CH703845B1 - Herstellung von Alumo-Phosphaten unter Rückgewinnung von Templaten. - Google Patents

Herstellung von Alumo-Phosphaten unter Rückgewinnung von Templaten. Download PDF

Info

Publication number: CH703845B1
Authority: CH; Switzerland
Prior art keywords: template; reactor; reaction mixture; water; mixture
Prior art date: 2010-09-22

Application number

CH01562/11A

Other languages

German (de)

English (en)

Other versions

CH703845A2 (de

Inventor

Silke Dr Sauerbeck

Rolf Dr Kurzhals

Dirk Täschner

Original Assignee

Süd Chemie Ip Gmbh & Co Kg

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2010-09-22

Filing date

2011-09-19

Publication date

2015-08-14

2011-09-19 Application filed by Süd Chemie Ip Gmbh & Co Kg filed Critical Süd Chemie Ip Gmbh & Co Kg

2012-03-30 Publication of CH703845A2 publication Critical patent/CH703845A2/de

2015-08-14 Publication of CH703845B1 publication Critical patent/CH703845B1/de

Links

238000011084 recovery Methods 0.000 title abstract description 10
238000004519 manufacturing process Methods 0.000 title description 8
ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical class O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 title description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 70
239000011541 reaction mixture Substances 0.000 claims abstract description 58
238000000034 method Methods 0.000 claims abstract description 36
239000000203 mixture Substances 0.000 claims abstract description 35
229910019142 PO4 Inorganic materials 0.000 claims abstract description 27
230000008569 process Effects 0.000 claims abstract description 15
229910052782 aluminium Inorganic materials 0.000 claims abstract description 14
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 14
239000010452 phosphate Substances 0.000 claims abstract description 10
239000007858 starting material Substances 0.000 claims abstract description 10
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 7
238000002360 preparation method Methods 0.000 claims abstract description 4
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 129
239000007789 gas Substances 0.000 claims description 16
239000003795 chemical substances by application Substances 0.000 claims description 13
JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 13
238000006243 chemical reaction Methods 0.000 claims description 9
RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 6
-1 hexamethylimine Chemical compound 0.000 claims description 6
PAMIQIKDUOTOBW-UHFFFAOYSA-N 1-methylpiperidine Chemical compound CN1CCCCC1 PAMIQIKDUOTOBW-UHFFFAOYSA-N 0.000 claims description 4
BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 claims description 4
NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 4
PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims description 4
JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 claims description 4
238000004821 distillation Methods 0.000 claims description 4
229910052757 nitrogen Inorganic materials 0.000 claims description 4
XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 claims description 4
RXYPXQSKLGGKOL-UHFFFAOYSA-N 1,4-dimethylpiperazine Chemical compound CN1CCN(C)CC1 RXYPXQSKLGGKOL-UHFFFAOYSA-N 0.000 claims description 3
HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 claims description 3
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 3
239000012074 organic phase Substances 0.000 claims description 3
XDIAMRVROCPPBK-UHFFFAOYSA-N 2,2-dimethylpropan-1-amine Chemical compound CC(C)(C)CN XDIAMRVROCPPBK-UHFFFAOYSA-N 0.000 claims description 2
BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 claims description 2
XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 claims description 2
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 2
UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 2
OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 claims description 2
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 claims description 2
229960001231 choline Drugs 0.000 claims description 2
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 claims description 2
WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 claims description 2
238000000605 extraction Methods 0.000 claims description 2
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 2
YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical compound O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 claims description 2
CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 claims description 2
JACMPVXHEARCBO-UHFFFAOYSA-N n-pentylpentan-1-amine Chemical compound CCCCCNCCCCC JACMPVXHEARCBO-UHFFFAOYSA-N 0.000 claims description 2
239000002798 polar solvent Substances 0.000 claims description 2
229920000768 polyamine Polymers 0.000 claims description 2
SBYHFKPVCBCYGV-UHFFFAOYSA-N quinuclidine Chemical compound C1CC2CCN1CC2 SBYHFKPVCBCYGV-UHFFFAOYSA-N 0.000 claims description 2
YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 claims description 2
IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 claims description 2
YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 claims description 2
UEYNAKVCMPHNHE-UHFFFAOYSA-M 4,4-dimethyl-4-azoniatricyclo[5.2.2.02,6]undec-8-ene hydroxide Chemical compound [OH-].C[N+]1(CC2C3C=CC(C2C1)CC3)C UEYNAKVCMPHNHE-UHFFFAOYSA-M 0.000 claims 1
125000001477 organic nitrogen group Chemical group 0.000 claims 1
239000003960 organic solvent Substances 0.000 claims 1
230000015572 biosynthetic process Effects 0.000 description 36
239000000243 solution Substances 0.000 description 34
238000003786 synthesis reaction Methods 0.000 description 31
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 30
239000010457 zeolite Substances 0.000 description 21
239000011148 porous material Substances 0.000 description 19
238000001816 cooling Methods 0.000 description 17
239000000047 product Substances 0.000 description 17
238000002441 X-ray diffraction Methods 0.000 description 15
229910052710 silicon Inorganic materials 0.000 description 15
239000000377 silicon dioxide Substances 0.000 description 15
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 14
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 14
239000010703 silicon Substances 0.000 description 14
235000012239 silicon dioxide Nutrition 0.000 description 14
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 13
229910052681 coesite Inorganic materials 0.000 description 12
229910052906 cristobalite Inorganic materials 0.000 description 12
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 12
229910052682 stishovite Inorganic materials 0.000 description 12
239000000725 suspension Substances 0.000 description 12
229910052905 tridymite Inorganic materials 0.000 description 12
229910021536 Zeolite Inorganic materials 0.000 description 11
230000000694 effects Effects 0.000 description 11
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 10
150000001768 cations Chemical class 0.000 description 10
238000001027 hydrothermal synthesis Methods 0.000 description 10
239000012535 impurity Substances 0.000 description 10
239000010936 titanium Substances 0.000 description 10
229910052719 titanium Inorganic materials 0.000 description 10
229910052725 zinc Inorganic materials 0.000 description 10
239000011701 zinc Substances 0.000 description 10
239000007795 chemical reaction product Substances 0.000 description 9
229910052804 chromium Inorganic materials 0.000 description 9
239000011651 chromium Substances 0.000 description 9
229910052759 nickel Inorganic materials 0.000 description 9
229910052802 copper Inorganic materials 0.000 description 8
239000010949 copper Substances 0.000 description 8
229910052593 corundum Inorganic materials 0.000 description 8
229910052742 iron Inorganic materials 0.000 description 8
229910001845 yogo sapphire Inorganic materials 0.000 description 8
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 7
229910052751 metal Inorganic materials 0.000 description 7
239000002184 metal Substances 0.000 description 7
229910052698 phosphorus Inorganic materials 0.000 description 7
239000011574 phosphorus Substances 0.000 description 7
239000000843 powder Substances 0.000 description 7
238000000926 separation method Methods 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
230000008901 benefit Effects 0.000 description 6
235000021317 phosphate Nutrition 0.000 description 6
239000000126 substance Substances 0.000 description 6
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
150000001412 amines Chemical class 0.000 description 5
229910017052 cobalt Inorganic materials 0.000 description 5
239000010941 cobalt Substances 0.000 description 5
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
239000013078 crystal Substances 0.000 description 5
150000002500 ions Chemical class 0.000 description 5
229910052748 manganese Inorganic materials 0.000 description 5
239000011572 manganese Substances 0.000 description 5
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
229910052909 inorganic silicate Inorganic materials 0.000 description 4
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 4
150000002739 metals Chemical class 0.000 description 4
238000000746 purification Methods 0.000 description 4
229910000831 Steel Inorganic materials 0.000 description 3
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
230000008859 change Effects 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
238000010348 incorporation Methods 0.000 description 3
229910001387 inorganic aluminate Inorganic materials 0.000 description 3
230000003993 interaction Effects 0.000 description 3
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
229910001388 sodium aluminate Inorganic materials 0.000 description 3
239000002904 solvent Substances 0.000 description 3
239000010959 steel Substances 0.000 description 3
241000269350 Anura Species 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
229910002651 NO3 Inorganic materials 0.000 description 2
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
238000013019 agitation Methods 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
238000009833 condensation Methods 0.000 description 2
230000005494 condensation Effects 0.000 description 2
239000000470 constituent Substances 0.000 description 2
125000004122 cyclic group Chemical group 0.000 description 2
239000000945 filler Substances 0.000 description 2
229910052733 gallium Inorganic materials 0.000 description 2
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
150000002466 imines Chemical class 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
239000011133 lead Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000012452 mother liquor Substances 0.000 description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
239000002245 particle Substances 0.000 description 2
238000005086 pumping Methods 0.000 description 2
230000005855 radiation Effects 0.000 description 2
239000000376 reactant Substances 0.000 description 2
230000001105 regulatory effect Effects 0.000 description 2
239000011780 sodium chloride Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000001179 sorption measurement Methods 0.000 description 2
238000003756 stirring Methods 0.000 description 2
229910052716 thallium Inorganic materials 0.000 description 2
239000002351 wastewater Substances 0.000 description 2
VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
238000004438 BET method Methods 0.000 description 1
GNVPRPSCDIEJPA-UHFFFAOYSA-N CCCCCCCC=CCC.O Chemical compound CCCCCCCC=CCC.O GNVPRPSCDIEJPA-UHFFFAOYSA-N 0.000 description 1
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
229910015818 MPO4 Inorganic materials 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
AVUYXHYHTTVPRX-UHFFFAOYSA-N Tris(2-methyl-1-aziridinyl)phosphine oxide Chemical compound CC1CN1P(=O)(N1C(C1)C)N1C(C)C1 AVUYXHYHTTVPRX-UHFFFAOYSA-N 0.000 description 1
238000005411 Van der Waals force Methods 0.000 description 1
HIVGXUNKSAJJDN-UHFFFAOYSA-N [Si].[P] Chemical group [Si].[P] HIVGXUNKSAJJDN-UHFFFAOYSA-N 0.000 description 1
239000002250 absorbent Substances 0.000 description 1
230000002745 absorbent Effects 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000002730 additional effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000001588 bifunctional effect Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
238000001354 calcination Methods 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
235000011089 carbon dioxide Nutrition 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
150000004985 diamines Chemical class 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000007710 freezing Methods 0.000 description 1
230000008014 freezing Effects 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000004128 high performance liquid chromatography Methods 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
238000005216 hydrothermal crystallization Methods 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
239000002608 ionic liquid Substances 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
229910052745 lead Inorganic materials 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
238000011068 loading method Methods 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
238000005259 measurement Methods 0.000 description 1
238000010297 mechanical methods and process Methods 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
229910001463 metal phosphate Inorganic materials 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
239000003921 oil Substances 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
125000004437 phosphorous atom Chemical group 0.000 description 1
229910001392 phosphorus oxide Inorganic materials 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000002243 precursor Substances 0.000 description 1
150000003242 quaternary ammonium salts Chemical class 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
230000003134 recirculating effect Effects 0.000 description 1
238000007670 refining Methods 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000010944 silver (metal) Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
238000005287 template synthesis Methods 0.000 description 1
DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 description 1
OSBSFAARYOCBHB-UHFFFAOYSA-N tetrapropylammonium Chemical compound CCC[N+](CCC)(CCC)CCC OSBSFAARYOCBHB-UHFFFAOYSA-N 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
239000011135 tin Substances 0.000 description 1
238000012546 transfer Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/04—Aluminophosphates [APO compounds]
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
- C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C01B39/38—Type ZSM-5
- C01B39/40—Type ZSM-5 using at least one organic template directing agent
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/54—Phosphates, e.g. APO or SAPO compounds

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
General Life Sciences & Earth Sciences (AREA)
Geology (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Materials Engineering (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)

CH01562/11A 2010-09-22 2011-09-19 Herstellung von Alumo-Phosphaten unter Rückgewinnung von Templaten. CH703845B1 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE102010046245A DE102010046245A1 (de)	2010-09-22	2010-09-22	Herstellung von Alumo-Phosphaten unter Rückgewinnung von Templaten

Publications (2)

Publication Number	Publication Date
CH703845A2 CH703845A2 (de)	2012-03-30
CH703845B1 true CH703845B1 (de)	2015-08-14

Family

ID=45768997

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH01562/11A CH703845B1 (de)	2010-09-22	2011-09-19	Herstellung von Alumo-Phosphaten unter Rückgewinnung von Templaten.

Country Status (4)

Country	Link
CH (1)	CH703845B1 (fr)
DE (1)	DE102010046245A1 (fr)
FR (1)	FR2964962A1 (fr)
NL (1)	NL2007457C2 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE102010055728A1 (de) *	2010-12-22	2012-06-28	Süd-Chemie AG	Verfahren zur Umsetzung stickstoffhaltiger Verbindungen
DE102010055729A1 (de) *	2010-12-22	2012-06-28	Süd-Chemie AG	Trocknungsvorrichtung enthaltend ein Titano-Alumo-Phosphat
EP2953896B1 (fr)	2013-02-08	2016-10-19	Chevron U.S.A. Inc.	Composition de matière de tamis moléculaire ssz-85
CN110759357B (zh) *	2018-07-25	2021-08-27	中国石油天然气股份有限公司	一种zsm-35/zsm-5共晶分子筛的合成方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4440871A (en)	1982-07-26	1984-04-03	Union Carbide Corporation	Crystalline silicoaluminophosphates
US4567029A (en)	1983-07-15	1986-01-28	Union Carbide Corporation	Crystalline metal aluminophosphates
EP0159624B1 (fr)	1984-04-13	1991-12-18	Uop	Compositions pour tamis moléculaires
US4861743A (en)	1987-11-25	1989-08-29	Uop	Process for the production of molecular sieves
US5637287A (en) *	1996-02-02	1997-06-10	Exxon Research & Engineering Company	Synthesis process for faujasite family zeolites using mother liquor recycle
JP4889865B2 (ja) *	2001-01-31	2012-03-07	住友化学株式会社	チタン含有珪素酸化物触媒の製造方法
DE102006030199A1 (de)	2006-06-30	2008-01-03	Klingenburg Gmbh	Feuchtigkeits- und/oder Wärmeaustauschvorrichtung, z.B. Plattenwärmetauscher, Sorptionsrotor, Adsorptionsentfeuchtungsrotor od.dgl.
CN101125665B (zh) *	2007-08-08	2011-07-20	华陆工程科技有限责任公司	液相晶化法制备sapo-34分子筛的方法

2010
- 2010-09-22 DE DE102010046245A patent/DE102010046245A1/de not_active Withdrawn
2011
- 2011-09-19 CH CH01562/11A patent/CH703845B1/de not_active IP Right Cessation
- 2011-09-19 FR FR1102829A patent/FR2964962A1/fr not_active Withdrawn
- 2011-09-22 NL NL2007457A patent/NL2007457C2/nl not_active IP Right Cessation

Also Published As

Publication number	Publication date
DE102010046245A1 (de)	2012-03-22
NL2007457A (nl)	2012-03-26
CH703845A2 (de)	2012-03-30
NL2007457C2 (nl)	2012-06-21
FR2964962A1 (fr)	2012-03-23

Legal Events

Date	Code	Title	Description
2012-07-13	PUE	Assignment	Owner name: SUED-CHEMIE IP GMBH & CO. KG Free format text: SUED-CHEMIE AG#LENBACHPLATZ 6#80333 MUENCHEN (DE) -TRANSFER TO- SUED-CHEMIE IP GMBH & CO. KG#LENBACHPLATZ 6#80333 MUENCHEN (DE)
2012-11-15	AZW	Rejection (application)
2013-01-15	NV	New agent	Representative=s name: STOLMAR AND PARTNER, CH
2014-07-15	PCAR	Change of the address of the representative	Free format text: NEW ADDRESS: SEEFELDSTRASSE 69, 8008 ZUERICH (CH)
2017-04-28	PL	Patent ceased

Publication	Publication Date	Title
DE69923642T2 (de)	2006-03-16	Methoden zur Herstellung von Methylaminen unter Verwendung von SAPO-34 Katalysatoren
DE69520208T3 (de)	2007-12-27	Herstellung von nicht-zeolithischen molekularsieben
DE69324668T2 (de)	1999-09-09	Verfahren zur herstellung von mikroporösen nichtzeolitischen molekularsieben
DE3873726T2 (de)	1993-04-01	Synthese-verfahren von nichtzeolitischen molekularsieben.
DE60006765T2 (de)	2004-05-19	Verfahren zur Herstellung von Zeolith des MTT-Typs mittels spezifischen Vorläufern des Strukturbildners
DE60004841T2 (de)	2004-06-09	Wärmebehandlung eines molekularsiebes und katalysator
DE60302664T2 (de)	2006-07-20	Synthese von silicoalumophosphaten
MXPA02004972A (es)	2002-09-18	Metodo para la sintesis de tamices moleculares.
US9889440B2 (en)	2018-02-13	Method for synthesizing silicoaluminophosphate-34 molecular sieves
EP1791786B1 (fr)	2017-10-18	Tamis moleculaire d'aluminophosphate, sa synthese et son utilisation
US10850267B2 (en)	2020-12-01	Preparation method for metal-modified SAPO molecular sieve
DE102014012681A1 (de)	2016-02-25	Zeolithische Materialien mit ausgeprägter Makroporosität im Einzelkristall und Verfahren zu deren Herstellung
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EP3433014A1 (fr)	2019-01-30	Fabrication d'un matériau composite à base de zéolithe avec une porosité hiérarchique
DE69210059T2 (de)	1996-09-19	Verfahren zur Herstellung von Aluminophosphatverbindungen und substituierten Derivaten von VFI-Strukturtyp
EP3183214B1 (fr)	2019-10-09	Procédé de synthèse de tamis moléculaires en silicoluminophosphate-34 en utilisant de la mono-isopropanolamine
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CH703927B1 (de)	2013-04-15	Verfahren zur Herstellung eines Silico-Alumo-Phosphats.
DE69125283T2 (de)	1997-06-26	Kristalline molekularsiebzusammensetzung
DE69207706T2 (de)	1996-06-27	Kristalline Aluminophosphate und verwandte Verbindungen
WO2010003680A1 (fr)	2010-01-14	Procédé pour produire des gallo-aluminosilicates de type zéolithiques cristallins
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