CH136837A - Process for the preparation of a vat dye. - Google Patents
Process for the preparation of a vat dye.Info
- Publication number
- CH136837A CH136837A CH136837DA CH136837A CH 136837 A CH136837 A CH 136837A CH 136837D A CH136837D A CH 136837DA CH 136837 A CH136837 A CH 136837A
- Authority
- CH
- Switzerland
- Prior art keywords
- preparation
- dye
- mol
- works
- vat dye
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 7
- 238000002360 preparation method Methods 0.000 title claims description 4
- 239000000984 vat dye Substances 0.000 title description 3
- KHUFHLFHOQVFGB-UHFFFAOYSA-N 1-aminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2N KHUFHLFHOQVFGB-UHFFFAOYSA-N 0.000 claims description 3
- 229920000742 Cotton Polymers 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 239000011230 binding agent Substances 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 238000004043 dyeing Methods 0.000 claims 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- 239000000975 dye Substances 0.000 description 4
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Darstellung eines Küpenfarbstoffes. Im Hauptpatent ist ein Verfahren zur Darstellung eines Küpenfarbstoffes be schrieben, bei dem man Monohalogendibenz- anthron mit 1 - Aminoanthrachinon um setzt.
Es wurde nun gefunden, da.ss man eben falls einen neuen wertvollen güpenfarbstoff erhält, wenn man 1 Mol. 6. 6' - Dihalogen- isodibenzanthron, mit 2 Mol. 1 - Aminoan- thrachinon umsetzt. Hierbei kann man in Gegenwart von Verdünnungsmitteln, Ka talysatoren und säurebindenden Mitteln ar beiten.
Der neue Farbstoff löst sich in konzen trierter Schwefelsäure mit grüner Farbe und liefert auf Baumwolle aus rotstichig- bläuer Küpe violette, hervorragend echte Färbungen, deren vorzügliche Wasch- und Beuchechtheit besonders zu erwähnen ist, und die beim Befeuchten mit Wasser die Farbe nicht ändern, <I>Beispiel:
</I> 61,5 Teile 6,6' - Dibromisodibenzanthron (dargestellt nach dem Schweizer - Patent 120711) werden in 1000 Teilen Nitrobenzol mit 50 Teilen Natriumacetat, 7 Teilen Kup feracetat und 50 Teilen 1- Aminoanthrachi- non solange unter Rühren gekocht, bis keine Zunahme der Farbstoffbildung mehr zu be obachten ist. Dann arbeitet man wie üblich auf.
Process for the preparation of a vat dye. In the main patent, a process for the preparation of a vat dye is described in which one sets monohalodibenzanthrone with 1 - aminoanthraquinone.
It has now been found that a new valuable high-quality dye is also obtained if 1 mole of 6,6'-dihalo-isodibenzanthrone is reacted with 2 moles of 1-aminoanthrachinone. Here you can work in the presence of diluents, Ka catalysts and acid-binding agents ar.
The new dye dissolves in concentrated sulfuric acid with a green color and, on cotton from a reddish-tinged blue vat, produces violet, extremely real dyes, whose excellent wash and touch fastness deserves special mention, and which do not change color when moistened with water, < I> Example:
</I> 61.5 parts of 6,6 '- dibromoisodibenzanthrone (represented according to the Swiss patent 120711) are boiled with stirring in 1000 parts of nitrobenzene with 50 parts of sodium acetate, 7 parts of copper acetate and 50 parts of 1-aminoanthraquinone until no increase in dye formation can be observed. Then you work up as usual.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE136837X | 1927-06-09 | ||
| CH134945T | 1928-06-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH136837A true CH136837A (en) | 1929-11-30 |
Family
ID=25712404
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH136837D CH136837A (en) | 1927-06-09 | 1928-06-01 | Process for the preparation of a vat dye. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH136837A (en) |
-
1928
- 1928-06-01 CH CH136837D patent/CH136837A/en unknown
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