CH140438A - Process for improving the corrosion resistance of fittings made of magnesium alloys. - Google Patents

Process for improving the corrosion resistance of fittings made of magnesium alloys.

Info

Publication number
CH140438A
CH140438A CH140438DA CH140438A CH 140438 A CH140438 A CH 140438A CH 140438D A CH140438D A CH 140438DA CH 140438 A CH140438 A CH 140438A
Authority
CH
Switzerland
Prior art keywords
improving
corrosion resistance
magnesium alloys
fittings made
bichromate
Prior art date
Application number
Other languages
German (de)
Inventor
Aktiengesellsc Farbenindustrie
Original Assignee
Ig Farbenindustrie Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ig Farbenindustrie Ag filed Critical Ig Farbenindustrie Ag
Publication of CH140438A publication Critical patent/CH140438A/en

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  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Description

  

  Verfahren zur Verbesserung der     Korrosionsbeständigkeit    von     Formstücken     aus     Nagnesiumlegierungen.       Werkstücke aus hochprozentigen     Magne-          siumlegierungen    besitzen häufig     oberflächliche     Verunreinigungen, welche zu einer beschleu  nigten Korrosion Veranlassung geben. So zum  Beispiel sind     Gussstücke    mit einer     Gusshaut     überzogen, welche leicht angreifbare Verbin  dungen des Magnesiums enthält.

   Gepresste,  gewalzte oder durch andere Mittel verformte  Teile haben häufig eine Haut, welche Eisen  und verkohlte organische Produkte enthält,  durch deren Gegenwart selbst nur in Spuren  wahrscheinlich infolge der Bildung von Lokal  elementen die korrodierende Wirkung der  angreifenden Substanzen erhöht wird.  



  Es ist gefunden worden, dass diese Unbe  ständigkeit gegen Korrosion, zum Beispiel  im Falle der     Gussstücke,    beseitigt werden  kann, wenn diese in einer wässerigen Lösung  von     Bicbromaten    (beispielsweise mit bis etwa  100     gr        Cr07t    im Liter) einige Zeit, beispiels  weise eine oder mehrere Stunden, gekocht    werden. Es lässt sich diese Oberflächenbe  handlung noch durch eine     Vorbehandlung     der Stücke in verdünnter beispielsweise  10      /oiger    Salpetersäure verbessern, durch  welche die     Gusshaut    zunächst blank -gebeizt  und von verschiedenen vom Giessen in den  Sandformen herstammenden Verunreinigungen  befreit wird.  



  Im Falle der durch Walzen, Pressen,       Spritzguss    und andere Mittel verformten Werk  stücke aus diesen Legierungen können eben  falls die Oberflächen durch Behandlung mit  dem kochenden     Bichromatbad,    welchem ge  gebenenfalls eine Vorbeize mit Salpetersäure  vorausgegangen ist, in einen gegen den An  griff von wässerigen Lösungen aussergewöhn  lich beständigen Zustand übergeführt werden.  Die durch die     Bichromatbehandlung    entste  hende veränderte Oberfläche weist ausserdem  die vorteilhafte Eigenschaft auf, aufgetragene  Lackschichten dauerhaft festzuhalten.



  Process for improving the corrosion resistance of fittings made of magnesium alloys. Workpieces made of high-percentage magnesium alloys often have superficial impurities, which give rise to accelerated corrosion. For example, castings are covered with a casting skin that contains easily attackable compounds of magnesium.

   Pressed, rolled or deformed parts by other means often have a skin which contains iron and carbonized organic products, the presence of which, even in traces, probably increases the corrosive effect of the attacking substances as a result of the formation of local elements.



  It has been found that this resistance to corrosion, for example in the case of castings, can be eliminated if they are in an aqueous solution of bicbromatics (for example with up to about 100 gr Cr07t per liter) for some time, for example one or more Hours to be cooked. This surface treatment can be improved by pretreating the pieces in dilute, for example, 10% nitric acid, by means of which the casting skin is initially pickled and freed from various impurities resulting from the casting in the sand molds.



  In the case of workpieces made of these alloys by rolling, pressing, injection molding and other means, the surfaces can also be treated with a boiling bichromate bath, which may have been preceded by pre-pickling with nitric acid, to protect them from attack by aqueous solutions be transferred to a stable state. The changed surface resulting from the bichromate treatment also has the advantageous property of permanently retaining applied layers of lacquer.

 

Claims (1)

PATENTANSPRUCH: Verfahren zur Verbesserung der Korrosions beständigkeit von Formstücken aus Magrre- siumlegierungen, dadurch gekennzeichnet, dass die Formstücke in einer wässerigen Lösung von Bichromat während mindestens einer Stunde gekocht werden. UNTERANSPRUCH: Verfahren nach Patentanspruch, dadurch gekennzeichnet, dass man die Formstücke vor der Lochung in der Bichromatlösung einer Beizung mit verdünnter Salpetersäure unter wirft. PATENT CLAIM: Process for improving the corrosion resistance of molded pieces made of magnesium alloys, characterized in that the molded pieces are boiled in an aqueous solution of bichromate for at least one hour. SUBSTANTIAL CLAIM: Process according to patent claim, characterized in that the shaped pieces are subjected to pickling with dilute nitric acid in the bichromate solution before the perforation.
CH140438D 1928-02-02 1929-01-08 Process for improving the corrosion resistance of fittings made of magnesium alloys. CH140438A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE140438X 1928-02-02

Publications (1)

Publication Number Publication Date
CH140438A true CH140438A (en) 1930-06-15

Family

ID=5668225

Family Applications (1)

Application Number Title Priority Date Filing Date
CH140438D CH140438A (en) 1928-02-02 1929-01-08 Process for improving the corrosion resistance of fittings made of magnesium alloys.

Country Status (1)

Country Link
CH (1) CH140438A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE745042C (en) * 1940-08-03 1944-02-24 Ig Farbenindustrie Ag Surface protection of magnesium alloys

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE745042C (en) * 1940-08-03 1944-02-24 Ig Farbenindustrie Ag Surface protection of magnesium alloys

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