CH192044A - Process for the production of a new azo dye. - Google Patents
Process for the production of a new azo dye.Info
- Publication number
- CH192044A CH192044A CH192044DA CH192044A CH 192044 A CH192044 A CH 192044A CH 192044D A CH192044D A CH 192044DA CH 192044 A CH192044 A CH 192044A
- Authority
- CH
- Switzerland
- Prior art keywords
- azo dye
- new azo
- production
- dye
- blue
- Prior art date
Links
- 239000000987 azo dye Substances 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 4
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 239000002253 acid Substances 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 6
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 4
- 150000008049 diazo compounds Chemical class 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 210000002268 wool Anatomy 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000000664 diazo group Chemical class [N-]=[N+]=[*] 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- DMLAVOWQYNRWNQ-UHFFFAOYSA-N azobenzene Chemical compound C1=CC=CC=C1N=NC1=CC=CC=C1 DMLAVOWQYNRWNQ-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B33/00—Disazo and polyazo dyes of the types A->K<-B, A->B->K<-C, or the like, prepared by diazotising and coupling
- C09B33/02—Disazo dyes
- C09B33/08—Disazo dyes in which the coupling component is a hydroxy-amino compound
- C09B33/10—Disazo dyes in which the coupling component is a hydroxy-amino compound in which the coupling component is an amino naphthol
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
Verfahren zur Herstellung eines neuen Azofarbstoffes. Es wurde gefunden, dass man einen neuen Azofarbstoff erhält, wenn man die Diazover- bindung des 1-Arninobenzol-4-nitr,o-2-methyl- sulfons in saurem Medium mit 1-Arnirro-8- oxyrraphthalirr-3,6-disulfonsäur-e vereinigt und diesen so erhältlichen Farbstoff in alkalischem Medium mit Diazobenzol umsetzt.
Der neue Azofarbstoff bildet ein dunkles Pulver, das sich in Wasser mit blauer Farbe löst und Wolle aus saurem Bade in blauschwarzen Tönen von guten Echtheitseigenschaften färbt.. <I>Beispiel:</I> 21,6 Teile 1-Amirrobenzol-4-nitro-2-methyl- sulforr werden fein pulverisiert und nach be kannten Methoden in konz. Schwefelsäure tnit 7 Teilen Natriunrnitrit diazotiert. Diese Diazolösung trägt man in Eiswasser ein und gibt unter Rühren 31,9 Teile fein gefällter 1-Amitro-8-oxynaphthalirt-3,6-disulfonsäure zu und rührt ca.
3 Stunden bei gewöhnlicher Temperatur. Dann trägt man das notwendige Natriumcarbonat ein und vereinigt in alka lischem Medium mit einer Diazolösung aus 9,3 Teilen Anilin, die auf bekannte Weise hergestellt wird. Der Farbstoff fällt aus lind wird abfiltriert. Durch Umlösen und Aus salzen wird er gereinigt. Nach dem Trocknen erhält man ein dunkles Pulver, das sich in Wasser mit blauer Farbe löst und Wolle aus saurem Bade blauschwarz färbt.
Process for the production of a new azo dye. It has been found that a new azo dye is obtained if the diazo compound of 1-aminobenzene-4-nitr, o-2-methyl-sulfone is used in an acidic medium with 1-amirro-8-oxyrraphthalir-3,6-disulfonic acid -e combined and this thus obtainable dye is reacted in an alkaline medium with diazobenzene.
The new azo dye forms a dark powder that dissolves in water with a blue color and dyes wool from an acid bath in blue-black shades with good fastness properties. <I> Example: </I> 21.6 parts of 1-amirrobenzene-4-nitro -2-methyl-sulforr are finely pulverized and concentrated by known methods. Sulfuric acid diazotized with 7 parts of sodium nitrite. This diazo solution is poured into ice water and 31.9 parts of finely precipitated 1-amitro-8-oxynaphthalate-3,6-disulfonic acid are added with stirring and the mixture is stirred for approx.
3 hours at ordinary temperature. Then you enter the necessary sodium carbonate and combined in alkaline medium with a diazo solution of 9.3 parts of aniline, which is prepared in a known manner. The dye precipitates and is filtered off. It is cleaned by dissolving and salting out. After drying, a dark powder is obtained which dissolves in water with a blue color and dyes wool from an acid bath blue-black.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH192044T | 1936-01-30 | ||
| CH190424T | 1936-01-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH192044A true CH192044A (en) | 1937-07-15 |
Family
ID=25721984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH192044D CH192044A (en) | 1936-01-30 | 1936-01-30 | Process for the production of a new azo dye. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH192044A (en) |
-
1936
- 1936-01-30 CH CH192044D patent/CH192044A/en unknown
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