CL2020003349A1 - Derivados heterocíclicos como plaguicidas - Google Patents

Derivados heterocíclicos como plaguicidas

Info

Publication number
CL2020003349A1
CL2020003349A1 CL2020003349A CL2020003349A CL2020003349A1 CL 2020003349 A1 CL2020003349 A1 CL 2020003349A1 CL 2020003349 A CL2020003349 A CL 2020003349A CL 2020003349 A CL2020003349 A CL 2020003349A CL 2020003349 A1 CL2020003349 A1 CL 2020003349A1
Authority
CL
Chile
Prior art keywords
pesticides
heterocyclic derivatives
acaricides
insecticides
intermediates
Prior art date
Application number
CL2020003349A
Other languages
English (en)
Inventor
Kerstin Ilg
Ulrich Görgens
Rüdiger Fischer
Laura Hoffmeister
Matthieu Willot
Dominik Hager
David Wilcke
Original Assignee
Bayer Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Ag filed Critical Bayer Ag
Publication of CL2020003349A1 publication Critical patent/CL2020003349A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
    • C07D471/04—Ortho-condensed systems
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A01N43/52—1,3-Diazoles; Hydrogenated 1,3-diazoles condensed with carbocyclic rings, e.g. benzimidazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Dentistry (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Catching Or Destruction (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Abstract

Compuestos de la Fórmula (I), en donde X, R1, R2, R3, V y n tienen los significados mencionados precedentemente, su uso como acaricidas y/o insecticidas para controlar plagas de animales y métodos e intermediarios para su preparación.
CL2020003349A 2018-06-26 2020-12-22 Derivados heterocíclicos como plaguicidas CL2020003349A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP18179885 2018-06-26

Publications (1)

Publication Number Publication Date
CL2020003349A1 true CL2020003349A1 (es) 2021-05-07

Family

ID=62791617

Family Applications (1)

Application Number Title Priority Date Filing Date
CL2020003349A CL2020003349A1 (es) 2018-06-26 2020-12-22 Derivados heterocíclicos como plaguicidas

Country Status (15)

Country Link
US (2) US11926623B2 (es)
EP (1) EP3814346B1 (es)
JP (1) JP7353310B2 (es)
KR (1) KR102744535B1 (es)
CN (1) CN112368280B (es)
AR (1) AR115637A1 (es)
AU (1) AU2019296166B2 (es)
BR (1) BR122023022434A2 (es)
CL (1) CL2020003349A1 (es)
ES (1) ES2980209T3 (es)
IL (1) IL279631A (es)
MX (1) MX2020013767A (es)
PH (1) PH12020552265A1 (es)
TW (1) TW202017925A (es)
WO (1) WO2020002082A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20230247994A1 (en) 2020-07-02 2023-08-10 Bayer Aktiengesellschaft Heterocyclene derivatives as pest control agents
CA3189161A1 (en) 2020-08-31 2022-03-03 Syngenta Crop Protection Ag Pesticidally active heterocyclic derivatives with sulfur containing substituents
PY2175588A (es) 2020-09-02 2022-06-14 Syngenta Crop Protection Ag Derivados heterocíclicos con sustituyentes que contienen azufre activos como plaguicidas
CN120584105A (zh) 2023-01-23 2025-09-02 先正达农作物保护股份公司 具有含硫取代基的杀有害生物活性的杂环衍生物
EP4680028A1 (en) 2023-03-14 2026-01-21 Syngenta Crop Protection AG Control of pests resistant to insecticides
WO2025026738A1 (en) 2023-07-31 2025-02-06 Bayer Aktiengesellschaft 6-[5-(ethylsulfonyl)-1-methyl-1h-imidazol-4-yl]-7-methyl-3-(pentafluoroethyl)-7h-imidazo[4,5-c]pyridazine derivatives as pesticides
WO2025098874A1 (en) 2023-11-10 2025-05-15 Bayer Aktiengesellschaft Active compound combinations having fungicidal/insecticidal/acaricidal properties
WO2025098875A1 (en) 2023-11-10 2025-05-15 Bayer Aktiengesellschaft Active compound combinations having insecticidal/acaricidal properties
WO2025098876A1 (en) 2023-11-10 2025-05-15 Bayer Aktiengesellschaft Active compound combinations having insecticidal/acaricidal properties
WO2025190927A1 (en) 2024-03-14 2025-09-18 Bayer Aktiengesellschaft Active compound combinations having insecticidal/acaricidal properties

Family Cites Families (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1532118A2 (en) * 2002-07-05 2005-05-25 Axxima Pharmaceuticals Aktiengesellschaft Imidazole compounds for the treatment of hepatitis c virus infections
BRPI1015315B1 (pt) * 2009-04-28 2020-02-04 Sumitomo Chemical Co composto heterocíclico fundido, seu uso, composição e método de controlar um artrópode nocivo
JP5790440B2 (ja) 2010-12-01 2015-10-07 住友化学株式会社 ピリミジン化合物およびその有害生物防除用途
BR112013016022B1 (pt) 2010-12-24 2019-05-07 Sumitomo Chemical Company, Limited Composto heterocíclico fundido e uso do mesmo para controle de peste.
TWI545119B (zh) 2011-08-04 2016-08-11 住友化學股份有限公司 稠合雜環化合物及其在病蟲害防制上之用途
WO2013033901A1 (en) 2011-09-08 2013-03-14 Merck Sharp & Dohme Corp. Heterocyclic-substituted benzofuran derivatives and methods of use thereof for the treatment of viral diseases
RU2627654C2 (ru) 2012-04-27 2017-08-09 ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи Пестицидные композиции и относящиеся к ним способы
WO2013180193A1 (ja) * 2012-05-31 2013-12-05 住友化学株式会社 縮合複素環化合物
JP6168055B2 (ja) 2012-06-18 2017-07-26 住友化学株式会社 縮合複素環化合物
UY35421A (es) 2013-03-15 2014-10-31 Nihon Nohyaku Co Ltd Compuesto heterocíclico condensado o su sal, insecticida agrícola u hortícola que comprende el comp uesto y método de uso del insecticida
WO2014148451A1 (ja) 2013-03-19 2014-09-25 日本農薬株式会社 縮合複素環化合物又はその塩類及び該化合物を含有する農園芸用殺虫剤並びにその使用方法
JP6350528B2 (ja) 2013-07-01 2018-07-04 住友化学株式会社 縮合複素環化合物及びその有害生物防除用途
US10939682B2 (en) 2013-07-02 2021-03-09 Syngenta Participations Ag Pesticidally active bi- or tricyclic heterocycles with sulfur containing substituents
EP2873668A1 (en) 2013-11-13 2015-05-20 Syngenta Participations AG. Pesticidally active bicyclic heterocycles with sulphur containing substituents
US9706776B2 (en) 2013-12-20 2017-07-18 Syngenta Participations Ag Pesticidally active substituted 5,5-bicyclic heterocycles with sulphur containing substituents
ES2987367T3 (es) 2014-02-17 2024-11-14 Bayer Cropscience Ag Derivados de heterociclos bicíclicos condensados sustituidos con 2-(het)arilo como agentes para combatir parásitos
AR099677A1 (es) 2014-03-07 2016-08-10 Sumitomo Chemical Co Compuesto heterocíclico fusionado y su uso para el control de plagas
CN106458901B (zh) 2014-06-26 2019-01-18 住友化学株式会社 用于制备稠合杂环化合物的方法
WO2015198859A1 (ja) 2014-06-26 2015-12-30 住友化学株式会社 縮合複素環化合物
CN106661021B (zh) 2014-07-08 2019-06-14 先正达参股股份有限公司 具有含硫取代基的杀有害生物活性杂环衍生物
WO2016020286A1 (en) 2014-08-07 2016-02-11 Syngenta Participations Ag Pesticidally active heterocyclic derivatives with sulphur containing substituents
JP6689821B2 (ja) 2014-08-12 2020-04-28 シンジェンタ パーティシペーションズ アーゲー 硫黄含有置換基を有する殺有害生物的に活性な複素環式誘導体
JP6695326B2 (ja) 2014-08-21 2020-05-20 シンジェンタ パーティシペーションズ アーゲー 硫黄含有置換基を有する殺有害生物的に活性な複素環式誘導体
TW201625522A (zh) 2014-09-12 2016-07-16 Nihon Nohyaku Co Ltd 咪唑嗒化合物或其鹽類及含有該化合物之農園藝用殺蟲劑及其使用方法
WO2016039444A1 (ja) 2014-09-12 2016-03-17 日本農薬株式会社 イミダゾピリダジン化合物又はその塩類及び該化合物を含有する農園芸用殺虫剤並びにその使用方法
JP6695865B2 (ja) 2014-09-16 2020-05-20 シンジェンタ パーティシペーションズ アーゲー 硫黄含有置換基を有する有害生物防除に活性である四環式誘導体
WO2016046071A1 (en) 2014-09-25 2016-03-31 Syngenta Participations Ag Pesticidally active heterocyclic derivatives with sulphur containing substituents
WO2016058928A1 (en) 2014-10-14 2016-04-21 Syngenta Participations Ag Pesticidally active heterocyclic derivatives with sulphur containing substituents
WO2016059145A1 (en) 2014-10-16 2016-04-21 Syngenta Participations Ag Pesticidally active tetracyclic heterocyclic derivatives with sulphur containing substituents
US10645928B2 (en) 2014-11-07 2020-05-12 Syngenta Participations Ag Pesticidally active polycyclic derivatives with sulfur containing substituents
ES2806598T3 (es) 2014-12-11 2021-02-18 Syngenta Participations Ag Derivados tetracíclicos activos como plaguicidas con sustituyentes que contienen azufre
UA122781C2 (uk) 2014-12-17 2021-01-06 Сінгента Партісіпейшнс Аг Пестицидно активні гетероциклічні похідні з сірковмісними замісниками
CN107108612B (zh) 2014-12-29 2020-05-15 先正达参股股份有限公司 具有含硫取代基的杀有害生物活性四环衍生物
JP6704397B2 (ja) 2014-12-31 2020-06-03 シンジェンタ パーティシペーションズ アーゲー 硫黄含有置換基を有する殺有害生物的に活性な多環式誘導体
BR112017014894A2 (pt) 2015-01-13 2018-06-19 Syngenta Participations Ag derivados de heterocíclicos ativos do ponto de vista pesticida com substituintes contendo enxofre
BR112017015514B1 (pt) 2015-01-19 2022-08-30 Syngenta Participations Ag Derivados policíclicos ativos com substituintes contendo enxofre ativo em termos pesticidas, composição pesticida e métodos para controle de pragas e proteção de sementes do ataque por pragas
TWI696612B (zh) 2015-01-29 2020-06-21 日商日本農藥股份有限公司 具有環烷基吡啶基的稠合雜環化合物或其鹽類及含有該化合物的農園藝用殺蟲劑以及其使用方法
WO2016125622A1 (ja) 2015-02-03 2016-08-11 住友化学株式会社 ベンゾオキサゾール化合物及びその有害節足動物防除用途
WO2016125621A1 (ja) 2015-02-03 2016-08-11 住友化学株式会社 ベンゾイミダゾール化合物及びその有害節足動物防除用途
UY36547A (es) 2015-02-05 2016-06-01 Bayer Cropscience Ag Derivados heterocíclicos condensados bicíclicos sustituidos por 2-(het)arilo como pesticidas
UY36548A (es) 2015-02-05 2016-06-01 Bayer Cropscience Ag Derivados heterocíclicos condensados bicíclicos sustituidos por 2-(het)arilo como pesticidas
MX2017010420A (es) 2015-02-12 2017-11-28 Nissan Chemical Ind Ltd Compuestos heterociclicos condensados y plaguicidas.
JP6779225B2 (ja) 2015-03-12 2020-11-04 シンジェンタ パーティシペーションズ アーゲー 硫黄含有置換基を有する有害生物防除に活性な四環式誘導体
JP6774955B2 (ja) 2015-03-12 2020-10-28 シンジェンタ パーティシペーションズ アーゲー 硫黄含有置換基を有する殺有害生物的に活性な四環式誘導体
BR112017021408B1 (pt) * 2015-04-08 2022-05-17 Bayer Cropscience Aktiengesellschaft Derivados de heterociclo bicíclico condensado, método para controlar pragas animais, e formulação agroquímica
JP2018513870A (ja) * 2015-04-24 2018-05-31 シンジェンタ パーティシペーションズ アーゲー 硫黄置換5員環複素環を有する殺有害生物的に活性な多環式誘導体
EP3286186B1 (en) 2015-04-24 2020-05-06 Syngenta Participations AG Pesticidally active polycyclic derivatives with sulfur substituted five membered ring heterocyles
WO2017026384A1 (ja) * 2015-08-07 2017-02-16 日本農薬株式会社 インダゾール化合物又はその塩類及び該化合物を含有する農園芸用殺虫剤並びにその使用方法
JP6871917B2 (ja) 2015-09-28 2021-05-19 バイエル・クロップサイエンス・アクチェンゲゼルシャフト 有害生物防除剤としての2−(ヘタ)アリール−置換縮合二環式ヘテロ環誘導体
WO2017061497A1 (ja) 2015-10-06 2017-04-13 日本農薬株式会社 縮合複素環化合物又はその塩類及び該化合物を含有する農園芸用殺虫剤並びにその使用方法
JP2018024657A (ja) * 2016-08-03 2018-02-15 日産化学工業株式会社 縮合複素環化合物及び有害生物防除剤
JP2018024658A (ja) 2016-08-03 2018-02-15 日産化学工業株式会社 縮合複素環化合物及び有害生物防除剤
TWI705066B (zh) 2016-08-10 2020-09-21 日商日產化學工業股份有限公司 稠雜環化合物及有害生物防除劑
AU2018208422B2 (en) * 2017-01-10 2021-11-11 Bayer Aktiengesellschaft Heterocyclene derivatives as pest control agents
UY37556A (es) * 2017-01-10 2018-07-31 Bayer Ag Derivados heterocíclicos como pesticidas
JP2020128340A (ja) * 2017-04-27 2020-08-27 日本農薬株式会社 5員環の含窒素複素環化合物又はその塩類及び該化合物を含有する農園芸用殺虫剤並びにその使用方法

Also Published As

Publication number Publication date
KR102744535B1 (ko) 2024-12-19
ES2980209T3 (es) 2024-09-30
CN112368280B (zh) 2023-01-20
TW202017925A (zh) 2020-05-16
WO2020002082A1 (de) 2020-01-02
AU2019296166B2 (en) 2024-01-18
EP3814346B1 (de) 2024-03-20
MX2020013767A (es) 2021-03-02
IL279631A (en) 2021-03-01
US20210139480A1 (en) 2021-05-13
JP2021529745A (ja) 2021-11-04
US11926623B2 (en) 2024-03-12
PH12020552265A1 (en) 2021-06-14
BR112020025892A2 (pt) 2021-03-16
BR122023022434A2 (pt) 2024-02-20
AU2019296166A1 (en) 2021-01-14
US20240190867A1 (en) 2024-06-13
KR20210024042A (ko) 2021-03-04
JP7353310B2 (ja) 2023-09-29
EP3814346A1 (de) 2021-05-05
AR115637A1 (es) 2021-02-10
CN112368280A (zh) 2021-02-12

Similar Documents

Publication Publication Date Title
CL2019001897A1 (es) Derivados heterocíclicos como pesticidas.
AR115637A1 (es) Derivados heterocíclicos como plaguicidas
CO2019002513A2 (es) Derivados de pirazolo [1,5-a]piridina y su uso como pesticidas
CO2018001204A2 (es) Derivados heterocíclicos condensados sustituidos por 2-(het)arilo como pesticidas
CO2018003427A2 (es) Derivados heterocíclicos condensados sustituidos por 2-(het)arilo como pesticidas
CO2020004156A2 (es) Derivados heterocíclicos como pesticidas
CO2018004344A2 (es) Derivados de heterociclos bicíclicos condensados como agentes de control de plagas
CO2018007136A2 (es) Derivados de heterocicleno como agentes de control de plagas
CL2019001907A1 (es) Derivados heterocíclicos como pesticidas.
UY36609A (es) Derivados heterocíclicos bicíclicos condensados como pesticidas
CL2021002250A1 (es) Derivados de heterociclos bicíclicos fusionados como pesticidas
CO2021003095A2 (es) Derivados heterocíclicos como plaguicidas
UY37365A (es) Derivados de heterociclos bicíclicos condensados como pesticidas
CL2019000125A1 (es) Derivados de heterociclos bicíclicos condensados como pesticidas.
UY37526A (es) Imidazopiridinas mesoiónicas como insecticidas
UY37677A (es) Imidazopiridinas mesoiónicas como insecticidas
CL2020002712A1 (es) Derivados heterocíclicos como plaguicidas
UY37720A (es) Derivados heterocíclicos condensados sustituidos con 2-(het)arilo como agentes plaguicidas
CO2019011754A2 (es) Derivados de heterociclos bicíclicos fusionados como plaguicidas
CO2019003391A2 (es) Derivados heterocíclicos bicíclicos condensados sustituidos por 2-(het)arilo como pesticidas