CH145306A - Process for the preparation of a nitrated mono-methyl-4.5.8.9-dibenzpyrene-3.10-quinone. - Google Patents
Process for the preparation of a nitrated mono-methyl-4.5.8.9-dibenzpyrene-3.10-quinone.Info
- Publication number
- CH145306A CH145306A CH145306DA CH145306A CH 145306 A CH145306 A CH 145306A CH 145306D A CH145306D A CH 145306DA CH 145306 A CH145306 A CH 145306A
- Authority
- CH
- Switzerland
- Prior art keywords
- dibenzpyrene
- methyl
- quinone
- mono
- nitrated
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 7
- 238000002360 preparation method Methods 0.000 title description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 230000000802 nitrating effect Effects 0.000 claims description 3
- 229920000742 Cotton Polymers 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 claims description 2
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Darstellung eines nitrierten Kono-methyl-l. <B>5 S.</B> 9-dibenzpyren- 3. 10-chinon. Gegenstand dieses Patentes ist ein Ver fahren zur Darstellung eines nitrierten Mono- metllyl-4. <B>5. 8.</B> 9-dibenzpyren-3. 10-eliinon, welches dadurch gekennzeielinet ist, dass man Mono-methyl-4. <B>5.
8.</B> 9-dibenzpyren-3. 10- chinon mit einem nitrierenden Mittel behan delt, gegebenenfalls in Gegenwart eines Ver dünnungsmittels und unter Erwärmen.
<I>Beispiel:</I> <B>9-0</B> Gewichtsteile Mono-metliyl-4. <B>5 . 8 -</B> 9- dibenzpyren-3 <B>.</B> 10-eliinon folgender Konsti- tutioli.
EMI0001.0022
werden mit<B>150</B> Gewichtsteilen konzentrierter Salpetersäure zunächst bei gewöhnlicher Temperatur verrührt. Das sich zunächst ab scheidende Nitroprodukt wird durch Erwär men in Lösung gebracht, worauf beim Erkal ten alles gelöst bleibt. -Man. gibt nun auf Wasser und isoliert das in gelben Flocken ab--eschiedene Produkt.
Es kristallisiert aus Nitrabenzol in gelben Nadeln und löst sich in konzentrierter Schwefelsäure mit braunroter Farbe. Bei der Reduktion erhält man eine orangerote Hydrosulfitk-iipe., aus welcher Baumwolle in olivgrünen Tönen angefärbt wird. Die Verbindung kann als Ausgangs material zur Herstellung von Küpenfarbstof- fen Verwendung finden.
Process for the preparation of a nitrated Kono-methyl-l. 5s. 9-dibenzpyrene-3. 10-quinone. The subject of this patent is a process for the preparation of a nitrated monometlyl-4. <B> 5. 8. 9-dibenzpyrene-3. 10-eliinon, which is characterized in that one mono-methyl-4. <B> 5.
8. 9-dibenzpyrene-3. 10-quinone treated with a nitrating agent, if necessary in the presence of a diluent and with heating.
<I> Example: </I> <B> 9-0 </B> parts by weight of mono-methyl-4. <B> 5. 8 - </B> 9- dibenzpyrene-3 <B>. </B> 10-eliinon of the following constituents.
EMI0001.0022
are initially stirred with <B> 150 </B> parts by weight of concentrated nitric acid at ordinary temperature. The nitro product which initially separates is brought into solution by heating, whereupon everything remains dissolved when it cools. -Man. now puts on water and isolates the product, which has separated out in yellow flakes.
It crystallizes from nitrabenzene in yellow needles and dissolves in concentrated sulfuric acid with a brownish-red color. The reduction gives an orange-red hydrosulfite tube, from which cotton is dyed in olive-green tones. The compound can be used as a starting material for the production of vat dyes.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE145306X | 1928-03-16 | ||
| CH141545T | 1929-02-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH145306A true CH145306A (en) | 1931-02-15 |
Family
ID=25713847
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH145306D CH145306A (en) | 1928-03-16 | 1929-02-22 | Process for the preparation of a nitrated mono-methyl-4.5.8.9-dibenzpyrene-3.10-quinone. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH145306A (en) |
-
1929
- 1929-02-22 CH CH145306D patent/CH145306A/en unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE546228C (en) | Process for the production of nitrogen-containing Kuepen dyes | |
| DE548616C (en) | Process for the preparation of Kuepen dyes of the 1íñ2íñ2'íñ1'-anthraquinonazine series | |
| DE525331C (en) | Process for the production of new Kuepen dyes | |
| DE867725C (en) | Process for the production of Kuepen dyes | |
| DE682820C (en) | Process for the production of Kuepen dyes | |
| DE891901C (en) | Process for the production of sulfur-containing compounds of the acedianthrone series | |
| DE578322C (en) | Process for the production of Kuepen dyes | |
| DE952901C (en) | Process for the preparation of 1-aminobenzophenonesulfone-2-aldehydes or ketones | |
| DE225132C (en) | ||
| DE439614C (en) | Process for the preparation of Kuepen dyes of the anthraquinone series | |
| CH145301A (en) | Process for the preparation of mononitro-3.4.8.9-dibenzpyrene-5.10-quinone. | |
| CH264603A (en) | Process for the preparation of a halogenated compound of the naphthoquinone imine series. | |
| CH145304A (en) | Process for the preparation of trinitro-4.5.8.9-dybenzpyrene-3.10-quinone. | |
| CH238636A (en) | Process for the production of a vat dye. | |
| CH154422A (en) | Process for the preparation of a dye. | |
| CH178964A (en) | Process for the preparation of a dye of the pyrene series. | |
| CH141545A (en) | Process for the preparation of mononitro-4.5.8.9-dibenzpyrene-3.10-quinone. | |
| CH247609A (en) | Process for the production of a vat dye. | |
| CH238635A (en) | Process for the production of a vat dye. | |
| CH261858A (en) | Process for the preparation of an anthraquinone dye. | |
| CH146858A (en) | Process for the preparation of a vat dye of the benzanthrone pyrazole anthrone series. | |
| CH145305A (en) | Method for the preparation of nitro-dibromo-3.4.8.9-dibenzpyrene-5.10-quinone. | |
| CH150183A (en) | Process for the preparation of a vat dye of the benzanthrone pyrazole anthrone series. | |
| CH96874A (en) | Process for the manufacture of a mass intended to serve as a mastic or a conglomerate, starting from the residual liquor from the treatment of wood by the sulphite method. | |
| CH148996A (en) | Process for the production of an etch-resistant dye of the gallocyanin series. |