CH194096A - Process for the preparation of a new anthraquinone dye. - Google Patents

Process for the preparation of a new anthraquinone dye.

Info

Publication number
CH194096A
CH194096A CH194096DA CH194096A CH 194096 A CH194096 A CH 194096A CH 194096D A CH194096D A CH 194096DA CH 194096 A CH194096 A CH 194096A
Authority
CH
Switzerland
Prior art keywords
preparation
dye
new
anthraquinone dye
new anthraquinone
Prior art date
Application number
Other languages
German (de)
Inventor
Sandoz Chemische Fabri Vormals
Original Assignee
Chem Fab Vormals Sandoz
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chem Fab Vormals Sandoz filed Critical Chem Fab Vormals Sandoz
Publication of CH194096A publication Critical patent/CH194096A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/50—Amino-hydroxy-anthraquinones; Ethers and esters thereof
    • C09B1/54—Amino-hydroxy-anthraquinones; Ethers and esters thereof etherified
    • C09B1/545—Anthraquinones with aliphatic, cycloaliphatic or araliphatic ether groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16—Amino-anthraquinones
    • C09B1/20—Preparation from starting materials already containing the anthracene nucleus
    • C09B1/26—Dyes with amino groups substituted by hydrocarbon radicals
    • C09B1/32—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

  

      Zusatzpatent    zum Hauptpatent Nr. 189647.    Verfahren zur Darstellung eines neuen     Anthr        achinonfarbstoffes.       Das vorliegende Verfahren betrifft die  Herstellung eines neuen     Arithrachinonfarb-          stoffes    und ist dadurch gekennzeichnet, dass  man     1-Amino-4(2',        6'-dimethylanilido-)        anthra-          chinorr-2-sulfonsäur-e    in Gegenwart von Ätz  natron mit     Glycerin    kondensiert und die er  haltene Verbindung mit Schwefelsäure be  handelt.  



  <I>Beispiel:</I>  Man löst in 100 Teilen Glycerin 10 Teile       Ätznatron    und fügt zur warmen Lösung 10  Teile des     Farbstoffes    der Formel  
EMI0001.0013     
    Nach einstündigem Rühren bei 120   lässt  man auf 80<B>0</B> abkühlen und verdünnt mit    Alkohol, worauf die Base kristallisiert aus  fällt. Sie wird gewaschen, getrocknet und  hierauf in der 5fachen Menge konzentrierter  Schwefelsäure bei<B>150</B> C gelöst. Nach kurzem  Rühren ist eine Probe vollständig wasser  löslich. Man giesst auf     Eis-Salzwassermischung,     saugt den Farbstoff ab, stellt ihn in Wasser  neutral und salzt mit Kochsalz aus.  



  Der erhaltene Farbstoff besitzt die Formel  
EMI0001.0015     
    und färbt Wolle in lebhaften rotvioletten  Tönen an.



      Additional patent to main patent no. 189647. Process for the preparation of a new anthracinone dye. The present process relates to the preparation of a new arithraquinone dye and is characterized in that 1-amino-4 (2 ', 6'-dimethylanilido) anthraquinor-2-sulfonic acid is condensed with glycerol in the presence of caustic soda and the compound he retained is treated with sulfuric acid.



  <I> Example: </I> 10 parts of caustic soda are dissolved in 100 parts of glycerine and 10 parts of the dye of the formula are added to the warm solution
EMI0001.0013
    After stirring for one hour at 120, the mixture is allowed to cool to 80 <B> 0 </B> and diluted with alcohol, whereupon the base crystallizes out. It is washed, dried and then dissolved in 5 times the amount of concentrated sulfuric acid at 150 C. A sample is completely water-soluble after brief stirring. It is poured onto a mixture of ice and salt water, the dye is suctioned off, made neutral in water and salted out with table salt.



  The dye obtained has the formula
EMI0001.0015
    and dyes wool in vivid red-violet tones.

Claims (1)

PATENTANSPRUCH: Verfahren zur Darstellung eines neuen Anthrachinonfarbstoffes, dadurch gekennzeich- net, dass man 1-Amino-4(2', 6'-diinethylanilido)- anthrachinon-2-sulfosäure in Gegenwart von Ätznatron mit Glycerin kondensiert und die erhaltene Verbindung mit Schwefelsäure be handelt. Der neue Farbstoff besitzt die Formel EMI0002.0006 und färbt Wolle in lebhaften rotvioletten Tönen an. PATENT CLAIM: Process for the preparation of a new anthraquinone dye, characterized in that 1-amino-4 (2 ', 6'-diinethylanilido) - anthraquinone-2-sulfonic acid is condensed in the presence of caustic soda with glycerol and the compound obtained is condensed with sulfuric acid acts. The new dye has the formula EMI0002.0006 and dyes wool in vivid red-violet tones.
CH194096D 1936-06-18 1936-06-18 Process for the preparation of a new anthraquinone dye. CH194096A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH189647T 1936-06-18
CH194096T 1936-06-18

Publications (1)

Publication Number Publication Date
CH194096A true CH194096A (en) 1937-11-15

Family

ID=25721823

Family Applications (1)

Application Number Title Priority Date Filing Date
CH194096D CH194096A (en) 1936-06-18 1936-06-18 Process for the preparation of a new anthraquinone dye.

Country Status (1)

Country Link
CH (1) CH194096A (en)

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