CA2956032C - Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore - Google Patents

Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore Download PDF

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Publication number
CA2956032C
CA2956032C CA2956032A CA2956032A CA2956032C CA 2956032 C CA2956032 C CA 2956032C CA 2956032 A CA2956032 A CA 2956032A CA 2956032 A CA2956032 A CA 2956032A CA 2956032 C CA2956032 C CA 2956032C
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lithium nickel
nickel manganese
manganese cobalt
phosphorous oxide
electrode
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CA2956032A
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CA2956032A1 (fr
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Chun-Chieh Chang
Tsun Yu Chang
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Changs Ascending Enterprise Co Ltd
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Changs Ascending Enterprise Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/30—Alkali metal phosphates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1242—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)-, e.g. LiMn2O4 or Li(MxMn2-x)O4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/043—Processes of manufacture in general involving compressing or compaction
    • H01M4/0435—Rolling or calendering
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

La présente invention concerne certains modes de réalisation d'une nouvelle voie de synthèse chimique pour des applications de batterie au lithium-ion. En conséquence, divers modes de réalisation sont focalisés sur la synthèse d'un nouveau matériau actif à l'aide de NMC (oxyde de lithium-nickel-manganèse-cobalt) utilisé en tant que précurseur pour un matériau phosphate présentant une structure cristalline en couches. La formation de phosphate partiel dans le matériau structuré en couche stabilise le matériau tout en maintenant la nature à grande capacité du matériau structuré en couches. Des matériaux ayant une composition représentée par : LixNi1/4Mn1/4Co1/4P(1/4-y) O2, dans laquelle 0 = x = 1, 0,001 = y = 0,25 et par : LixX(2/3 +y)P(1/3-y)O2, dans laquelle 0 = x = 1, 0,001 = y = 0,33 et X représente le nickel ou une combinaison d'éléments métaux de transition, peuvent être préparés.
CA2956032A 2014-07-24 2014-07-24 Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore Active CA2956032C (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA3002650A CA3002650C (fr) 2014-07-24 2014-07-24 Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IB2014/001067 WO2016012823A1 (fr) 2014-07-24 2014-07-24 Synthèse et caractérisation d'oxyde de lithium-nickel-manganèse-cobalt phosphoré

Related Child Applications (1)

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CA3002650A Division CA3002650C (fr) 2014-07-24 2014-07-24 Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore

Publications (2)

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CA2956032A1 CA2956032A1 (fr) 2016-01-28
CA2956032C true CA2956032C (fr) 2019-04-16

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CA2956032A Active CA2956032C (fr) 2014-07-24 2014-07-24 Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore
CA3002650A Active CA3002650C (fr) 2014-07-24 2014-07-24 Synthese et caracterisation d'oxyde de lithium-nickel-manganese-cobalt phosphore

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KR (1) KR101884142B1 (fr)
CA (2) CA2956032C (fr)
WO (1) WO2016012823A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL235260B1 (pl) 2016-05-23 2020-06-15 Univ Jagiellonski Materiały katodowe LKMNO i sposób ich wytwarzania
CN114256451B (zh) * 2021-11-29 2024-12-13 广东邦普循环科技有限公司 一种钠离子电池正极材料及其制备方法和应用

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7799301B2 (en) * 2004-11-02 2010-09-21 Nippon Mining & Metals Co., Ltd. Cathode material for lithium secondary battery and manufacturing method thereof
WO2008054547A2 (fr) * 2006-05-31 2008-05-08 Uchicago Argonne, Llc Électrodes stabilisées en surface pour des batteries au lithium
JP5268042B2 (ja) * 2006-11-24 2013-08-21 国立大学法人九州大学 正極活物質の製造方法およびそれを用いた非水電解質電池
WO2012038412A1 (fr) * 2010-09-21 2012-03-29 Basf Se Procédé de production de matériaux d'électrode à surface modifiée
KR101475922B1 (ko) * 2012-12-27 2014-12-23 전자부품연구원 망간 인산화물이 코팅된 리튬 이차전지용 양극 활물질 및 그의 제조 방법

Also Published As

Publication number Publication date
WO2016012823A1 (fr) 2016-01-28
CA3002650C (fr) 2022-04-12
CA2956032A1 (fr) 2016-01-28
KR20170074847A (ko) 2017-06-30
KR101884142B1 (ko) 2018-07-31
CA3002650A1 (fr) 2016-01-28

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