CH299708A - Process for the production of a condensation product. - Google Patents

Process for the production of a condensation product.

Info

Publication number
CH299708A
CH299708A CH299708DA CH299708A CH 299708 A CH299708 A CH 299708A CH 299708D A CH299708D A CH 299708DA CH 299708 A CH299708 A CH 299708A
Authority
CH
Switzerland
Prior art keywords
condensation product
production
compound
product
chlorophenoxy
Prior art date
Application number
Other languages
German (de)
Inventor
Ag Variapat
Original Assignee
Ag Variapat
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ag Variapat filed Critical Ag Variapat
Publication of CH299708A publication Critical patent/CH299708A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/41—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton
    • C07C309/42—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton having the sulfo groups bound to carbon atoms of non-condensed six-membered aromatic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

         

      Verfahren    zur Herstellung     eines    Kondensationsproduktes.         Gegenstand    des vorliegenden Patentes ist  ein Verfahren zur Herstellung eines Kondensa  tionsproduktes der wahrscheinlichen Formel  
EMI0001.0004     
    dadurch gekennzeichnet, dass man den bei  spielsweise aus     m-Trifltiormethyl-phenyl-iso-          eya.nat    und     (2-Sulfo-4-chlor-phenoxy)-anilin     hergestellten     N-m-Trifluormethyl-phenyl-N'-2-          (2'    -     sulfo    - 4' -     ehlorphenoxy)

          -pheny    l -     harnstoff          chloriert    und das     Chlorierungsprodukt    mit  einer     Natriumverbindung    in das     Natriumsalz     überführt.  



  Als     Chlorierungsmittel    kommen beispiels  weise Chlorgas (mit oder ohne Katalysator),  Chlorkalk,     unterehlorige    Säure usw. in Frage.  



  Durch die     Chlorierung,    z.     B.    mit Chlor in       hises5ig,    werden zwei Atome Chlor in das       Molekül        eingeführt,    wobei wahrscheinlich die  Verbindung der Formel I entsteht. Diese bil  det ein weisses, in heissem Wasser klar lösliches  kristallines Pulver, das als     Mottenschutzmit-          i        e1    verwendet werden kann.

           Beispiel:     100 'feile des     N-m-Trifluormetliyl-plienyl-          N'-2-        (2'-sttlfo-4'    -     chlorphenoxy)    -     plienyl    - harn  stoffes werden in 600 Teilen Eisessig gelöst  und bei etwa 10  während einigen Stunden  mit Chlorgas gesättigt.    Der Eisessig wird zum grössten Teil ab  destilliert und der     Rückstand    mit etwa     25o/oiger     Natronlauge schwach alkalisch gestellt, wobei  die Verbindung ölig ausfällt. Die überste  hende Lösung wird     abdekantiert    und das Öl in  10 000 Teilen Wasser von 95  gelöst und mit  wenig Kohle filtriert.

   Durch Zusatz von ge  sättigter Kochsalzlösung und Stehenlassen  über Nacht wird die Verbindung in befriedi  gender Reinheit erhalten. Diese bildet ein wei  sses, in heissem Wasser klar lösliches kristal  lines Pulver.



      Process for the production of a condensation product. The present patent is a process for the preparation of a condensation product of the probable formula
EMI0001.0004
    characterized in that the Nm-trifluoromethyl-phenyl-N'-2- (2 '-) produced for example from m-trifluoromethyl-phenyl-isoeya.nat and (2-sulfo-4-chlorophenoxy) sulfo - 4 '- ehlorphenoxy)

          -pheny l - chlorinated urea and converted the chlorination product into the sodium salt with a sodium compound.



  As chlorinating agents, for example, chlorine gas (with or without a catalyst), chlorinated lime, lower chlorous acid, etc. come into question.



  By chlorination, e.g. B. with chlorine in hises5ig, two atoms of chlorine are introduced into the molecule, which probably creates the compound of formula I. This forms a white crystalline powder which is clearly soluble in hot water and which can be used as a moth repellent.

           Example: 100 'files of the N-m-trifluoromethyl-plienyl-N'-2- (2'-sttlfo-4' - chlorophenoxy) - plienyl - urea are dissolved in 600 parts of glacial acetic acid and saturated with chlorine gas at about 10 hours. Most of the glacial acetic acid is distilled off and the residue is made slightly alkaline with about 25% strength sodium hydroxide solution, the compound precipitating as an oily product. The supernatant solution is decanted off and the oil is dissolved in 10,000 parts of water at 95 and filtered with a little charcoal.

   The compound is obtained in satisfactory purity by adding saturated saline solution and leaving it to stand overnight. This forms a white crystalline powder that is clearly soluble in hot water.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines Konden sationsproduktes der wahrscheinlichen Formel EMI0001.0037 dadurch gekennzeichnet, dass man N-m-Tri- fluormethyl- phenyl-N'- 2- (2'- sulfo- 4'- chlor- phenoxy)-phenyl-harnstoff chloriert und das Chlorierungsprodukt mit einer Natriumver- bindung in das Natriumsalz überführt. PATENT CLAIM: Process for the production of a condensation product of the probable formula EMI0001.0037 characterized in that N-m-trifluoromethylphenyl-N'- 2- (2'-sulfo- 4'-chlorophenoxy) -phenyl-urea is chlorinated and the chlorination product is converted into the sodium salt with a sodium compound. Das neue Kondensationsprodukt bildet ein weisses, in heissem Wasser klar lösliches kri stallines Pulver, das als Mottenschutzmittel verwendet werden kann. . The new condensation product forms a white crystalline powder that is clearly soluble in hot water and can be used as a moth repellent. .
CH299708D 1950-04-29 1950-04-29 Process for the production of a condensation product. CH299708A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH299708T 1950-04-29

Publications (1)

Publication Number Publication Date
CH299708A true CH299708A (en) 1954-06-30

Family

ID=4490403

Family Applications (1)

Application Number Title Priority Date Filing Date
CH299708D CH299708A (en) 1950-04-29 1950-04-29 Process for the production of a condensation product.

Country Status (1)

Country Link
CH (1) CH299708A (en)

Similar Documents

Publication Publication Date Title
CH299708A (en) Process for the production of a condensation product.
DE828547C (en) Process for the production of complex salt formers
CH305313A (en) Process for the production of a condensation product.
CH305312A (en) Process for the production of a condensation product.
DE450022C (en) Process for the preparation of allylarsic acid
DE726431C (en) Process for the preparation of arylides from ª ‰ -ketone carboxylic acids
DE217477C (en)
DE1126393B (en) Process for the production of new, amphoteric, biocidal compounds
AT235853B (en) Process for the production of new thiobarbituric acids
DE713353C (en) Process for the production of aryl phenols and their aryl ethers
CH280731A (en) Process for the preparation of a copper-containing disazo dye.
CH304268A (en) Process for the production of a condensation product.
CH304262A (en) Process for the production of a condensation product.
CH270399A (en) Process for the preparation of p-amino-salicylic acid.
CH258713A (en) Process for the preparation of a substituted benzoic acid ester.
CH304261A (en) Process for the production of a condensation product.
CH304263A (en) Process for the production of a condensation product.
CH306289A (en) Process for the preparation of a piperidine derivative.
CH304265A (en) Process for the production of a condensation product.
CH304269A (en) Process for the production of a condensation product.
CH304260A (en) Process for the production of a condensation product.
CH304266A (en) Process for the production of a condensation product.
CH358418A (en) Process for the preparation of unsubstituted alkyl mercuri salts with lower alkyl radicals
CH548402A (en) PROCESS FOR THE PREPARATION OF 3-METHOXY-2-SULFANILAMIDOPYRAZINE.
DE1034640B (en) Process for the production of orotic acid