CH210973A - Process for the preparation of a urea derivative. - Google Patents
Process for the preparation of a urea derivative.Info
- Publication number
- CH210973A CH210973A CH210973DA CH210973A CH 210973 A CH210973 A CH 210973A CH 210973D A CH210973D A CH 210973DA CH 210973 A CH210973 A CH 210973A
- Authority
- CH
- Switzerland
- Prior art keywords
- urea derivative
- preparation
- water
- phosgene
- pale
- Prior art date
Links
- 150000003672 ureas Chemical class 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims description 4
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 claims description 3
- 159000000000 sodium salts Chemical class 0.000 claims description 3
- 239000004552 water soluble powder Substances 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical group NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 230000002940 repellent Effects 0.000 claims description 2
- 239000005871 repellent Substances 0.000 claims description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C309/45—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton
- C07C309/51—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton at least one of the nitrogen atoms being part of any of the groups, X being a hetero atom, Y being any atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Darstellung eines Harnstoffderivates. Gegenstand des vorliegenden Patentes ist ein Verfahren zur Herstellung eines Harn- atoffderivates der Formel
EMI0001.0004
dadurch gekennzeichnet, dass man 2-Amino- 4'-chlor - 3'- methyl-6'-isopropyl-1,1'-diphenyt- äther-4-sulfonsäure mit Phosgen umsetzt. Das neue Harnstoffderivat bildet als Natriumsalz ein helles, gut wasserlösliches Pulver, das sich zur Verwendung als Mottenschutzmittel eignet.
Beispiel: 20 Teile 2-Amiiio-4'-chlor-3'-methyl-6'- isopropyl -1,1' - dipheriyläther - 4 - sulfonsäure werden in 2"00 Teilen Wasser mit der nötigen Menge 10 o/oiger Sodalösung in Lösung ge bracht. Zu dieser Lösung gibt man 25 Teile kristallisiertes Natriumacetat hinzu und leitet bei 40-50<B>0</B> C Phosgen ein, bis eine Probe kein freies Amin mehr anzeigt.
Hierauf wird das Natriumsalz des neuen Harnstoffderivates durch Zusatz von Kochsalz abgeschieden. Es wird nach dem Abtrennen, Trocknen und Mahlen als helles, gut wasserlösliches Pulver erhalten. Die Ausbeute ist quantitativ.
Process for the preparation of a urea derivative. The present patent relates to a process for the production of a urea derivative of the formula
EMI0001.0004
characterized in that 2-amino-4'-chloro-3'-methyl-6'-isopropyl-1,1'-diphenyte ether-4-sulfonic acid is reacted with phosgene. The new urea derivative forms a pale, water-soluble powder as a sodium salt, which is suitable for use as a moth repellent.
Example: 20 parts of 2-Amiiio-4'-chloro-3'-methyl-6'-isopropyl -1,1 '- Dipheriyläther - 4 - sulfonic acid are in 2 "00 parts of water with the necessary amount of 10% soda solution in 25 parts of crystallized sodium acetate are added to this solution and phosgene is passed in at 40-50 ° C. until a sample no longer shows any free amine.
The sodium salt of the new urea derivative is then deposited by adding common salt. It is obtained as a pale, readily water-soluble powder after it has been separated off, dried and ground. The yield is quantitative.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH536047X | 1938-06-16 | ||
| CH210973T | 1938-06-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH210973A true CH210973A (en) | 1940-08-15 |
Family
ID=25724962
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH210973D CH210973A (en) | 1938-06-16 | 1938-06-16 | Process for the preparation of a urea derivative. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH210973A (en) |
-
1938
- 1938-06-16 CH CH210973D patent/CH210973A/en unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CH210972A (en) | Process for the preparation of a urea derivative. | |
| CH210970A (en) | Process for the preparation of a urea derivative. | |
| CH210967A (en) | Process for the preparation of a urea derivative. | |
| CH210966A (en) | Process for the preparation of a urea derivative. | |
| CH210969A (en) | Process for the preparation of a urea derivative. | |
| CH210963A (en) | Process for the preparation of a urea derivative. | |
| CH210965A (en) | Process for the preparation of a urea derivative. | |
| CH210971A (en) | Process for the preparation of a urea derivative. | |
| CH210964A (en) | Process for the preparation of a urea derivative. | |
| CH210968A (en) | Process for the preparation of a urea derivative. | |
| DE853380C (en) | Process for obtaining a pepper substitute | |
| AT133505B (en) | Process for the preparation of ω-Oxyacylaminobenzolarsin- or -stibinoxden or ω-Oxyacylaminobenzolarsin- or -stibinsäuren. | |
| AT131127B (en) | Process for the preparation of salts of iodomethanesulfonic acid or its homologues. | |
| AT215984B (en) | Process for the preparation of new amino-trifluorotoluene-disulfonamides | |
| AT216671B (en) | Process for the preparation of compounds of various penicillins with sulfonamides | |
| CH242493A (en) | Process for the preparation of a new benzenesulfonamide derivative. | |
| CH192762A (en) | Process for the preparation of a water-soluble dye. | |
| CH132212A (en) | Process for producing a solid diazoazo compound. | |
| CH175885A (en) | Process for the preparation of a substantive copper-containing azo dye. | |
| CH132204A (en) | Process for producing a solid diazoazo compound. | |
| CH227886A (en) | Process for the preparation of N-phenacyl-tetrahydro-p-oxazine. | |
| CH140312A (en) | Process for the preparation of a strong, durable diazo compound. | |
| CH134865A (en) | Process for the preparation of a therapeutically valuable dye preparation. | |
| CH132205A (en) | Process for producing a solid diazoazo compound. | |
| CH140318A (en) | Process for the preparation of a strong, durable diazo compound. |