CH483374A - Bulk material for filling cavities and processes for their manufacture - Google Patents
Bulk material for filling cavities and processes for their manufactureInfo
- Publication number
- CH483374A CH483374A CH1522666A CH1522666A CH483374A CH 483374 A CH483374 A CH 483374A CH 1522666 A CH1522666 A CH 1522666A CH 1522666 A CH1522666 A CH 1522666A CH 483374 A CH483374 A CH 483374A
- Authority
- CH
- Switzerland
- Prior art keywords
- binder
- grains
- material according
- bulk material
- foam
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 8
- 239000013590 bulk material Substances 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000011230 binding agent Substances 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- 239000006260 foam Substances 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 239000003822 epoxy resin Substances 0.000 claims description 4
- 239000004794 expanded polystyrene Substances 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 239000008187 granular material Substances 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 230000001419 dependent effect Effects 0.000 claims 1
- 239000004033 plastic Substances 0.000 claims 1
- 239000011257 shell material Substances 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 description 6
- 229920002223 polystyrene Polymers 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000009413 insulation Methods 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000006004 Quartz sand Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/14—Arrangements for the insulation of pipes or pipe systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/20—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 for porous or cellular articles, e.g. of foam plastics, coarse-pored
- B29C67/207—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 for porous or cellular articles, e.g. of foam plastics, coarse-pored comprising impregnating expanded particles or fragments with a binder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/12—Multiple coating or impregnating
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B30/00—Compositions for artificial stone, not containing binders
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/224—Surface treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2309/00—Use of inorganic materials not provided for in groups B29K2303/00 - B29K2307/00, as reinforcement
- B29K2309/08—Glass
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Composite Materials (AREA)
- Building Environments (AREA)
- Thermal Insulation (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Description
Schüttinaterial zum Ausfüllen von Hohlräumen und Verfahren zu dessen Herstellung
Gemäss vorliegender Erfindung ist ein Schüttmaterial zum Ausfüllen von Hohlräumen zum Zwecke der Wärmeisolierung dadurch gekennzeichnet, dass es aus losen, runden Schaumstoffkörnern besteht, die je eine erhärtete Bindemittelschale mit darin eingebetteten und aussen festklebendem Feststoffpulver aufweisen.
Ein Verfahren zum Herstellen von solchem Schnittmaterial ist erfindungsgemäss dadurch gekennzeichnet, dass runde Schaumstoffkörner mit flüssigem, aushärtbarem Bindemittel bis zur vollständigen Oberflächenbenetzung und anschliessend mit Feststoffpulver bis zur vollständigen Umhüllung der Bindemittelschicht vermischt werden, worauf die Bindemittelschichten ausgehärtet werden.
Als Schaumstoffkörner werden vorzugsweise lose geblähte Polystyrolkörner verwendet. Die Hüllen bzw.
Schalen dieser Schaumstoffkörner bestehen vorzugsweise aus aushärtbarem Kunstharz, z. B. Epoxyharz mit darin eingebettetem und daran festhaftendem Mineralmehl z. B. Quarzmehl oder imprägniertem Gipsmehl oder auch Metall- z. B. Aluminiumpulver bestehen. Zum Aushärten der Bindemittelschichten ist es vorteilhaft, das im Mischprozess gewonnene, wie das unbehandelte Polystyrolkorumaterial extrem leicht bewegliche Körnermaterial einem Warmluftstrom auszusetzen. Das erfindungsgemässe Herstellungsverfahren für das Zuschlagmaterial ist in der Zeichnung beispielsweise veranschaulicht.
Es zeigen:
Fig. 1 : Ein Beispiel für die Ausführung des ersten Verfahrensschrittes, nämlich die Benetzung von geblähten Polystyrolkörnern mit härtbarer Epoxyharz-Flüssigkeit.
Fig. 2: Ein Beispiel für die Ausführung der zweiten Verfahrensstufe, nämlich die Umhüllung der vom Bindemittel benetzten Polystyrolkörnern mit pulverigem Feststoff.
Gemäss Fig. 1 werden in einen mit einem Rührwerk versehenen Mischbehälter 1 aus einem Gefäss 2 geblähte Polystyrolkörner 10 von rundlicher Form und einem Litergewicht von ca. 5-10 g eingebracht. Ihr Durchmesser wird im Mittel 36 mm betragen. Auf ca.
10-15 1 solcher Polystyrolkörner werden aus einem Gefäss 3 eine Menge von ca. 250-300 g Epoxyharz Flüssigkeit, z. B. Araldit (geschützter Name) mit vorgeschriebenem Härterzusatz zugemischt und das Ganze innig vermischt, bis alle Polystyrolkörner gleichmässig mit einer Bindemittelschicht 30 benetzt sind. Es werden je nach der Menge der zugesetzten Bindemittelflüssigkeit und je nach deren Zähigkeit dünnere oder dickere Bindemittelschichten auf den Polystyrolkörnern erzeugt.
Im Mittel soll diese Bindemittel-Schichtdicke ca.
0,08-0,25 mm betragen. Gemäss Fig. 2 wird anschliessend aus einem Sack 4 in den Mischbehälter 1 eine Menge von feinkörnigem Quarzsand 40, ev. auch von anderem Mineralsand oder auch Metallpulver, z. B.
Aluminiumpulver einer Korngrösse von 0,05-0,25 mm, d. h. etwa gleich der Dicke der Bindemittelschicht 30 beigemischt, welche ausreicht, um die mit flüssigem Bindemittel benetzten Polystyrolkörner 10 vollständig mit einer äusserlich trockenen, feinkörnigen Sandschicht 40 zu umhüllen, deren Körner einzeln im Bindemittel 30 kleben. Die Vermischung kann in einem Greifer oder Trommelmischer, beispielsweise auch in hintereinander angerodneten Behältern für die einzelnen Verfahrensschritte erfolgen. Es ergibt sich am Ende des beschriebenen Prozesses ein trockenes, leicht bewegliches Kornmaterial mit einem Litergewicht von ca. 0,1-0,15 kg.
Vorzugsweise wird dieses Material nun einem Warmluftstrom ausgesetzt, um die Aushärtung des Bindemittels zu beschleunigen. Vorzugsweise wird ein solcher Warmluftstrom von unten her in einen, solches Kornmaterial enthaltenden Behälter eingeblasen, um gleichzeitig die Körper in einem quasischwimmenden und leicht beweglichen Zustand zu halten, damit sie nicht miteinander verkleben.
Es wird dann ein loses, kugeliges Material mit dünnen, aber ziemlich stabilen Schalen gewonnen, das sich mit grossem Vorteil als Schüttmaterial zum Ausfüllen von Hohlräumen zum Zwecke der Wärmeisolierung an Stelle von Korkschrot, Ziegelschrot oder auch von Gesteinswolle und Glaswolle eignet.
Das Material nimmt praktisch kein Wasser auf, zersetzt sich auch unter ungünstigen klimatischen Verhältnissen nicht, bleibt stets lose und hat ein sehr niedriges spezifisches Gewicht und ein entsprechend geringes Wärmeleitvermögen.
PATENTANSPRÜGICHE
I. Schüttmaterial zum Ausfüllen von Hohlräumen zum Zwecke der Wärmeisolierung, dadurch gekennzeichnet, dass es aus losen, runden Schaumstoffkörnern besteht, die je eine erhärtete Bindemittelschale mit darin eingebettetem und aussen festklebendem Feststoffpulver aufweisen.
Loose material for filling cavities and processes for the manufacture thereof
According to the present invention, a bulk material for filling cavities for the purpose of thermal insulation is characterized in that it consists of loose, round foam grains, each of which has a hardened binder shell with solid powder embedded therein and adhering to the outside.
A method for producing such cutting material is characterized according to the invention in that round foam grains are mixed with liquid, curable binder until the surface is completely wetted and then with solid powder until the binder layer is completely covered, whereupon the binder layers are cured.
Loosely expanded polystyrene grains are preferably used as foam grains. The covers resp.
Shells of these foam grains are preferably made of curable synthetic resin, e.g. B. epoxy resin with embedded therein and adhering to it mineral powder z. B. quartz powder or impregnated gypsum powder or metal z. B. consist of aluminum powder. In order to harden the binder layers, it is advantageous to expose the granular material obtained in the mixing process, such as the untreated polystyrene corum material, to a stream of warm air. The manufacturing method according to the invention for the aggregate material is illustrated in the drawing, for example.
Show it:
Fig. 1: An example for the execution of the first process step, namely the wetting of expanded polystyrene grains with curable epoxy resin liquid.
Fig. 2: An example of the execution of the second process stage, namely the coating of the polystyrene grains wetted by the binder with powdery solid.
According to FIG. 1, expanded polystyrene grains 10 of round shape and a liter weight of approx. 5-10 g are introduced into a mixing container 1 provided with a stirrer from a vessel 2. Their diameter will be 36 mm on average. At approx.
10-15 1 of such polystyrene grains are from a vessel 3 an amount of about 250-300 g epoxy resin liquid, z. B. Araldit (protected name) mixed with the prescribed hardener additive and the whole intimately mixed until all polystyrene grains are evenly wetted with a binder layer 30. Depending on the amount of binder liquid added and depending on its toughness, thinner or thicker layers of binder are produced on the polystyrene grains.
On average, this binder layer thickness should be approx.
0.08-0.25 mm. According to FIG. 2, a quantity of fine-grained quartz sand 40, possibly also of other mineral sand or metal powder, e.g. B.
Aluminum powder with a grain size of 0.05-0.25 mm, i.e. H. approximately equal to the thickness of the binder layer 30, which is sufficient to completely envelop the polystyrene grains 10 wetted with liquid binder with an externally dry, fine-grained sand layer 40, the grains of which stick individually in the binder 30. The mixing can take place in a gripper or drum mixer, for example also in containers arranged one behind the other for the individual process steps. At the end of the process described, a dry, easily mobile grain material with a liter weight of approx. 0.1-0.15 kg results.
This material is then preferably exposed to a stream of hot air in order to accelerate the hardening of the binder. Such a stream of hot air is preferably blown from below into a container containing such granular material in order to simultaneously keep the bodies in a quasi-floating and easily movable state so that they do not stick to one another.
A loose, spherical material with thin but fairly stable shells is then obtained, which is suitable with great advantage as a bulk material for filling cavities for the purpose of thermal insulation instead of cork shot, brick shot or rock wool and glass wool.
The material absorbs practically no water, does not decompose even under unfavorable climatic conditions, always remains loose and has a very low specific weight and a correspondingly low thermal conductivity.
PATENT CLAIMS
I. Bulk material for filling cavities for the purpose of thermal insulation, characterized in that it consists of loose, round foam grains, each of which has a hardened binder shell with solid powder embedded therein and adhering to the outside.
Claims (1)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1522666A CH483374A (en) | 1966-07-01 | 1966-10-20 | Bulk material for filling cavities and processes for their manufacture |
| US3598672D US3598672A (en) | 1966-03-23 | 1968-08-13 | Method of producing shaped bodies of low specific gravity |
| US3723232D US3723232A (en) | 1966-03-23 | 1971-02-16 | Bdies of low specific gravity |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH960166A CH473740A (en) | 1966-07-01 | 1966-07-01 | Aggregate material for concrete and other pourable masses and methods for producing the aggregate material |
| CH1522666A CH483374A (en) | 1966-07-01 | 1966-10-20 | Bulk material for filling cavities and processes for their manufacture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH483374A true CH483374A (en) | 1969-12-31 |
Family
ID=25705044
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH1522666A CH483374A (en) | 1966-03-23 | 1966-10-20 | Bulk material for filling cavities and processes for their manufacture |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH483374A (en) |
-
1966
- 1966-10-20 CH CH1522666A patent/CH483374A/en not_active IP Right Cessation
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased |