CH691059A5 - Phosphorverbindungen als Stabilisatoren für Polymere. - Google Patents

Phosphorverbindungen als Stabilisatoren für Polymere. Download PDF

Info

Publication number: CH691059A5
Authority: CH; Switzerland
Prior art keywords: formula; composition; compounds; iiia; polymeric material
Prior art date: 1995-09-28

Application number

CH232896A

Other languages

German (de)

English (en)

Inventor

Dr Peter Staniek

Original Assignee

Clariant Finance Bvi Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-09-28

Filing date

1996-09-24

Publication date

2001-04-12

1996-09-24 Application filed by Clariant Finance Bvi Ltd filed Critical Clariant Finance Bvi Ltd

2001-04-12 Publication of CH691059A5 publication Critical patent/CH691059A5/de

Links

229920000642 polymer Polymers 0.000 title claims description 19
239000003381 stabilizer Substances 0.000 title description 5
150000003018 phosphorus compounds Chemical class 0.000 title 1
239000003054 catalyst Substances 0.000 claims description 37
-1 pinenyl Chemical group 0.000 claims description 37
150000001875 compounds Chemical class 0.000 claims description 33
239000000203 mixture Substances 0.000 claims description 24
239000000463 material Substances 0.000 claims description 18
238000000034 method Methods 0.000 claims description 12
XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 12
229920000098 polyolefin Polymers 0.000 claims description 12
239000007787 solid Substances 0.000 claims description 11
150000001412 amines Chemical class 0.000 claims description 8
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 6
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 6
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 6
229910052794 bromium Inorganic materials 0.000 claims description 6
229910000073 phosphorus hydride Inorganic materials 0.000 claims description 6
239000002253 acid Substances 0.000 claims description 5
125000000753 cycloalkyl group Chemical group 0.000 claims description 5
229910052736 halogen Inorganic materials 0.000 claims description 5
150000002367 halogens Chemical class 0.000 claims description 5
125000000923 (C1-C30) alkyl group Chemical group 0.000 claims description 4
239000004793 Polystyrene Substances 0.000 claims description 4
229920001577 copolymer Polymers 0.000 claims description 4
229920002223 polystyrene Polymers 0.000 claims description 4
229920002635 polyurethane Polymers 0.000 claims description 4
239000004814 polyurethane Substances 0.000 claims description 4
230000000087 stabilizing effect Effects 0.000 claims description 4
125000004400 (C1-C12) alkyl group Chemical group 0.000 claims description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
239000000654 additive Substances 0.000 claims description 3
150000001342 alkaline earth metals Chemical class 0.000 claims description 3
125000002877 alkyl aryl group Chemical group 0.000 claims description 3
150000005840 aryl radicals Chemical class 0.000 claims description 3
239000002585 base Substances 0.000 claims description 3
230000015556 catabolic process Effects 0.000 claims description 3
239000000460 chlorine Substances 0.000 claims description 3
229910052801 chlorine Inorganic materials 0.000 claims description 3
238000006731 degradation reaction Methods 0.000 claims description 3
NLFBCYMMUAKCPC-KQQUZDAGSA-N ethyl (e)-3-[3-amino-2-cyano-1-[(e)-3-ethoxy-3-oxoprop-1-enyl]sulfanyl-3-oxoprop-1-enyl]sulfanylprop-2-enoate Chemical compound CCOC(=O)\C=C\SC(=C(C#N)C(N)=O)S\C=C\C(=O)OCC NLFBCYMMUAKCPC-KQQUZDAGSA-N 0.000 claims description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 3
239000012442 inert solvent Substances 0.000 claims description 3
125000002868 norbornyl group Chemical group C12(CCC(CC1)C2)* 0.000 claims description 3
229920000728 polyester Polymers 0.000 claims description 3
LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 claims description 3
150000003512 tertiary amines Chemical class 0.000 claims description 3
125000006704 (C5-C6) cycloalkyl group Chemical group 0.000 claims description 2
239000004609 Impact Modifier Substances 0.000 claims description 2
239000004952 Polyamide Substances 0.000 claims description 2
239000012963 UV stabilizer Substances 0.000 claims description 2
239000006096 absorbing agent Substances 0.000 claims description 2
239000003513 alkali Substances 0.000 claims description 2
125000003342 alkenyl group Chemical group 0.000 claims description 2
125000004183 alkoxy alkyl group Chemical group 0.000 claims description 2
239000003963 antioxidant agent Substances 0.000 claims description 2
239000002216 antistatic agent Substances 0.000 claims description 2
125000003710 aryl alkyl group Chemical group 0.000 claims description 2
125000003118 aryl group Chemical group 0.000 claims description 2
239000003139 biocide Substances 0.000 claims description 2
125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 claims description 2
125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims description 2
GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 2
239000003822 epoxy resin Substances 0.000 claims description 2
239000000945 filler Substances 0.000 claims description 2
239000003063 flame retardant Substances 0.000 claims description 2
239000000417 fungicide Substances 0.000 claims description 2
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
229960001545 hydrotalcite Drugs 0.000 claims description 2
229910001701 hydrotalcite Inorganic materials 0.000 claims description 2
239000000314 lubricant Substances 0.000 claims description 2
239000006078 metal deactivator Substances 0.000 claims description 2
239000002667 nucleating agent Substances 0.000 claims description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
239000000049 pigment Substances 0.000 claims description 2
239000004014 plasticizer Substances 0.000 claims description 2
229920000058 polyacrylate Polymers 0.000 claims description 2
229920002647 polyamide Polymers 0.000 claims description 2
229920000647 polyepoxide Polymers 0.000 claims description 2
229920000193 polymethacrylate Polymers 0.000 claims description 2
238000002360 preparation method Methods 0.000 claims description 2
229920005573 silicon-containing polymer Polymers 0.000 claims description 2
125000001424 substituent group Chemical group 0.000 claims description 2
125000003545 alkoxy group Chemical group 0.000 claims 1
239000012968 metallocene catalyst Substances 0.000 claims 1
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
239000004743 Polypropylene Substances 0.000 description 7
229920001155 polypropylene Polymers 0.000 description 7
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
239000005977 Ethylene Substances 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
238000001125 extrusion Methods 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 5
150000003003 phosphines Chemical group 0.000 description 5
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
239000004698 Polyethylene Substances 0.000 description 4
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
238000001816 cooling Methods 0.000 description 4
229920000573 polyethylene Polymers 0.000 description 4
239000000243 solution Substances 0.000 description 4
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238000003786 synthesis reaction Methods 0.000 description 4
101100328895 Caenorhabditis elegans rol-8 gene Proteins 0.000 description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
238000000576 coating method Methods 0.000 description 3
150000001923 cyclic compounds Chemical class 0.000 description 3
239000002612 dispersion medium Substances 0.000 description 3
235000014666 liquid concentrate Nutrition 0.000 description 3
239000000155 melt Substances 0.000 description 3
238000002844 melting Methods 0.000 description 3
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229920000515 polycarbonate Polymers 0.000 description 3
238000006116 polymerization reaction Methods 0.000 description 3
229920006324 polyoxymethylene Polymers 0.000 description 3
239000000126 substance Substances 0.000 description 3
ZKVZJKGOURPMRI-UHFFFAOYSA-N 1,2,3,4-tetracyclohexyltetraphosphetane Chemical compound C1CCCCC1P1P(C2CCCCC2)P(C2CCCCC2)P1C1CCCCC1 ZKVZJKGOURPMRI-UHFFFAOYSA-N 0.000 description 2
238000005727 Friedel-Crafts reaction Methods 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
239000004594 Masterbatch (MB) Substances 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
BEIOEBMXPVYLRY-UHFFFAOYSA-N [4-[4-bis(2,4-ditert-butylphenoxy)phosphanylphenyl]phenyl]-bis(2,4-ditert-butylphenoxy)phosphane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(C=1C=CC(=CC=1)C=1C=CC(=CC=1)P(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C BEIOEBMXPVYLRY-UHFFFAOYSA-N 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
150000001558 benzoic acid derivatives Chemical class 0.000 description 2
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
235000013539 calcium stearate Nutrition 0.000 description 2
239000013078 crystal Substances 0.000 description 2
ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
150000008282 halocarbons Chemical class 0.000 description 2
239000007788 liquid Substances 0.000 description 2
150000002681 magnesium compounds Chemical class 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 2
229920001748 polybutylene Polymers 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
239000007858 starting material Substances 0.000 description 2
239000000725 suspension Substances 0.000 description 2
BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
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238000004383 yellowing Methods 0.000 description 2
HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
WPWHSFAFEBZWBB-UHFFFAOYSA-N 1-butyl radical Chemical group [CH2]CCC WPWHSFAFEBZWBB-UHFFFAOYSA-N 0.000 description 1
RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 1
WKUJXKQEUURINH-UHFFFAOYSA-N 2,4,4-trimethylpentylphosphane Chemical compound PCC(C)CC(C)(C)C WKUJXKQEUURINH-UHFFFAOYSA-N 0.000 description 1
HTTGVORJOBRXRJ-UHFFFAOYSA-N 2-(triazin-4-yl)phenol Chemical class OC1=CC=CC=C1C1=CC=NN=N1 HTTGVORJOBRXRJ-UHFFFAOYSA-N 0.000 description 1
CJMKSYKFEDJPMM-UHFFFAOYSA-N 2-hydroxy-6-phenylbenzoic acid Chemical class OC(=O)C1=C(O)C=CC=C1C1=CC=CC=C1 CJMKSYKFEDJPMM-UHFFFAOYSA-N 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
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238000003747 Grignard reaction Methods 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
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NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
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229910052698 phosphorus Inorganic materials 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
229920001643 poly(ether ketone) Polymers 0.000 description 1
229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
229920002492 poly(sulfone) Polymers 0.000 description 1
229920003251 poly(α-methylstyrene) Polymers 0.000 description 1
229920002401 polyacrylamide Polymers 0.000 description 1
229920002239 polyacrylonitrile Polymers 0.000 description 1
229920013639 polyalphaolefin Polymers 0.000 description 1
229920002312 polyamide-imide Polymers 0.000 description 1
229920001707 polybutylene terephthalate Polymers 0.000 description 1
229920006393 polyether sulfone Polymers 0.000 description 1
229920001601 polyetherimide Polymers 0.000 description 1
229920000139 polyethylene terephthalate Polymers 0.000 description 1
239000005020 polyethylene terephthalate Substances 0.000 description 1
229920001721 polyimide Polymers 0.000 description 1
229920000582 polyisocyanurate Polymers 0.000 description 1
239000011495 polyisocyanurate Substances 0.000 description 1
229920002959 polymer blend Polymers 0.000 description 1
239000004926 polymethyl methacrylate Substances 0.000 description 1
229920000306 polymethylpentene Polymers 0.000 description 1
229920001955 polyphenylene ether Polymers 0.000 description 1
229920000069 polyphenylene sulfide Polymers 0.000 description 1
229920012287 polyphenylene sulfone Polymers 0.000 description 1
229920005629 polypropylene homopolymer Polymers 0.000 description 1
229920001343 polytetrafluoroethylene Polymers 0.000 description 1
239000004810 polytetrafluoroethylene Substances 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
229920002620 polyvinyl fluoride Polymers 0.000 description 1
239000005033 polyvinylidene chloride Substances 0.000 description 1
229920002981 polyvinylidene fluoride Polymers 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
150000003336 secondary aromatic amines Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
229920002050 silicone resin Polymers 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
235000015424 sodium Nutrition 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
238000009987 spinning Methods 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
229920006305 unsaturated polyester Polymers 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/50—Phosphorus bound to carbon only
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/504—Organo-phosphines containing a P-P bond
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
- C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Molecular Biology (AREA)
Life Sciences & Earth Sciences (AREA)
Biochemistry (AREA)
General Health & Medical Sciences (AREA)
Polymers & Plastics (AREA)
Medicinal Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Compositions Of Macromolecular Compounds (AREA)
Detergent Compositions (AREA)
Polyesters Or Polycarbonates (AREA)
Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

CH232896A 1995-09-28 1996-09-24 Phosphorverbindungen als Stabilisatoren für Polymere. CH691059A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US442895P	1995-09-28	1995-09-28

Publications (1)

Publication Number	Publication Date
CH691059A5 true CH691059A5 (de)	2001-04-12

Family

ID=21710749

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH232896A CH691059A5 (de)	1995-09-28	1996-09-24	Phosphorverbindungen als Stabilisatoren für Polymere.

Country Status (7)

Country	Link
JP (1)	JPH09124672A (ja)
CH (1)	CH691059A5 (ja)
DE (1)	DE19638924A1 (ja)
ES (1)	ES2152760B1 (ja)
FR (1)	FR2739381B1 (ja)
GB (1)	GB2306478B (ja)
IT (1)	IT1285791B1 (ja)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US7083743B2 (en)	1999-12-20	2006-08-01	Clariant Finance (Bvi) Limited	Mixture of phosphanes and chromane derivatives
DE19961464A1 (de) *	1999-12-20	2001-06-21	Clariant Internat Ltd Muttenz	Mischungen aus Phosphanen und Chroman-Derivaten
TWI226351B (en)	2000-07-14	2005-01-11	Clariant Int Ltd	Synergistic mixtures of phosphorus-containing compounds for stabilizing polymers
ATE435230T1 (de) *	2002-12-04	2009-07-15	Ciba Holding Inc	Verfahren zur synthese von cycloorganylphosphanen und von di(alkali/erdalkalimetall)oligophosphandiiden
DE102004000058A1 (de) *	2004-12-01	2006-06-08	Kuraray Specialities Europe Gmbh	Organophosphin-stabilisierte Polymermischungen
WO2006120578A2 (en) *	2005-05-10	2006-11-16	Philip Morris Products S.A.	Gas phase synthesis of polyhydride phosphorus polymers
US8519035B2 (en)	2007-09-04	2013-08-27	Basf Se	Cyclic phosphines as flame retardants
ES2672250T3 (es) *	2014-03-27	2018-06-13	Basf Se	Compuestos derivados de heptafósforo como retardadores de llama
CN111225947B (zh) *	2017-10-18	2022-07-26	奥升德功能材料运营有限公司	含卤素的阻燃性聚酰胺组合物

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB859373A (en) *	1957-12-21	1961-01-18	Koppers Co Inc	Process for the preparation of organophosphines
FR1297100A (fr) *	1960-08-12	1962-06-22	American Cyanamid Co	Composés phosphorés et procédé pour leur préparation
NL268004A (ja) *	1960-08-12
JPS4843357B1 (ja) *	1970-10-13	1973-12-18
US3932318A (en) *	1973-04-18	1976-01-13	E. I. Du Pont De Nemours And Company	Chloral copolymers
US4111899A (en) *	1977-07-20	1978-09-05	The Dow Chemical Company	Heat stabilized thermoplastic resins containing compounds with phosphorus to phosphorus bonds
GB2276387B (en) *	1993-03-25	1996-10-02	Sandoz Ltd	Stabilizing polyolefins with phosphorus compounds
WO1995032231A1 (en) *	1994-05-20	1995-11-30	Asahi Kasei Kogyo Kabushiki Kaisha	Linear crystalline polyuretedione
JPH07309926A (ja) *	1994-05-20	1995-11-28	Asahi Chem Ind Co Ltd	ウレトジオン基含有ポリイソシアネートの製造方法

1996
- 1996-09-23 FR FR9611648A patent/FR2739381B1/fr not_active Expired - Fee Related
- 1996-09-23 DE DE1996138924 patent/DE19638924A1/de not_active Withdrawn
- 1996-09-24 GB GB9619916A patent/GB2306478B/en not_active Expired - Fee Related
- 1996-09-24 CH CH232896A patent/CH691059A5/de not_active IP Right Cessation
- 1996-09-26 ES ES9602032A patent/ES2152760B1/es not_active Expired - Fee Related
- 1996-09-27 JP JP25617996A patent/JPH09124672A/ja not_active Withdrawn
- 1996-09-27 IT IT96RM000662A patent/IT1285791B1/it active IP Right Grant

Also Published As

Publication number	Publication date
GB2306478A (en)	1997-05-07
FR2739381B1 (fr)	1999-06-11
ES2152760A1 (es)	2001-02-01
FR2739381A1 (fr)	1997-04-04
ES2152760B1 (es)	2001-11-01
DE19638924A1 (de)	1997-04-03
GB2306478B (en)	1998-12-09
IT1285791B1 (it)	1998-06-24
JPH09124672A (ja)	1997-05-13
GB9619916D0 (en)	1996-11-06
ITRM960662A1 (it)	1998-03-27

Legal Events

Date	Code	Title	Description
2001-04-12	NV	New agent
2005-04-15	PL	Patent ceased

Publication	Publication Date	Title
KR100452653B1 (ko)	2005-01-17	아민옥사이드안정화제조성물을함유한중합체조성물
DE69732426T2 (de)	2006-01-05	Modifizierungsmittel für polyolefine
EP0002821A1 (de)	1979-07-11	Cyclische Phosphite und mit deren Hilfe stabilisiertes organisches Material
CH686519A5 (de)	1996-04-15	Stabilisatoren fuer polymere Materialien.
DE19735255B4 (de)	2007-08-23	Synergistisches Stabilisatorgemisch auf Basis von Polyalkyl-1-oxa-diazaspirodecan-Verbindungen und dessen Verwendung
DE69418387T2 (de)	1999-12-30	Neo-Diol Phosphite als Polymer-Stabilisatoren
CH679862A5 (ja)	1992-04-30
EP0002261B1 (de)	1982-04-07	Alkylierte 2,2'-Biphenylen-phosphonite und mit deren Hilfe stabilisierte Gemische
JPH08113672A (ja)	1996-05-07	安定剤組成物
CH691059A5 (de)	2001-04-12	Phosphorverbindungen als Stabilisatoren für Polymere.
US5488079A (en)	1996-01-30	Polyolefin stabilization
JPS59213741A (ja)	1984-12-03	防炎組成物
GB2260764A (en)	1993-04-28	Stabilizing composition for polymers
EP0015237B1 (de)	1982-12-15	Homo- und Copolymerisate von Vinyläthern von Polyalkylpiperidinolen und deren Verwendung als Stabilisatoren für Kunststoffe
US6369140B1 (en)	2002-04-09	Phosphorus compounds
AU668231B2 (en)	1996-04-26	Cycloolefin polymer molding composition of improved stability to chemical degradation
GB2265377A (en)	1993-09-29	Phosphonite-hals and phosphite-hals compounds as polymer stabilizers
GB2261667A (en)	1993-05-26	Stabilized polymeric compositions
DE60114626T2 (de)	2006-06-01	Mischungen aus phosphor-enthaltenden verbindungen zur verwendung als polymerstabilsatoren
DE112004000970T5 (de)	2006-10-19	Polymerzusammensetzungen, die Stabilisatorverbindungen umfassen, welche Tricyclodecylmethylgruppen besitzen
DE69429219T2 (de)	2002-08-08	Diphosphite als Polymer-Stabilisatoren
DE4408500B4 (de)	2008-07-03	Phosporverbindungen enthaltende polyolefinische Zusammensetzungen
EP0633287B1 (en)	1997-09-10	Clarifying nucleating and/or large-improving compositions
DE69226676T2 (de)	1999-04-08	Als Stabilisatoren geeignete Polymere, Verbindungen, die sterisch gehinderte Aminogruppen enthalten, und diese enthaltende polymere Zusammensetzungen
DE69629224T2 (de)	2004-06-03	Stabilisation von Polyolefinen, die Silica-gestützten Katalysator enthalten, mittels Phosphit