CH642384A5 - Verfahren zur verminderung des monomergehaltes in expandierbaren perlen aus thermoplastischem material. - Google Patents

Verfahren zur verminderung des monomergehaltes in expandierbaren perlen aus thermoplastischem material. Download PDF

Info

Publication number: CH642384A5
Authority: CH; Switzerland
Prior art keywords: beads; water; polymerization; monomers; temperature
Prior art date: 1978-06-08

Application number

CH538979A

Other languages

German (de)

English (en)

Inventor

Joergen Petersen

Original Assignee

Kema Nord Ab

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-06-08

Filing date

1979-06-08

Publication date

1984-04-13

1979-06-08 Application filed by Kema Nord Ab filed Critical Kema Nord Ab

1984-04-13 Publication of CH642384A5 publication Critical patent/CH642384A5/de

Links

239000000178 monomer Substances 0.000 title claims description 44
238000000034 method Methods 0.000 title claims description 36
239000011049 pearl Substances 0.000 title claims description 11
239000012815 thermoplastic material Substances 0.000 title description 3
239000011324 bead Substances 0.000 claims description 46
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 23
238000006116 polymerization reaction Methods 0.000 claims description 22
239000004604 Blowing Agent Substances 0.000 claims description 18
239000007788 liquid Substances 0.000 claims description 16
239000000203 mixture Substances 0.000 claims description 8
239000003505 polymerization initiator Substances 0.000 claims description 6
239000002002 slurry Substances 0.000 claims description 6
229920001169 thermoplastic Polymers 0.000 claims 2
239000004416 thermosoftening plastic Substances 0.000 claims 2
239000007900 aqueous suspension Substances 0.000 claims 1
230000000379 polymerizing effect Effects 0.000 claims 1
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 12
229920000642 polymer Polymers 0.000 description 12
239000002609 medium Substances 0.000 description 9
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 8
229920001577 copolymer Polymers 0.000 description 8
238000009835 boiling Methods 0.000 description 6
238000010438 heat treatment Methods 0.000 description 6
239000003999 initiator Substances 0.000 description 6
230000000052 comparative effect Effects 0.000 description 5
238000002474 experimental method Methods 0.000 description 5
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 4
239000007789 gas Substances 0.000 description 4
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
239000002699 waste material Substances 0.000 description 4
230000000694 effects Effects 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
239000007858 starting material Substances 0.000 description 3
239000000375 suspending agent Substances 0.000 description 3
LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
239000004793 Polystyrene Substances 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
238000009792 diffusion process Methods 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
239000001282 iso-butane Substances 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 2
229920002223 polystyrene Polymers 0.000 description 2
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
238000003825 pressing Methods 0.000 description 2
150000003254 radicals Chemical class 0.000 description 2
239000000725 suspension Substances 0.000 description 2
UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
229910001870 ammonium persulfate Inorganic materials 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
230000001413 cellular effect Effects 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000008119 colloidal silica Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
150000002432 hydroperoxides Chemical class 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
238000009413 insulation Methods 0.000 description 1
231100001231 less toxic Toxicity 0.000 description 1
239000000463 material Substances 0.000 description 1
125000005397 methacrylic acid ester group Chemical group 0.000 description 1
-1 methyl isobutyl ketone peroxide Chemical class 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
229920002239 polyacrylonitrile Polymers 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052939 potassium sulfate Inorganic materials 0.000 description 1
230000002028 premature Effects 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/006—Removal of residual monomers by chemical reaction, e.g. scavenging
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)

CH538979A 1978-06-08 1979-06-08 Verfahren zur verminderung des monomergehaltes in expandierbaren perlen aus thermoplastischem material. CH642384A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
SE7806665A SE429238B (sv)	1978-06-08	1978-06-08	Sett att reducera monomerhalten i expanderbara termoplastperlor

Publications (1)

Publication Number	Publication Date
CH642384A5 true CH642384A5 (de)	1984-04-13

Family

ID=20335152

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH538979A CH642384A5 (de)	1978-06-08	1979-06-08	Verfahren zur verminderung des monomergehaltes in expandierbaren perlen aus thermoplastischem material.

Country Status (15)

Country	Link
JP (1)	JPS5835618B2 (fr)
AT (1)	AT379162B (fr)
AU (1)	AU512761B2 (fr)
BE (1)	BE876836A (fr)
CA (1)	CA1105650A (fr)
CH (1)	CH642384A5 (fr)
DE (1)	DE2923310B2 (fr)
DK (1)	DK238379A (fr)
FI (1)	FI65793C (fr)
FR (1)	FR2428057A1 (fr)
GB (1)	GB2025429B (fr)
IT (1)	IT1116551B (fr)
NL (1)	NL177497C (fr)
NO (1)	NO151663C (fr)
SE (1)	SE429238B (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4550003A (en) *	1983-12-13	1985-10-29	Asahi Kasei Kogyo Kabushiki Kaisha	Vinylidene chloride type resin expandable particles, foam particles, in-mold foam molding by use thereof and process for producing them
US10093783B2 (en)	2014-11-26	2018-10-09	Matsumoto Yushi-Seiyaku Co., Ltd.	Heat-expandable microspheres and application thereof
CN109456506A (zh) *	2018-11-07	2019-03-12	西能化工科技(上海)有限公司	低残余单体含量的热膨胀性微球及其制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1160184B (de) *	1961-08-22	1963-12-27	Oldrich Marek	Verfahren zur Herstellung von verschaeumbaren thermoplastischen Polymeren
US3425966A (en) *	1965-03-01	1969-02-04	Dow Chemical Co	Three stage suspension polymerization process for vinyl aryl monomers
FR1480502A (fr) *	1965-05-13	1967-05-12	Foster Grant Co Inc	Procédé de préparation de particules plastiques dilatables
DE2511315A1 (de) *	1975-03-19	1976-09-23	Sealed Air Corp	Verfahren zur herstellung von aufschaeumbaren styrolpolymerstueckchen
DE2734607A1 (de) *	1977-08-01	1979-02-15	Basf Ag	Verfahren zur herstellung von kugelfoermigen, expandierbaren styrolpolymerisaten

1978
- 1978-06-08 SE SE7806665A patent/SE429238B/sv not_active IP Right Cessation
- 1978-06-09 FI FI781847A patent/FI65793C/fi not_active IP Right Cessation
1979
- 1979-05-18 AU AU47200/79A patent/AU512761B2/en not_active Expired
- 1979-05-28 AT AT0386279A patent/AT379162B/de not_active IP Right Cessation
- 1979-06-06 JP JP54070017A patent/JPS5835618B2/ja not_active Expired
- 1979-06-06 NL NLAANVRAGE7904447,A patent/NL177497C/xx not_active IP Right Cessation
- 1979-06-06 IT IT49329/79A patent/IT1116551B/it active
- 1979-06-07 CA CA329,252A patent/CA1105650A/fr not_active Expired
- 1979-06-07 FR FR7914526A patent/FR2428057A1/fr active Granted
- 1979-06-07 BE BE0/195626A patent/BE876836A/fr not_active IP Right Cessation
- 1979-06-07 NO NO791908A patent/NO151663C/no unknown
- 1979-06-08 DK DK238379A patent/DK238379A/da not_active Application Discontinuation
- 1979-06-08 GB GB7920135A patent/GB2025429B/en not_active Expired
- 1979-06-08 CH CH538979A patent/CH642384A5/de not_active IP Right Cessation
- 1979-06-08 DE DE2923310A patent/DE2923310B2/de not_active Ceased

Also Published As

Publication number	Publication date
SE7806665L (sv)	1979-12-09
JPS5835618B2 (ja)	1983-08-03
NO151663C (no)	1985-05-15
FI781847A7 (fi)	1979-12-09
GB2025429B (en)	1982-12-01
AT379162B (de)	1985-11-25
CA1105650A (fr)	1981-07-21
IT1116551B (it)	1986-02-10
SE429238B (sv)	1983-08-22
NO151663B (no)	1985-02-04
DE2923310B2 (de)	1980-12-11
IT7949329A0 (it)	1979-06-06
BE876836A (fr)	1979-12-07
GB2025429A (en)	1980-01-23
FR2428057A1 (fr)	1980-01-04
ATA386279A (de)	1985-04-15
AU512761B2 (en)	1980-10-23
NL7904447A (nl)	1979-12-11
JPS54163966A (en)	1979-12-27
NL177497C (nl)	1985-10-01
FR2428057B1 (fr)	1984-09-14
NO791908L (no)	1979-12-11
AU4720079A (en)	1979-12-13
DK238379A (da)	1979-12-09
NL177497B (nl)	1985-05-01
FI65793C (fi)	1984-07-10
DE2923310A1 (de)	1979-12-13
FI65793B (fi)	1984-03-30

Legal Events

Date	Code	Title	Description
1999-06-30	PL	Patent ceased

Publication	Publication Date	Title
DE69220214T2 (de)	1997-12-04	Verfahren zur herstellung gleichförmiger makroporöser polymerperlen
DE69116804T2 (de)	1996-08-08	Expandierbare thermoplastische Mikrokugeln und ein Verfahren zu Herstellung und ihre Verwendung
DE69703742T2 (de)	2001-05-23	Verfahren zur herstellung polymerer teilchen
DE69703114T2 (de)	2001-05-03	Verfahren zur herstellung polymere teilchen
DE2744727C2 (de)	1982-03-11	Verfahren zur Herstellung von selbstvernetzten Mischpolymerisaten, von Acrylsäure und acrylsaurem Alkaliacrylat
WO2002055594A1 (fr)	2002-07-18	Polymeres styreniques expansibles contenant des particules de carbone
DE1595627B2 (de)	1979-01-18	Verfahren zur Herstellung verschäumbarer Polymerisatteilchen
DE1570238B2 (de)	1975-03-20	Verfahren zur Herstellung feinteiliger expandierbarer Styrolpolymerisate
DE1546497A1 (de)	1970-07-23	Verfahren und Zusammensetzung zum Loeschen und zur Verhuetung von Braenden in entflammbaren Fluessigkeiten
DE3129515C2 (de)	1986-07-24	Schäumbare Styrolharzmasse und Verfahren zu ihrer Herstellung
DE3921148A1 (de)	1991-01-10	Perlfoermige expandierbare styrolpolymerisate mit hohem expandiervermoegen
CH642384A5 (de)	1984-04-13	Verfahren zur verminderung des monomergehaltes in expandierbaren perlen aus thermoplastischem material.
DE2162508C3 (de)	1981-06-19	Verfahren zur Herstellung eines vernetzten, porösen Mischpolymerisates
DE1520611A1 (de)	1969-04-10	Verfahren zur Herstellung von expandierbaren Styrolmischpolymerisaten
DE1136489B (de)	1962-09-13	Verfahren zur Suspensionspolymerisation von Styrol
DE2755005C3 (de)	1982-04-22	Verfahren zur Herstellung von expandierbaren Kügelchen aus thermoplastischen Materialien
DE3325392A1 (de)	1985-01-24	Feinteilige, expandierbare styrolpolymerisate, die zur herstellung schnellentformbarer zellkoerper geeignet sind
DE1165270B (de)	1964-03-12	Verfahren zur Herstellung von feinteiligen verschaeumbaren Styrolpolymerisaten
DE3936595A1 (de)	1991-05-08	Verfahren zur herstellung von expandierbaren styrolpolymerisaten
EP1432757B1 (fr)	2011-01-19	Procede de production de polystyrene expanse
EP0642546B1 (fr)	1996-10-30	Polymerisats de styrene expansibles, a haute resistance a la deformation a chaud
DE2338133A1 (de)	1975-02-27	Verfahren zur herstellung von styrolpolymerisatteilchen
DE2953585A1 (de)	1982-02-04	Method of obtaining latexes of copolymers of butylacrylate and of 1-metacrylate-1-tertiobutylperoxyethane
DE4416863A1 (de)	1995-11-16	Expandierbare Styrolpolymerisate
DE1241976B (de)	1967-06-08	Verfahren zum Herstellen von verschaeumbaren Formmassen aus alkenylaromatischen Polymeren