CA2895253C - Procede et systeme de production d'acide oxalique, et produits de la reduction de l'acide oxalique - Google Patents

Procede et systeme de production d'acide oxalique, et produits de la reduction de l'acide oxalique Download PDF

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Publication number
CA2895253C
CA2895253C CA2895253A CA2895253A CA2895253C CA 2895253 C CA2895253 C CA 2895253C CA 2895253 A CA2895253 A CA 2895253A CA 2895253 A CA2895253 A CA 2895253A CA 2895253 C CA2895253 C CA 2895253C
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Prior art keywords
oxalic acid
region
oxalate
electrochemical cell
cathode
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CA2895253A
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English (en)
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CA2895253A1 (fr
Inventor
Kyle Teamey
Jerry J. Kaczur
Emily Barton Cole
Narayanappa Sivasankar
Paul Majsztrik
George Leonard
Rishi Parajuli
Kate A. Keets
Theodore J. KRAMER
Robert Farrauto
Robert Augustine
Setrak Tanielyan
Mohanreddy KASIREDDY
Yizu Zhu
Zbigniew Twardowski
Farah DHUN
Alexander Bauer
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Avantium Knowledge Centre BV
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Avantium Knowledge Centre BV
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Priority claimed from US13/724,996 external-priority patent/US8691069B2/en
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Publication of CA2895253A1 publication Critical patent/CA2895253A1/fr
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/24—Halogens or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/081—Supplying products to non-electrochemical reactors that are combined with the electrochemical cell, e.g. Sabatier reactor
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/083—Separating products
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/085—Removing impurities
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/087—Recycling of electrolyte to electrochemical cell
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/07—Oxygen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C25B3/26—Reduction of carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/05—Pressure cells
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/13—Single electrolytic cells with circulation of an electrolyte
    • C25B9/15—Flow-through cells
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La présente invention concerne un procédé et un système de production d'acide oxalique, ainsi que des produits de la réduction de l'acide oxalique. La production d'acide oxalique et les produits de la réduction de l'acide oxalique peuvent comprendre la conversion électrochimique de CO2 en oxalate et en acide oxalique. Le procédé et le système de production d'acide oxalique, et les produits de la réduction de l'acide oxalique peuvent également comprendre l'acidification de l'oxalate en acide oxalique, la purification de l'acide oxalique et l'hydrogénation de l'acide oxalique afin d'obtenir des produits de la réduction de l'acide oxalique.
CA2895253A 2012-12-21 2013-12-23 Procede et systeme de production d'acide oxalique, et produits de la reduction de l'acide oxalique Active CA2895253C (fr)

Applications Claiming Priority (13)

Application Number Priority Date Filing Date Title
US201261745204P 2012-12-21 2012-12-21
US61/745,204 2012-12-21
US13/724,996 US8691069B2 (en) 2012-07-26 2012-12-21 Method and system for the electrochemical co-production of halogen and carbon monoxide for carbonylated products
US13/724,996 2012-12-21
US201361794230P 2013-03-15 2013-03-15
US61/794,230 2013-03-15
US201361816531P 2013-04-26 2013-04-26
US61/816,531 2013-04-26
US201361844755P 2013-07-10 2013-07-10
US61/844,755 2013-07-10
US201361846944P 2013-07-16 2013-07-16
US61/846,944 2013-07-16
PCT/US2013/077610 WO2014100828A1 (fr) 2012-12-21 2013-12-23 Procédé et système de production d'acide oxalique, et produits de la réduction de l'acide oxalique

Publications (2)

Publication Number Publication Date
CA2895253A1 CA2895253A1 (fr) 2014-06-26
CA2895253C true CA2895253C (fr) 2022-03-01

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA2895253A Active CA2895253C (fr) 2012-12-21 2013-12-23 Procede et systeme de production d'acide oxalique, et produits de la reduction de l'acide oxalique

Country Status (3)

Country Link
EP (1) EP2935654B1 (fr)
CA (1) CA2895253C (fr)
WO (1) WO2014100828A1 (fr)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012166997A2 (fr) 2011-05-31 2012-12-06 Clean Chemistry, Llc Réacteur électrochimique et procédé associé
US9517955B2 (en) 2012-09-07 2016-12-13 Clean Chemistry, Llc System and method for generation of point of use reactive oxygen species
WO2016037149A1 (fr) 2014-09-04 2016-03-10 Clean Chemistry, Inc. Procédé de traitement de l'eau au moyen d'une solution oxydante de péracétate
CA2981034C (fr) 2015-03-26 2024-06-25 Clean Chemistry, Inc. Systemes et procedes de reduction d'une population bacterienne dans de l'eau a teneur elevee en sulfure d'hydrogene
EP3386925B1 (fr) 2015-12-07 2025-03-05 Clean Chemistry, Inc. Procédés de lutte microbienne
US10883224B2 (en) 2015-12-07 2021-01-05 Clean Chemistry, Inc. Methods of pulp fiber treatment
KR101750279B1 (ko) 2016-07-20 2017-06-23 서강대학교산학협력단 이산화탄소의 전기화학적 전환 시스템
US11136714B2 (en) 2016-07-25 2021-10-05 Clean Chemistry, Inc. Methods of optical brightening agent removal
EP3625283B1 (fr) 2017-05-18 2025-05-07 Avantium Knowledge Centre B.V. Copolymère de polyester
EP3625284B1 (fr) 2017-05-18 2025-05-07 Avantium Knowledge Centre B.V. Copolymère de polyester
US11311012B1 (en) 2017-09-07 2022-04-26 Clean Chemistry, Inc. Bacterial control in fermentation systems
US11001864B1 (en) 2017-09-07 2021-05-11 Clean Chemistry, Inc. Bacterial control in fermentation systems
EP3536823A1 (fr) 2018-03-05 2019-09-11 Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO Procédé de réduction électrochimique de dioxyde de carbone
US20200010964A1 (en) * 2018-07-06 2020-01-09 Yusif Abdullayev Methods of and systems for electrochemical reduction of substrates
KR20210094600A (ko) 2018-11-22 2021-07-29 아반티움 놀리지 센터 비.브이. 하나 이상의 폴리에스터 공중합체의 제조방법, 하나 이상의 올리고머, 올리고머 조성물 및 폴리에스터 공중합체의 제조방법
CN116020536B (zh) * 2021-10-26 2025-09-26 中石化石油工程技术服务股份有限公司 一种Mo基催化剂及其制备方法和用于含油污泥油品催化热解反应中的应用
CN114921800B (zh) * 2022-06-16 2023-10-31 肯特催化材料股份有限公司 一种四丙基氢氧化铵的制备方法及其制备的四丙基氢氧化铵水溶液

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69027304T2 (de) * 1989-01-17 1997-01-23 Davy Process Technology Ltd., London Kontinuierliches Verfahren zur Herstellung von Carbonsäureestern
WO1993017151A1 (fr) * 1992-02-22 1993-09-02 Hoechst Aktiengesellschaft Procede electrochimique de preparation d'acide glyoxylique
TW200911693A (en) * 2007-06-12 2009-03-16 Solvay Aqueous composition containing a salt, manufacturing process and use
US20110114502A1 (en) 2009-12-21 2011-05-19 Emily Barton Cole Reducing carbon dioxide to products
EP3595066A3 (fr) * 2010-03-18 2020-04-01 Blacklight Power, Inc. Système électrique électrochimique à catalyseur d'hydrogène
CN101879448B (zh) * 2010-06-24 2012-05-23 天津大学 用于草酸酯加氢制乙二醇的规整结构催化剂及其制备方法
WO2012166997A2 (fr) * 2011-05-31 2012-12-06 Clean Chemistry, Llc Réacteur électrochimique et procédé associé
EP2729601B1 (fr) 2011-07-06 2018-05-09 Avantium Knowledge Centre B.V. Réduction de dioxyde de carbone en acide oxalique, et hydration de celui-ci

Also Published As

Publication number Publication date
EP2935654A4 (fr) 2016-07-06
WO2014100828A1 (fr) 2014-06-26
CA2895253A1 (fr) 2014-06-26
EP2935654A1 (fr) 2015-10-28
EP2935654B1 (fr) 2018-02-28

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