CH156014A - Process for the manufacture of a nitrogenous product. - Google Patents
Process for the manufacture of a nitrogenous product.Info
- Publication number
- CH156014A CH156014A CH156014DA CH156014A CH 156014 A CH156014 A CH 156014A CH 156014D A CH156014D A CH 156014DA CH 156014 A CH156014 A CH 156014A
- Authority
- CH
- Switzerland
- Prior art keywords
- product
- chlorine
- manufacture
- solution
- water
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims description 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 title claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 3
- 235000020778 linoleic acid Nutrition 0.000 claims description 3
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000013067 intermediate product Substances 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000004753 textile Substances 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- BFRDVOMJFPXZPX-UHFFFAOYSA-N C(CCCCCCCC=C/CCCCCCCC)(=O)O.[Cl] Chemical compound C(CCCCCCCC=C/CCCCCCCC)(=O)O.[Cl] BFRDVOMJFPXZPX-UHFFFAOYSA-N 0.000 description 1
- QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical compound ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 230000009435 amidation Effects 0.000 description 1
- 238000007112 amidation reaction Methods 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Herstellung eines stickstoffhaltigen Produktes. Vorliegendes Patent bezieht sich auf ein Verfahren zur Darstellung eines stickstoffhal tigen Produktes, dadurch gekennzeichnet, dass man eine Hexachlorleinölsäure, die man durch Einwirkung von Chlor auf Leinölsäure bis zum Eintritt von 6 Chloratomen erhält, mit einer Lösung von Ammoniak in einem orga nischen Lösungsmittel erhitzt.
Das neue Produkt stellt ein hellbraunes in Wasser und verdünnten Säuren lösliches Öl dar. <I>Beispiel:</I> 24,5 kg einer durch Chlorieren von 14 kg Leinölsäure mit 10,5 kg Chlor erhältlichen Chlorleinölsäure werden mit einer Lösung von 14 kg Ammoniak in 100 kg gewöhnlichem, ungefähr 95 %igem Alkohol 3 Stunden bei einem Druck von etwa 20 Atmosphären auf 140-150 o erhitzt. Nach dem Erkalten erhält man eine klare alkoholische Lösung der ent standenen Base, die von dem ausgeschiedenen Chlorammonium abfiltriert wird. Nach dem Abdestillieren des Alkohols erhält man ein hellbraunes, in Wasser und verdünnten Säuren lösliches Öl.
Das neue Produkt stellt eine ungesättigte freie Aminochlorfettsäure dar und enthält im Molekül anscheinend zwei Aminogruppen, zwei Chloratome und eine Doppelbindung. Eine Veresterung bezw. Ami- dierung der Carboxylgruppe ist hier nicht oder in nur sehr geringem Masse erfolgt. Das Öl wird aus der wässerigen Lösung durch Zusatz von Lauge ausgesalzen und geht durch Verdünnen mit Wasser wieder in Lösung.
Es soll als Textilhilfsmittel und als Zwi schenprodukt zur Herstellung Breiterer tech nisch wertvoller Verbindungen Verwendung finden.
Process for the manufacture of a nitrogenous product. The present patent relates to a process for the preparation of a nitrogen-containing product, characterized in that a hexachloreinoleic acid, which is obtained by the action of chlorine on linoleic acid until 6 chlorine atoms enter, is heated with a solution of ammonia in an organic solvent.
The new product is a light brown oil that is soluble in water and dilute acids. <I> Example: </I> 24.5 kg of a chlorine oleic acid obtained by chlorinating 14 kg of linoleic acid with 10.5 kg of chlorine are mixed with a solution of 14 kg Ammonia in 100 kg of common, approximately 95% alcohol, heated to 140-150 o for 3 hours at a pressure of about 20 atmospheres. After cooling, a clear alcoholic solution of the base formed is obtained, which is filtered off from the chlorammonium which has separated out. After the alcohol has been distilled off, a light brown oil is obtained which is soluble in water and dilute acids.
The new product is an unsaturated free aminochloro fatty acid and apparently contains two amino groups, two chlorine atoms and a double bond in the molecule. An esterification resp. Amidation of the carboxyl group has not taken place here or has only taken place to a very small extent. The oil is salted out from the aqueous solution by adding lye and redissolving by diluting it with water.
It should be used as a textile auxiliary and as an inter mediate product for the production of broader technically valuable compounds.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE156014X | 1929-01-14 | ||
| CH151959T | 1930-01-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH156014A true CH156014A (en) | 1932-07-15 |
Family
ID=25715912
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH156014D CH156014A (en) | 1929-01-14 | 1930-01-06 | Process for the manufacture of a nitrogenous product. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH156014A (en) |
-
1930
- 1930-01-06 CH CH156014D patent/CH156014A/en unknown
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