CA2889342C - Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree - Google Patents

Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree Download PDF

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Publication number
CA2889342C
CA2889342C CA2889342A CA2889342A CA2889342C CA 2889342 C CA2889342 C CA 2889342C CA 2889342 A CA2889342 A CA 2889342A CA 2889342 A CA2889342 A CA 2889342A CA 2889342 C CA2889342 C CA 2889342C
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Prior art keywords
manganese
ions
electrolytic cell
solution
iii
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CA2889342A
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English (en)
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CA2889342A1 (fr
Inventor
Trevor Pearson
Terence Clarke
Roshan V. Chapaneri
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MacDermid Acumen Inc
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Priority claimed from US13/677,798 external-priority patent/US9752241B2/en
Application filed by MacDermid Acumen Inc filed Critical MacDermid Acumen Inc
Priority to CA3056665A priority Critical patent/CA3056665A1/fr
Publication of CA2889342A1 publication Critical patent/CA2889342A1/fr
Application granted granted Critical
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/042—Electrodes formed of a single material
    • C25B11/043—Carbon, e.g. diamond or graphene
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/22—Roughening, e.g. by etching
    • C23C18/24—Roughening, e.g. by etching using acid aqueous solutions
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/21—Manganese oxides
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1646—Characteristics of the product obtained
    • C23C18/165—Multilayered product
    • C23C18/1653—Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating

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  • Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Chemically Coating (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

L'invention concerne une cellule électrolytique et un procédé d'oxydation électrochimique d'ions de manganèse (II) vers des ions de manganèse (III) dans la cellule électrolytique. La cellule électrolytique comprend (1) une solution d'électrolyte d'ions de manganèse (II) dans une solution de 9 à 15 moles par litre d'acide sulfurique ; (2) une cathode immergée dans la solution d'électrolyte ; et (3) une anode immergée dans la solution d'électrolyte et espacée de la cathode. Divers matériaux d'anode sont décrits y compris le carbone vitreux, le carbone vitreux réticulé, et les fibres de carbone tissées.
CA2889342A 2012-11-15 2013-09-26 Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree Active CA2889342C (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA3056665A CA3056665A1 (fr) 2012-11-15 2013-09-26 Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/677,798 US9752241B2 (en) 2012-01-23 2012-11-15 Electrolytic generation of manganese (III) ions in strong sulfuric acid using an improved anode
US13/677,798 2012-11-15
PCT/US2013/061860 WO2014077957A1 (fr) 2012-11-15 2013-09-26 Génération électrolytique d'ions de manganèse (iii) dans l'acide sulfurique fort à l'aide d'une anode améliorée

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CA3056665A Division CA3056665A1 (fr) 2012-11-15 2013-09-26 Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree

Publications (2)

Publication Number Publication Date
CA2889342A1 CA2889342A1 (fr) 2014-05-22
CA2889342C true CA2889342C (fr) 2019-11-12

Family

ID=50731593

Family Applications (2)

Application Number Title Priority Date Filing Date
CA3056665A Abandoned CA3056665A1 (fr) 2012-11-15 2013-09-26 Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree
CA2889342A Active CA2889342C (fr) 2012-11-15 2013-09-26 Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CA3056665A Abandoned CA3056665A1 (fr) 2012-11-15 2013-09-26 Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree

Country Status (12)

Country Link
EP (1) EP2920341B1 (fr)
JP (1) JP6060270B2 (fr)
KR (2) KR101950169B1 (fr)
CN (1) CN104838044B (fr)
BR (1) BR112015011123B1 (fr)
CA (2) CA3056665A1 (fr)
ES (1) ES2704672T3 (fr)
MX (1) MX2015006178A (fr)
PL (1) PL2920341T3 (fr)
TR (1) TR201900116T4 (fr)
TW (1) TWI500582B (fr)
WO (1) WO2014077957A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
HUE045344T2 (hu) * 2013-03-12 2019-12-30 Macdermid Acumen Inc Mangán(III)-ionok elõállítása elektrolitikai úton erõs kénsavban
US11047052B2 (en) 2014-07-10 2021-06-29 Okuno Chemical Industries Co., Ltd. Resin plating method
CN107078291A (zh) * 2014-08-28 2017-08-18 英克罗恩有限公司 结晶过渡氧化物颗粒及制备该结晶过渡氧化物颗粒的连续方法
US10889905B2 (en) * 2018-12-11 2021-01-12 Rohm And Haas Electronic Materials Llc Methods of generating manganese (III) ions in mixed aqueous acid solutions using ozone

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US3065155A (en) * 1960-09-02 1962-11-20 Manganese Chemicals Corp Electrolytic manganese dioxide process
AT310285B (de) 1966-02-22 1973-09-25 Photocircuits Corp Verfahren zur Herstellung eines Schichtkörpers für gedruckte Schaltungen
US4042729A (en) 1972-12-13 1977-08-16 Kollmorgen Technologies Corporation Process for the activation of resinous bodies for adherent metallization
IT1159931B (it) * 1978-10-13 1987-03-04 Oronzio De Nora Impianti Procedimento industriale per la produzione di biossido di titanio da ilmenite
US4279705A (en) * 1980-02-19 1981-07-21 Kerr-Mcgee Corporation Process for oxidizing a metal of variable valence by constant current electrolysis
IT1132194B (it) * 1980-07-15 1986-06-25 Anic Spa Processo elettrochimico per la sintesi di composti organici
JPS58502027A (ja) * 1981-11-23 1983-11-24 バロ−ス・コ−ポレ−ション 低デ−タ転送率の直列入出力インタ−フェイスをモニタするようにされた周辺装置
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JPS6447890A (en) * 1987-08-13 1989-02-22 Kenzo Yamaguchi Electrolytic synthesis method
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GB9714275D0 (en) * 1997-07-08 1997-09-10 Ciba Geigy Ag Oxidation process
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US10260000B2 (en) * 2012-01-23 2019-04-16 Macdermid Acumen, Inc. Etching of plastic using acidic solutions containing trivalent manganese

Also Published As

Publication number Publication date
CA3056665A1 (fr) 2014-05-22
PL2920341T3 (pl) 2019-05-31
CN104838044A (zh) 2015-08-12
CA2889342A1 (fr) 2014-05-22
JP6060270B2 (ja) 2017-01-11
CN104838044B (zh) 2017-12-05
BR112015011123A2 (pt) 2017-07-11
TWI500582B (zh) 2015-09-21
JP2016504492A (ja) 2016-02-12
ES2704672T3 (es) 2019-03-19
MX2015006178A (es) 2015-11-06
KR20170039315A (ko) 2017-04-10
EP2920341A4 (fr) 2016-04-27
KR20150082636A (ko) 2015-07-15
EP2920341B1 (fr) 2018-11-14
TW201431793A (zh) 2014-08-16
KR101950169B1 (ko) 2019-02-20
WO2014077957A1 (fr) 2014-05-22
BR112015011123B1 (pt) 2021-08-03
TR201900116T4 (tr) 2019-01-21
EP2920341A1 (fr) 2015-09-23

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CA2889342C (fr) Generation electrolytique d'ions de manganese (iii) dans l'acide sulfurique fort a l'aide d'une anode amelioree
US10246788B2 (en) Electrolytic generation of manganese (III) ions in strong sulfuric acid using an improved anode

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