CA2854899A1 - Process for preparing bicomponent fibers comprising poly(trimethylene terephthalate) - Google Patents
Process for preparing bicomponent fibers comprising poly(trimethylene terephthalate) Download PDFInfo
- Publication number
- CA2854899A1 CA2854899A1 CA2854899A CA2854899A CA2854899A1 CA 2854899 A1 CA2854899 A1 CA 2854899A1 CA 2854899 A CA2854899 A CA 2854899A CA 2854899 A CA2854899 A CA 2854899A CA 2854899 A1 CA2854899 A1 CA 2854899A1
- Authority
- CA
- Canada
- Prior art keywords
- fiber
- intrinsic viscosity
- starting material
- melt
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 130
- -1 poly(trimethylene terephthalate) Polymers 0.000 title claims abstract description 42
- 229920002215 polytrimethylene terephthalate Polymers 0.000 title claims abstract description 40
- 238000004519 manufacturing process Methods 0.000 title abstract description 10
- 239000007858 starting material Substances 0.000 claims abstract description 33
- 238000000034 method Methods 0.000 claims description 37
- 230000008569 process Effects 0.000 claims description 29
- 239000000155 melt Substances 0.000 claims description 14
- 238000010791 quenching Methods 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 230000000171 quenching effect Effects 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 abstract description 13
- 230000009467 reduction Effects 0.000 abstract description 5
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 20
- 238000001542 size-exclusion chromatography Methods 0.000 description 12
- 238000009826 distribution Methods 0.000 description 11
- 238000009987 spinning Methods 0.000 description 8
- 239000008188 pellet Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 6
- 229920013627 Sorona Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 230000008602 contraction Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002074 melt spinning Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920001634 Copolyester Polymers 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- NMYFVWYGKGVPIW-UHFFFAOYSA-N 3,7-dioxabicyclo[7.2.2]trideca-1(11),9,12-triene-2,8-dione Chemical group O=C1OCCCOC(=O)C2=CC=C1C=C2 NMYFVWYGKGVPIW-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000003491 array Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000007942 carboxylates Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000013213 extrapolation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/22—Formation of filaments, threads, or the like with a crimped or curled structure; with a special structure to simulate wool
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/05—Filamentary, e.g. strands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/91—Heating, e.g. for cross linking
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D1/00—Treatment of filament-forming or like material
- D01D1/06—Feeding liquid to the spinning head
- D01D1/09—Control of pressure, temperature or feeding rate
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Multicomponent Fibers (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161561281P | 2011-11-18 | 2011-11-18 | |
| US61/561,281 | 2011-11-18 | ||
| PCT/US2012/064662 WO2013074453A2 (en) | 2011-11-18 | 2012-11-12 | Process for preparing bicomponent fibers comprising poly(trimethylene terephthalate) |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2854899A1 true CA2854899A1 (en) | 2013-05-23 |
Family
ID=47226468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2854899A Abandoned CA2854899A1 (en) | 2011-11-18 | 2012-11-12 | Process for preparing bicomponent fibers comprising poly(trimethylene terephthalate) |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20140306363A1 (de) |
| EP (1) | EP2780496A2 (de) |
| JP (1) | JP2015501887A (de) |
| KR (1) | KR20140093992A (de) |
| CN (1) | CN103930602A (de) |
| BR (1) | BR112014011864A2 (de) |
| CA (1) | CA2854899A1 (de) |
| TW (1) | TW201326485A (de) |
| WO (1) | WO2013074453A2 (de) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020006043A1 (en) * | 2018-06-28 | 2020-01-02 | Dupont Industrial Biosciences Usa, Llc | Spun yarn comprising polyester staple fibre and fabric comprising the same |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3704536B2 (ja) * | 1999-03-11 | 2005-10-12 | 帝人ファイバー株式会社 | 潜在捲縮性ポリエステル複合繊維 |
| BR0014392A (pt) * | 1999-09-30 | 2002-11-19 | Asahi Chemical Ind | Fio multifilamentar de tereftalato de politrimetileno formado de filamentos únicos, fio de tereftalato de politrimetileno texturizado de torção preliminar, fio de tereftalato de politrimetileno meio-estirado formado de filamentos únicos, e, processos para produzir os mesmos |
| WO2001068962A2 (en) * | 2000-03-15 | 2001-09-20 | Shell Internationale Research Maatschappij B.V. | Poly(trimethylene) terephthalate textile staple production |
| JP3885468B2 (ja) * | 2000-08-10 | 2007-02-21 | 東レ株式会社 | 嵩高性ポリエステル系複合糸およびその製造方法ならびに布帛 |
| CN1243861C (zh) * | 2001-02-02 | 2006-03-01 | 旭化成株式会社 | 后加工性能优良的复合纤维及其制造方法 |
| US6846560B2 (en) * | 2002-05-27 | 2005-01-25 | Asahi Kasei Kabushiki Kaisha | Conjugate fiber and method of producing same |
| US6641916B1 (en) * | 2002-11-05 | 2003-11-04 | E. I. Du Pont De Nemours And Company | Poly(trimethylene terephthalate) bicomponent fibers |
| MXPA04012278A (es) | 2002-12-23 | 2005-02-25 | Du Pont | Proceso de fibra bicomponente de poli(tereftalato de trimetileno). |
| US7357985B2 (en) * | 2005-09-19 | 2008-04-15 | E.I. Du Pont De Nemours And Company | High crimp bicomponent fibers |
-
2012
- 2012-11-12 KR KR1020147016177A patent/KR20140093992A/ko not_active Withdrawn
- 2012-11-12 JP JP2014542365A patent/JP2015501887A/ja active Pending
- 2012-11-12 US US14/358,184 patent/US20140306363A1/en not_active Abandoned
- 2012-11-12 WO PCT/US2012/064662 patent/WO2013074453A2/en not_active Ceased
- 2012-11-12 EP EP12791385.3A patent/EP2780496A2/de not_active Withdrawn
- 2012-11-12 CA CA2854899A patent/CA2854899A1/en not_active Abandoned
- 2012-11-12 CN CN201280055503.8A patent/CN103930602A/zh active Pending
- 2012-11-12 BR BR112014011864A patent/BR112014011864A2/pt not_active Application Discontinuation
- 2012-11-13 TW TW101142156A patent/TW201326485A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013074453A3 (en) | 2013-09-19 |
| JP2015501887A (ja) | 2015-01-19 |
| CN103930602A (zh) | 2014-07-16 |
| KR20140093992A (ko) | 2014-07-29 |
| WO2013074453A2 (en) | 2013-05-23 |
| US20140306363A1 (en) | 2014-10-16 |
| EP2780496A2 (de) | 2014-09-24 |
| TW201326485A (zh) | 2013-07-01 |
| BR112014011864A2 (pt) | 2017-05-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |
Effective date: 20161114 |