirr in einer geschirrspülmaschine
GB0522658D0 (en)	2005-11-07	2005-12-14	Reckitt Benckiser Nv	Composition
DE102006037905A1 (de) *	2006-08-11	2008-02-14	Zucholl, Klaus, Dr.	Spülmaschine mit Elektrolysezelle
JP2008154656A (ja)	2006-12-21	2008-07-10	Sanyo Electric Co Ltd	洗浄装置における水再利用方法及び洗濯機
CH705830B1 (de)	2007-11-30	2013-06-14	Aonsys Technologies Ltd	Verfahren und Geschirrspüler zum Reinigen von Geschirr mit elektrolysiertem Wasser mittels oxidativen Radikalen, erzeugt durch Diamant-Elektroden.
US8371315B2 (en) *	2008-12-17	2013-02-12	Tennant Company	Washing systems incorporating charged activated liquids

2012
- 2012-09-04 JP JP2014527695A patent/JP2014529455A/ja active Pending
- 2012-09-04 WO PCT/EP2012/067220 patent/WO2013034548A1/fr not_active Ceased
- 2012-09-04 CN CN201280042900.1A patent/CN103781392A/zh active Pending
- 2012-09-04 MX MX2014001739A patent/MX2014001739A/es unknown
- 2012-09-04 CA CA2842396A patent/CA2842396A1/fr not_active Abandoned
- 2012-09-04 BR BR112014003043A patent/BR112014003043A2/pt not_active IP Right Cessation
- 2012-09-04 RU RU2014113179/12A patent/RU2014113179A/ru not_active Application Discontinuation
- 2012-09-04 KR KR1020147008127A patent/KR20140072064A/ko not_active Withdrawn
- 2012-09-04 EP EP12753512.8A patent/EP2753226A1/fr not_active Withdrawn
- 2012-09-05 US US13/604,122 patent/US20130056364A1/en not_active Abandoned

Also Published As

Publication number	Publication date
RU2014113179A (ru)	2015-10-20
BR112014003043A2 (pt)	2017-03-01
KR20140072064A (ko)	2014-06-12
EP2753226A1 (fr)	2014-07-16
JP2014529455A (ja)	2014-11-13
CN103781392A (zh)	2014-05-07
MX2014001739A (es)	2014-03-31
WO2013034548A1 (fr)	2013-03-14
US20130056364A1 (en)	2013-03-07

Legal Events

Date	Code	Title	Description
2016-10-18	FZDE	Dead	Effective date: 20160906

Publication	Publication Date	Title
US20130056364A1 (en)	2013-03-07	Method for the bleaching of kitchenware in a dishwasher
EP1506279B1 (fr)	2007-03-07	Procede de lave-vaisselle automatique
JP3317505B2 (ja)	2002-08-26	洗浄剤の製造方法および製造装置
RU2750490C2 (ru)	2021-06-28	Электролитическая система для автоматического мытья посуды
MXPA04011400A (es)	2005-02-14	Metodos electroquimicos con base en senal para el lavado automatico de platos y utensilios.
JPWO2000020549A1 (ja)	2000-12-19	洗浄剤の製造方法および製造装置
JP2008539836A (ja)	2008-11-20	食器および他の台所用品を浄化、殺菌および消毒する方法および浄化装置
US10526713B2 (en)	2020-01-07	Electrochemical enhancement of detergent alkalinity
US20130125316A1 (en)	2013-05-23	System and a Method for Washing, Cleaning, Disinfecting and Sanitizing Laundry Using Electrolytic Cell Having Boron-Doped Diamond Electrode
EP1739207A2 (fr)	2007-01-03	Dispositig et méthode de génération de péroxyde
TW200809009A (en)	2008-02-16	Electrolytic cells
CN101448980B (zh)	2011-08-24	产生过氧化氢
KR102326356B1 (ko)	2021-11-12	전기화학적으로 활성화가능한 음이온성 매개체 화합물을 포함하는 세척제 또는 세정제
JP2001254096A (ja)	2001-09-18	洗浄液及びそれを用いた洗浄装置
CN215687595U (zh)	2022-02-01	用于洗碗机的组合式槽及洗碗机
EP2550389B1 (fr)	2014-05-07	Machine, procédé et combinaison électrochimique de nettoyage de textiles ainsi qu'une balle de blanchissage electrolytique
JPH11156312A (ja)	1999-06-15	洗浄装置
US6140298A (en)	2000-10-31	Bleaching compositions based on air, uncomplexed transition metal ions and aromatic aldehydes
JPH11256192A (ja)	1999-09-21	洗浄剤
JP2001192698A (ja)	2001-07-17	洗浄液、洗浄液生成装置、及び器具洗浄装置
MXPA00005441A (en)	2001-07-03	Method and apparatus for producing cleaning agent