CA2895253C - Procede et systeme de production d'acide oxalique, et produits de la reduction de l'acide oxalique - Google Patents

Procede et systeme de production d'acide oxalique, et produits de la reduction de l'acide oxalique Download PDF

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Publication number
CA2895253C
CA2895253C CA2895253A CA2895253A CA2895253C CA 2895253 C CA2895253 C CA 2895253C CA 2895253 A CA2895253 A CA 2895253A CA 2895253 A CA2895253 A CA 2895253A CA 2895253 C CA2895253 C CA 2895253C
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Canada
Prior art keywords
oxalic acid
region
oxalate
electrochemical cell
cathode
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Active
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CA2895253A
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English (en)
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CA2895253A1 (fr
Inventor
Kyle Teamey
Jerry J. Kaczur
Emily Barton Cole
Narayanappa Sivasankar
Paul Majsztrik
George Leonard
Rishi Parajuli
Kate A. Keets
Theodore J. KRAMER
Robert Farrauto
Robert Augustine
Setrak Tanielyan
Mohanreddy KASIREDDY
Yizu Zhu
Zbigniew Twardowski
Farah DHUN
Alexander Bauer
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Avantium Knowledge Centre BV
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Avantium Knowledge Centre BV
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Priority claimed from US13/724,996 external-priority patent/US8691069B2/en
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Publication of CA2895253A1 publication Critical patent/CA2895253A1/fr
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Publication of CA2895253C publication Critical patent/CA2895253C/fr
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/24—Halogens or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/081—Supplying products to non-electrochemical reactors that are combined with the electrochemical cell, e.g. Sabatier reactor
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/083—Separating products
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/085—Removing impurities
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/087—Recycling of electrolyte to electrochemical cell
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/07—Oxygen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C25B3/26—Reduction of carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/05—Pressure cells
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/13—Single electrolytic cells with circulation of an electrolyte
    • C25B9/15—Flow-through cells
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La présente invention concerne un procédé et un système de production d'acide oxalique, ainsi que des produits de la réduction de l'acide oxalique. La production d'acide oxalique et les produits de la réduction de l'acide oxalique peuvent comprendre la conversion électrochimique de CO2 en oxalate et en acide oxalique. Le procédé et le système de production d'acide oxalique, et les produits de la réduction de l'acide oxalique peuvent également comprendre l'acidification de l'oxalate en acide oxalique, la purification de l'acide oxalique et l'hydrogénation de l'acide oxalique afin d'obtenir des produits de la réduction de l'acide oxalique.
CA2895253A 2012-12-21 2013-12-23 Procede et systeme de production d'acide oxalique, et produits de la reduction de l'acide oxalique Active CA2895253C (fr)

Applications Claiming Priority (13)

Application Number Priority Date Filing Date Title
US201261745204P 2012-12-21 2012-12-21
US61/745,204 2012-12-21
US13/724,996 2012-12-21
US13/724,996 US8691069B2 (en) 2012-07-26 2012-12-21 Method and system for the electrochemical co-production of halogen and carbon monoxide for carbonylated products
US201361794230P 2013-03-15 2013-03-15
US61/794,230 2013-03-15
US201361816531P 2013-04-26 2013-04-26
US61/816,531 2013-04-26
US201361844755P 2013-07-10 2013-07-10
US61/844,755 2013-07-10
US201361846944P 2013-07-16 2013-07-16
US61/846,944 2013-07-16
PCT/US2013/077610 WO2014100828A1 (fr) 2012-12-21 2013-12-23 Procédé et système de production d'acide oxalique, et produits de la réduction de l'acide oxalique

Publications (2)

Publication Number Publication Date
CA2895253A1 CA2895253A1 (fr) 2014-06-26
CA2895253C true CA2895253C (fr) 2022-03-01

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA2895253A Active CA2895253C (fr) 2012-12-21 2013-12-23 Procede et systeme de production d'acide oxalique, et produits de la reduction de l'acide oxalique

Country Status (3)

Country Link
EP (1) EP2935654B1 (fr)
CA (1) CA2895253C (fr)
WO (1) WO2014100828A1 (fr)

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* Cited by examiner, † Cited by third party
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US9551076B2 (en) 2011-05-31 2017-01-24 Clean Chemistry, Inc. Electrochemical reactor and process
US20170107128A1 (en) 2012-09-07 2017-04-20 Clean Chemistry, Inc. System and method for generation of reactive oxygen species and applications thereof
US10259729B2 (en) 2014-09-04 2019-04-16 Clean Chemistry, Inc. Systems and method of water treatment utilizing reactive oxygen species and applications thereof
CA2981034C (fr) 2015-03-26 2024-06-25 Clean Chemistry, Inc. Systemes et procedes de reduction d'une population bacterienne dans de l'eau a teneur elevee en sulfure d'hydrogene
EP3386948B1 (fr) 2015-12-07 2025-03-05 Clean Chemistry, Inc. Procédés de traitement de fibres de pâte à papier
US10883224B2 (en) 2015-12-07 2021-01-05 Clean Chemistry, Inc. Methods of pulp fiber treatment
KR101750279B1 (ko) 2016-07-20 2017-06-23 서강대학교산학협력단 이산화탄소의 전기화학적 전환 시스템
US11136714B2 (en) 2016-07-25 2021-10-05 Clean Chemistry, Inc. Methods of optical brightening agent removal
JP7159213B2 (ja) 2017-05-18 2022-10-24 アバンティウム・ナレッジ・センター・ベー・フェー ポリエステルコポリマー
US11548980B2 (en) 2017-05-18 2023-01-10 Avantium Knowledge Centre B.V. Polyester copolymer
US11001864B1 (en) 2017-09-07 2021-05-11 Clean Chemistry, Inc. Bacterial control in fermentation systems
US11311012B1 (en) 2017-09-07 2022-04-26 Clean Chemistry, Inc. Bacterial control in fermentation systems
EP3536823A1 (fr) 2018-03-05 2019-09-11 Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO Procédé de réduction électrochimique de dioxyde de carbone
US20200010964A1 (en) * 2018-07-06 2020-01-09 Yusif Abdullayev Methods of and systems for electrochemical reduction of substrates
EP3883985A1 (fr) 2018-11-22 2021-09-29 Avantium Knowledge Centre B.V. Procédé de production d'un ou plusieurs copolymères de polyester, procédé de préparation d'un ou plusieurs oligomères, composition d'oligomère et copolymère de polyester
CN116020536B (zh) * 2021-10-26 2025-09-26 中石化石油工程技术服务股份有限公司 一种Mo基催化剂及其制备方法和用于含油污泥油品催化热解反应中的应用
CN114921800B (zh) * 2022-06-16 2023-10-31 肯特催化材料股份有限公司 一种四丙基氢氧化铵的制备方法及其制备的四丙基氢氧化铵水溶液

Family Cites Families (8)

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Publication number Priority date Publication date Assignee Title
JP2921977B2 (ja) * 1989-01-17 1999-07-19 デイヴイ・プロセス・テクノロジー・リミテッド プロセス及び装置
BR9305923A (pt) * 1992-02-22 1997-08-26 Hoechst Ag Processo eletroquimico para a preparação de ácido glioxálico
TW200911693A (en) * 2007-06-12 2009-03-16 Solvay Aqueous composition containing a salt, manufacturing process and use
US20110114502A1 (en) 2009-12-21 2011-05-19 Emily Barton Cole Reducing carbon dioxide to products
KR20180127523A (ko) * 2010-03-18 2018-11-28 브릴리언트 라이트 파워, 인크. 전기화학적 수소-촉매 전력 시스템
CN101879448B (zh) * 2010-06-24 2012-05-23 天津大学 用于草酸酯加氢制乙二醇的规整结构催化剂及其制备方法
US9551076B2 (en) * 2011-05-31 2017-01-24 Clean Chemistry, Inc. Electrochemical reactor and process
JP2014518335A (ja) 2011-07-06 2014-07-28 リキッド・ライト・インコーポレーテッド 二酸化炭素のカルボン酸、グリコール、及びカルボキシレートへの還元

Also Published As

Publication number Publication date
WO2014100828A1 (fr) 2014-06-26
EP2935654A1 (fr) 2015-10-28
CA2895253A1 (fr) 2014-06-26
EP2935654A4 (fr) 2016-07-06
EP2935654B1 (fr) 2018-02-28

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