CH100362A - Process for the preparation of an aryloxynaphthyl ketone. - Google Patents

Process for the preparation of an aryloxynaphthyl ketone.

Info

Publication number
CH100362A
CH100362A CH100362DA CH100362A CH 100362 A CH100362 A CH 100362A CH 100362D A CH100362D A CH 100362DA CH 100362 A CH100362 A CH 100362A
Authority
CH
Switzerland
Prior art keywords
ketone
carboxylic acid
act
aryloxynaphthyl
oxynaphthyl
Prior art date
Application number
Other languages
German (de)
Inventor
Gesellschaft Fuer Chemis Basel
Original Assignee
Chem Ind Basel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chem Ind Basel filed Critical Chem Ind Basel
Publication of CH100362A publication Critical patent/CH100362A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C65/32—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing keto groups
    • C07C65/40—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing keto groups containing singly bound oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/82—Ketones containing a keto group bound to a six-membered aromatic ring containing hydroxy groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

  

  Verfahren zur Herstellung eines     Aryloaynaphtylketons.       <B>Es</B> wurde gefunden,     .dass    man ein     Aryl-          oxynaphty        lketon    herstellen kann, wenn man  auf     1-Oxynaphthalin-2-carbonsäure,    mit oder  ohne Zusatz von     Verdünnungs-        bezw.    Kon  densationsmitteln, aber unter Ausschluss von       Alkalien,        2,4-Diclilorbenzotrichlorid    einwir  ken lässt.

   Die so gewonnene 1-(2' .     4'-Dichlor-          phenyl)-        l#.eton-4-oxynaphtyl    - 3 -     carbonsäure          bildet    weisse Nadeln, die bei 201 ' unter Zer  setzung schmelzen und sich in     Ätzalkalien     und in konzentrierter Schwefelsäure mit gel  ber Farbe     lösen.     



       Beispiel:     26,4 Teile     2,4-Dichlorbenzotrichlorid    und  <B>18,8</B> Teile     1-Oxynaphtalin-2-carbonsäure    wer  den bei Zimmertemperatur in 100 Teile kon  zentrierte Schwefelsäure eingetragen und so  lange zusammen gerührt, bis sich keine Salz  säure mehr entwickelt. Hierauf giesst man in       Wasser,    filtriert die ausgeschiedene 1-(2' . 4'       I)ieliloiThenyl)-heton-4-oxynaphtyl-3=carbon-          Aure    ab und reinigt sie durch     Umkristalli-          sieren    ihres     Natriumsalzes.  



  Process for the production of an aryloaynaphthyl ketone. It has been found that an aryl oxynaphthalene ketone can be produced if one uses 1-oxynaphthalene-2-carboxylic acid, with or without the addition of diluent or. 2,4-diclilobenzotrichloride can act as condensation agents, but with the exclusion of alkalis.

   The 1- (2 '. 4'-dichlorophenyl) - l # .eton-4-oxynaphthyl - 3 - carboxylic acid obtained in this way forms white needles which melt at 201' with decomposition and are incorporated into caustic alkalis and concentrated sulfuric acid dissolve yellow over color.



       Example: 26.4 parts of 2,4-dichlorobenzotrichloride and 18.8 parts of 1-oxynaphthalene-2-carboxylic acid are added to 100 parts of concentrated sulfuric acid at room temperature and stirred together until none Hydrochloric acid more developed. It is then poured into water, the precipitated 1- (2 '. 4' I) ieliloiThenyl) -hetone-4-oxynaphthyl-3-carbonic acid is filtered off and purified by recrystallizing its sodium salt.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines Aryl- oxynaphtylketons, der 1-(2' . 4'-Dichlorphe- nyl)-keton-4-oxynaphtyl-3 - carbonsäure, da durch gekennzeichnet, dass man auf 1-Oxy- naplitalin-2-carbonsäure unter Ausschluss von Alkalien 2,4-Dichlorbenzotrichlorid einwir ken lässt. PATENT CLAIM: A process for the production of an aryl oxynaphthyl ketone, the 1- (2 '. 4'-dichlorophenyl) -ketone-4-oxynaphthyl-3-carboxylic acid, characterized in that 1-oxynaplitalin-2- carboxylic acid with the exclusion of alkalis 2,4-dichlorobenzotrichloride can act Die 1-(2'. 4'-Dichlorphenyl)-heton- 4-naphtyl-3-carbonsäure bildet weisse Nadeln, die bei 261' unter Zersetzung schmelzen und sieh in Ätzalkalien und in konzentrierter Schwefelsäure mit gelber Farbe lösen. UNTERANSPRüCHE: 1.. Verfahren gemäss Patentanspruch, dadurch gekennzeichnet, dass man 2,4-Dichlorbenzo- trichorid mit Zusatz von Verdünnungsmit teln einwirken lässt. 2. 1- (2 ', 4'-dichlorophenyl) -hetone-4-naphthyl-3-carboxylic acid forms white needles which melt at 261' with decomposition and dissolve in caustic alkalis and in concentrated sulfuric acid with a yellow color. SUBClaims: 1 .. Process according to patent claim, characterized in that 2,4-dichlorobenzotrichoride is allowed to act with the addition of diluents. 2. Verfahren gemäss Patentanspruch, dadurch gekennzeichnet, dass man 2,4-Dichlorbenzo- trichlorid mit Zusatz von Kondensations mitteln einwirken lässt. Process according to patent claim, characterized in that 2,4-dichlorobenzotrichloride is allowed to act with the addition of condensation agents.
CH100362D 1921-09-24 1921-09-24 Process for the preparation of an aryloxynaphthyl ketone. CH100362A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH98559T 1921-09-24
CH100362T 1921-09-24

Publications (1)

Publication Number Publication Date
CH100362A true CH100362A (en) 1923-07-16

Family

ID=25705433

Family Applications (1)

Application Number Title Priority Date Filing Date
CH100362D CH100362A (en) 1921-09-24 1921-09-24 Process for the preparation of an aryloxynaphthyl ketone.

Country Status (1)

Country Link
CH (1) CH100362A (en)

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